After Showcasing Water Innovation: Updates on Beneficial Reuse of Sediment as a Growing Media

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After Showcasing Water Innovation: Updates on Beneficial Reuse of Sediment as a Growing Media Melissa Ryan, M.Sc., P.Eng. City of Kitchener Francine Kelly-Hooper, PhD CH2M TRIECA Conference 2016

Presentation Overview Showcasing Water Innovation Grant (MOECC) Sediment Disposal Options Lessons Learned Testing 21 SWMFs in Kitchener Plant Growth Experiment Results Next Steps

It all started with a lake

A study begins Undertook an EA to address water quality 50,000 tonnes of sediment

Sediment Quality Detailed design - tested 17 sediment samples Material did not meet Table 1 or Table 2 of O.Reg 153/04

Disposal Considerations Normally disposal = contractor Stantec & CH2M - proposed Excess Material Plan

The Stars Align Disposal site ahead of tender Showcasing Water Innovation Grant applications due Region of Waterloo Waste Management Master Plan Future SWMF cleanouts

Showcasing Water Innovation Testing sediment over 2 years Feasibility Study for Soil Campus Look into alternative uses

Construction Begins 45,000 t sediment & 45,000 t subsoil

Meanwhile at the landfill

After drying more

Sediment Trials

3 Experiments 1) Large Windrows 2) smaller - +urea & tarped portions 3) + compost Parameters: PHCs Metals Inorganics PAHs, TOC, TKN, TP, K ph BOD, COD & NOD

Overall Results Noticed decreases in PAHs and PHCs but above Table 1 & 2 Exceedances in boron and SAR & EC Nutrient test & compost test enhanced biological activity No re-use found

Soil Campus Study was completed by Golder Projected est. quantity of material in Region Quality was unknown Recommended a soil matching database

Lessons Learned Crop advisor input would have helped Market demand for soil product Risk Assessment Takes time

Next Steps for City Further Study: Get better understanding of SWMF sediment quality in city Explore beneficial reuse 21 SWMFs residential + full of sediment Retained CH2M experience + previous progress on pilots

SWMF Sediment Plant Growth Greenhouse Experiments Cities of Kitchener and Waterloo Presented by: Francine Kelly-Hooper, PhD Potential Beneficial Use as Roadside Topsoil Amendment Materials

Ontario SWMF Sediment Beneficial Use Regulatory Framework Discussion Excess Soils BMP Approach

Excess Soil Risk Management Evaluation Waste Disposal versus Beneficial Use Question #1: Does the sediment pass O. Reg. 153/04 Table 1 (background) soil standards? Pass uncontaminated unregulated disposal/use Fail Question #2: Does the sediment pass O. Reg. 153/04 Table 2,3 (risk) soil standards for residential/parkland/institutional use? Fail Question #3: Does the sediment pass O. Reg. 153/04 Table 2,3 soil standards for industrial/commercial/community use? Fail Pass Pass Consider re-use options for residential/parkland/ institutional sites Consider re-use options for industrial/commercial/ community use Conduct O. Reg. 347 leachate test to determine if sediment must be sent to a municipal or hazardous waste landfill facility. Represents significant financial losses due to landfill tipping fees.

2005-2015 Residential Sediment Quality Survey Findings Most Common Exceedences of O.Reg.153/04 Soil Standards Almost all SWMF sediments triggered regulated waste management requirements The 21 Kitchener SWMFs and the 40 other municipal SWMFs had similar exceedences of the O.Reg. 153/04 soil standards. 98% of F3 PHCs exceeded Table 1 PHCs and PAHs were the most common causes of regulated waste management requirements 52% of PAHs exceeded Tables 2 & 3 16% of SAR and 17% of metals exceeded Tables 2 & 3

SWMF Sediment Plant Growth Experiments 21-Day Growth Periods #1 Victoria Park Lake #2 SWMF Wetland 46 #3 Silver Lake #4 SWMF Wetland 53

Plant Growth Experiment Objective To determine if turf grass species would successfully grow in SWMF sediments with contaminant levels that exceeded one or more of the following O.Reg. 153/04 Table 1, 2, 3 soil standards: Polyaromatic Hydrocarbons (PAHs) naturally biodegradable Petroleum Hydrocarbons (PHCs) naturally biodegradable Sodium Adsorption Ratio (SAR) road salt can be reduced by gypsum rinses *Samples with elevated trace metals concentrations were excluded due to land application bioaccumulation risks.

