Material Safety Data Sheet

Transcription

1 Material SORELMETAL Section 1. Chemical product and company identification Common name SORELMETAL Material uses Iron ( % C) - Pig iron for cast iron foundries. Supplier/Manufacturer QIT-Fer et Titane inc Marie-Victorin, Sorel-Tracy, Québec, Canada J3R 1M6 Tel In case of emergency Section 2. Hazards identification Physical state Emergency overview Routes of entry Potential acute health effects Eyes Skin Inhalation Ingestion Potential chronic health effects Medical conditions aggravated by overexposure See toxicological information (section 11) Solid. (Ingot.) No specific hazard. USE WITH CARE. Follow good industrial hygiene practice. Dermal contact. Eye contact. Inhalation. Ingestion. May cause eye irritation. No known significant effects or critical hazards. May cause respiratory tract irritation. No known significant effects or critical hazards. Carcinogenic effects Not classified or listed by IARC, NTP, OSHA, EU and ACGIH. Mutagenic effects Not available. Teratogenic effects Not available. NO EXPOSURE WHEN USED IN ITS ORIGINAL FORM. Processing of product such as grinding, welding and melting may produce dust and fumes. Repeated inhalation of dust or fumes can cause various degrees of respiratory irritation or lung damage (siderosis). Section 3. Composition, Information on Ingredients Ingredient name Classification North America UN number IDLH H F R Special CAS number % by weight Iron, furnace Not regulated Silicon UN Europe Classification EC number Iron, furnace Not classified Silicon Not classified See section 16 for the full text of the R-phrases declared above This material is classified as not hazardous under OSHA regulations in the United States, the WHMIS in Canada, the NOM-018-STPS-2000 in Mexico, Brazil NBR , the European Directives and in any other country in Asia/Pacific, Africa or the Middle-East. This product has not been tested as a whole for all potential health effects. Cr +6 is less than 1 ppm. This product is not radioactive i.e. SORELMETAL is analyzed annually to determine the emission of alpha, beta and gamma radionuclides and the results indicate that SORELMETAL does not emit any alpha, beta or gamma radionuclides above the background level. Date of issue 12/04/2009 Page 1/6

2 SORELMETAL See Sections 8, 11 and 14 for details. Section 4. First aid measures Eye contact Skin contact Inhalation Ingestion Notes to physician Section 5. Fire-fighting measures Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 20 minutes. Get medical attention if irritation occurs. Wash with soap and water. Get medical attention if irritation occurs. Move person to fresh air. Get medical attention if breathing difficulty persists. Do not induce vomiting. Never give anything by mouth to an unconscious person. Get medical attention if symptoms appear. No specific antidote. Flammability of the product Fire-fighting media and instructions Special protective equipment for fire-fighters Special remarks on explosion hazards Non-flammable. Use an extinguishing agent suitable for the surrounding fire. Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full facepiece operated in positive pressure mode. Moisture can be present on the ingot surface causing an EXPLOSION hazard if a cold or wet ingot is dropped into molten metal. Always heat the ingots sufficiently to remove moisture and surface irregularities, before dropping these into molten metal. Section 6. Accidental release measures In case of a major spill Personal precautions Keep unnecessary personnel away. Use suitable protective equipment. Environmental precautions Avoid dispersal of spilled material, runoff and contact with soil, waterways, drains and sewers. Methods for cleaning up Place spilled material in an appropriate container for disposal. Section 7. Handling and storage Handling If used in a process that creates dust or fumes, avoid inhalation and wear appropriate Storage personal protective clothing. Avoid prolonged contact with eyes, skin and clothing. Wash thoroughly after handling. Use in a well-ventitaled area. The product absorbs moisture on long-term storage mostly under high humidity conditions. Remove moisture from the surface by DRYING/HEATING the ingots before use. Section 8. Exposure controls/personal protection Engineering controls Personal protection Eyes Use process enclosures, local exhaust ventilation or other engineering controls to keep airborne levels below recommended exposure limits. If user operations generate dust, fumes or mist, use ventilation to keep exposure to airborne contaminants below the exposure limit. Safety eyewear complying with an approved standard should be used and selected based on the task being performed and the risks involved (avoid exposure to dusts). Where there is a risk of exposure to high velocity particles safety glasses or face shield complying with an approved standard should be used to protect against impact. Where there is a risks of exposure to dusts, goggles should be used. Date of issue 12/04/2009 Page 2/6

3 SORELMETAL Respiratory Hands Use a properly fitted, particulate filter respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Recommended Leather gloves. Skin/Body Personal protective equipment for the body should be selected based on the task being performed and the risks involved. Recommended Overall. Personal protection in case of a large spill Safety glasses and or goggles and or face shield should be used depending on the task being performed. Leather gloves. Overall. Boots. Wear approved respiratory apparatus if required. Product name Exposure limits Iron ACGIH TLV (United States). TWA 10 mg/m³ 8 hour(s). Form Inhalable particle. Silicon NIOSH REL (United States, 12/2001). TWA 10 mg/m³ 10 hour(s). Form Total OSHA PEL (United States, 11/2006). TWA 5 mg/m³ 8 hour(s). Form Respirable fraction TWA 15 mg/m³ 8 hour(s). Form Total dust Consult local authorities for acceptable exposure limits. Section 9. Physical and chemical properties Physical state Color Odor Melting/freezing point Specific gravity Bulk density Granulometry Dispersibility properties Solubility Solid. (Ingot.) Gray. (Dark.) Odorless to 1200 C (2102 to 2192 F) 7.2 (Water = 1) Not available. Not available. Not dispersible in the following materials cold water, hot water. Insoluble in cold water, hot water. Section 10. Stability and reactivity Stability and reactivity Incompatibility with various substances Hazardous decomposition products Hazardous polymerization The product is stable. Reactive with oxidizing materials and reducing materials. Contact with acids may liberate extremely flammable gas (Hydrogen). Not available. Will not occur. Date of issue 12/04/2009 Page 3/6

4 SORELMETAL Section 11. Toxicological information Toxicity data Ingredient name Test Result Route Species Silicon LD mg/kg Oral Rat Acute Effects Eyes Skin Inhalation Ingestion Potential chronic health effects Medical conditions aggravated by overexposure Section 12. Ecological information Products of degradation Waste disposal May cause eye irritation. No known significant effects or critical hazards. May cause respiratory tract irritation. No known significant effects or critical hazards. Carcinogenic effects Not classified or listed by IARC, NTP, OSHA, EU and ACGIH. Mutagenic effects Not available. Teratogenic effects Not available. NO EXPOSURE WHEN USED IN ITS ORIGINAL FORM. Processing of product such as grinding, welding and melting may produce dust and fumes. Repeated inhalation of dust or fumes can cause various degrees of respiratory irritation or lung damage (siderosis). Some metallic oxides. Section 13. Disposal considerations The generation of waste should be avoided or minimized wherever possible. Avoid dispersal of spilled material, runoff and contact with soil, waterways, drains and sewers. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional and local authority requirements. Consult your local or regional authorities. Section 14. Transport information Classification ADN / ADR / TDG / DOT/ IMDG/ IATA Not regulated. NAERG Not applicable. Label Not applicable. Additional information Not applicable. Section 15. Regulatory information United States HCS Classification U.S. Federal regulations Not regulated. TSCA All components listed. SARA 302/304/311/312 extremely hazardous substances No products were found. SARA 302/304 emergency planning and notification No products were found. SARA 302/304/311/312 hazardous chemicals Silicon SARA 311/312 MSDS distribution - chemical inventory - hazard identification Iron Fire hazard; Silicon Fire hazard, Immediate (acute) health hazard Clean Water Act (CWA) 307 No products were found. Clean Water Act (CWA) 311 No products were found. Date of issue 12/04/2009 Page 4/6

5 SORELMETAL State regulations Clean Air Act (CAA) 112 accidental release prevention No products were found. Clean Air Act (CAA) 112 regulated flammable substances No products were found. Clean Air Act (CAA) 112 regulated toxic substances No products were found. Pennsylvania RTK Hazardous Substances Silicon (generic environmental hazard); Manganese (environmental hazard, generic environmental hazard) Massachusetts Substances Silicon; Manganese New Jersey Silicon; Manganese Canada WHMIS (Canada) Mexico Classification California prop. 65 No products were found. Not controlled under WHMIS (Canada). DSL All components listed. 0 Health 1 0 Flammability Reactivity Special EU regulations Risk phrases This product is not classified according to EU legislation. Product use Classification and labeling have been performed according to EU Directives 67/548/EEC and 1999/45/EC (including amendments) and the intended use. - Industrial applications. International regulations International lists Section 16. Other information This product is not listed on major international inventories or exempted from being listed in Australia (AICS), Europe (EINECS/ELINCS), Korea (TCCL), Japan (METI/MOL), Philippines (RA6969). Label requirements Hazardous Material Information System (U.S.A.) USE WITH CARE. Health Fire hazard Reactivity Personal protection C National Fire Protection Association (U.S.A.) Health 1 0 Flammability 0 Instability Special Full text of R-phrases referred to in sections 2 and 3 - Europe Not applicable. Full text of classifications referred to in sections 2 and 3 - Europe Not applicable. Date of issue 12/04/2009 Page 5/6

6 SORELMETAL References ANSI Z400.1, MSDS Standard, Manufacturer's Material. - 29CFR Part OSHA MSDS Requirements. - 49CFR Table List of Hazardous Materials, UN#, Proper Shipping Names, PG. - Canada Gazette Part II, Vol. 122, No. 2. Registration SOR/88-64, 31 December Hazardous Products Act "Ingredient Disclosure List" - Canadian Transport of Dangerous Goods, Regulations and Schedules, Clear Language version Official Mexican Standards NOM-018-STPS-2000 and NOM-004-SCT Brazil NBR Date of issue Date of previous issue Version 12/04/ /05/ Notice to reader To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.

