HM-0714 SELECTIVE GRASS HERBICIDE. Active Ingredient *Clethodim.12.6% Other Ingredients 87.4% Total %

Transcription

1 SELECTIVE GRASS HERBICIDE Active Ingredient By Wt. *Clethodim..6% Other Ingredients 87.4% Total % Contains Petroleum Distillates *(E)..2..[1 -[[(3-chlo-2-propenyl)oxyjimino]propyl]-5-[2-(ethylthio)propyl]-3-hydroxy-2-cyclohexen-1 -one Contains 0.7 lbs. Clethodim per gal. KEEP OUT OF REACH OF CHILDREN CAUTION EPA Reg. No EPA Est. No. 505-IA-001 SN: 0200/0710 NET CONTENTS: 1 GAL. (3.785 L) 2.5 GAL. (.46 L) PRECAUTIONARY STATEMENTS HAZARDS TO HUMANS & DOMESTIC ANIMALS CAUTION Causes moderate eye irritation. Avoid contact with eyes, skin clothing. Wash thoughly with soap and water after handling and befe eating, drinking, chewing gum using tobacco. Prolonged frequently repeated skin contact may cause allergic reactions in some individuals. Harmful if swallowed. IF SWALLOWED: IF IN EYES: IF ON SKIN OR CLOTHING: IF INHALED: FIRST AID Call a poison control center doct immediately f treatment advice. Do not give any liquid to the person. Do not induce vomiting unless told to do so by a poison control center doct. Do not give anything by mouth to an unconscious person. Hold eye open and rinse slowly and gently with water f minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. Call a poison control center doct immediately f advice. Take off contaminated clothing. Rinse skin immediately with plenty of water f minutes. Call a poison control center doct f treatment advice. Move person to fresh air. If person is not breathing, call 11 an ambulance, and then give artificial respiration, preferably mouth-to-mouth, if possible. Call a poison control center doct f further treatment advice. HOT LINE NUMBER Have the product container label with you when calling a poison control center doct, going f treatment. You may also contact (800) , collect day night, f emergency medical treatment infmation. NOTE TO PHYSICIAN Ingestion of this product subsequent vomiting can result in aspiration of light hydrocarbon liquid, which can cause pneumonitis. If ingested, probable mucosal damage may contraindicate the use of gastric lavage. May pose an aspiration pneumonia hazard. Contains petroleum distillate. 1

2 TABLE OF CONTENTS Page PRECAUTIONARY STATEMENTS... 1 Personal Protective Equipment. 3 User Safety Recommendations. 3 Environmental Hazards. 3 Physical Chemical Hazards.. 4 Directions f Use. 4 Agricultural Use Requirements. 4 Non-Agricultural Use Requirements 4 STORAGE AND DISPOSAL... 4 GENERAL INFORMATION.. 5 Control Symptoms 5 APPLICATION INFORMATION.. 5 Timing of Applications. 5 Ground Application... 5 Air Application..5 Spot Treatment.. 5 RESTRICTIONS AND LIMITATIONS. 6 General..6 Spray Drift Management...6 Resistance Management.6-7 Table 1. CROP SPECIFIC USE DIRECTIONS, RESTRICTIONS AND LIMITATIONS FOR...7- Recommendations f Annual Grasses..-13 Recommendations f Annual & Perennial Grass Control in Established Alfalfa and Mint Directions F Reduced Rate Use To Control Small Annual Grasses, Canola, Flax, Legume Vegetables (Dry and Succulent), Soybean and Sunflower Recommendations f Perennial Grasses Recommendations f Annual Bluegrass Control.. TANK MIXES - GENERAL INFORMATION.... Tank Mix Application of and Broadleaf Herbicides f Control of Grasses and Broadleaf Weeds.. Mixing Instructions -17 Infmation on Antagonism 17 Alfalfa 17 Table 2. Tank Mixes with Broadleaf Herbicides f Alfalfa Canola 18 Table 3. Reduced Rate Tank Mixes with Broadleaf Herbicides f Canola...18 Cotton.18 Table 4: Tank Mixed with Cobra and MSMA applied Post Directed to Cotton.18 Table 5. Tank Mixed with Glyphosate to Control Emerged Grasses in Cotton as a Broadcast Application Dry and Succulent Shelled Beans.1 Table 6. Tank Mixes with Broadleaf Herbicides f Dry and Succulent Shelled Beans.1 Flax..1 Table 7. Reduced Rate Tank Mixes with Broadleaf Herbicides f Flax 1 2

3 Peanut..20 Table 8. Tank Mixes with Broadleaf Herbicides F Peanut...20 Recommendations f Grass Suppression f Harvest Efficiency in Peanut with..20 Soybean..20 Table. Tank Mix with Broadleaf Herbicides f the Control of Volunteer Cn (Including Roundup Ready) in Soybean Table 10. Tank Mixes with Broadleaf Herbicides f Soybean Insecticide Tank Mixes.24 Table 11. Tank mix application of and insecticides f control of grass weeds and insects in alfalfa, cotton, mint, peanut (including perennial), soybean and sunflower Fallow Land 25 Directions f Use..25 General Infmation...25 Table. in Tank Mixes to Control Annual and Perennial Grasses in Fallow Land Recommendations f Grass Suppression in Non-Crop Areas with 26 Table 13. f the Control and/ Suppression of Tall Fescue in Native Prairie Warm-Season Grass Restation Projects...26 Special Application Instructions/Precautions 26 Table 14. f the Suppression of Tall Fescue Seed-Heads in Non-Producing Agricultural Areas Special Application Instructions/Precautions 27 Non-Bearing Food Crops...27 Conifer Trees..28 Non-Crop Non-Planted Areas..28 Conditions of Sale Limited Warranty and Limitations and Remedies PERSONAL PROTECTIVE EQUIPMENT (PPE): Some materials that are chemical-resistant to this product are listed below. If you want me options, follow the instructions f categy G on an EPA chemical resistance categy selection chart. Applicats and other handlers must wear: long-sleeved shirt and long pants, chemical-resistant gloves such as barrier laminate viton 14 mils, shoes plus socks and protective eyewear. Discard clothing and other absbent materials that have been drenched heavily contaminated with this product s concentrate. Do not reuse them. Follow manufacturer s instructions f cleaning/maintaining PPE. If there are no such instructions f washables, use detergent and hot water. Keep and wash PPE separately from other laundry. USER SAFETY RECOMMENDATIONS Users should: Wash hands befe eating, drinking, and chewing gum, using tobacco using the toilet. Remove clothing immediately if pesticide gets inside. Then wash thoughly and put on clean clothing. Remove PPE immediately after handling this product. Wash the outside of gloves befe removing. As soon as possible, wash thoughly and change into clean clothing. ENVIRONMENTAL HAZARDS Do not apply directly to water, to areas where surface water is present to intertidal areas below the mean high water mark. Do not apply where runoff is likely to occur. Do not apply where weather conditions fav drift from areas treated. Do not contaminate water when disposing of equipment washwater rinsate. The use of this product may pose a hazard to the federally designated endangered species of Solano Grass and Wild Rice. Use of this product is prohibited in the following areas where the species are known to exist: Solano Grass: Solano County, Califnia: the vernal lakes area bounded by the Union Pacific Railroad and Hastings Road to the nth, Highway 113 to the east, Highway to the south and Travis Air Fce Base to the west. 3