Targeted Topsoil Amendment Beneficial Use - Municipal Roadside Planting Programs - Too Much Sediment with Costly Landfill Fees Sediment + Compost Too Much Unwanted Compost Takes Up Landfill Space Cities Need Topsoil for Routine Roadside Rehab = Topsoil Cost Savings

SWMF Sediment Plant Growth Experiments - SWMF Selection Criteria - All four SWMFs met the following sediment quality selection criteria for typical exceedences of O.Reg. 153/04 Tables 1, 2 and 3 soil standards: 1) No exceedences of Table 1 trace metal soil standards; 2) All SWMFs exceeded Table 1 F3 PHC soil standards; 3) All SWMFs exceeded Table 2&3 PAH soil standards; and 4) SAR Only Silver Lake and Wetland 53 exceeded all SAR standards, but levels were sufficiently reduced by gypsum treatments

21-Day Plant Growth Experiment Designs Kitchener Treatments 20 fescue + ryegrass seeds/pot 5 replicates/treatment Waterloo Treatments 10 fescue seeds/pot 3 replicates/ treatment 10 ryegrass seeds/pot 3 replicates/ treatment (1) Control Miracle Grow Soil (1) Control Miracle Grow Soil (2) VP Lake Sediment + Wood Chips (2) Silver Lake Sediment + Compost (3) Wetland 46 Sediment + Compost (3) Wetland 53 Sediment + Compost (4) Wetland 46 Sediment (No Compost)

Laboratory Topsoil Report Jack Legg, Certified Crop Advisor provided compost mixing ratio recommendations This topsoil amendment beneficial use approach was developed through several years of discussions between Jack Legg (SGS AgriFood), Dale McComb (OMAFRA) and Francine Kelly-Hooper (CH2M)

Boron (hot water extractable) Concentrations for Unmixed Sediment, Compost and Potting Soil HWE Boron (mg/kg) Boron is an essential plant nutrient but high concentrations can be toxic HWE Boron is typically: - low in SWMF sediments - high in compost VP Lake Silver Lake WL 46 WL 53 Municipal Compost SWMF Sediments Miracle Grow Soil Compost & Soil Table 2 soil standard for commercial/ industrial property use

F3 Petroleum Hydrocarbon Concentrations for Unmixed Sediment, Compost and Potting Soil Asphalt & tar are main sources of F3 PHCs FALSE PHC detections in clean compost and soil F3 PHCs (mg/kg) Natural organic matter can cause false F3 PHC detections in compost, soils and SWMF sediments Table 1 soil standard for all property uses VP Lake Silver Lake WL 46 WL 53 Municipal Compost Miracle Grow Soil SWMF Sediments Compost & Soil

21-Day Plant Growth Results

Plant Shoot and Root Lengths Shoot Length 14 12 10 8 6 4 2 0 Statistically significant differences between the sediments and the City of Kitchener Results 16 14 Miracle Grow potting soil were not 12 10 detected in most of the data 8 6 4 2 0 Shoot Length 18 City of Waterloo Results 25 20 25 20 Root Length 15 10 5 0 Miracle Grow 15 The smallest plant roots 10 and shoots were 5 measured in the 100% SWMF 46 sediments 0 that were not amended with compost VPL Wood Chips WL46 Compost 100 WL46 Root Length Miracle Grow Silver Lake Pond 53 Miracle Grow Silver L Compost WL53 Compost

Bottom Line? Sediments were non-toxic to the test plants But what about food chain transfer risks?

The Sediment PAHs & PHCs Have Very Low Water Solubility Lower Uptake Risk for Plants Higher Uptake Risk for Soil Organisms Plant roots absorb very little PAHs or PHCs Earthworms and other organisms consume soils along with adsorbed PAHs and PHCs

Next Steps? Update MOECC and OMAFRA on plant growth test results Expand benchscale plant growth tests to larger field trials Possible invertebrate benchscale studies

Thank You Melissa Ryan, M.Sc.,P.Eng. City of Kitchener melissa.ryan@kitchener.ca C: 519-498-6612 Francine Kelly-Hooper, PhD CH2M Francine.kellyhooper@ch2m.com C:519-502-3122