7 Stainless Steel and Alloys of Stainless Steel According To Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules And Regulations Revision Date 12/15/2014 Date of issue 10/30/2014 Version 1.0 SECTION 1 IDENTIFICATION 1.1. Product Identifier Product Form Mixture Product Name Stainless Steel and Alloys of Stainless Steel Synonyms Alloy #200; Alloy #900; Alloy #STAGCG57; Alloy #342; Alloy #2SA 1.2. Intended Use of the Product Use of the Substance/Mixture No use is specified Name, Address, and Telephone of the Responsible Party Distributor ThyssenKrupp Materials NA, Inc W. Eleven Mile Road Southfield, Michigan TEL Emergency Telephone Number Emergency Number SECTION 2 HAZARDS IDENTIFICATION 2.1. Classification of the Substance or Mixture Classification (GHS-US) Not classified 2.2. Label Elements GHS-US Labeling No labeling applicable 2.3. Other Hazards This product is present in a massive form as an alloy. It does not present the same hazards when the individual components are in their powdered forms. The materials present in this product in their powdered forms present aquatic toxicity to the environment, pyrophoricity, flammability, self-heating capabilities, carcinogenicity, water reactivity, and acute toxicity. When processed or where dust is generated a combustible dust hazard may be present. Avoid generating dust, generating sparks, ignition sources, and take all precautions. Inhalation of dusts and fumes can cause metal fume fever. Symptoms can include a metallic or sweet taste in the mouth, sweating, shivering, headache, throat irritation, fever, chills, thirstiness, muscle aches, nausea, vomiting, weakness, fatigue, and shortness of breath. Under normal use and handling of the solid form of this material there are few health hazards. Cutting, welding, melting, grinding etc. of these materials will produce dust, fume or particulate containing the component elements of these materials. Exposure to the dust, fume or particulate of these materials may present significant health hazards. Exposure to dust or fume may cause irritation of the eyes, skin and respiratory tract. Fine particulates dispersed in air may present an explosion hazard Unknown Acute Toxicity (GHS-US) No data available SECTION 3 COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substances Not applicable Name Product Identifier % (w/w) Classification (GHS-US) Iron (CAS No) Not classified Chromium (CAS No) < 0.1, 0.1-1, 1-5, 5-10, Comb. Dust Nickel (CAS No) < 0.1, 0.1-1, 1-5, 5-10, Skin Sens. 1, H317 Carc. 2, H351 STOT RE 1, H372 Aquatic Acute 1, H400 Aquatic Chronic 3, H412 Manganese (CAS No) < 0.1, Comb. Dust 12/15/2014 EN (English US) 1/20

8 Stainless Steel and Alloys of Stainless Steel According To Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules And Regulations 1, 1-5, 5-6 Molybdenum (CAS No) < 0.1, 0.1-1, 1-5, 5-6 Titanium (CAS No) < 0.1, 0.1-1, 1-5, 5-6 Copper (CAS No) < 0.1, 0.1-1, 1-5, 5-6 Sulfur dioxide (CAS No) < 0.1, 0.1-1, 1-2 Phosphorus elemental (CAS No) < 0.1, 0.1-1, 1-2 Cobalt (CAS No) < 0.1, 0.1-1, 1-2 Carbon (CAS No) < 0.1, 0.1-1, 1-2 Silicon (CAS No) < 0.1, 0.1-1, 1-2 Tungsten (CAS No) < 0.1, 0.1-1, 1-2 Niobium (CAS No) < 0.1, 0.1-1, 1-2 Aluminum (CAS No) < 0.1, Comb. Dust Flam. Sol. 1, H228 Comb. Dust Aquatic Acute 1, H400 Aquatic Chronic 3, H412 Compressed gas, H280 Acute Tox. 3 (Inhalationgas), H331 Skin Corr. 1B, H314 Eye Dam. 1, H318 Not classified Acute Tox. 4 (Oral), H302 Acute Tox. 1 (Inhalationdust,mist), H330 Eye Irrit. 2A, H319 Resp. Sens. 1B, H334 Skin Sens. 1, H317 Carc. 2, H351 Repr. 2, H361 Aquatic Acute 3, H402 Aquatic Chronic 1, H410 Comb. Dust Comb. Dust Flam. Sol. 1, H228 Self-heat. 2, H252 Flam. Sol. 1, H228 Comb. Dust Flam. Sol. 1, H228 Water-react. 2, H261 Tantalum (CAS No) Flam. Sol. 1, H228 Selenium (CAS No) < 0.1, Acute Tox. 3 (Oral), H301 Acute Tox. 3 (Inhalationdust,mist), H331 STOT RE 2, H373 Aquatic Chronic 4, H413 Full text of H-phrases see section 16 More than one of the ranges of concentration prescribed by Controlled Products Regulations has been used where necessary due to varying composition. SECTION 4 FIRST AID MEASURES 4.1. Description of First Aid Measures General IF exposed or concerned Get medical advice/attention. Never give anything by mouth to an unconscious person. Inhalation When symptoms occur go into open air and ventilate suspected area. Keep at rest and in a position comfortable for breathing. Obtain medical attention if breathing difficulty persists. 12/15/2014 EN (English US) 2/20

9 Stainless Steel and Alloys of Stainless Steel According To Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules And Regulations Skin Contact Cool skin rapidly with cold water after contact with molten product. Removal of solidified molten material from skin requires medical assistance. Remove contaminated clothing. Drench affected area with water for at least 15 minutes. Wash with plenty of soap and water. Wash contaminated clothing before reuse. Obtain medical attention if irritation persists. Eye Contact Removal of solidified molten material from the eyes requires medical assistance. Immediately rinse with water for a prolonged period (at least 15 minutes) while holding the eyelids wide open. Remove contact lenses, if present and easy to do. Continue rinsing. Obtain medical attention if irritation develops or persists. Ingestion Rinse mouth. Do NOT induce vomiting. Call a POISON CENTER/doctor/physician if you feel unwell Most Important Symptoms and Effects Both Acute and Delayed General Welding, cutting, or processing this material may release dust or fumes that are hazardous. Inhalation Inhalation of dusts and fumes can cause metal fume fever. Symptoms can include a metallic or sweet taste in the mouth, sweating, shivering, headache, throat irritation, fever, chills, thirstiness, muscle aches, nausea, vomiting, weakness, fatigue, and shortness of breath. Skin Contact May cause an allergic skin reaction. Dust from physical alteration of this product causes skin irritation. Causes severe skin burns. Contact with fumes or metal powder will irritate skin. Contact with hot, molten metal will cause thermal burns. Dust may cause irritation in skin folds or by contact in combination with tight clothing. Mechanical damage via flying particles and chipped slag is possible. Eye Contact Dust may cause mechanical irritation to eyes, nose, throat, and lungs. Ingestion Ingestion is likely to be harmful or have adverse effects. Chronic Symptoms In massive form, no hazard exists. If physically altered to present slivers, ribbons, dusts or fumes from molten material Aluminum Inhalation of finely divided aluminum powder may cause pulmonary fibrosis. Inhalation of iron oxide fumes undergoing decomposition may cause irritation and flu-like symptoms, otherwise iron oxide is not hazardous. Inhalation of Nickel compounds has been shown in studies to provide an increased incidence of cancer of the nasal cavity, lung and possibly larynx in nickel refinery workers. Nickel May cause a form of dermatitis known as nickel itch and intestinal irritation, which may cause disorders, convulsions and asphyxia. Chromium Certain hexavalent chromium compounds have been demonstrated to be carcinogenic on the basis of epidemiological investigations on workers and experimental studies in animals. Increased incidences of respiratory cancer have been found in chromium (VI) workers.there is an increased incidence of lung cancer in industrial workers exposed to chromium (VI) compounds. Please refer to IARC volume 23 for a more detailed discussion. Manganese Chronic exposure can cause inflammation of the lung tissue, scarring the lungs (pulmonary fibrosis). Copper Overexposure to fumes may cause metal fume fever (chills, muscle aches, nausea, fever, dry throat, cough, weakness, lassitude); metallic or sweet taste; discoloration of skin and hair. Tissue damage of mucous membranes may follow chronic dust exposure. Silicon Can cause chronic bronchitis and narrowing of the airways Indication of Any Immediate Medical Attention and Special Treatment Needed If exposed or concerned, get medical advice and attention. SECTION 5 FIRE-FIGHTING MEASURES 5.1. Extinguishing Media Suitable Extinguishing Media Use extinguishing media appropriate for surrounding fire. Dry sand; Class D Extinguishing Agent (for metal powder fires). Unsuitable Extinguishing Media Do not use a heavy water stream. Use of heavy stream of water may spread fire. Do not use water when molten material is involved, may react violently or explosively on contact with water Special Hazards Arising From the Substance or Mixture Fire Hazard A non-combustible material, not considered flammable but will melt above 1300 C (2372 F). Explosion Hazard In molten state reacts violently with water (moisture). Reactivity Hazardous reactions will not occur under normal conditions Advice for Firefighters Precautionary Measures Fire Under fire conditions, hazardous fumes will be present. Firefighting Instructions Exercise caution when fighting any chemical fire. Protection During Firefighting Do not enter fire area without proper protective equipment, including respiratory protection. Hazardous Combustion Products Oxides of nickel. Oxides of copper. Chromium oxides. Oxides of silicone and carbon. Oxides of aluminum. Phosphorus oxides. Molybdenum oxides. Sulfur compounds. Cobalt oxide. Oxides of Tantalum. 12/15/2014 EN (English US) 3/20

10 Stainless Steel and Alloys of Stainless Steel According To Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules And Regulations Reference to Other Sections Refer to section 9 for flammability properties. SECTION 6 ACCIDENTAL RELEASE MEASURES 6.1. Personal Precautions, Protective Equipment and Emergency Procedures General Measures Do not handle until all safety precautions have been read and understood. Do not breathe vapors from molten product For Non-Emergency Personnel Protective Equipment Use appropriate personal protection equipment (PPE). Emergency Procedures Evacuate unnecessary personnel For Emergency Personnel Protective Equipment Equip cleanup crew with proper protection. Emergency Procedures Ventilate area Environmental Precautions Prevent entry to sewers and public waters Methods and Material for Containment and Cleaning Up For Containment Contain and collect as any solid. Methods for Cleaning Up Clear up spills immediately and dispose of waste safely. For particulates and dust Avoid actions that cause dust to become airborne during clean-up such as dry sweeping or using compressed air. Use HEPA vacuum or thoroughly wet with water to clean-up dust. Use PPE described in Section 8. Vacuum must be fitted with HEPA filter to prevent release of particulates during clean-up Reference to Other Sections See heading 8, Exposure Controls and Personal Protection. Concerning disposal elimination after cleaning, see item 13. SECTION 7 HANDLING AND STORAGE 7.1. Precautions for Safe Handling Additional Hazards When Processed May generate flammable/explosive dusts or turnings when brushed, machined or ground. Use care during processing to minimize generation of dust. Where excessive dust may result, use approved respiratory protection equipment. Heating of product can release toxic or irritating fumes; ensure proper ventilation is employed, proper precautions are enforced, and applicable regulations are followed. Inhalation of fumes may cause metal fume fever. Hygiene Measures Handle in accordance with good industrial hygiene and safety procedures. Wash hands and other exposed areas with mild soap and water before eating, drinking, or smoking and again when leaving work. Do not eat, drink or smoke when using this product. Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reuse Conditions for Safe Storage, Including Any Incompatibilities Storage Conditions Store in a dry, cool and well-ventilated place. Incompatible Materials Strong acids, strong bases, strong oxidizers. Alkalis. Metal oxides. Water, humidity. Corrosive substances in contact with metals may produce flammable hydrogen gas Specific End Use(s) No use is specified. SECTION 8 EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control Parameters For substances listed in section 3 that are not listed here, there are no established Exposure limits from the manufacturer, supplier, importer, or the appropriate advisory agency including ACGIH (TLV), NIOSH (REL), OSHA (PEL), Canadian provincial governments, or the Mexican government. Chromium ( ) Mexico OEL TWA (mg/m³) 0.5 mg/m³ USA ACGIH ACGIH TWA (mg/m³) 0.5 mg/m³ USA OSHA OSHA PEL (TWA) (mg/m³) 1 mg/m³ USA NIOSH NIOSH REL (TWA) (mg/m³) 0.5 mg/m³ USA IDLH US IDLH (mg/m³) 250 mg/m³ Alberta OEL TWA (mg/m³) 0.5 mg/m³ British Columbia OEL TWA (mg/m³) 0.5 mg/m³ Manitoba OEL TWA (mg/m³) 0.5 mg/m³ 12/15/2014 EN (English US) 4/20

