WACKER SILICONES IN THE OIL & GAS INDUSTRY

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1 CREATING TOMORROW S SOLUTIONS Proppants I surfactants I demulsifiers & defoamers WACKER SILICONES IN THE OIL & GAS INDUSTRY Historically, silicones in the oil and gas industry were primarily used as foam control agents. This practice continues today. However, the use of silicone chemistry has greatly expanded into other applications with success. This application expansion is the result of silicone being a unique chemistry. Unique stability is offered in extreme low and high temperature conditions and in high pressure environments from deep drilling. Unique functionality offers the ability to significantly reduce material usage through enhanced process efficiencies. These key features have expanded development into: Demulsification Profoaming Well bore stabilization Sand consolidation Proppant adhesion promoters and modifiers Cement additives Fluorosilicone defoamers The unique physical properties of silicones have allowed new application areas to be explored where performance needs haven t been met with traditional chemistries. For example: Silicone modifiers introduce flexibility and strength to proppant coatings allowing for improvements in conductivity, crush resistance, and chemical resistance, resulting in a longer life down hole. Silicone additives introduce lubricity to drilling muds allowing lower surface tension to facilitate backflow and extend well use with faster drill times Silicone additives introduce shale swell stability during drilling, reducing downtime, and maximizing well output. Wacker Chemie AG, the parent of Wacker Chemical Corporation, is among the world leaders in the chemical industry, having sales of 4.63 billion (2012), and more than 3000 siliconbased products. WACKER is close to its global customers with 24 production sites, 22 technical centers, and 53 sales offices in all major regions of the world. WACKER's expertise in the oil & gas industry spans more than 30 years of active involvement. WACKER's customer support model is unique for a silicone chemical supplier in this industry, and offers many benefits designed to help improve your production and operation. Technical Support: Available local technical support involving materials selection guidance, assistance with operations, scale-up feasibility and silicone processing expertise for optimizing manufacturing. Product Customization: WACKER's application experts will offer the right product recommendation whether it is off-the-shelf or requires specific customization that is uniquely tailored to fit your specific application need. Technology Innovation: Working with WACKER also provides access to our global innovation resources. Our goal is to exactly meet your needs, even if it requires developing new technologies. We have invested in both application and materials. WACKER's Oil & Gas customer support model, market knowledge, and technical expertise are designed to optimize your business processes and incorporate the advantages and benefits of silicones into new applications. When new, cutting edge solutions are required; WACKER's technical experts are always available to collaborate with your innovation team to develop next generation solutions. WACKER, SILFOAM, SILRES and GENIOSIL are registered trademarks of Wacker Chemie AG.

2 Product Type Product Name Property Active Ingredient approx [%] Viscosity approx [mpa.s] 25ºC Suitable Diluent Suitable for Stong Acid & Alkaline systems Defoamers SILFOAM SP 150 powder 20 n/a - SILFOAM SE 2210 emulsion water SILFOAM SE 21 emulsion water SILFOAM SE 24 emulsion water SILFOAM SE 55A emulsion water SILFOAM SD 986 self-dispersing 6 5 solvent SILFOAM SD 860 self-dispersing solvent SILFOAM SD 670 self-dispersing water SILFOAM SC 132 compound solvent WACKER AK 1000 fluid solvent WACKER AK fluid solvent WACKER AK fluid solvent WACKER AK fluid solvent WACKER AK fluid solvent WACKER AK fluid solvent WACKER AF 98 10,000 fluid solvent WACKER AKF 3385 fluid solvent Surfactants WACKER SG 3378 fluid water or solvent WACKER SG 3379 fluid water or solvent WACKER SG 3380 fluid water or solvent WACKER SG 3381 fluid water or solvent WACKER SG 3382 fluid water or solvent WACKER SG 3383 fluid water or solvent Additives SILRES BS 4004 emulsion water SILRES BS17040 emulsion water GENIOSIL GF 91 silane water or solvent GENIOSIL GF 93 silane water or solvent GENIOSIL GF 96 silane water or solvent GENIOSIL GF 80 silane water or solvent SILRES SY 231 resin solvent SILRES IC 232 resin solvent SILRES SY 300 resin 100 N/A solvent SILRES IC 836 resin 100 N/A solvent SILRES HP 1250 resin solvent SILRES HP 2000 resin solvent 2

3 Product Name SILFOAM SP 150 Drilling Fluid Cementing Stimulation Proppant Water Treatment Gas Oil Separators SILFOAM SE 2210 SILFOAM SE 21 SILFOAM SE 24 SILFOAM SE 55A SILFOAM SD 986 SILFOAM SD 860 SILFOAM SD 670 SILFOAM SC 132 WACKER AK 1000 WACKER AK WACKER AK WACKER AK WACKER AK WACKER AK WACKER AF 98 10,000 WACKER AKF 3385 WACKER SG 3378 WACKER SG 3379 WACKER SG 3380 WACKER SG 3381 WACKER SG 3382 WACKER SG 3383 SILRES BS 4004 SILRES BS17040 GENIOSIL GF 91 GENIOSIL GF 93 GENIOSIL GF 96 GENIOSIL GF 80 SILRES SY 231 SILRES IC 232 SILRES SY 300 SILRES IC 836 SILRES HP 1250 SILRES HP