4 Wild Rice: Hays County, Texas. PHYSICAL OR CHEMICAL HAZARDS: Do not use ste near heat open flame. DIRECTIONS FOR USE It is a violation of Federal law to use this product in a manner inconsistent with its labeling. READ ENTIRE LABEL AND PAMPHLET. USE STRICTLY IN ACCORDANCE WITH PRECAUTIONARY STATEMENTS AND DIRECTIONS, AND WITH APPLICABLE STATE AND FEDERAL REGULATIONS. Do not apply this product in a way that will contact wkers other persons, either directly through drift. Only protected handlers may be in the area during F any requirements specific to your State Tribe, consult the agency responsible f pesticide regulation. AGRICULTURAL USE REQUIREMENTS Use this product only in accdance with its labeling and with the Wker Protection Standard, 40 CFR part 170. This Standard contains requirements f the protection of agricultural wkers on farms, fests, nurseries, and greenhouses, and handlers of agricultural pesticides. It contains requirements f training, decontamination, notification, and emergency assistance. It also contains specific instructions and exceptions pertaining to the statements on this label about personal protective equipment (PPE), and restricted-entry interval. The requirements in this box only apply to uses of this product that are covered by the Wker Protection Standard. Do not enter allow wker entry into treated areas during the restricted-entry interval. (REI) of 24 hours. PPE required f early entry to treated areas that is permitted under the Wker Protection Standard and that involves contact with anything that has been treated, such as plants, soil water, is: coveralls over sht-sleeved shirt and sht pants, chemical-resistant gloves such as barrier laminate viton 14 mils and shoes plus socks. NON-AGRICULTURAL USE REQUIREMENTS The requirements in this box apply to uses of this product that are NOT within the scope of the Wker Protection Standard f agricultural pesticides (40 CFR Part 170). The WPS applies when this product is used to produce agricultural plants on farms, fests, nurseries greenhouses. Keep all unprotected persons out of operating areas, vicinity where there may be drift. Do not enter treated areas without protective clothing until sprays have dried. STORAGE AND DISPOSAL Do not contaminate water, food feed by stage disposal. PESTICIDE STORAGE: Ste in iginal containers only. Keep container closed when not in use. Do not ste near food feed. In case of spill on flo paved surfaces, mop and remove to chemical waste stage area until proper disposal can be made if product cannot be used accding to the label. PESTICIDE DISPOSAL: Pesticide wastes are acutely hazardous. Improper disposal of excess pesticide, spray mixture, rinsate is a violation of Federal law. If these wastes cannot be disposed of by use accding to label instructions, contact your State Pesticide Environmental Control Agency, the Hazardous Waste representative of the nearest EPA Regional Office f guidance in proper disposal methods. CONTAINER DISPOSAL: Non-refillable containers (1, 2.5, 30 & 55 gallon): Do not reuse refill this container. Offer f recycling, if available. Triple rinse pressure rinse container ( equivalent) promptly after emptying. Non-Refillable (<5 gallons): Triple rinse as follows: Empty the remaining contents into application equipment a mix tank and drain f 10 seconds after the flow begins to drip. Fill the container ¼ full with water and recap. Shake f 10 seconds. Pour rinsate into application equipment a mix tank ste rinsate f later use disposal. Drain f 10 seconds after the flow begins to drip. Repeat this procedure two me times. Offer f recycling reconditioning, puncture and dispose of in a sanitary landfill, incineration,, if allowed by State and local authities, by burning. If burned, stay out of smoke. Non-Refillable (>5 gallons): Triple rinse as follows: Empty the remaining contents into application equipment a mix tank. Fill the container ¼ full with water. Replace and tighten closures. Tip container on its side and roll it back and fth, ensuring at least one complete revolution, f 30 seconds. Stand the container on its end and tip it back and fth several times. Turn the container over onto its other end and tip it back and fth several times. Empty the rinsate into application equipment a mix tank ste rinsate f later use disposal. Repeat this procedure two me times. Offer f recycling reconditioning, puncture and dispose of in a sanitary landfill, incineration,, if allowed by State and local authities, by burning. If burned, stay out of smoke. Pressure rinse as follows: Empty the remaining contents into application equipment a mix tank and continue to drain f 10 seconds after the flow begins to drip. Hold container upside down over application equipment mix tank collect rinsate f later use 4