11 Stainless Steel and Alloys of Stainless Steel According To Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules And Regulations New Brunswick OEL TWA (mg/m³) 0.5 mg/m³ Newfoundland & Labrador OEL TWA (mg/m³) 0.5 mg/m³ Nova Scotia OEL TWA (mg/m³) 0.5 mg/m³ Nunavut OEL STEL (mg/m³) 1.5 mg/m³ Nunavut OEL TWA (mg/m³) 0.5 mg/m³ Northwest Territories OEL STEL (mg/m³) 1.5 mg/m³ Northwest Territories OEL TWA (mg/m³) 0.5 mg/m³ Ontario OEL TWA (mg/m³) 0.5 mg/m³ Prince Edward Island OEL TWA (mg/m³) 0.5 mg/m³ Québec VEMP (mg/m³) 0.5 mg/m³ Saskatchewan OEL STEL (mg/m³) 1.5 mg/m³ Saskatchewan OEL TWA (mg/m³) 0.5 mg/m³ Yukon OEL STEL (mg/m³) 3.0 mg/m³ Yukon OEL TWA (mg/m³) 0.1 mg/m³ Nickel ( ) Mexico OEL TWA (mg/m³) 1 mg/m³ USA ACGIH ACGIH TWA (mg/m³) 1.5 mg/m³ (inhalable fraction) USA OSHA OSHA PEL (TWA) (mg/m³) 1 mg/m³ USA NIOSH NIOSH REL (TWA) (mg/m³) mg/m³ USA IDLH US IDLH (mg/m³) 10 mg/m³ Alberta OEL TWA (mg/m³) 1.5 mg/m³ British Columbia OEL TWA (mg/m³) 0.05 mg/m³ Manitoba OEL TWA (mg/m³) 1.5 mg/m³ (inhalable fraction) New Brunswick OEL TWA (mg/m³) 1 mg/m³ Newfoundland & Labrador OEL TWA (mg/m³) 1.5 mg/m³ (inhalable fraction) Nova Scotia OEL TWA (mg/m³) 1.5 mg/m³ (inhalable fraction) Nunavut OEL STEL (mg/m³) 2 mg/m³ Nunavut OEL TWA (mg/m³) 1 mg/m³ Northwest Territories OEL STEL (mg/m³) 2 mg/m³ Northwest Territories OEL TWA (mg/m³) 1 mg/m³ Ontario OEL TWA (mg/m³) 1 mg/m³ (inhalable) Prince Edward Island OEL TWA (mg/m³) 1.5 mg/m³ (inhalable fraction) Québec VEMP (mg/m³) 1 mg/m³ Saskatchewan OEL STEL (mg/m³) 3 mg/m³ (inhalable fraction) Saskatchewan OEL TWA (mg/m³) 1.5 mg/m³ (inhalable fraction) Yukon OEL STEL (mg/m³) 3 mg/m³ Yukon OEL TWA (mg/m³) 1 mg/m³ Manganese ( ) Mexico OEL TWA (mg/m³) 0.2 mg/m³ 1 mg/m³ (fume) Mexico OEL STEL (mg/m³) 3 mg/m³ (fume) USA ACGIH ACGIH TWA (mg/m³) 0.02 mg/m³ (respirable fraction) 0.1 mg/m³ (inhalable fraction) USA OSHA OSHA PEL (Ceiling) (mg/m³) 5 mg/m³ (fume) USA NIOSH NIOSH REL (TWA) (mg/m³) 1 mg/m³ (fume) USA NIOSH NIOSH REL (STEL) (mg/m³) 3 mg/m³ USA IDLH US IDLH (mg/m³) 500 mg/m³ Alberta OEL TWA (mg/m³) 0.2 mg/m³ British Columbia OEL TWA (mg/m³) 0.2 mg/m³ Manitoba OEL TWA (mg/m³) 0.02 mg/m³ (respirable fraction) New Brunswick OEL TWA (mg/m³) 0.2 mg/m³ 12/15/2014 EN (English US) 5/20

12 Stainless Steel and Alloys of Stainless Steel According To Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules And Regulations Newfoundland & Labrador OEL TWA (mg/m³) 0.02 mg/m³ (respirable fraction) Nova Scotia OEL TWA (mg/m³) 0.02 mg/m³ (respirable fraction) Nunavut OEL Ceiling (mg/m³) 5 mg/m³ Nunavut OEL STEL (mg/m³) 3 mg/m³ (fume) Nunavut OEL TWA (mg/m³) 1 mg/m³ (fume) Northwest Territories OEL Ceiling (mg/m³) 5 mg/m³ Northwest Territories OEL STEL (mg/m³) 3 mg/m³ (fume) Northwest Territories OEL TWA (mg/m³) 1 mg/m³ (fume) Ontario OEL TWA (mg/m³) 0.2 mg/m³ Prince Edward Island OEL TWA (mg/m³) 0.02 mg/m³ (respirable fraction) Québec VEMP (mg/m³) 0.2 mg/m³ (total dust and fume) Saskatchewan OEL STEL (mg/m³) 0.6 mg/m³ Saskatchewan OEL TWA (mg/m³) 0.2 mg/m³ Yukon OEL Ceiling (mg/m³) 5 mg/m³ Molybdenum ( ) USA ACGIH ACGIH TWA (mg/m³) 10 mg/m³ (inhalable fraction) 3 mg/m³ (respirable fraction) USA IDLH US IDLH (mg/m³) 5000 mg/m³ Alberta OEL TWA (mg/m³) 10 mg/m³ (total) British Columbia OEL TWA (mg/m³) 3 mg/m³ (respirable) Manitoba OEL TWA (mg/m³) 10 mg/m³ (inhalable fraction) Newfoundland & Labrador OEL TWA (mg/m³) 10 mg/m³ (inhalable fraction) Nova Scotia OEL TWA (mg/m³) 10 mg/m³ (inhalable fraction) Ontario OEL TWA (mg/m³) 10 mg/m³ (metal-inhalable) Prince Edward Island OEL TWA (mg/m³) 10 mg/m³ (inhalable fraction) Saskatchewan OEL STEL (mg/m³) 20 mg/m³ (inhalable fraction) Saskatchewan OEL TWA (mg/m³) 10 mg/m³ (inhalable fraction) Copper ( ) Mexico OEL TWA (mg/m³) 0.2 mg/m³ (fume) 1 mg/m³ (dust and mist) Mexico OEL STEL (mg/m³) 2 mg/m³ (fume) 2 mg/m³ (dust and mist) USA ACGIH ACGIH TWA (mg/m³) 0.2 mg/m³ (fume) USA OSHA OSHA PEL (TWA) (mg/m³) 0.1 mg/m³ (fume) 1 mg/m³ (dust and mist) USA NIOSH NIOSH REL (TWA) (mg/m³) 1 mg/m³ (dust and mist) 0.1 mg/m³ (fume) USA IDLH US IDLH (mg/m³) 100 mg/m³ (dust, fume and mist) Alberta OEL TWA (mg/m³) 0.2 mg/m³ (fume) British Columbia OEL TWA (mg/m³) 1 mg/m³ (dust and mist) Manitoba OEL TWA (mg/m³) 0.2 mg/m³ (fume) New Brunswick OEL TWA (mg/m³) 0.2 mg/m³ (fume) Newfoundland & Labrador OEL TWA (mg/m³) 0.2 mg/m³ (fume) Nova Scotia OEL TWA (mg/m³) 0.2 mg/m³ (fume) Nunavut OEL STEL (mg/m³) 0.6 mg/m³ (fume) Nunavut OEL TWA (mg/m³) 0.2 mg/m³ (fume) Northwest Territories OEL STEL (mg/m³) 0.6 mg/m³ (fume) Northwest Territories OEL TWA (mg/m³) 0.2 mg/m³ (fume) Ontario OEL TWA (mg/m³) 0.2 mg/m³ (fume) Prince Edward Island OEL TWA (mg/m³) 0.2 mg/m³ (fume) Québec VEMP (mg/m³) 0.2 mg/m³ (fume) 12/15/2014 EN (English US) 6/20

13 Stainless Steel and Alloys of Stainless Steel According To Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules And Regulations Saskatchewan OEL STEL (mg/m³) 0.6 mg/m³ (fume) Saskatchewan OEL TWA (mg/m³) 0.2 mg/m³ (fume) Yukon OEL STEL (mg/m³) 0.2 mg/m³ (fume) Yukon OEL TWA (mg/m³) 0.2 mg/m³ (fume) Sulfur dioxide ( ) Mexico OEL TWA (mg/m³) 5 mg/m³ Mexico OEL TWA (ppm) 2 ppm Mexico OEL STEL (mg/m³) 10 mg/m³ Mexico OEL STEL (ppm) 5 ppm USA ACGIH ACGIH STEL (ppm) 0.25 ppm USA OSHA OSHA PEL (TWA) (mg/m³) 13 mg/m³ USA OSHA OSHA PEL (TWA) (ppm) 5 ppm USA NIOSH NIOSH REL (TWA) (mg/m³) 5 mg/m³ USA NIOSH NIOSH REL (TWA) (ppm) 2 ppm USA NIOSH NIOSH REL (STEL) (mg/m³) 13 mg/m³ USA NIOSH NIOSH REL (STEL) (ppm) 5 ppm USA IDLH US IDLH (ppm) 100 ppm Alberta OEL STEL (mg/m³) 13 mg/m³ Alberta OEL STEL (ppm) 5 ppm Alberta OEL TWA (mg/m³) 5.2 mg/m³ Alberta OEL TWA (ppm) 2 ppm British Columbia OEL STEL (ppm) 5 ppm British Columbia OEL TWA (ppm) 2 ppm Manitoba OEL STEL (ppm) 0.25 ppm New Brunswick OEL STEL (mg/m³) 13 mg/m³ New Brunswick OEL STEL (ppm) 5 ppm New Brunswick OEL TWA (mg/m³) 5.2 mg/m³ New Brunswick OEL TWA (ppm) 2 ppm Newfoundland & Labrador OEL STEL (ppm) 0.25 ppm Nova Scotia OEL STEL (ppm) 0.25 ppm Nunavut OEL STEL (mg/m³) 13 mg/m³ Nunavut OEL STEL (ppm) 5 ppm Nunavut OEL TWA (mg/m³) 5 mg/m³ Nunavut OEL TWA (ppm) 2 ppm Northwest Territories OEL STEL (mg/m³) 13 mg/m³ Northwest Territories OEL STEL (ppm) 5 ppm Northwest Territories OEL TWA (mg/m³) 5 mg/m³ Northwest Territories OEL TWA (ppm) 2 ppm Ontario OEL STEL (mg/m³) 10.4 mg/m³ Ontario OEL STEL (ppm) 5 ppm Ontario OEL TWA (mg/m³) 5.2 mg/m³ Ontario OEL TWA (ppm) 2 ppm Prince Edward Island OEL STEL (ppm) 0.25 ppm Québec VECD (mg/m³) 13 mg/m³ Québec VECD (ppm) 5 ppm Québec VEMP (mg/m³) 5.2 mg/m³ Québec VEMP (ppm) 2 ppm Saskatchewan OEL STEL (ppm) 5 ppm Saskatchewan OEL TWA (ppm) 2 ppm Yukon OEL STEL (mg/m³) 13 mg/m³ Yukon OEL STEL (ppm) 5 ppm 12/15/2014 EN (English US) 7/20

