UN 3082 Packing Group III Environmentally hazardous substance, liquid, N.O.S. (contains boscalid and epoxiconazole) Marine Pollutant

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Deuce A broad spectrum fungicide for use in winter wheat, spring wheat, durum wheat, winter barley, spring barley, oats, rye and triticale. A suspension concentrate containing 233 g/litre (20.8% w/w) boscalid plus 67 g/litre (6.0% w/w) epoxiconazole. Contains 1,2 benzisothiazol-3(2h0-one. May produce an allergic reaction. Risk and Safety Information Danger: Causes serious eye irritation. Suspected of causing cancer. May damage the unborn child. Suspected of damaging fertility. Very toxic to aquatic life with long lasting effects. Wear protective gloves/clothing/eye protection. Do not handle until all safety precautions have been read and understood. If in eyes: rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If exposed or concerned: call a poison centre or doctor /physician. Store locked up. Dispose of contents/container to a licensed hazardous waste disposal contractor or collection site except for triple rinsed empty containers which can be disposed of as non-hazardous waste. To protect aquatic organisms respect an unsprayed buffer zone of 5m to surface water bodies. To avoid risks to human health and the environment, comply with the instructions for use. 5 L UN 3082 Packing Group III Environmentally hazardous substance, liquid, N.O.S. (contains boscalid and epoxiconazole) Marine Pollutant PCS No: 04993 Supplied by: BASF Ireland Limited P.O. Box 4, Earl Road Cheadle Hulme, CHEADLE Cheshire SK8 6QG, UK Tel: 01 825 5701 Fax: 01 825 2038 Emergency Information (24 hours freephone): 0049 180 227 3112 Technical Enquiries: 0044 (0)845 602 2553 (office hours) = Registered trademark of BASF Authorization holder: BASF plc, P O Box 4, Earl Road, Cheadle Hulme, Cheshire, SK8 6QG, UK 81101094IE1105 ~xmam1449674127.indd 1 09.12.2015 16:15:30

FOR USE ONLY AS AN AGRICULTURAL FUNGICIDE, as directed below: Crops Maximum Maximum number Latest time individual dose of treatments of application Winter and spring 1.5 litre product 2 per crop Up to and including wheat, Durum per hectare flowering (anthesis) just wheat, rye and complete (GS 69) triticale Winter and spring 1.5 litre product 2 per crop Up to and including barley per hectare emergence of ear just Oats complete (GS 59) A minimum interval of 21 days between applications must be observed. READ ALL PRECAUTIONS BEFORE USE PCS No. 04993 PRECAUTIONS WEAR SUITABLE PROTECTIVE CLOTHING (COVERALLS), SUITABLE PROTECTIVE GLOVES AND FACE PROTECTION (FACESHIELD) when handling the concentrate. WEAR SUITABLE PROTECTIVE CLOTHING (COVERALLS) AND SUITABLE GLOVES when handling contaminated surfaces. IF YOU FEEL UNWELL, seek medical advice immediately (Show the label where possible) WASH HANDS AND EXPOSED SKIN before meals and after work. WHEN USING DO NOT EAT, DRINK OR SMOKE. KEEP AWAY FROM FOOD, DRINK AND ANIMAL FEEDING STUFFS. KEEP OUT OF REACH OF CHILDREN. TOXIC TO AQUATIC ORGANISMS, may cause long-term adverse effects in the aquatic environment. Do not contaminate surface waters or ditches with chemical or used container. Do not contaminate water with the product or its container. (Do not clean application equipment near surface water / Avoid contamination via drains from farmyards and roads). To protect aquatic organisms respect an unsprayed buffer zone of 5m to surface water bodies. KEEP IN ORIGINAL CONTAINER, tightly closed, in a safe place. Do not re-use container for any purpose. RINSE CONTAINER THOROUGHLY by using an integrated pressure rinsing device or manually rinsing three times. Add washings to sprayer at time of filling and dispose of safely. STORAGE Store in a suitable pesticide store, keep dry and protect from frost. ~xmam1449674127.indd 2 09.12.2015 16:15:30

DIRECTIONS FOR USE IMPORTANT: This information is approved as part of the Product Label. All instructions within this section must be read carefully in order to obtain safe and successful use of this product. Deuce is a broad spectrum fungicide for use in winter wheat, spring wheat, durum wheat, winter barley, spring barley, oats, rye and triticale. 1. Restrictions/Warnings For professional use only. For use by tractor mounted/trailed sprayers only. Avoid spray drift on to neighbouring crops. This product may cause damage to broad-leaved plant species. Effects on baking have not been fully tested. Consult the grain merchant or processor before use. 2. Disease Control Deuce is a broad spectrum fungicide for use in winter and spring wheat, durum wheat, winter and spring barley, oats, rye and triticale for disease control as summarised below: winter wheat spring wheat durum wheat winter barley spring barley oats rye triticale Septoria leaf blotch MC MC MC - - - - MC (Mycosphaerella graminicola) Brown rust C C C C C - C C Rhynchosporium - - - R R - R - secalis (leaf scald) Net blotch - - - MC MC - - - Ramularia - R R Tan spot R R R - - - - - Eyespot MC MC MC MC MC MC MC MC (Oculimacula spp) Crown rust - - - - - C - - C = Control MC = Moderate Control R = Reduction ~xmam1449674127.indd 3 09.12.2015 16:15:30