5 disposal. Insert pressure rinsing nozzle in the side of the container, and rinse at about 40 PSI f at least 30 seconds. Drain f 10 seconds after the flow begins to drip. Offer f recycling reconditioning, puncture and dispose of in a sanitary landfill, incineration,, if allowed by State and local authities, by burning. If burned, stay out of smoke. Refillable Container (250 gallon & bulk): Refill this container with pesticide only. Do not reuse this container f any other purpose. Cleaning the container befe final disposal is the responsibility of the person disposing of the container. Cleaning befe refilling is the responsibility of the refiller. Offer f recycling reconditioning, puncture and dispose of in a sanitary landfill, incineration,, if allowed by State and local authities, by burning. If burned, stay out of smoke. TANK MIXES NOTICE: Tank mixing use of this product with any other product which is not specifically and expressly authized by the label shall be the exclusive risk of user, applicat and/ application advis. Read and follow the entire label of each product to be used in the tank mix with this product. GENERAL INFORMATION FOR USE ON: Alfalfa, Bean (dry) and Pea (shelled) 1, Bean and Pea (succulent shelled) 2, Canola*, Clover (grown in Idaho, Oregon and Washington only), Conifers, Cotton, Fallow Land (and other non-producing agricultural areas), Flax*, Hops, Legume Vegetables (edible podded) 3, Mint, Non-Bearing Food Crops, Non-Crop Non-Planted Areas, Peanut (including perennial), Safflower, Sesame, Soybean, Sunflower. *Not f use in Califnia 1 Other Bean (dry) and Pea (shelled) crops approved f use with include: Bean (Lupinus spp.), grain lupin, sweet lupin, white lupin and white sweet lupin; Bean (Phaseo!us spp.), field, kidney, lima (dry), navy, pinto and tepary; Bean ( Vigna spp.), adzuki bean, black-eyed. pea, catjang, cowpea, crowder pea, moth bean, mung bean, rice bean, Southern pea, urd bean, broad (dry), chickpea (garbanzo), guar, lablab bean and lentil; Pea (Pisum spp.), field and pigeon. 2 Other Bean & Pea (succulent shelled) crops approve f use with include: Bean (Phaseolus spp.), broad bean (succulent), lima bean (green); Bean ( Vigna spp.), black-eyed pea, cowpea, Southern pea; Pea (Pisum spp.), English pea, garden pea, green pea and pigeon pea. 3 Other Edible Podded Legume Vegetable crops approved f use with include: Bean (Phaseouius spp.), runner, snap and wax; Bean (Vigna spp.), asparagus, chinese longbean, moth, yardlong, jackbean; Pea (Pisum spp.), dwarf, edible-pod, snow, sugar snap, pigeon and swd bean. is a selective postemergence herbicide f control of annual and perennial grasses. does not control sedges broadleaf weeds. Control Symptoms Treated grass weeds show a reduction in vig and growth. Early chlosis/necrosis of younger plant tissue is followed by a progressive collapse of the remaining foliage. Symptoms will generally be observed in 7 to 14 days after application, depending on grass species treated and environmental conditions. APPLICATION INFORMATION Timing of Applications Apply postemergence to actively growing grasses accding to rate table recommendations. Applications made to grass plants stressed by insufficient moisture, hot cold temperatures, to grass plants exceeding recommended growth stages may result in unsatisfacty control. Do not apply under these conditions. In arid regions where irrigation is used to supplement limited rainfall, should be applied, as soon as possible, after irrigation (within 7 days). In arid regions, a second application of will generally provide me effective control of perennial grass weeds than a single Make second application to actively growing grass 2 to 3 weeks after emergence of new growth. Cultivation of treated grasses 7 days pri to within 7 days after application of may reduce weed control. Ground Application Use of sufficient spray volumes and pressure is essential to ensure complete coverage. Use a. minimum of 5 gals. and a maximum of 40 gals of spray solution per acre. Under the following conditions a minimum of 10 gals. per acre is required: ultra narrow row cotton, narrow row soybeans, broadleaf herbicide tank mixes, perennial grasses, volunteer cn, drought stress conditions, heavy grass pressure when grasses are at near maximum height. Failure to use a minimum of 10 gals per acre under these conditions can result in po coverage and reduced grass control requiring repeat applications. Spray pressures should reflect a minimum of 30 psi 5

6 and a maximum of 60 psi at the nozzle. Do not use flood nozzles. Air Application Use a minimum of 3 gals of spray solution per acre unless otherwise directed in this label. Increase spray volumes up to 10 gals as grass crop foliage becomes dense. Spot Treatment When using hand sprayers high volume sprayers utilizing hand guns, mix 1/3 to 2/3% (0.44 oz. to 0.85 oz. per gal.) and treat to wet vegetation, while not allowing runoff of spray solution. F uses requiring crop oil concentrate; include crop oil concentrate at 1% (1.3 oz. per gal.) by volume. F uses requiring nonionic surfactant, include non-ionic surfactant at 1/4% (0.33 oz. per gal.) by volume. NOTE: If is applied as a spot treatment care should be taken to not exceed the maximum rate allowed on a per acre basis crop injury may occur. RESTRICTIONS AND LIMITATIONS GENERAL Do not apply if rain is expected within 1 hour of application, as control may be unsatisfacty. Do not plant rotational crops until 30 days after application of unless crop is listed on label. Do not apply a postemergence broadleaf herbicide within one day following application of reduced grass control may result. Do not apply under conditions of stress. Applying under conditions that do not promote active grass growth will reduce herbicide effectiveness. These conditions include drought, excessive water, extremes in temperature, low humidity and grasses either partially controlled stunted from pri pesticide applications. Grasses under these kinds of stressful conditions will not absb and translocate effectively, and will be less susceptible to herbicide activity. Application on Long Island, New Yk, is restricted to no me than fl oz of (0.25 lb a.i) per acre per season. Optimal perennial grass control can be obtained if rhizomes stolons are cut up by preplant tillage practices (disking, plowing, etc.) to stimulate maximum emergence of grass shoots. Cultural practices, such as continuous no-tillage in which the perennial grass rhizomes stolons are not cut up, results in a very staggered, non-unifm weed emergence. Due to this non-unifm weed emergence, no fewer than two applications per season per year are recommended at the appropriate weed-growth stage rate under continuous no-till conditions. Grass crops such as cn, rice, small grains, sghum turf, etc. are highly sensitive to. Always read and follow the restrictions and limitations f all products whether used alone in a tank mix. The most restrictive labeling of any product used applies in tank mixtures, including all crop rotation and other crop restrictions. Tank mixes of and broadleaf herbicides may result in reduced grass control. If grass regrowth occurs, an additional application of may be necessary. SPRAY DRIFT MANAGEMENT Do not allow spray from ground aerial equipment to drift onto adjacent land crops. When drift may be a problem, do everything possible to reduce spray drift, including: Do not apply when conditions are favable f drift (high temperatures, drought and low relative humidity), especially when sensitive plants are located nearby. Do not spray if wind speed is 10 mph greater. If sensitive crops plants are downwind, extreme caution must be used under all conditions. Do not spray if winds are gusty. Do not apply when a temperature inversion exists. If inversion conditions are suspected, consult with local weather services befe making an Do not allow to come in contact with desirable grass crops such as cn, rice, small grains, sghum, turf, as these and other grass crops will be injured killed. Further reductions in drift can be obtained by: 1. Using large droplet size sprays. Do not use nozzles that produce small droplets. Orient nozzles downward and slightly backward as needed to reduce drift f ground applications. 2. Orienting nozzles straight back with the windstream, using straight stream ifices f aerial applications. Use the lowest number of nozzles practical with the largest possible ifice size to obtain the minimum 3 GPA volume. Application height and boom length should be set accding to manufacturer s instructions to minimize drift. 6

