Overview of fire retardants solutions PIN Flame Retardants in PVC cables
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1 1 Click to edit Master title style Overview of fire retardants solutions PIN Flame Retardants in PVC cables PVC4cables Conference Lyon France 26 October 2017 Philippe Salémis, Reiner Sauerwein
2 Content Who is Pinfa PIN Flame Retardants Fire Safety and Flame retardants efficacy PIN FR s in Cables : Overview of fire retardants solutions Conclusions 2
3 Pinfa, mission, vision, raison d être the Phosphorus, Inorganic and Nitrogen Flame Retardants Association established in 2009 as a Sector Group within Cefic, the European Chemical Industry Council 29 members Pinfa members are committed to sustainable fire safety via environmentally- friendly flame retardants 3
4 4 Click to edit Master title style Pinfa members shared vision : Vision: continuously improving the environmental and health profile of their flame retardant products, offering innovative solutions for sustainable fire safety Concept of an ideal flame retardant: fit for purpose, not toxic, risk and hazard controlled does not migrate out of finished products does not contribute to release additional toxic or corrosive gases in case of fire does not impede the recycling of finished materials degradable in the environment or remains neutral as naturally occurring substances Commitment: providing safe and none hazardous products to enable high fire safety standards which minimize the risk of fire to the general public
5 Content Who is Pinfa PIN Flame Retardants Fire Safety and Flame retardants efficacy PIN FR s in Cables : Overview of fire retardants solutions Conclusions 5
6 Flame Retardants 6 Bromine Chlorine Antimony Phosphorus Inorganic compounds Nitrogen PINFA
7 Content Who is Pinfa PIN Flame Retardants Fire Safety and Flame retardants efficacy PIN FR s in Cables : Overview of fire retardants solutions Conclusions 7
8 Fire Safety and Flame retardants efficacy Several questions are asked about flame retardants: - Why Flame retardants? - What do they do for the fire safety? - Are they useful? - Are they sustainable chemicals? This short video is aimed at providing some answers. 8
9 Content Who is Pinfa PIN Flame Retardants Fire Safety and Flame retardants efficacy PIN FR s in Cables : Quick overview of fire retardants solutions Conclusions 9
10 PIN FR s in Cables : Overview of fire retardants solutions Mostly from the following starting chemicals : Aluminium Magnesium Phosphate Zinc Product selector : Showing regulatory status and possible applications
11 Click to PIN edit FR s Master in Cables title : style Metal hydrates of Al and Mg > 200 C 2 Al(OH) kj/kg > 320 C Mg(OH) kj/kg > 340 C 2 AlOOH 700 kj/kg Al 2 O H 2 O MgO + H 2 O Al 2 O 3 + H 2 O Energy consumption formation of oxide layer cooling of surface thinning of burnable gases 11
12 PIN FR s in Cables : Flammability and FR loading PVC 100 DINP 50 Ca/Zn-Stabilizer 5 PE-Wax 0.5 ATH / AOH / MDH 0-80 LOI = Limiting Oxygen Index PVC 100 DINP Ca/Zn-Stabilizer 5 PE-Wax 0.5 ATH ATH AOH 34 LOI (%O 2 ) MDH LOI (%O 2 ) FR filler in phr DINP 12
13 Click to PIN edit FR s Master in Cables title : style Smoke reduction ATO - reduced PVC 100 DINP 50 Ca/Zn-Stabilizer 5 PE-Wax 0.5 ATO + ATH 5-33 Cone Calorimetry ATO - free PVC 100 DINP 50 Ca/Zn-Stabilizer 5 PE-Wax 0.5 ATH phr ATO 30 PVC - no FR phr ATO + 30 phr ATH 25 PVC + 30 phr ATH smoke density (m²/s*m²) phr ATO + 30 phr ATH 2.4 phr ATO + 40 phr ATH smoke density (m²/s*m²) PVC + 50 phr ATH PVC + 80 phr ATH time (s) time (s) 13
14 PIN FR s in Cables : Overview of FR solutions Other Chemistries not covered in this presentation Zn- Borate ( Smoke suppression synergist) Sn derivatives On going developments. Product selector : Showing regulatory status and possible applications
15 Conclusions PIN Flame Retardants are effective solutions to combat fire PIN Fr s nicely couple with PVC and act as smoke reducer in case of fire Generally no restrictions on pin FR s Thank you for your attention Philippe Salémis, General Secretary psa@cefic.be Tel : Dr Reiner Sauerwein, Nabaltec - pinfa member More info visit:
Three fire retardant soft PVC with excellent environmental performance, ready for industrial use
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