4 Product Name Gas Sweetening Crude Vacuum Cracking Asphalt with Amines Distillation Distillation Process Processing SILFOAM SP 150 SILFOAM SE 2210 SILFOAM SE 21 SILFOAM SE 24 SILFOAM SE 55A SILFOAM SD 986 SILFOAM SD 860 SILFOAM SD 670 SILFOAM SC 132 WACKER AK 1000 WACKER AK WACKER AK WACKER AK WACKER AK WACKER AK WACKER AF 98 10,000 WACKER AKF 3385 WACKER SG 3378 WACKER SG 3379 WACKER SG 3380 WACKER SG 3381 WACKER SG 3382 WACKER SG 3383 SILRES BS 4004 SILRES BS17040 GENIOSIL GF 91 GENIOSIL GF 93 GENIOSIL GF 96 GENIOSIL GF 80 SILRES SY 231 SILRES IC 232 SILRES SY 300 SILRES IC 836 SILRES HP 1250 SILRES HP 2000 Delayed Coaker 4

5 WACKER SILICONES ENGINEERED FOR OIL & GAS APPLICATIONS DRILLING: High Efficiency Minimal Downtime The appropriate choice of additives is critical to your process and resulting profitably. One potential choice is WACKER's line of SILFOAM silicon defoamers. The correct form of defoamer allows the user to optimize performance of drilling fluids by eliminating foam interference. In addition to a broad line of proven defoamers, WACKER also offers lubricity additives and new innovative products targeting shale stabilization. This foam generation can lead to pump cavitation variable densities from inconsistent mixing, and inconsistent cement integrity. WACKER offers an additive line engineered to meet the needs of down-hole cement during installation and production life. Not only are silicon-based materials ideal for defoaming cementitious materials, but they can be used to enhance the overall physical performance of the cement. This results in improved cement integrity with reduced failure potential and longer life in use. Proppant Manufacturers: WACKER SG product line provides resin coated manufacturers with process aids that can result in free flowing, non-static, non-agglomerating, proppants while delivering improved cycle times during manufacturing, and stability during delivery and storage. Resin and Proppant Manufacturers: WACKER's GENIOSIL silane products improve the adhesion of a polymer coating to proppants. This translates into higher conductivity and pack life for fracture jobs. Resin Manufacturers: WACKER resin modifiers offer the various resins used in the proppant market the ability to address performance needs. WACKER silicon modifiers provide innovative approaches to modify these coatings to impart improvements in crush resistance, chemical resistance, pack life, and the reduction in the development of fines. CEMENTING: Improved Hydrophobicity and Long Term Durability Cementing is critical to the structural integrity of the well and long term production performance. During the mixing of the cement slurry many essential additives, such as those for cement integrity, performance enhancers, fluid loss and anti-settling agents, are added causing air entrapment and generation of foam. 5 STIMULATION: At the Forefront of Hydraulic Fracking Fracking has changed the direction of oil and gas production and is a critical application for productivity. An integral part of this process is the production and use of resin coated proppants. WACKER offers a broad line of silicon based products to address the needs of the resin coated proppants market.

6 CREATING TOMORROW S SOLUTIONS Proppants I surfactants I demulsifiers & defoamers GLOBAL TECHNOLOGY INDUSTRY KNOWLEDGE PRODUCT INNOVATION PRODUCTION: Enabling a More Efficient Production Process Flow An efficient production process is crucial for optimizing oil & gas throughput. Key processes in production, such as gas/oil/ water separation, are often plagued with efficiency issues related to foaming and separation dynamics. WACKER's SILFOAM product line controls and regulates foam formation maximizing production rates. Additionally, The WACKER SG series offers a full line of demulsifiers and surfactants to meet performance requirements or extreme conditions that cannot be met with standard offerings. These products may be used at full strength or as booster agents for these processes. REFINING: Extreme Conditions Demand Extreme Solutions The extreme conditions of the refining process make WACKER silicon products the ideal solution to address the foaming issues that can occur and impede refinery production rates. WACKER s SILFOAM defoamers and WACKER AK fluids offer the enhanced performance, improved efficiency, and low loading levels that will help keep the refinery processes operating at the highest possible output. WACKER's SILFOAM defoamers are formulated to control foam in the distillation (vacuum or atmospheric) columns, in high temperature visbreakers and cokers, and for refinery waste water treatment. Local Warehousing/On-Time Supply / Robust Supply Chain WACKER's customer support model offers world class distribution services through Brenntag for local support, logistics, warehousing, and JIT deliveries. Brenntag is a leading global distributor of chemical products and is a worldwide WACKER distribution partner. Brenntag s extensive network of locations ensures local coverage for customers in North and South America. Brenntag offers a broad range of industrial and specialty chemicals, including WACKER s Oil & Gas product line. World Class Technology Trade names of WACKER, SILFOAM, GENIOSIL, and SILRES have gained global recognition for achieving high levels of performance and efficiency. Our GENIOSIL silanes not only act as effective adhesion promoters, but in combination with our silicon modifiers can change resin properties and improve in use performance of resin coated proppants. Our WACKER, SILFOAM, and SILRES products are known for high levels of performance and efficiency, allowing minimal usage to achieve effectiveness, stability and performance under adverse conditions. Wacker Chemical Corporation, 3301 Sutton Road, Adrian, MIchighan 49221, UA info.usa@wacker.com, The data presented in this information sheet are in accordance with the present state of our knowledge but do not absolve the user from carefully checking all supplies immediately on receipt. We reserve the right to alter product constants within the scope of technical progress or new developments. The recommendations made in this information sheet should be checked by preliminary trials because of conditions during processing over which we have no control, especially where other companies raw materials are also being used. The information provided by us does not absolve the user from the obligation of investigating the possibility of infringement of third parties rights and, if necessary, clarifying the position. Recommendations for use do not constitute a warranty, either express or implied, of the fitness or suitability of the product for a particular purpose us/8.13

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