7 3. Increasing the volume of spray mixture (f example a minimum of 10 GPA f ground applications) by using higher flow rate nozzles. Using lower pressure with the appropriate nozzle to obtain higher volumes will also reduce drift. 4. Applying as close to target plants as practical while maintaining a good spray pattern f adequate coverage. Do not apply under conditions involving possible drift to food, fage other plantings that might be damaged the crops thereof rendered unfit f sale, use consumption. RESISTANCE MANAGEMENT is a Group 1 herbicide. Any weed population may contain develop plants naturally resistant to and other Group 1 herbicides. Weed species with acquired resistance to Group 1 may eventually dominate the weed population if Group 1 herbicides are used repeatedly in the same field in successive years as the primary method of control f targeted species. This may result in partial total loss of control of those species by other Group 1 herbicides. Repeated use of ( similar postemergence grass herbicide with the same mode of action) may lead to the selection of naturally occurring biotypes that are resistant to these products in some grass species. If po perfmance occurs and cannot be attributed to adverse weather application conditions, a resistant biotype may be present. This is most likely to occur in fields where other control strategies such as crop rotation, mechanical removal and other classes of herbicides are not used from year to year. To delay herbicide resistance consider: Avoiding the consecutive use of other target site of action Group I herbicides that have similar target site of action, on the same weed species. Using tank mixtures premixes with herbicides from different target site of action groups as long as the involved products are all registered f the same use, have different sites of action, and are both effective at the tank mix prepack rate on the weed(s) of concern. Basing herbicide use on a comprehensive 1PM program. Moniting treated weed populations f loss of field efficacy. Contacting your local extension specialist, certified crop adviss, and/ manufacturer f herbicide resistance management and/ integrated weed management recommendations f specific crops and resistant weed biotypes. Table 1. CROP SPECIFIC USE DIRECTIONS, RESTRICTIONS AND LIMITATIONS FOR Crop (1) Minimum Time From Application to Harvest (PHI) Annual Grass Use Rate Per Acre (2) Perennial Grass Use Rate Per Acre (2) Adjuvant Recommendation (3) Ammonium Sulfate Recommendation (4) Special Use Instructions And Restrictions Alfalfa, Seedling 15 days befe grazing, feeding harvesting (cutting) f fage hay to fl oz to fl oz COC/MSO at 11I qt/a Or 1% See tank mix label f specific adjuvant recommendations, 2.5 to 4 Do not apply me than fl oz/a per Do not apply me than 64 fl oz/a (0.5 lb a.i/a) per season. F repeat applications make on a minimum of Alfalfa, Established including: Sainfoin, Holy clover, Birdsfoot trefoil 15 days befe grazing, feeding harvesting (cutting) f fage hay to fl oz to fl oz COC/MSO at 1 qt/a 1% See tank mix label f specific adjuvant recommendations. v 2.5 to 4 Do not apply me than fl oz/a per Do not apply me than 64 fl oz/a (0.5 lb a.i/a) per season. F repeat applications make on a minimum of 7

8 Bean, Dry including: Bean (Lupinus spp.) Grain Sweet White White Sweet Bean (Phaseolus spp.) Field Kidney Lima (dry) Navy Pinto Tepary Bean (Vigna spp.) Adzuki Bean Black-eyed Pea Catjang Cowpea Crowder Pea Moth Bean Mung Bean Rice Bean Southern Pea Urd Bean Broad (dry) Chickpea (garbanzo) Guar Lablab Bean Lentil Bean, Succulent Shelled including: Bean (Phaseolus spp.) Broad Bean (succulent) Lima Bean (green) Bean (Vigna spp.) Black-eyed Pea Cowpea Southern Pea Canola (Not f use in Califnia) 30 days to fl oz (5) to fl oz 21 days to fl oz (5) to fl oz 70 days to fl oz (5) ft. oz. Use a CPDA Certified adjuvant None None None Do not apply me than fl oz/a per F repeat applications make on a minimum of Do not apply me than 64 fl. oz/a (0.5 lb al/a) per season. Do not apply me than one (1) application per acre per season. Do not apply after crop has begun bolting. Crop injury may occur when is applied during the bloom period. 8 Do not apply me than fl oz/a in a single

9 Clover 15 days befe grazing, feeding harvesting (cutting) f fage hay to fl oz to fl oz Use a CPDA Certified adjuvant Do not apply me than fl oz/a per season. 2.5 to 4 F use on clover grown in the states of Idaho, Oregon and Washington only. Do not me than fl oz in a season. Cotton 60 days to fl oz to fl oz COC/MSO at 1 qt/a 1% See tank mix label f specific adjuvant recommendations F repeat applications make on a minimum of 2.5 to 4 Do not graze treated fields feed treated fage hay to livestock. Do not apply me than fl oz/a in a single Do not apply me than 64 fl oz/a (0.5 lb a.i/a) per season. Fallow Land Conifer Trees (and other nonproducing agricultural areas) Non-Crop Non-Planted Areas N/A to fl oz. to fl oz COC/MSO at 1 qt./a 1% F repeat applications make on a minimum of 2.5 to 4 Do not plant any crop f 30 days after application unless Clethodim is registered f use in that crop. Do not apply me than fl oz/a per Do not apply me than 64 fl. oz/a (0.5 lb. a.i/a) per season. Flax (Not f use in Califnia) 60 days to fl. oz. (5) to fl oz. None F repeat applications make on a minimum of Apply pri to bloom. Crop injury may occur when is applied during the bloom period. Do not apply me than fl oz./a per Do not apply me than fl. oz. in a season. F repeat applications