14 Stainless Steel and Alloys of Stainless Steel According To Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules And Regulations Yukon OEL TWA (mg/m³) 13 mg/m³ Yukon OEL TWA (ppm) 5 ppm Phosphorus elemental ( ) Alberta OEL TWA (mg/m³) 0.1 mg/m³ (yellow) New Brunswick OEL TWA (mg/m³) 0.1 mg/m³ (yellow) New Brunswick OEL TWA (ppm) 0.02 ppm (yellow) Québec VEMP (mg/m³) 0.1 mg/m³ (yellow) Cobalt ( ) Mexico OEL TWA (mg/m³) 0.1 mg/m³ (dust and fume) USA ACGIH ACGIH TWA (mg/m³) 0.02 mg/m³ USA OSHA OSHA PEL (TWA) (mg/m³) 0.1 mg/m³ (dust and fume) USA NIOSH NIOSH REL (TWA) (mg/m³) 0.05 mg/m³ (dust and fume) USA IDLH US IDLH (mg/m³) 20 mg/m³ (dust and fume) Alberta OEL TWA (mg/m³) 0.02 mg/m³ British Columbia OEL TWA (mg/m³) 0.02 mg/m³ Manitoba OEL TWA (mg/m³) 0.02 mg/m³ New Brunswick OEL TWA (mg/m³) 0.02 mg/m³ Newfoundland & Labrador OEL TWA (mg/m³) 0.02 mg/m³ Nova Scotia OEL TWA (mg/m³) 0.02 mg/m³ Nunavut OEL STEL (mg/m³) 0.3 mg/m³ (dust and fume) Nunavut OEL TWA (mg/m³) 0.1 mg/m³ (metal-dust and fume) Northwest Territories OEL STEL (mg/m³) 0.3 mg/m³ (dust and fume) Northwest Territories OEL TWA (mg/m³) 0.1 mg/m³ (dust and fume) Ontario OEL TWA (mg/m³) 0.02 mg/m³ Prince Edward Island OEL TWA (mg/m³) 0.02 mg/m³ Québec VEMP (mg/m³) 0.02 mg/m³ Saskatchewan OEL STEL (mg/m³) 0.06 mg/m³ Saskatchewan OEL TWA (mg/m³) 0.02 mg/m³ Yukon OEL STEL (mg/m³) 0.15 mg/m³ (dust and fume) Yukon OEL TWA (mg/m³) 0.05 mg/m³ (dust and fume) Carbon ( ) Mexico OEL TWA (mg/m³) 2 mg/m³ (dust) Silicon ( ) Mexico OEL TWA (mg/m³) 10 mg/m³ (inhalable fraction) Mexico OEL STEL (mg/m³) 20 mg/m³ USA OSHA OSHA PEL (TWA) (mg/m³) 15 mg/m³ (total dust) 5 mg/m³ (respirable fraction) USA NIOSH NIOSH REL (TWA) (mg/m³) 10 mg/m³ (total dust) 5 mg/m³ (respirable dust) British Columbia OEL TWA (mg/m³) 10 mg/m³ (total dust) New Brunswick OEL TWA (mg/m³) 10 mg/m³ Nunavut OEL TWA (mg/m³) 5 mg/m³ (respirable mass) Northwest Territories OEL TWA (mg/m³) 5 mg/m³ (respirable mass) Ontario OEL TWA (mg/m³) 10 mg/m³ (total dust) Québec VEMP (mg/m³) 10 mg/m³ (containing no Asbestos and <1% Crystalline silica-total dust) Saskatchewan OEL STEL (mg/m³) 20 mg/m³ Saskatchewan OEL TWA (mg/m³) 10 mg/m³ Yukon OEL STEL (mg/m³) 20 mg/m³ Yukon OEL TWA (mg/m³) 30 mppcf 12/15/2014 EN (English US) 8/20

15 Stainless Steel and Alloys of Stainless Steel According To Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules And Regulations Tungsten ( ) USA ACGIH ACGIH TWA (mg/m³) 5 mg/m³ USA ACGIH ACGIH STEL (mg/m³) 10 mg/m³ USA NIOSH NIOSH REL (TWA) (mg/m³) 5 mg/m³ USA NIOSH NIOSH REL (STEL) (mg/m³) 10 mg/m³ Alberta OEL STEL (mg/m³) 10 mg/m³ Alberta OEL TWA (mg/m³) 5 mg/m³ British Columbia OEL STEL (mg/m³) 10 mg/m³ British Columbia OEL TWA (mg/m³) 5 mg/m³ Manitoba OEL STEL (mg/m³) 10 mg/m³ Manitoba OEL TWA (mg/m³) 5 mg/m³ Newfoundland & Labrador OEL STEL (mg/m³) 10 mg/m³ Newfoundland & Labrador OEL TWA (mg/m³) 5 mg/m³ Nova Scotia OEL STEL (mg/m³) 10 mg/m³ Nova Scotia OEL TWA (mg/m³) 5 mg/m³ Nunavut OEL STEL (mg/m³) 10 mg/m³ Nunavut OEL TWA (mg/m³) 5 mg/m³ Northwest Territories OEL STEL (mg/m³) 10 mg/m³ Northwest Territories OEL TWA (mg/m³) 5 mg/m³ Ontario OEL STEL (mg/m³) 10 mg/m³ Ontario OEL TWA (mg/m³) 5 mg/m³ Prince Edward Island OEL STEL (mg/m³) 10 mg/m³ Prince Edward Island OEL TWA (mg/m³) 5 mg/m³ Saskatchewan OEL STEL (mg/m³) 10 mg/m³ Saskatchewan OEL TWA (mg/m³) 5 mg/m³ Yukon OEL STEL (mg/m³) 10 mg/m³ Yukon OEL TWA (mg/m³) 5 mg/m³ Aluminum ( ) Mexico OEL TWA (mg/m³) 10 mg/m³ (dust) USA ACGIH ACGIH TWA (mg/m³) 1 mg/m³ (respirable fraction) USA OSHA OSHA PEL (TWA) (mg/m³) 15 mg/m³ (total dust) 5 mg/m³ (respirable fraction) USA NIOSH NIOSH REL (TWA) (mg/m³) 10 mg/m³ (total dust) 5 mg/m³ (respirable dust) Alberta OEL TWA (mg/m³) 10 mg/m³ (dust) British Columbia OEL TWA (mg/m³) 1.0 mg/m³ (respirable) Manitoba OEL TWA (mg/m³) 1 mg/m³ (respirable fraction) New Brunswick OEL TWA (mg/m³) 10 mg/m³ (metal dust) Newfoundland & Labrador OEL TWA (mg/m³) 1 mg/m³ (respirable fraction) Nova Scotia OEL TWA (mg/m³) 1 mg/m³ (respirable fraction) Nunavut OEL STEL (mg/m³) 20 mg/m³ Nunavut OEL TWA (mg/m³) 10 mg/m³ Northwest Territories OEL STEL (mg/m³) 20 mg/m³ Northwest Territories OEL TWA (mg/m³) 10 mg/m³ Ontario OEL TWA (mg/m³) 1 mg/m³ (respirable) Prince Edward Island OEL TWA (mg/m³) 1 mg/m³ (respirable fraction) Québec VEMP (mg/m³) 10 mg/m³ Saskatchewan OEL STEL (mg/m³) 20 mg/m³ (dust) Saskatchewan OEL TWA (mg/m³) 10 mg/m³ (dust) Tantalum ( ) Mexico OEL TWA (mg/m³) 5 mg/m³ 12/15/2014 EN (English US) 9/20

16 Stainless Steel and Alloys of Stainless Steel According To Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules And Regulations Mexico OEL STEL (mg/m³) 10 mg/m³ USA OSHA OSHA PEL (TWA) (mg/m³) 5 mg/m³ USA NIOSH NIOSH REL (TWA) (mg/m³) 5 mg/m³ (dust) USA NIOSH NIOSH REL (STEL) (mg/m³) 10 mg/m³ (dust) USA IDLH US IDLH (mg/m³) 2500 mg/m³ (dust) Alberta OEL TWA (mg/m³) 5 mg/m³ (dust) British Columbia OEL TWA (mg/m³) 5 mg/m³ New Brunswick OEL TWA (mg/m³) 5 mg/m³ (dust) Nunavut OEL STEL (mg/m³) 10 mg/m³ Nunavut OEL TWA (mg/m³) 5 mg/m³ Northwest Territories OEL STEL (mg/m³) 10 mg/m³ Northwest Territories OEL TWA (mg/m³) 5 mg/m³ Québec VEMP (mg/m³) 5 mg/m³ (dust) Saskatchewan OEL STEL (mg/m³) 10 mg/m³ Saskatchewan OEL TWA (mg/m³) 5 mg/m³ Yukon OEL STEL (mg/m³) 10 mg/m³ Yukon OEL TWA (mg/m³) 5 mg/m³ Selenium ( ) USA ACGIH ACGIH TWA (mg/m³) 0.2 mg/m³ USA NIOSH NIOSH REL (TWA) (mg/m³) 0.2 mg/m³ USA IDLH US IDLH (mg/m³) 1 mg/m³ Alberta OEL TWA (mg/m³) 0.2 mg/m³ British Columbia OEL TWA (mg/m³) 0.1 mg/m³ Manitoba OEL TWA (mg/m³) 0.2 mg/m³ New Brunswick OEL TWA (mg/m³) 0.2 mg/m³ Newfoundland & Labrador OEL TWA (mg/m³) 0.2 mg/m³ Nova Scotia OEL TWA (mg/m³) 0.2 mg/m³ Ontario OEL TWA (mg/m³) 0.2 mg/m³ Prince Edward Island OEL TWA (mg/m³) 0.2 mg/m³ Québec VEMP (mg/m³) 0.2 mg/m³ Saskatchewan OEL STEL (mg/m³) 0.6 mg/m³ Saskatchewan OEL TWA (mg/m³) 0.2 mg/m³ 8.2. Exposure Controls Appropriate Engineering Controls Use local exhaust or general dilution ventilation or other suppression methods to maintain dust levels below exposure limits. Power equipment should be equipped with proper dust collection devices. Ensure all national/local regulations are observed. Personal Protective Equipment Protective clothing. Gloves. Safety glasses. Dust formation dust mask. Insufficient ventilation wear respiratory protection. Materials for Protective Clothing Chemically resistant materials and fabrics. With molten material wear thermally protective clothing. Hand Protection Wear chemically resistant protective gloves. If material is hot, wear thermally resistant protective gloves. Eye Protection Chemical goggles or safety glasses. Skin and Body Protection Wear suitable protective clothing. Wash contaminated clothing before reuse. Respiratory Protection Use a NIOSH-approved respirator or self-contained breathing apparatus whenever exposure may exceed established Occupational Exposure Limits. 12/15/2014 EN (English US) 10/20

