UV LED Measurement Status Update

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UV LED Measurement Status Update Jim Raymont September 19, 2016

Presentation Overview UV Measurement Fundamentals & Variables UV LEDs Measurement of UV LEDs Save Time & Money Copy of Presentation email: uv@eit.com

Hg spectra modified with added materials 100 Broadband Spectral Output Arc, Microwave, Spot Sources 90 Gallium 80 relative spectral radiance 70 60 50 40 30 20 Mercury Iron 10 0 200 250 300 350 400 450 500 wavelength [nm] Hg Ga Fe

Instrument Responses EIT UVA, UVB, UVC, UVV Transmission Scans 100 90 80 Normalized % T 70 60 50 40 UVV UVA UVB UVC 30 20 10 0 230 240 250 260 270 280 290 300 310 320 330 340 350 360 370 380 390 400 410 420 430 440 450 460 wave length EIT LLC. 2/26/09 The traditional approach has been to define the band response based only on the filter response

Work in past to improve & understand UV measurement 3M, Heraeus, International Light, EIT RadTech Measurement CD Educate & Communicate Challenges Measuring Broadband UV Sources Why are there differences between instruments? Optics Different Bands/Manufacturers Define response by 10% Power Point or 50% Power Point (FWHM) Electronics Dynamic range Sampling rates RMS vs Instantaneous Watts Threshold Differences Calibration Sources/Points One source type does not always fit Data Collection Techniques User Errors User Expectations Fraction of a percent?

UV LEDs Wide variety of UV LED sources Multiple suppliers with wide level of expertise, support, finances More than someone with SMT equipment? Experience in industrial UV, visible lighting, semiconductor industry? Ties to formulators? Match source to your application & process Economics of source selected (ROI) Images courtesy Baldwin, Dymax, Integration Technology, Excelitas & Phoseon Technology

UV LED Adoption The UV LED train has left the station

UV LED Adoption Graphic Arts / Printing Digital (standard format, wide format, direct to substrate) Screen (simple carousel machines, complex industrial) Flexographic (narrow, wide) Offset Adhesives Spot (off the shelf) Industrial (large/wide or custom formulation) Coatings Wood Fiber Optics Protective Hard Coats Other Courtesy Paul Mills: UV LED Tipping Point

LED Adoption Rate Digital Print Technical hurdles / Barriers to entry Business case for LED is stronger Vertical Integration Competitiveness of users Competitiveness of suppliers Suppliers: End Users: Courtesy Paul Mills: UV LED Tipping Point

UV LED Power Output vs. Wavelength 10 Increasing UV LED power 8 6 4 Increasing types of LED chips available 405 395 385 375 365 Mercury Lamp 2 0 240 260 280 300 320 340 360 380 400 420

UV LEDs: Measurement What do you want to measure? What do you want to measure? Individual LED Array Production system Where do you measure? What values do you want? Industrial UV: W/cm 2 & J/Cm 2 Visible LEDs: Flux?/Color?

Measurement of 395 nm LED Δ = 60% Δ = 95% Using UVA to measure a 385 nm or 395 nm LED

NIST comparison of UV LED sources Study completed by Robert F. Berg, NIST Looked at three LED units with two different radiometers Right Upper: Detector C exposure vs. detector A exposure Right Lower: The ratio of the two detectors exposures vs. the exposure of detector A No surprise there were differences From NIST report generated by Robert F. Berg (Figure 9 in report)

UV LED Emission Spectra Width of the LED at the 50% Power Point Variations between suppliers: Binning Longer wavelengths Sold as +/- 5 nm from center wavelength (CWL) Overall spread of UV LED made us rethink width of UVA2 band 395 nm LED array output measured on a spectral radiometer Courtesy EIT

UV L395 nm Band L Band Wide (+/- 100 nm) vs. Narrow (+/- 50 nm) Approach Advantages & Disadvantages to each approach Goal: Flat Response L395 LED Output Spectra Showing + 5nm Spread of Cp Along with Required Filter Response to Obtain 2% Measurement

Control of overall optics to flatten OVERALL response of instrument All Optical Components not just the filter Total Instrument Response

Total Measured Optics Response Instrument Response

Instrument Feedback Spectral response looks very good based on measurements of 385nm, 395nm and 405nm LEDs A 365nm lamp showed very little response with the EIT meter, indicating the spectral response has a steep skirt Very consistent peak irradiance and energy density measurements at various scan speeds Scan speeds varied from 1.2 to 6 meters/min Repeated measurements showed very little variation Good correlation to a NIST traceable meter from another manufacturer

Instrument Performance LEDCure Profiling Radiometer Stability between two different L395 instruments on 16 runs Variation: 0.995 to 1.0025 1.003 1 0.995

Instrument Performance LEDCure Profiling Radiometer Stability between two different L395 instruments on 16 runs Ratio 0.250% 0.0% -0.200%

EIT LED-R Series LEDCure Radiometer 40 Watt Dynamic Range Display Plus Profiler or Non- Profiler Option L395 Total Optics Response Additional L-Band Options

Calibration Challenges Industrial LED sources have exceeded 50W/cm 2 Typical irradiance levels, sources and standards that NIST has worked with are much lower (mw/cm 2 -µw/cm 2 ) Reduce variation and errors introduced in transfer process Fixtures Direct evaluation of EIT master unit by NIST from 220 nm past visible region Uniformity of UV LED source used with working standard and unit under test

CORM Council Optical Radiation Measurement Worldwide, approximately 20 members USA, Korea, Japan, China, UK, Germany, Denmark, South Africa Diverse Well Rounded Membership National Standards Organizations (NIST) Equipment Suppliers (Heraeus, Efsen Engineering) Instrument Suppliers (EIT, Gigahetz-Optik, International Light Technologies) Academic (University of Colorado, Boulder) End Users (3M) Trade Organizations (RadTech, IUVA)

Resources Thousand s of visitors per month Hub for information about UV LED technology Free to join www.uvledcommunity.org www.radtech.org

Jim Raymont Phone: 703-478-0700 eit.com Copy of Presentation email: uv@eit.com