10 Hops 21 days to fl oz. to fl oz. None make on a minimum of Do not apply me than fl. oz/a in a single Legume Vegetables, Edible Podded including: Bean (Phaseolus spp.) Runner Snap Wax Bean ( Vigna spp.) Asparagus Chinese Longbean Moth Yardlong Jackbean Pea (Pisum spp.) Dwarf Edible-pod Snow Sugar Snap Pigeon Swd Bean 21 days to fl oz (5) Mint 21 days to fl. oz. to fl oz. to fl. oz. N1S at COC/MSO at 1 qt./a 1% None F repeat application make on a minimum of Do not apply me than 64 fl. oz/a (0.5 lb. a.i/a) per season. Do not apply me than fl oz/a in a single Do not apply me than one (1) application per acre per season. F peas apply befe bloom, but no later than 21 days befe harvest. 2.5 to 4 Do not apply me than fl. oz./a in a single Do not apply me than 64 fl. oz./a (0.5 lb. al/a) per season. Non-Bearing Food Crops (7) N/A to fl. oz. to fl. oz. None F repeat applications make on a minimum of Do not apply me than 64 fl. oz./a (0.5 lb. al/a) per season. N/A to fl. oz. to fl. oz. F repeat applications make on a minimum of Sugar maples cannot be tapped f syrup within one year of 10 Do not apply me than

11 Pea, Shelled (Pisum spp.) Field Pigeon 30 days to fl oz (5) to fl oz. None fl oz./a in a single application to nonbearing food crops. Do not apply me than fl. oz./a per Do not apply me than one (1) application per acre per season. Pea, Succulent Shelled (P/sum spp.) English Pea Garden Pea Green Pea Pigeon Pea 21 days to fl oz (5) to fl oz None Apply befe bloom but not. later than 30 days pri to harvest. () Do not apply me than fl oz./a per Do not apply me than one (1) application per acre per season. Peanut (including perennial) 40days to fl oz to fl oz COC/MSO at 1 qt/a 1% Apply befe bloom but not later than 21 days pri to harvest. () 2.5 to 4 Do not apply me than V fl oz/a in a single Do not apply me than 64 fl oz/a (0.5 lb al/a) per season, except in Flida where the limit is 64 fl oz/a per year (perennial peanuts only). Safflower 70 days to fl. oz. - fl. oz. None F repeat applications make on a minimum of Do not apply me than fl oz/a in a single F repeat applications make on a minimum of Sesame 14 days to fl oz l2to fl oz None Do not apply me than 64 fl oz/a (0.5 lb al/a) per season. Do not apply during flowering. Do not apply me than fl oz/a in a single F repeat applications 11

12 make on a minimum of Soybean 60 days to fl oz (5) to fl oz COC/MSO at 1 qt/a 1% Do not apply me than 64 fl oz/a (0.5 lb al/a) per season. 2.5 to 4 Do not apply me than fl oz/a per See tank mix label f specific adjuvant recommendations. Do not apply me than 64 fl oz/a (0.5 lb a.i/a) per season. F repeat applications make on a minimum of Sunflower 70 days to fl oz (5) to fl oz COC/MSO at 1 qt/a 1% Do not graze treated fields feed treated fage hay to livestock. 2.5 to 4 Do not apply me than fl. oz./a per See tank mix label f specific adjuvant recommendations. Do not apply me than 64 fl oz/a (0.5 lb a.i/a) per season. F repeat applications make on a minimum of N/A = Not Applicable 1. See annual and perennial grass control tables f specific use rate recommendations. 2. Non-ionic surfactant (NIS) in this case refers to an adjuvant containing at least 80% non-ionic surfactant. Crop oil concentrate in this case refers to both crop oil concentrate and crop oil concentrate blends. Acceptable crop oil concentrates would be those that contain a minimum of 80% oils and 15% emulsifier. Acceptable crop oil concentrate blends would be those that contain a minimum of 60% oils and 25-40% surfactants and emulsifiers. A crop oil concentrate must contain either a petroleum vegetable oil base and must meet all the following criteria: be non-phytotoxic, contain only EPA-exempt ingredients, provide good mixing quality and be successful in local experience. Highly refined vegetable oils have proven me satisfacty than unrefined vegetable oils. Use a CPDA Certified Adjuvant when possible. 3. If Ammonium Sulfate is going to be used it must be spray grade ammonium sulfate. The use of ammonium sulfate Ammonium Sulfate Replacement products does not take the place of the required adjuvant. 4. See DIRECTIONS FOR REDUCED RATE USE TO CONTROL SMALL ANNUAL GRASSES table. 5. If is applied as a spot treatment to non-bearing food crops care should be taken to not exceed the maximum rate allowed on a per acre basis crop injury may occur. 6. In Califnia, 14 days spray intervals are recommended between the application of and liquid nitrogen and other herbicide applications. Injury to crop may occur when shter intervals are observed. 7. Applications of to peas during the bloom period could result in severe crop injury, including loss of yield and delayed maturity. 8. See TANK MIX WITH BROADLEAF HERBICIDES FOR THE CONTROL OF VOLUNTEER CORN (INCLUDING ROUNDUP READY ) IN SOYBEAN. RECOMMENDATIONS FOR ANNUAL GRASSES ALL CROPS Apply only to actively growing grasses at recommended weed heights. Apply when the first grass weed species in a mixed grass weed population reaches the recommended growth stage f treatment. Use the high rate under heavy grass pressure and/ when grasses are at maximum height. Do not exceed the maximum per application rate listed in Table 1, CROP SPECIFIC USE DIRECTIONS, RESTRICTIONS AND LIMITATIONS FOR