17 Stainless Steel and Alloys of Stainless Steel According To Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules And Regulations SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on Basic Physical and Chemical Properties Physical State Solid Appearance Metallic Odor Odorless Odor Threshold Not available ph Not available Evaporation Rate Not available Melting Point 1300 C (2372 F) Freezing Point Not available Boiling Point Not available Flash Point Not applicable Auto-ignition Temperature Not available Decomposition Temperature Not available Flammability (solid, gas) Not available Lower Flammable Limit Not available Upper Flammable Limit Not available Vapor Pressure Not available Relative Vapor Density at 20 C Not available Relative Density Not available Specific Gravity 7.9 Solubility Insoluble in water Partition Coefficient N-octanol/water Not available Viscosity Not available Explosion Data Sensitivity to Mechanical Impact Not expected to present an explosion hazard due to mechanical impact. Explosion Data Sensitivity to Static Discharge Not expected to present an explosion hazard due to static discharge. SECTION 10 STABILITY AND REACTIVITY Reactivity Hazardous reactions will not occur under normal conditions Chemical Stability Stable under recommended handling and storage conditions (see section 7) Possibility of Hazardous Reactions Hazardous polymerization will not occur Conditions to Avoid Avoid creating or spreading dust. Sparks, heat, open flame and other sources of ignition Incompatible Materials When molten water. Strong acids, strong bases, strong oxidizers. Alkalis. Metal oxides. Moisture. Corrosive substances in contact with metals may produce flammable hydrogen gas Hazardous Decomposition Products Oxides of iron and carbon. Organic acid vapors. Chromium (VI) compounds. Sulfur compounds. SECTION 11 TOXICOLOGICAL INFORMATION Information on Toxicological Effects - Product Acute Toxicity Not classified. Not classified. LD50 and LC50 Data Not available Skin Corrosion/Irritation Not classified. Serious Eye Damage/Irritation Not classified. Respiratory or Skin Sensitization Not classified. Not classified. Germ Cell Mutagenicity Not classified Teratogenicity Not classified Carcinogenicity Not classified. Specific Target Organ Toxicity (Repeated Exposure) Not classified. Reproductive Toxicity Not classified. Specific Target Organ Toxicity (Single Exposure) Not classified Aspiration Hazard Not classified 12/15/2014 EN (English US) 11/20

18 Stainless Steel and Alloys of Stainless Steel According To Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules And Regulations Symptoms/Injuries After Inhalation Inhalation of dusts and fumes can cause metal fume fever. Symptoms can include a metallic or sweet taste in the mouth, sweating, shivering, headache, throat irritation, fever, chills, thirstiness, muscle aches, nausea, vomiting, weakness, fatigue, and shortness of breath. Symptoms/Injuries After Skin Contact May cause an allergic skin reaction. Dust from physical alteration of this product causes skin irritation. Causes severe skin burns. Contact with fumes or metal powder will irritate skin. Contact with hot, molten metal will cause thermal burns. Dust may cause irritation in skin folds or by contact in combination with tight clothing. Mechanical damage via flying particles and chipped slag is possible. Symptoms/Injuries After Eye Contact Dust may cause mechanical irritation to eyes, nose, throat, and lungs. Symptoms/Injuries After Ingestion Ingestion is likely to be harmful or have adverse effects. Chronic Symptoms In massive form, no hazard exists. If physically altered to present slivers, ribbons, dusts or fumes from molten material Aluminum Inhalation of finely divided aluminum powder may cause pulmonary fibrosis. Inhalation of iron oxide fumes undergoing decomposition may cause irritation and flu-like symptoms, otherwise iron oxide is not hazardous. Inhalation of Nickel compounds has been shown in studies to provide an increased incidence of cancer of the nasal cavity, lung and possibly larynx in nickel refinery workers. Nickel May cause a form of dermatitis known as nickel itch and intestinal irritation, which may cause disorders, convulsions and asphyxia. Chromium Certain hexavalent chromium compounds have been demonstrated to be carcinogenic on the basis of epidemiological investigations on workers and experimental studies in animals. Increased incidences of respiratory cancer have been found in chromium (VI) workers.there is an increased incidence of lung cancer in industrial workers exposed to chromium (VI) compounds. Please refer to IARC volume 23 for a more detailed discussion. Manganese Chronic exposure can cause inflammation of the lung tissue, scarring the lungs (pulmonary fibrosis). Copper Overexposure to fumes may cause metal fume fever (chills, muscle aches, nausea, fever, dry throat, cough, weakness, lassitude); metallic or sweet taste; discoloration of skin and hair. Tissue damage of mucous membranes may follow chronic dust exposure. Silicon Can cause chronic bronchitis and narrowing of the airways Information on Toxicological Effects - Ingredient(s) LD50 and LC50 Data Chromium ( ) LD50 Oral Rat > 5000 mg/kg Nickel ( ) LD50 Oral Rat Manganese ( ) LD50 Oral Rat Molybdenum ( ) LD50 Oral Rat LD50 Dermal Rat Sulfur dioxide ( ) LC50 Inhalation Rat ATE US (gases) > 9000 mg/kg > 2000 mg/kg > 2000 mg/kg > 2000 mg/kg 2500 ppm/1h 1, ppmv/4h Phosphorus elemental ( ) LD50 Oral Rat 3.03 mg/kg LD50 Dermal Rat 100 mg/kg LC50 Inhalation Rat 4.3 mg/l (Exposure time 1 h) Cobalt ( ) LD50 Oral Rat mg/kg LC50 Inhalation Rat > 10 mg/l (Exposure time 1 h) ATE US (dust, mist) 0.01 mg/l/4h Carbon ( ) LD50 Oral Rat Niobium ( ) LD50 Oral Rat > mg/kg > 10 g/kg 12/15/2014 EN (English US) 12/20

19 Stainless Steel and Alloys of Stainless Steel According To Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules And Regulations Selenium ( ) ATE US (oral) ATE US (dust, mist) Chromium ( ) IARC Group 3 Nickel ( ) IARC Group National Toxicity Program (NTP) Status Sulfur dioxide ( ) IARC Group 3 Cobalt ( ) IARC Group Selenium ( ) IARC Group 3 SECTION 12 ECOLOGICAL INFORMATION Toxicity No additional information available Nickel ( ) LC50 Fish 1 EC50 Daphnia 1 LC 50 Fish 2 EC50 Daphnia 2 EC50 Other Aquatic Organisms 2 Manganese ( ) NOEC chronic fish Copper ( ) LC50 Fish 1 EC50 Daphnia 1 EC50 Other Aquatic Organisms 1 LC 50 Fish 2 EC50 Other Aquatic Organisms mg/kg body weight 0.50 mg/l/4h 2B Reasonably anticipated to be Human Carcinogen. 2B 100 mg/l (Exposure time 96 h - Species Brachydanio rerio) 13 (13-200) μg/l (Exposure time 48h - Species Ceriodaphnia dubia [static]) 1.3 mg/l (Exposure time 96 h - Species Cyprinus carpio [semi-static]) 1 mg/l (Exposure time 48 h - Species Daphnia magna [Static]) ( ) mg/l (Exposure time 96 h - Species Pseudokirchneriella subcapitata [static]) 3.6 mg/l (Exposure time 96h; Species Oncorhynchus mykiss) <= ( ) mg/l (Exposure time 96 h - Species Pimephales promelas) 0.03 mg/l (Exposure time 48 h - Species Daphnia magna [Static]) ( ) mg/l (Exposure time 72 h - Species Pseudokirchneriella subcapitata [static]) 0.3 mg/l (Exposure time 96 h - Species Pimephales promelas [static]) ( ) mg/l (Exposure time 96 h - Species Pseudokirchneriella subcapitata [static]) Cobalt ( ) LC50 Fish mg/l (Exposure time 96 h - Species Brachydanio rerio [static]) Persistence and Degradability Stainless Steel and Alloys of Stainless Steel Persistence and Degradability Not established. Copper ( ) Persistence and Degradability Not readily biodegradable Bioaccumulative Potential Stainless Steel and Alloys of Stainless Steel Bioaccumulative Potential Not established. Sulfur dioxide ( ) BCF Fish 1 (no bioaccumulation expected) Cobalt ( ) BCF Fish 1 (no bioaccumulation) Mobility in Soil Not available 12/15/2014 EN (English US) 13/20

20 Stainless Steel and Alloys of Stainless Steel According To Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules And Regulations Other Adverse Effects Other Information Avoid release to the environment. SECTION 13 DISPOSAL CONSIDERATIONS Waste treatment methods Waste Treatment Methods Recycle product or dispose properly. Waste Disposal Recommendations Dispose of waste material in accordance with all local, regional, national, and international regulations. SECTION 14 TRANSPORT INFORMATION In Accordance with DOT Not regulated for transport In Accordance with IMDG Not regulated for transport In Accordance with IATA Not regulated for transport In Accordance with TDG Not regulated for transport SECTION 15 REGULATORY INFORMATION US Federal Regulations Stainless Steel and Alloys of Stainless Steel SARA Section 311/312 Hazard Classes Iron ( ) Listed on the United States TSCA (Toxic Substances Control Act) inventory Chromium ( ) Listed on the United States TSCA (Toxic Substances Control Act) inventory Listed on United States SARA Section 313 SARA Section Emission Reporting 1.0 % Nickel ( ) Listed on the United States TSCA (Toxic Substances Control Act) inventory Listed on United States SARA Section 313 RQ (Reportable Quantity, Section 304 of EPA's List of Lists) 100 lb (only applicable if particles are < 100 µm) SARA Section Emission Reporting 0.1 % Manganese ( ) Listed on the United States TSCA (Toxic Substances Control Act) inventory Listed on United States SARA Section 313 SARA Section Emission Reporting 1.0 % Molybdenum ( ) Listed on the United States TSCA (Toxic Substances Control Act) inventory Titanium ( ) Listed on the United States TSCA (Toxic Substances Control Act) inventory Copper ( ) Listed on the United States TSCA (Toxic Substances Control Act) inventory Listed on United States SARA Section 313 SARA Section Emission Reporting 1.0 % Sulfur dioxide ( ) Listed on the United States TSCA (Toxic Substances Control Act) inventory Listed on the United States SARA Section 302 SARA Section 302 Threshold Planning Quantity (TPQ) 500 Phosphorus elemental ( ) Listed on the United States TSCA (Toxic Substances Control Act) inventory Listed on the United States SARA Section 302 Listed on United States SARA Section 313 SARA Section 302 Threshold Planning Quantity (TPQ) Delayed (chronic) health hazard 100 (This material is a reactive solid. The TPQ does not default to pounds for non-powder, non-molten, non-solution form) 12/15/2014 EN (English US) 14/20