2.1 Resistance Management Use Deuce as part of an Integrated Crop Management (ICM) strategy incorporating other methods of control, including where appropriate other fungicides with a different mode of action. Deuce contains epoxiconazole, a DMI fungicide. Resistance to some DMI fungicides has been identified in Septoria leaf blotch (Mycosphaerella graminicola) which may seriously affect the performance of some products. For further advice on resistance management in DMIs contact your agronomist or specialist advisor, and visit the FRAG-UK website. Deuce contains boscalid which belongs to the SDHI (carboxamide) group of fungicides. To minimise the risk of resistance occurring, apply a maximum of two SDHI fungicide sprays per cereal crop. 3. Crops Deuce is a fungicide for use in winter wheat, spring wheat, durum wheat, winter barley, spring barley, oats, rye and triticale. 4. Mixing & Application 4.1 Time of Application Apply Deuce at the start of foliar or stem based disease attack. A maximum of two applications can be made up to and including flowering (anthesis) just complete (GS69) in winter wheat, spring wheat, durum wheat, rye & triticale, and up to and including emergence of ear just complete (GS59) in winter barley, spring barley and oats, 4.2 Rate of Application Apply 1.5 litres Deuce per hectare. 4.3 Mixing Never prepare more spray solution than is required. Three quarters fill the tank with clean water and start the agitation. To ensure thorough mixing of the product, invert the container several times before opening. Add the required quantity of Deuce to the spray tank while re-circulating. Add the remainder of the water and continue agitation until spraying is complete. On emptying the container, rinse container thoroughly by using an integrated pressure rinsing device or by manually rinsing three times. Add washings to tank at time of filling and dispose of container safely. 4.4 Application Apply Deuce in 200 l/ha water volume as a MEDIUM spray as defined by BCPC. Deuce may be applied at 1.5 litres per hectare in 100 litres of water per hectare although efficacy at this reduced volume has not been evaluated. Therefore application at 100 litres of water per hectare is at user s risk with regard to biological efficacy. Reducing the water volume is not recommended where control of stem base diseases is required. ~xmam1449674127.indd 4 09.12.2015 16:15:30

To ensure optimum spray coverage and minimize spray drift, adjust the spray boom to the appropriate height above the crop, according to guidance provided by the sprayer and/or nozzle manufacture. 4.5 Sprayer cleaning Wash sprayer thoroughly immediately after use, using clean water and following the sprayer cleaning guidance provided by the equipment manufacturer. 5. Following crops After treating a cereal crop with Deuce the crops listed below may be sown as a following crop:- Winter wheat Oilseed rape Maize Carrots Winter barley Sugar beet Lettuce Potatoes Oats Peas Onions Sunflowers Ryegrass Beans Cabbage Clover The following does not form part of the product label under S.I. No. 159 of 2012: With many products there is a general risk of resistance developing to the active ingredients. For this reason a change in activity cannot be ruled out. It is generally impossible to predict with certainty how resistance may develop because there are so many crop and use connected ways of influencing this. We therefore have to exclude liability for damage or loss attributable to any such resistance that may develop. To help minimise any loss in activity the BASF recommended rate should in all events be adhered to. Numerous, particularly regional or regionally attributable, factors can influence the activity of the product. Examples include weather and soil conditions, crop plant varieties, crop rotation, treatment times, application amounts, admixture with other products, appearance of organisms resistant to active ingredients and spraying techniques. Under particular conditions a change in activity or damage to plants cannot be ruled out. The manufacturer or supplier is therefore unable to accept any liability in such circumstances. All goods supplied by us are of high grade and we believe them to be suitable, but as we cannot exercise control over their mixing or use or the weather conditions during and after application, which may affect the performance of the material, all conditions and warranties, statutory or otherwise, as to the quality or fitness for any purpose of our goods are excluded and no responsibility will be accepted by us for any damage or injury whatsoever arising from their storage, handling, application or use; but nothing should be deemed to exclude or restrict any liability upon us which cannot be excluded or restricted under the provisions of the Unfair Contract Terms Act 1977 or any similar applicable law. ~xmam1449674127.indd 5 09.12.2015 16:15:30

Safety data sheet To access the Safety Data Sheet for this product scan the QR code or use the weblink below: http://www.agricentre.basf.ie/go/deuce_sds Alternatively, contact your supplier. ~xmam1449674127.indd 6 09.12.2015 16:15:30

Deuce A broad spectrum fungicide for use in winter wheat, spring wheat, durum wheat, winter barley, spring barley, oats, rye and triticale. A suspension concentrate containing 233 g/litre (20.8% w/w) boscalid plus 67 g/litre (6.0% w/w) epoxiconazole. Contains 1,2 benzisothiazol-3(2h0-one. May produce an allergic reaction. Risk and Safety Information Danger: Causes serious eye irritation. Suspected of causing cancer. May damage the unborn child. Suspected of damaging fertility. Very toxic to aquatic life with long lasting effects. Wear protective gloves/clothing/eye protection. Do not handle until all safety precautions have been read and understood. If in eyes: rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If exposed or concerned: call a poison centre or doctor /physician. Store locked up. Dispose of contents/container to a licensed hazardous waste disposal contractor or collection site except for triple rinsed empty containers which can be disposed of as non-hazardous waste. To protect aquatic organisms respect an unsprayed buffer zone of 5m to surface water bodies. To avoid risks to human health and the environment, comply with the instructions for use. UN 3082 Packing Group III Environmentally hazardous substance, liquid, N.O.S. (contains boscalid and epoxiconazole) 5 L Marine Pollutant PCS No: 04993 Supplied by: BASF Ireland Limited P.O. Box 4, Earl Road Cheadle Hulme, CHEADLE Cheshire SK8 6QG, UK Tel: 01 825 5701 Fax: 01 825 2038 Emergency Information (24 hours freephone): 0049 180 227 3112 Technical Enquiries: 0044 (0)845 602 2553 (office hours) = Registered trademark of BASF Authorization holder: BASF plc, P O Box 4, Earl Road, Cheadle Hulme, Cheshire, SK8 6QG, UK 81101094IE1105 ~xmam1449674127.indd 7 09.12.2015 16:15:30