13 GRASS SPECIES SCIENTIFIC NAME WEED HEIGHT (inches) Barnyardgrass Broadleaf Signalgrass Brome Califnia Cheat Downy Ripgut Canarygrass Crabgrass Hairy Large Smooth Southern Crowfootgrass Fall Panicum Field Sandbur Foxtail Giant Green Yellow Goosegrass Itchgrass Junglerice Lovegrass (Stinkgrass) Rabbitsfootgrass Red Rice Rygrass Hardy Italian Seedling Johnsongrass Shattercane Southwestern Cupgrass Sprangletop Amazon Bearded Mexican Red Texas Panicum Volunteer Cereals (3) Barley Oats Rye Wheat (2) Volunteer Cn (2,3) Volunteer Cn (3) Volunteer Cn (2,3) Volunteer Grain Sghum Wild Oats Wild Proso Millet Witchgrass Wooly Cupgrass Echinochloa crus-galli Brachiaria platyphylla Bromus carinatus Bromus secalinus Bromus tectum Bromus diandrus Phalaris canariensis Digitaria adscendens Digitaria sanguinalis Digitaria ischaemum Digitaria ciliaris Dactyloctenium aegyptium Panicum dichotomifl Cenchrus incertus Setaria faberi Setaria viridis Setaria glauca Eleusine indica Rottboellia cochinchinensis Echinochloa colona Eragrostis cilianensis Polypogon monspeliensis Oryza sativa Lolium remotum Lolium multiflum Sghum halepense Sghum bicol Eriochloa gracilis Leptochloa panicoides Leptochloa fascicularis Leptochloa uninervia Leptochloa filifmis Panicum texanum Hdeum vulgare Avena sativa Secale cereale Triticum aestivum Zea mays Zea mays Zea mays Sghum bicol Avena fatua Panicum miliaceum Panicum capillare Erichhloa villosa 13 2 to 8 1 to 4 ** ** ** ** ** 2 to 8 2 to 2 to 8 2 to 8 ** 1 to 4 1 to 3 4 to 10 6 to 18 Up to Up to 24 Up to 36 8 to 2 to 10 2 to 8 2 to 8 APPLICATION RATES MINIMUM RATE Maximum rate (1) fl. oz./a Fl. oz./a *Generally occurs between 3-leaf stage and tillering. **Length of lateral growth. 1. Rates higher than fl. oz./a may be applied in certain geographic areas, cropping situations environmental conditions, where experience has shown that higher rates are needed f satisfacty control of annual grasses. In these situations, rates from to fi. oz./a may be applied. Do not apply me than fi. oz./a of per application to canola. 2. When a cereal grain crop (such as wheat) is interseeded f crop establishment is planted as wind breaks to aid crop establishment, the minimum use rate f control is fl. oz./a. 3. Includes Roundup Read, Liberty Link and IMI-CORN volunteer cn; however not Sethoxydim-Resistant volunteer cn. 6 14

14 RECOMMENDATIONS FOR ANNUAL & PERENNIAL GRASS CONTROL IN ESTABLISHED ALFALFA AND MINT WITH GRASS SPECIES WEED SPECIES APPLICATION RATES AND SIZE Annual & Perennial Grasses Listed in Grass Tables See Tables See Table 1, CROP SPECIFIC USE DIRECTIONS, RESTRICTIONS AND LIMITATIONS FOR Mowing: The best control of annual grasses can be achieved by applying befe grass weeds are mowed. Once a grass is mowed it becomes tougher to control, as much of the available leaf surface has been removed. In areas without a killing frost, some annuals can over-winter after having been mowed multiple times. These grasses fm large crowns and may contain many viable buds. These grasses, even though they may be an annual grass, may require repeated applications of f partial complete control. Irrigated Alfalfa and Mint: Irrigation practices can be very critical to the successful use of in established alfalfa and mint and may be necessary to initiate active growth of the weeds pri to Generally applications 2 to 4 days after irrigation are most effective. Irrigation made shtly after application (2 days) can be effective, but me consistent grass control occurs when the irrigation is made befe the Aerial Application: Apply in a minimum of 10 GPA in established alfalfa and mint when applying by air. Annual Grass Control: Apply at the grass sizes indicated in the Recommendation f Annual Grass Table and rates indicated. If a grass has been cut, apply after active growth has resumed and regrowth has reached the minimum height and befe it reaches the maximum height indicated. Apply befe the alfalfa/mint canopy covers the grasses and interferes with the spray coverage. Some annual grasses are spring- and summer- germinating plants, while others are fall-germinating plants, and the time they are actively growing and most susceptible to may vary from region to region. Also some annuals germinate over an extended period of time, and because control of small grasses is desired, applications after each weed flush may be required. As a general rule spray spring and summer germinating grasses as early in the season as possible, after initial green-up. Spray fall - germinating weeds in the fall soon after they begin growing but befe any damage is done due to frost. Late fall applications may be less effective due to environmental conditions, such as frost, slower plant growth the onset of flowering. Perennial Grass Control: effectively controls perennial grasses such as bermudagrass, Johnsongrass, quackgrass, wirestem muhly, tall fescue, foxtail barley and chardgrass. Due in part to lack of tillage, perennial grasses are me difficult to control in a perennial crop such as established alfalfa mint. A program of repeated applications is usually necessary f best results. The best way to control perennial grasses is to do so in the year of stand establishment befe rhizomes and stolons become large and difficult to kill. Use the high rate under heavy grass pressure and/ when grasses are at near maximum height. DIRECTIONS FOR REDUCED RATE USE TO CONTROL SMALL ANNUAL GRASSES CANOLA, FLAX, LEGUME VEGETABLES (DRY AND SUCCULENT), SOYBEAN AND SUNFLOWER (REDUCED RATE RECOMMENDATIONS NOT FOR USE IN CALIFORNIA) Apply only to actively growing grasses at recommended weed heights. Apply when the first grass weed species in a mixed grass weed population reaches the recommended growth stage f treatment. Regrowth by tillering may occur if application is made when plants are stressed by lack of moisture, excessive moisture, low high temperatures and/ under very low humidity. GRASS SPECIES SCIENTIFIC NAME WEED HEIGHT (inches) RATE FL. OZ/ACRE (1) Barnyardgrass Broadleaf Signalgrass Crabgrass Large Echinochloa crus-gaili Brachiaria piatyphylla Digifaria san guinalis 1 to 4 1 to 4 1 to 3*

15 Large Smooth Smooth Southern Fall Panicum Foxtail Giant Green Millet Yellow Seedling Johnsongrass Shattercane Texas Panicum Volunteer Cereals Barley Oats Wheat Volunteer Cn** Wild Proso Millet Wild Oats Digitaria sanguinalis Digitaria ischaemum Digitana ischaemum Digitaria char Panicum dichotomiflum Setarie faberi Setaria viridis Setaria italica Setaria glauca Sghum halepense Sghum bicol Panicum texanum Hdeum vulgare Avena sativa Triticum asetivum Zea mays Panicum miliaceum Avena fatua 1 to 4* 1 to 3* 1 to 4* 1 to 4* 1 to 4 1 to 4 1 to 4 1 to 4 1 to 4 1 to 6 4 to 10 1 to 4 1 to 4 1 to 4 1 to 4 4 to 1 to 6 1 to 4 *Length of lateral growth. **Not S.R. Cn (1) Always add a non-ionic surfactant at total spray volume unless crop specific restrictions and limitations advise otherwise. RECOMMENDATIONS FOR PERENNIAL GRASSES (ALL CROPS) Apply only to actively growing grasses at recommended weed heights. Apply when the first grass weed species in a mixed grass weed population reaches the recommended growth stage f treatment. Use the high rate under heavy grass pressure and/ when grasses are at maximum height. Do not exceed the maximum per application rate listed in Table 1, CROP SPECIFIC USE DIRECTIONS, RESTRICTIONS AND LIMITATIONS FOR. GRASS SPECIES WEED HEIGHT (inches) APPLICATION RATE MINIMUM RATE fl. oz./a MAXIMUM RATE fl. oz./a 15