21 Stainless Steel and Alloys of Stainless Steel According To Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules And Regulations SARA Section Emission Reporting Cobalt ( ) Listed on the United States TSCA (Toxic Substances Control Act) inventory Listed on United States SARA Section 313 SARA Section Emission Reporting 0.1 % Carbon ( ) Listed on the United States TSCA (Toxic Substances Control Act) inventory Silicon ( ) Listed on the United States TSCA (Toxic Substances Control Act) inventory Tungsten ( ) Listed on the United States TSCA (Toxic Substances Control Act) inventory Niobium ( ) Listed on the United States TSCA (Toxic Substances Control Act) inventory 1.0 % (yellow or white) Aluminum ( ) Listed on the United States TSCA (Toxic Substances Control Act) inventory Listed on United States SARA Section 313 SARA Section Emission Reporting 1.0 % (dust or fume only) Tantalum ( ) Listed on the United States TSCA (Toxic Substances Control Act) inventory Selenium ( ) Listed on the United States TSCA (Toxic Substances Control Act) inventory Listed on United States SARA Section 313 SARA Section Emission Reporting 1.0 % US State Regulations Nickel ( ) U.S. - California - Proposition 65 - Carcinogens List Sulfur dioxide ( ) U.S. - California - Proposition 65 - Developmental Toxicity Cobalt ( ) U.S. - California - Proposition 65 - Carcinogens List Chromium ( ) U.S. - Massachusetts - Right To Know List U.S. - New Jersey - Right to Know Hazardous Substance List U.S. - Pennsylvania - RTK (Right to Know) - Environmental Hazard List U.S. - Pennsylvania - RTK (Right to Know) - Special Hazardous Substances U.S. - Pennsylvania - RTK (Right to Know) List Nickel ( ) U.S. - Massachusetts - Right To Know List U.S. - New Jersey - Right to Know Hazardous Substance List U.S. - Pennsylvania - RTK (Right to Know) - Environmental Hazard List U.S. - Pennsylvania - RTK (Right to Know) - Special Hazardous Substances U.S. - Pennsylvania - RTK (Right to Know) List Manganese ( ) U.S. - Massachusetts - Right To Know List U.S. - New Jersey - Right to Know Hazardous Substance List U.S. - Pennsylvania - RTK (Right to Know) - Environmental Hazard List WARNING This product contains chemicals known to the State of California to cause cancer. WARNING This product contains chemicals known to the State of California to cause birth defects. WARNING This product contains chemicals known to the State of California to cause cancer. 12/15/2014 EN (English US) 15/20

22 Stainless Steel and Alloys of Stainless Steel According To Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules And Regulations U.S. - Pennsylvania - RTK (Right to Know) List Molybdenum ( ) U.S. - Massachusetts - Right To Know List U.S. - New Jersey - Right to Know Hazardous Substance List U.S. - Pennsylvania - RTK (Right to Know) List Titanium ( ) U.S. - New Jersey - Right to Know Hazardous Substance List Copper ( ) U.S. - Massachusetts - Right To Know List U.S. - New Jersey - Right to Know Hazardous Substance List U.S. - Pennsylvania - RTK (Right to Know) - Environmental Hazard List U.S. - Pennsylvania - RTK (Right to Know) List Sulfur dioxide ( ) U.S. - Massachusetts - Right To Know List U.S. - New Jersey - Right to Know Hazardous Substance List U.S. - Pennsylvania - RTK (Right to Know) - Environmental Hazard List U.S. - Pennsylvania - RTK (Right to Know) List Phosphorus elemental ( ) U.S. - Massachusetts - Right To Know List U.S. - New Jersey - Right to Know Hazardous Substance List U.S. - Pennsylvania - RTK (Right to Know) - Environmental Hazard List U.S. - Pennsylvania - RTK (Right to Know) List Cobalt ( ) U.S. - Massachusetts - Right To Know List U.S. - New Jersey - Right to Know Hazardous Substance List U.S. - Pennsylvania - RTK (Right to Know) - Environmental Hazard List U.S. - Pennsylvania - RTK (Right to Know) List Silicon ( ) U.S. - Massachusetts - Right To Know List U.S. - New Jersey - Right to Know Hazardous Substance List U.S. - Pennsylvania - RTK (Right to Know) List Tungsten ( ) U.S. - Massachusetts - Right To Know List U.S. - New Jersey - Right to Know Hazardous Substance List U.S. - Pennsylvania - RTK (Right to Know) List Aluminum ( ) U.S. - Massachusetts - Right To Know List U.S. - New Jersey - Right to Know Hazardous Substance List U.S. - Pennsylvania - RTK (Right to Know) - Environmental Hazard List U.S. - Pennsylvania - RTK (Right to Know) List Tantalum ( ) U.S. - Massachusetts - Right To Know List U.S. - New Jersey - Right to Know Hazardous Substance List U.S. - Pennsylvania - RTK (Right to Know) List Selenium ( ) U.S. - Massachusetts - Right To Know List U.S. - New Jersey - Right to Know Hazardous Substance List U.S. - Pennsylvania - RTK (Right to Know) - Environmental Hazard List U.S. - Pennsylvania - RTK (Right to Know) List Canadian Regulations Stainless Steel and Alloys of Stainless Steel 12/15/2014 EN (English US) 16/20

23 Stainless Steel and Alloys of Stainless Steel According To Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules And Regulations WHMIS Classification Iron ( ) Listed on the Canadian DSL (Domestic Substances List) WHMIS Classification Class B Division 4 - Flammable Solid Chromium ( ) Listed on the Canadian DSL (Domestic Substances List) Listed on the Canadian IDL (Ingredient Disclosure List) IDL Concentration 0.1 % WHMIS Classification Uncontrolled product according to WHMIS classification criteria Nickel ( ) Listed on the Canadian DSL (Domestic Substances List) Listed on the Canadian IDL (Ingredient Disclosure List) IDL Concentration 0.1 % WHMIS Classification Class D Division 2 Subdivision B - Toxic material causing other toxic effects Manganese ( ) Listed on the Canadian DSL (Domestic Substances List) Listed on the Canadian IDL (Ingredient Disclosure List) IDL Concentration 1 % WHMIS Classification Uncontrolled product according to WHMIS classification criteria Molybdenum ( ) Listed on the Canadian DSL (Domestic Substances List) Listed on the Canadian IDL (Ingredient Disclosure List) IDL Concentration 1 % WHMIS Classification Uncontrolled product according to WHMIS classification criteria Titanium ( ) Listed on the Canadian DSL (Domestic Substances List) Copper ( ) Listed on the Canadian DSL (Domestic Substances List) Listed on the Canadian IDL (Ingredient Disclosure List) IDL Concentration 1 % WHMIS Classification Uncontrolled product according to WHMIS classification criteria Sulfur dioxide ( ) Listed on the Canadian DSL (Domestic Substances List) Listed on the Canadian IDL (Ingredient Disclosure List) IDL Concentration 1 % WHMIS Classification Phosphorus elemental ( ) Listed on the Canadian DSL (Domestic Substances List) Listed on the Canadian IDL (Ingredient Disclosure List) IDL Concentration 1 % WHMIS Classification Cobalt ( ) Listed on the Canadian DSL (Domestic Substances List) Uncontrolled product according to WHMIS classification criteria Class A - Compressed Gas Class D Division 1 Subdivision A - Very toxic material causing immediate and serious toxic effects Class D Division 2 Subdivision B - Toxic material causing other toxic effects Class E - Corrosive Material Class B Division 4 - Flammable Solid Class D Division 1 Subdivision A - Very toxic material causing immediate and serious toxic effects Class E - Corrosive Material 12/15/2014 EN (English US) 17/20

24 Stainless Steel and Alloys of Stainless Steel According To Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules And Regulations Listed on the Canadian IDL (Ingredient Disclosure List) IDL Concentration 0.1 % WHMIS Classification Class D Division 2 Subdivision A - Very toxic material causing other toxic effects Class D Division 2 Subdivision B - Toxic material causing other toxic effects Carbon ( ) Listed on the Canadian DSL (Domestic Substances List) WHMIS Classification Uncontrolled product according to WHMIS classification criteria Silicon ( ) Listed on the Canadian DSL (Domestic Substances List) WHMIS Classification Uncontrolled product according to WHMIS classification criteria Tungsten ( ) Listed on the Canadian DSL (Domestic Substances List) Listed on the Canadian IDL (Ingredient Disclosure List) IDL Concentration 1 % WHMIS Classification Uncontrolled product according to WHMIS classification criteria Niobium ( ) Listed on the Canadian DSL (Domestic Substances List) WHMIS Classification Uncontrolled product according to WHMIS classification criteria Aluminum ( ) Listed on the Canadian DSL (Domestic Substances List) Listed on the Canadian IDL (Ingredient Disclosure List) IDL Concentration 1 % WHMIS Classification Class B Division 6 - Reactive Flammable Material Class B Division 4 - Flammable Solid Tantalum ( ) Listed on the Canadian DSL (Domestic Substances List) Listed on the Canadian IDL (Ingredient Disclosure List) IDL Concentration 1 % WHMIS Classification Uncontrolled product according to WHMIS classification criteria Selenium ( ) Listed on the Canadian DSL (Domestic Substances List) Listed on the Canadian IDL (Ingredient Disclosure List) IDL Concentration 0.1 % WHMIS Classification Class D Division 1 Subdivision B - Toxic material causing immediate and serious toxic effects Class D Division 2 Subdivision B - Toxic material causing other toxic effects This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the SDS contains all of the information required by CPR. SECTION 16 OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Revision Date 12/15/2014 Other Information GHS Full Text Phrases Acute Tox. 1 (Inhalationdust,mist) Acute Tox. 3 (Inhalationdust,mist) This document has been prepared in accordance with the SDS requirements of the OSHA Hazard Communication Standard 29 CFR Acute toxicity (inhalationdust,mist) Category 1 Acute toxicity (inhalationdust,mist) Category Acute Tox. 3 (Inhalationgas) Acute toxicity (inhalationgas) Category Acute Tox. 3 (Oral) Acute toxicity (oral) Category 3 12/15/2014 EN (English US) 18/20

