Early Warning Solutions

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1 Early Warning Solutions for Airborne Toxic Industrial Chemicals René Braun Research and Development Remote Sensing

2 Early Warning Solutions for Airborne Toxic Industrial Chemicals REMOTE SENSING COVERING LARGE AREAS ANALYTICAL CERTAINTY FAST RESPONSE 24/7/365 PERMANENT MONITORING DAY AND NIGHT OPERATION

3 Bruker Early Warning Corporation Solutions Groups for Airborne & Divisions Toxic Industrial Chemicals Bruker BioSpin Group Bruker CALID Group Bruker NANO Group Bruker EST (BEST) Magnetic Resonance Spectroscopy (MRS) Mass Spectrometry (Daltonics) REMOTE SENSING COVERING LARGE AREAS ANALYTICAL CERTAINTY FAST RESPONSE Bruker Nano Surface Supercon wire and devices Preclinical Imaging (PCI) Infrared & Raman Spectroscopy (Optics) X-ray Analysis 24/7/365 PERMANENT MONITORING DAY AND RAPID NIGHT SITUATION OPERATION OVERVIEW Applied, Industrial and Clinical (AIC) CBRNE (Detection) CALID = Chemical, Applied Markets, Life Science, In-Vitro Diagnostics, Detection Bruker Nano Analytics BEST: Bruker Energy and Supercon Technologies

4 Bruker Optics Bruker Optics 600+ employees worldwide Headquarters Production centers Bruker Optics distribution and service offices Numerous further representatives worldwide

5 Bruker Permanent Optics Monitoring Imaging Remote Sensing COMMON SECURITY MEASURES Detector networks Propagation simulation software Local gas sensors or pipeline monitoring systems FTIR FT NIR RAMAN Gas Analysis R&D Solution Remote Sensing

6 Permanent Monitoring Imaging Remote Sensing WATCHTOWER Identification from long distances Providing situation overview Intuitive visualization of localization and propagation direction

7 SIGIS 2 Scanning Infrared Gas Imaging System Austria Belgium Czechia Danmark (2 Systems) Germany (10 Systems) Italy Portugal Brasil (7 Systems) China (3 Systems) Great Britain Irak (3 Systems) Singapore (3 Systems) South-Korea (6 Systems) 19. November 2017

8 SIGIS 2 Scanning Infrared Gas Imaging System Scanner-Head GPS Video-Camera IR-Camera Spectrometer Unit Telescope 19. November 2017

9 SIGIS 2 Scanning Infrared Gas Imaging System

10 SIGIS 2 Scanning Infrared Gas Imaging System 360

11 SIGIS 2 Scanning Infrared Gas Imaging System PASSIVE MEASUREMENT TECHNIQUE

12 SIGIS 2 Scanning Infrared Gas Imaging System

13 SIGIS 2 Scanning Infrared Gas Imaging System Ammonia Acetone Acroleine Acrylonitrile Aniline Benzene Hydrogen Cyanide AC Chlorobenzene Chloroform Ethanol Formaldehyde n-hexane Hydrazine Methane Methanol Methyl bromide Phosgene CG Phosphine Nitric acid Sulfur dioxide Carbon disulfide Hydrogen sulfide Nitrogen dioxide Styrene Tetrachloroethene NH 3 Atmospheric gases: Componsation: Target Gas Identification Water, Ozone, Methane, Carbon Dioxide, > 420 Compounds

14 24/7 YARA Rostock Distance: 5 km Event Yara Rostock: Production Evening and 7/12/2012 Storage site for ammonium nitrate outside temperature around -5 C SIGIS2 monitoring (23 F) critical infrastructure since 2014 light wind from south-east direction Strong ammonia smell reported from Warnemunde Reaction Operators quickly identified origin Accidental release of ammonia by lifting safety valve on one of the atmospheric tanks Release stopped by starting extra cooling capacity, lowering the pressure in the tanks Consequence No one injured Local media attention

15 SIGIS 2 Permanent YARA Rostock

16 Identification of Ammonia Screenshot WARNING: NH 3 IDENTIFIED

17 Real-Time Monitoring PERMANENT MONITORING GAS IDENTIFICATION SOURCE LOCALIZATION

18 Real-Time Monitoring Production Site in Urban Areas

19 Areas of Interest STORAGE PIPELINE STORAGE LOADING STATION PRODUCTION

20 Monitoring Critical Infrastructure 4/7/365 STORAGE FACILITIES VALVES PIPELINES LOADING AREAS ETC.

21 Monitoring Critical Infrastructure Automatic Programmable Sector Scan

22 Monitoring Critical Infrastructure Automatic Programmable Sector Scan

23 Rapid Monitoring SEVESO areas 24/7/365

24 Pipeline Monitoring 27 January

25 Fast Scanning Pattern 16 SCANS PER s

26 Fast Scanning Pattern 1 km 60

27 Fast Scanning Pattern 1 km SCAN-TIME: 4.5 s

28 Fast Scanning Pattern SCAN-TIME: 4.5 s FOR A STACK OF PIPELINES

29 Measurement Example Detection of Leak in Ammonia Pipeline GAS LEAK IDENTIFIED AS AMMONIA

30 3D-Leak Detection 24/7/365

31 3D-Leak Detection Control Room Interface Autonomous SIGIS2 Live-View 3D Control Room

32 Localization Automatic Data Export to Google Earth

33 Rapid Monitoring SEVESO areas 24/7/365

34 HI 90 Realtime Identification Ethylen SO 2

35 HI 90 Realtime Identification Acetone Ethanol

36 HI 90 Automatic Source Localization Acetone

37 Grand Perspective TECHNIQUE DESIGN VITAL INFORMATION FOR CONTAINMENT STRATEGY CONTRIBUTION TO HEALTH & SAFETY ENVIRONMENTAL PROTECTION PROMOTING SAFETY PROFILE

38 Bruker Scientific Israel LTD David Zaks M.Sc. FT-IR, Raman, FT-NIR, TD-NMR Sales & Applications Bruker Scientific Israel LTD 5 Golda Me'ir st., Science Park Ness Ziona, Israel Phone: Mobile: David.Zaks@bruker.com 19. November Copyright Bruker Corporation. All rights reserved

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