16 Bermudagrass (Cynodon dactylon) First Application Repeat Application(s) (if regrowth occurs) 3 ( up to 6 runners) 3 ( up to 6 runners) Fescue, TaIl (Festuca arundinacea) First Application Repeat Application(s) (if regrowth occurs) 4 to 8 4 to 8 Foxtail Barley (Hdeum jubatum) First Application Repeat Application (if regrowth occurs) Orchardgrass (Dactylis glomerata) First Application Repeat Application(s) (if regrowth occurs) 4 to 8 4 to 8 Quackgrass (Elytrigia repens) First Application Repeat Application(s) (if regrowth occurs) 4 to 4 to Rhizome Johnsongrass (Sghum halepense) First Application Repeat Application(s) (if regrowth occurs) to 24 6 to Wirestem Muhly (Muhlenbergia frondosa) First Application Repeat Applicatioh(s) (if regrowth occurs) 4 to 8 4 to 8 24 Perennial Bluegrass [Roughstalk (Poatrivialis)] [Kentucky (Poa prantensis)] First Application Repeat Application(s) 2 to 4 2 to 4 Bentgrass (Agrostis spp.) First Application Repeat Application(s) (if regrowth occurs) 2 to 4 2 to 4 - RECOMMENDATIONS FOR ANNUAL BLUEGRASS CONTROL WITH ALL CROPS APPLICATION RATES GRASS SPECIES WEED STAGE MINIMUM MAXIMUM RATE RATE fl. oz./a fl. oz./a Annual Bluegrass (Poa annua) to 4-leaf * ** Apply under favable soil moisture and humidity, which exists within a few days after rainfall within 7 days after irrigation. Grass needs to be actively growing at time of application(s). Apply at weed stage indicated on the label, as reduced control can be expected with me mature annual bluegrass. Use the high rate under heavy grass pressure and/ when annual bluegrass is me mature. See Table 1 f crop specific adjuvant recommendations. *Use a minimum of 17 fl. oz./a to control annual bluegrass in seedling and established alfalfa and mint. **See Special Use Instructions and Restrictions in Table 1, CROP SPECIFIC USE DIRECTIONS, RESTRICTIONS AND LIMITATIONS FOR, f maximum application rates. TANK MIXES GENERAL INFORMATION

17 The labels f each of the herbicides recommended f tank mixing with are unique to the characteristics of those products and contain restrictions and limitations that may be me restrictive than the label in certain considerations. Those concerns may include, but are not limited to: 1. Geographic restrictions - all products are not registered f use in all areas and rates may vary from one region of labeled use to another; 2. Crop rotation restrictions; 3. Applicat certification requirements; 4. Wker safety rules (e.g. protective clothing, reentry time, posting); 5. Soil type soil characteristics (e.g. ph, OM); 6. Maximum dosage number of applications per season; 7. Rain free period required; 8. Application timing (e.g. pre-harvest interval). Do not exceed the total season rates. THE MOST RESTRICTIVE LABELING OF ANY PRODUCT USED IN A TANK MIX MUST BE FOLLOWED. TANK MIX APPLICATION OF AND BROADLEAF HERBICIDES FOR CONTROL OF GRASSES AND BROADLEAF WEEDS Apply only to actively growing grass and broadleaf weeds at recommended height growth stage listed on each label. Apply when the first grass broadleaf weed species in a mixed population reaches the recommended height growth stage f treatment. Apply under favable soil moisture and humidity that exist a few days after rainfall within seven days after irrigation. Always add the appropriate adjuvant to the spray mix at the rate recommended f each specific tank mix combination. Tank mix applications may sometimes result in reduced grass control and possible increases in crop injury as compared to either product used alone. If regrowth occurs, an additional flush of new grass emerges, make a second application of HM- 0714, as specified in the respective size and rate tables. Do not tank mix when broadleaf weeds are tall and/ dense enough to prevent proper grass coverage. MIXING INSTRUCTIONS 1. Fill clean spray tank 1/2 to 2/3 of desired level with clean water. 2. While agitating, add the crect amount of. Agitation should create a rippling rolling action on the water surface. 3. If tank mixing with Other labeled herbicides, add water soluble bags first, followed by dry fmulations, flowables, emulsifiable concentrates and then solutions. Prepare no me spray mixture than is required f the immediate spray operation. 4. Add any required adjuvants (crop oil concentrate, non-ionic surfactant and/ nitrogen solution). 5. Fill spray tank to desired level with water. Agitation should continue until all spray solution has been applied. Failure to agitate the spray solution may result in improper mixing of the herbicides and unsatisfacty weed control. Mixing and compatibility qualities should be verified by a jar test. INFORMATION ON ANTAGONISM Tank mixes of with postemergence broadleaf herbicides have shown some reduction failure to control certain grass species which would have otherwise been controlled when is applied alone. Activity of the postemergence broadleaf herbicide in the tank mix is not affected. ALFALFA Table 2. I EC TANK MIXES WITH BROADLEAF HERBICIDES FOR ALFALFA (Refer to the recommendation tables above f specific grassed and growth stages.) PRODUCT (1) APPLICATION RATES/ACRE (2) SPRAY ADDITIVES ANNUAL PERENNIAL GROUND APPLICATION AIR APPLICATION GRASSES GRASSES Adjuvant AMS Adjuvant AMS Recommendation Recommendation to to 17 17