25 Stainless Steel and Alloys of Stainless Steel According To Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules And Regulations Acute Tox. 4 (Oral) Acute toxicity (oral) Category Aquatic Acute 1 Hazardous to the aquatic environment - Acute Hazard Category Aquatic Acute 3 Hazardous to the aquatic environment - Acute Hazard Category Aquatic Chronic 1 Hazardous to the aquatic environment - Chronic Hazard Category Aquatic Chronic 3 Hazardous to the aquatic environment - Chronic Hazard Category Aquatic Chronic 4 Hazardous to the aquatic environment - Chronic Hazard Category Carc. 2 Carcinogenicity Category Comb. Dust Combustible Dust Compressed gas Gases under pressure Compressed gas Eye Dam. 1 Serious eye damage/eye irritation Category Eye Irrit. 2A Serious eye damage/eye irritation Category 2A Flam. Sol. 1 Flammable solids Category Repr. 2 Reproductive toxicity Category Resp. Sens. 1B Respiratory sensitisation Category 1B Self-heat. 2 Self-heating substances and mixtures Category Skin Corr. 1B Skin corrosion/irritation Category 1B Skin Sens. 1 Skin sensitization Category STOT RE 1 Specific target organ toxicity (repeated exposure) Category STOT RE 2 Specific target organ toxicity (repeated exposure) Category Water-react. 2 Substances and mixtures which in contact with water emit flammable gases Category H228 Flammable solid May form combustible dust concentrations in air H252 Self-heating in large quantities; may catch fire H261 In contact with water releases flammable gases H280 Contains gas under pressure; may explode if heated H301 Toxic if swallowed H302 Harmful if swallowed H314 Causes severe skin burns and eye damage H317 May cause an allergic skin reaction H318 Causes serious eye damage H319 Causes serious eye irritation H330 Fatal if inhaled H331 Toxic if inhaled H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled H351 Suspected of causing cancer H361 Suspected of damaging fertility or the unborn child H372 Causes damage to organs through prolonged or repeated exposure H373 May cause damage to organs through prolonged or repeated exposure H400 Very toxic to aquatic life H402 Harmful to aquatic life H410 Very toxic to aquatic life with long lasting effects H412 Harmful to aquatic life with long lasting effects H413 May cause long lasting harmful effects to aquatic life Party Responsible for the Preparation of This Document ThyssenKrupp Materials NA, Inc W. Eleven Mile Road Southfield, Michigan TEL /15/2014 EN (English US) 19/20

26 Stainless Steel and Alloys of Stainless Steel According To Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules And Regulations This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product. North America GHS US 2012 & WHMIS 2 12/15/2014 EN (English US) 20/20

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30 SECTION 1 Identification 1.1. Identification Product form Product name Product code Epic S7295B according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations Revision date 09/26/2016 Mixture Epic S7295B S7295B 1.2. Relevant identified uses of the substance or mixture and uses advised against No additional information available 1.3. Details of the supplier of the safety data sheet Epic Resins 600 Industrial Blvd. Palmyra, WI USA T Emergency telephone number Emergency number CHEMTREC SECTION 2 Hazard(s) identification 2.1. Classification of the substance or mixture Classification (GHS-US) Skin corrosion/irritation Category 1B Skin sensitization Category 1 Full text of H statements see section Label elements GHS-US labeling H314 H317 Hazard pictograms (GHS-US) Signal word (GHS-US) Hazard statements (GHS-US) Precautionary statements (GHS-US) Danger GHS05 GHS07 GHS09 H314 - Causes severe skin burns and eye damage H317 - May cause an allergic skin reaction P262 - Do not get in eyes, on skin, or on clothing P261 - Avoid breathing vapors P264 - Wash hands, forearms and face thoroughly after handling P272 - Contaminated work clothing must not be allowed out of the workplace P280 - Wear eye protection, protective gloves P301+P330+P331 - If swallowed rinse mouth. Do NOT induce vomiting P302+P352 - If on skin Wash with plenty of soap and water P303+P361+P353 - If on skin (or hair) Take off immediately all contaminated clothing. Rinse skin with water/shower P304+P340 - If inhaled Remove person to fresh air and keep comfortable for breathing P305+P351+P338 - If in eyes Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P333+P313 - If skin irritation or rash occurs Get medical advice/attention P363 - Wash contaminated clothing before reuse P273 - Avoid release to the environment P501 - Dispose of contents/container to.. P270 - Do not eat, drink or smoke when using this product 2.3. Other hazards No additional information available 2.4. Unknown acute toxicity (GHS US) Not applicable 09/26/2016 EN (English US) Page 1

31 Epic S7295B according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations SECTION 3 Composition/information on ingredients 3.1. Substance Not applicable 3.2. Mixture Name Product identifier % Classification (GHS-US) Calicum Carbonate (CAS No) Not classified Polymers of tofa with linoleic acid dimers (CAS No) Not classified Nonyl Phenol (CAS No) Acute Tox. 4 (Oral), H302 Skin Corr. 1B, H314 Aquatic Acute 1, H400 Aquatic Chronic 1, H410 Silicon Dioxide (CAS No) Not classified Tetraethylenepentamine (CAS No) Acute Tox. 4 (Oral), H302 Acute Tox. 3 (Dermal), H311 Skin Corr. 1A, H314 Skin Sens. 1, H317 Aquatic Chronic 2, H411 N-Aminoethylpiperazine (CAS No) Flam. Liq. 4, H227 Acute Tox. 4 (Oral), H302 Acute Tox. 4 (Dermal), H312 Skin Corr. 1A, H314 Skin Sens. 1, H317 Aquatic Chronic 3, H412 Carbon Black (CAS No) < 1 Carc. 2, H351 Full text of classification categories and H statements see section 16 SECTION 4 First aid measures 4.1. Description of first aid measures First-aid measures general First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact Never give anything by mouth to an unconscious person. Remove the victim into fresh air. Gently wash with plenty of soap and water. IF IN EYES Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing Most important symptoms and effects, both acute and delayed Symptoms/injuries Skin rash/inflammation. Symptoms/injuries after skin contact Causes skin irritation. Symptoms/injuries after eye contact Causes eye irritation Indication of any immediate medical attention and special treatment needed No additional information available SECTION 5 Firefighting measures 5.1. Extinguishing media Suitable extinguishing media ABC powder. Dry powder. Water spray Special hazards arising from the substance or mixture Reactivity The product is non-reactive under normal conditions of use, storage and transport Advice for firefighters No additional information available SECTION 6 Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures For non-emergency personnel Protective equipment EN 166. Gloves For emergency responders No additional information available 6.2. Environmental precautions Avoid release to the environment. 09/26/2016 EN (English US) 2/9

32 Epic S7295B according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 6.3. Methods and material for containment and cleaning up For containment Methods for cleaning up 6.4. Reference to other sections No additional information available SECTION 7 Handling and storage 7.1. Precautions for safe handling No additional information available Collect spillage. Absorb spillage to prevent material damage Conditions for safe storage, including any incompatibilities Maximum storage period 12 months Storage temperature 25 C SECTION 8 Exposure controls/personal protection 8.1. Control parameters N-Aminoethylpiperazine ( ) Not applicable Nonyl Phenol ( ) Not applicable Carbon Black ( ) ACGIH ACGIH TWA (mg/m³) 3 mg/m³ (Carbon black; USA; Time-weighted average exposure limit 8 h; TLV - Adopted Value; Inhalable fraction) Not applicable Calicum Carbonate ( ) Not applicable Silicon Dioxide ( ) Not applicable Polymers of tofa with linoleic acid dimers ( ) Not applicable Tetraethylenepentamine ( ) Not applicable 8.2. Exposure controls Materials for protective clothing Hand protection Eye protection butyl rubber. neoprene. nitrile rubber. Gloves. Safety glasses. SECTION 9 Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state Color Odor Odor threshold ph Melting point Freezing point Liquid dark gray There may be no odour warning properties, odour is subjective and inadequate to warn of overexposure. Mixture contains one or more component(s) which have the following odour(s) Ammonia odour Odourless Phenol odour Irritating/pungent odour Smell of fish No data available No data available No data available No data available Boiling point > 200 C 09/26/2016 EN (English US) 3/9

33 Epic S7295B according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations Flash point > 195 C Relative evaporation rate (butyl acetate=1) Flammability (solid, gas) Vapor pressure Relative vapor density at 20 C Relative density Specific gravity / density 1.42 Solubility Log Pow Auto-ignition temperature Decomposition temperature Viscosity, kinematic Viscosity, dynamic Explosion limits Explosive properties Oxidizing properties 9.2. Other information No additional information available SECTION 10 Stability and reactivity Reactivity No data available No data available < 1 mm Hg No data available No data available No data available No data available No data available No data available No data available cp No data available No data available No data available The product is non-reactive under normal conditions of use, storage and transport Chemical stability Stable under normal conditions Possibility of hazardous reactions No additional information available Conditions to avoid No additional information available Incompatible materials No additional information available Hazardous decomposition products No additional information available SECTION 11 Toxicological information Information on toxicological effects Acute toxicity N-Aminoethylpiperazine ( ) ATE US (oral) ATE US (dermal) Nonyl Phenol ( ) LD50 oral rat LD50 dermal rabbit ATE US (oral) Carbon Black ( ) LD50 oral rat LD50 dermal rabbit Calicum Carbonate ( ) LD50 oral rat ATE US (oral) Not classified mg/kg body weight mg/kg body weight mg/kg (Rat; Literature study) > 2000 mg/kg (Rabbit; Literature study) mg/kg body weight > 8000 mg/kg (Rat; Equivalent or similar to OECD 401; Experimental value) > 3000 mg/kg (Rabbit) 6450 mg/kg (Rat; Literature study) mg/kg body weight 09/26/2016 EN (English US) 4/9