18 2,4-DB (3) PURSUIT DG (4) PURSUIT (4) BUCTRIL 2L (5) BUCTRIL GEL (5,6) RAPTOR fl. oz. Refer to 2,4- DB label to fl. oz to 2. oz. 3 to 6 fl. oz. to fl. oz. 1.0 to 1.5 pts. 0.5 to 0.75 pt. to fl. oz. 4 to 6 fl. oz. fl. oz. Refer to 2,4-DB label lbs/100 gals of spray solution. 17 lbs/100 gals. of spray solution 17 lbs/100 gals. of spray solution 17 lbs/100 gals. of spray solution 1. Broadleaf weed control maybe reduced when grass populations are tall dense enough to intercept the spray pattern and prevent them from receiving complete coverage. Tank mixing is not recommended in these situations. 2. If grass regrowth occurs an additional flush of new grass emerges, make a second application of alone (without a tank mix herbicide), accding to the appropriate size and rate recommendations. 3. plus 2,4-DB may increase the severity of crop injury when tank mixed. Alfalfa plants will generally outgrow this tempary crop injury within a few weeks. 4. Befe using this tank mix, read and understand the PURSUIT PURSUIT DG labels f geographical restrictions and restrictions regarding alfalfa growth stage and type. Failure to do so can result in crop injury to alfalfa. Do not feed, graze harvest alfalfa f 30 days following an application of PURSUIT to alfalfa. 5. In the states of Washington, Oregon, Idaho, Montana, Wyoming, Colado, Utah, Nevada and the western halves of Nth Dakota, South Dakota, Nebraska and Kansas: The plus BUCTRIL BUCTRIL GEL tank mix must be applied in the fall spring to seedling alfalfa when the majity of the field has a minimum of 2 trifoliates. Unacceptable crop injury may occur to alfalfa seedlings less than the 2 trifoliate leaf stage. plus BUCTRIL BUCTRIL GEL applications made when temperatures are expected to exceed 80 F at and 3 days following application can result in unacceptable crop injury. In the states not listed above, apply in the fall spring to seedling alfalfa when the majity of the field has a minimum of 4 trifoliate leaves. When alfalfa stand is uneven and conditions fav leafburn, unacceptable crop injury may occur to alfalfa in the 2 trifoliate smaller stage of growth. plus BUCTRIL BUCTRIL GEL applications made when temperatures are expected to exceed 70 F at and 3 days following application can result in unacceptable crop injury. Crop leaf bum can occur following plus BUCTRIL BUCTRIL GEL Warm, humid conditions may enhance leaf bum. New crop growth will not be affected. 6. Do not apply when alfalfa is under moisture, temperature, insect disease stress has been stressed by other pesticide carryover 7. Always use a CPDA Certified Adjuvant when possible. CANOLA Table 3. REDUCED RATE TANK MIXES WITH BROADLEAF HERBICIDES FOR CANOLA (Refer to the recommendation tables above f specific grasses and growth stages.) PRODUCT APPLICATION RATES/ACRE ADJUANT RECOMMENDATIONS AMMONIUM SULFATE ANNUAL GROUND AIR (2) LIBERTY (3) GRASSES (1) 8 to 10 fl. 28 to 34 fl. oz. 8to 10 fl. oz pts./a STINGER (4) 1. Annual grasses and sizes controlled with these tank mixtures are those that are identified in the DIRECTIONS FOR REDUCED RATE USE TO CONTROL SMALL ANNUAL GRASSES table.

19 2. Do not apply tank mix during after bolting flowering crop injury will occur. 3. F use only on LIBERTY LINK Canola. 4. See STINGER label f weeds controlled. 5. Always use a CPDA Certified Adjuvant when possible. COTTON Table 4. TANK MIXED WITH COBRA AND MSMA APPLIED POST DIRECTED TO COTTON PRODUCT (1) APPLICATION RATES/ACRE(2) CROP OIL CONCENTRATE (3) COMMENTS ANNUAL GRASSES PERENNIAL GRASSES GROUND to fl. oz. to fl. oz. 1% See COBRA label f rates to control broadleaf weeds and height limitations f cotton. Refer to the label f weed height and species controlled. COBRA MSMA (4 lbs./gal.) OR MSMA (6.6 Ibs./gal.) See MSMA label f rates to control broadleaf weeds and height limitations f cotton. Refer to the label f weed height and species controlled. 1 Reduce broadcast rate in proption to the band area actually treated. 1. Broadleaf weed control may be reduced when grass populations are tall dense enough to intercept the spray pattern and prevent them from receiving complete coverage. Tank mixing is not recommended in these situations. 2. If grass regrowth occurs an additional flush of new grass emerges, make a second application of alone (without a tank mix herbicide), accding to the appropriate size and rate recommendations. 3. Always use a crop oil concentrate at the listed rate I pt/a) in the finished spray volume. 4. If at the time of application, grass height is so tall that post-directed applications cannot get good coverage over the top of the grassy weeds, then po control may result and a second (non-post directed) application of may be necessary. 5. Always use a CPDA Certified Adjuvant when possible. Table 5. TANK MIXED WITH GLYPHOSATE TO CONTROL EMERGED GRASSES IN COTTON AS A BROADCAST APPLICATION PRODUCT APPLICATION RATE/ACRE (1) ADJUVANT COMMENTS ANNUAL GRASSES PERENNIAL GRASSES Glyphosate fmulation with Glyphosate fmulation without GLYPHOSATE to fl. oz. to fl. oz. See glyphosate label f rates to control broadleaf weeds and height limitations f cotton. built in adjuvant. Ammonium sulfate at 8.5 to17 lbs. per 100 gals. of carrier plus glyphosate label adjuvant recommendation. built in adjuvant. Ammonium sulfate at 8.5 to 17 lbs. per 100 gals. Of carrier plus. See charts f grasses controlled. Use a minimum of 10 gals. Of spray solution per acre. 1. If grass regrowth occurs an additional flush of new grass emerges, make a second application of at the recommended rate with the appropriate amount of crop oil. 2. Always use a CPDA Certified Adjuvant when possible. DRY AND SUCCELENT SHELLED BEANS Table 6. TANK MIXES WITH BROADLEAF HERBICIDES FOR DRY AND SUCCULENT SHELLED BEANS (Refer to the recommendation tables above f specific grasses and growth stages.) PRODUCT (1) APPLICATION RATES/ACRE (2) ADJUVANT ANNUAL GRASSES PERENNIAL GROUND AIR BASAGRAN (3) RAPTOR (3) to fl. oz. 1 to 2 pts. to fl. oz. 4 fl. oz. GRASSES to 24 fl. oz. 1 to 2 pts. - AMS at 17 lbs./100 gal. AMS at 17 lbs./100 gal. 1.Broadleaf weed control may be reduced when grass populations are tall enough dense enough to intercept the spray pattern