34 Epic S7295B according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations Silicon Dioxide ( ) LD50 oral rat LD50 dermal rabbit ATE US (oral) Tetraethylenepentamine ( ) LD50 oral rat LD50 dermal rabbit ATE US (oral) ATE US (dermal) Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitization Germ cell mutagenicity Carcinogenicity 3160 mg/kg (Rat) > 5000 mg/kg (Rabbit) mg/kg body weight 3990 mg/kg (Rat; Literature study; 3250 mg/kg bodyweight; Rat; Literature study) 660 mg/kg (Rabbit; Literature study; mg/kg bodyweight; Rabbit; Literature study) mg/kg body weight mg/kg body weight Causes severe skin burns and eye damage. Not classified May cause an allergic skin reaction. Not classified Not classified Carbon Black ( ) IARC group Silicon Dioxide ( ) IARC group Reproductive toxicity Specific target organ toxicity (single exposure) 2B - Possibly carcinogenic to humans 3 - Not classifiable Not classified Not classified Specific target organ toxicity (repeated exposure) Not classified Aspiration hazard Symptoms/injuries after skin contact Symptoms/injuries after eye contact Not classified Causes skin irritation. Causes eye irritation. SECTION 12 Ecological information Toxicity N-Aminoethylpiperazine ( ) LC50 fish 1 EC50 Daphnia 1 Threshold limit algae 2 Nonyl Phenol ( ) EC50 Daphnia 1 LC50 fish 2 EC50 Daphnia 2 Threshold limit algae 1 Threshold limit algae 2 Carbon Black ( ) LC50 fish 1 EC50 Daphnia 1 LC50 fish 2 Threshold limit algae 1 > 100 mg/l (LC50; OECD 203 Fish, Acute Toxicity Test; 96 h; Oncorhynchus mykiss; Semistatic system; Fresh water; Experimental value) 58 mg/l (EC50; OECD 202 Daphnia sp. Acute Immobilisation Test; 48 h; Daphnia magna; Static system) > 1000 mg/l (EC50; OECD 201 Alga, Growth Inhibition Test; 72 h; Selenastrum capricornutum; Fresh water) 0.14 mg/l (EC50; 48 h; Daphnia magna) mg/l (LC50; 96 h; Salmo gairdneri; Static system; Fresh water) < 0.1 mg/l (EC0; 48 h; Daphnia magna) 1.3 mg/l (EC50; UBA; 72 h; Scenedesmus subspicatus) 0.5 mg/l (EC10; UBA; 72 h; Scenedesmus subspicatus) > 1000 mg/l (LC50; OECD 203 Fish, Acute Toxicity Test; 96 h; Brachydanio rerio) > 5600 mg/l (EC50; OECD 202 Daphnia sp. Acute Immobilisation Test; 24 h; Daphnia magna; Static system; Fresh water) 1000 mg/l (LC0; OECD 203 Fish, Acute Toxicity Test; 96 h; Brachydanio rerio; Semi-static system; Fresh water; Experimental value) > mg/l (EC50; OECD 201 Alga, Growth Inhibition Test; 72 h; Scenedesmus subspicatus; Static system; Fresh water; Experimental value) 09/26/2016 EN (English US) 5/9

35 Epic S7295B according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations Tetraethylenepentamine ( ) EC50 Daphnia 1 LC50 fish 2 Threshold limit algae 1 Threshold limit algae mg/l (EC50; EU Method C.2; 48 h; Daphnia magna; Static system) 420 mg/l (LC50; EU Method C.1; 96 h; Poecilia reticulata; Semi-static system; Fresh water; Experimental value) 0.5 mg/l (NOEC; OECD 201 Alga, Growth Inhibition Test; 72 h; Selenastrum capricornutum) 6.8 mg/l (EC50; OECD 201 Alga, Growth Inhibition Test; 72 h; Selenastrum capricornutum) Persistence and degradability N-Aminoethylpiperazine ( ) Persistence and degradability Chemical oxygen demand (COD) Nonyl Phenol ( ) Persistence and degradability ThOD Carbon Black ( ) Persistence and degradability ThOD Calicum Carbonate ( ) Persistence and degradability Biochemical oxygen demand (BOD) Chemical oxygen demand (COD) ThOD Silicon Dioxide ( ) Persistence and degradability Biochemical oxygen demand (BOD) Chemical oxygen demand (COD) ThOD Tetraethylenepentamine ( ) Persistence and degradability Not readily biodegradable in water. Low potential for mobility in soil g O₂/g substance Not readily biodegradable in water. Non degradable in the soil. Adsorbs into the soil. Photolysis in the air g O₂/g substance Biodegradability not applicable. Biodegradability in soil not applicable. Adsorbs into the soil. Not applicable Biodegradability not applicable. Not applicable Not applicable Not applicable Biodegradability not applicable. Not applicable Not applicable Not applicable Not readily biodegradable in water. Low potential for mobility in soil. Adsorbs into the soil Bioaccumulative potential N-Aminoethylpiperazine ( ) BCF fish 1 Log Pow <= >0.3<=6.3,BCF; OECD 305 Bioconcentration Flow-Through Fish Test; >4<=6 weeks; Cyprinus carpio; Flow-through system; Fresh water; Read-across (Experimental value; OECD 107 Partition Coefficient (n-octanol/water) Shake Flask Method; 20 C) Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4). Nonyl Phenol ( ) BCF fish (BCF; 20 days; Pimephales promelas; Fresh water) Log Pow 3.28 (Test data; OECD 107 Partition Coefficient (n-octanol/water) Shake Flask Method; 20 C) Bioaccumulative potential Low potential for bioaccumulation (BCF < 500). Carbon Black ( ) Bioaccumulative potential Calicum Carbonate ( ) Bioaccumulative potential Silicon Dioxide ( ) Bioaccumulative potential Not bioaccumulative. No bioaccumulation data available. Not bioaccumulative. Tetraethylenepentamine ( ) BCF other aquatic organisms (BCF) 09/26/2016 EN (English US) 6/9

36 Epic S7295B according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations Tetraethylenepentamine ( ) Log Pow (Calculated; EPIWIN) Bioaccumulative potential Low potential for bioaccumulation (BCF < 500) Mobility in soil N-Aminoethylpiperazine ( ) Log Koc Carbon Black ( ) Ecology - soil log Koc,4.57; Read-across; GLP Not toxic to plants. Not toxic to animals Other adverse effects Effect on the global warming GWPmix comment No known effects from this product. No known effects from this product. SECTION 13 Disposal considerations Waste treatment methods Waste disposal recommendations Dispose in a safe manner in accordance with local/national regulations. SECTION 14 Transport information Department of Transportation (DOT) In accordance with DOT Transport document description UN1760 Corrosive liquids, n.o.s. (Tetraethylenepentamine, Nonyl phenol), 8, III UN-No.(DOT) UN1760 Proper Shipping Name (DOT) Corrosive liquids, n.o.s. (Tetraethylenepentamine, Nonyl phenol) Class (DOT) 8 - Class 8 - Corrosive material 49 CFR Packing group (DOT) III - Minor Danger Hazard labels (DOT) 8 - Corrosive Marine pollutant Yes (IMDG only) DOT Packaging Non Bulk (49 CFR 173.xxx) 203 DOT Packaging Bulk (49 CFR 173.xxx) 241 DOT Symbols DOT Special Provisions (49 CFR ) DOT Packaging Exceptions (49 CFR 173.xxx) 154 G - Identifies PSN requiring a technical name IB3 - Authorized IBCs Metal (31A, 31B and 31N); Rigid plastics (31H1 and 31H2); Composite (31HZ1 and 31HA2, 31HB2, 31HN2, 31HD2 and 31HH2). Additional Requirement Only liquids with a vapor pressure less than or equal to 110 kpa at 50 C (1.1 bar at 122 F), or 130 kpa at 55 C (1.3 bar at 131 F) are authorized, except for UN2672 (also see Special Provision IP8 in Table 2 for UN2672) T (d)(2) Normal (d)(3) TP1 - The maximum degree of filling must not exceed the degree of filling determined by the following Degree of filling = 97 / 1 + a (tr - tf) Where tr is the maximum mean bulk temperature during transport, and tf is the temperature in degrees celsius of the liquid during filling TP28 - A portable tank having a minimum test pressure of 2.65 bar (265 kpa) may be used provided the calculated test pressure is 2.65 bar or less based on the MAWP of the hazardous material, as defined in of this subchapter, where the test pressure is 1.5 times the MAWP 09/26/2016 EN (English US) 7/9

37 Epic S7295B according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations DOT Quantity Limitations Passenger aircraft/rail (49 CFR ) DOT Quantity Limitations Cargo aircraft only (49 CFR ) DOT Vessel Stowage Location DOT Vessel Stowage Other 5 L 60 L Emergency Response Guide (ERG) Number 154 A - The material may be stowed on deck or under deck on a cargo vessel and on a passenger vessel 40 - Stow clear of living quarters Other information No supplementary information available. TDG Transport by sea UN-No. (IMDG) 1760 Proper Shipping Name (IMDG) CORROSIVE LIQUID, N.O.S. Class (IMDG) 8 - Corrosive substances Packing group (IMDG) III - substances presenting low danger Limited quantities (IMDG) 5 L Air transport UN-No. (IATA) 1760 Proper Shipping Name (IATA) Class (IATA) Packing group (IATA) SECTION 15 Regulatory information US Federal regulations Corrosive liquid, n.o.s. 8 - Corrosives III - Minor Danger All components of this product are listed, or excluded from listing, on the United States Environmental Protection Agency Toxic Substances Control Act (TSCA) inventory except for Silicon Dioxide CAS No % This product or mixture does not contain a toxic chemical or chemicals in excess of the applicable de minimis concentration as specified in 40 CFR (a) subject to the reporting requirements of section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372. Polymers of tofa with linoleic acid dimers ( ) EPA TSCA Regulatory Flag XU - XU - indicates a substance exempt from reporting under the Inventory Update Reporting Rule, i.e, Partial Updating of the TSCA Inventory Data Base Production and Site Reports (40 CFR 710(C)) International regulations CANADA WHMIS D-2B EU-Regulations No additional information available National regulations Carbon Black ( ) Listed on IARC (International Agency for Research on Cancer) US State regulations 09/26/2016 EN (English US) 8/9

38 Epic S7295B according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations California Proposition 65 - This product contains, or may contain, trace quantities of a substance(s) known to the state of California to cause cancer and/or reproductive toxicity Carbon Black ( ) U.S. - California - Proposition 65 - Carcinogens List U.S. - California - Proposition 65 - Developmental Toxicity U.S. - California - Proposition 65 - Reproductive Toxicity - Female Yes No No No U.S. - California - Proposition 65 - Reproductive Toxicity - Male No significant risk level (NSRL) N-Aminoethylpiperazine ( ) U.S. - New Jersey - Right to Know Hazardous Substance List Carbon Black ( ) U.S. - New Jersey - Right to Know Hazardous Substance List Calicum Carbonate ( ) U.S. - New Jersey - Right to Know Hazardous Substance List Tetraethylenepentamine ( ) U.S. - New Jersey - Right to Know Hazardous Substance List SECTION 16 Other information Revision date 09/26/2016 Full text of H-phrases H227 Combustible liquid H302 Harmful if swallowed H311 Toxic in contact with skin H312 Harmful in contact with skin H314 Causes severe skin burns and eye damage H317 May cause an allergic skin reaction H351 Suspected of causing cancer H400 Very toxic to aquatic life H410 Very toxic to aquatic life with long lasting effects H411 Toxic to aquatic life with long lasting effects H412 Harmful to aquatic life with long lasting effects HMIS III Rating Health Flammability Physical Personal Protection 3 Serious Hazard - Major injury likely unless prompt action is taken and medical treatment is given 1 Slight Hazard - Materials that must be preheated before ignition will occur. Includes liquids, solids and semi solids having a flash point above 200 F. (Class IIIB) 0 Minimal Hazard - Materials that are normally stable, even under fire conditions, and will NOT react with water, polymerize, decompose, condense, or self-react. Non-Explosives. B B - Safety glasses, Gloves SDS US (GHS HazCom 2012) This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product 09/26/2016 EN (English US) 9/9

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