Date of issue 07/05/2015 Revision date Version SECTION 1 Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form Mixture Product name Chematic 82EURO Product code 000083 1.2. Relevant identified uses of the substance or mixture and uses advised against 1.2.1. Relevant identified uses Industrial/Professional use spec Use of the substance/mixture Industrial For professional use only Alkaline Concentrated Detergent 1.2.2. Uses advised against 1.3. Details of the supplier of the safety data sheet Supplier Dober Chemical Corp 11230 Katherine's Crossing 60517 Woodridge, IL - US T 630-410-7300 - F 630-410-7444 regulatory@dobergroup.com - www.dobergroup.com Only Representative Doronwell Limited SN7 8WL Oxfordshire - United Kingdom T 44 (0) 1367 870192 1.4. Emergency telephone number Emergency number 1-800-255-3924 / 1-813-248-0585 ChemTel SECTION 2 Hazards identification 2.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP] Acute Tox. 4 (Oral) H302 Skin Corr. 1A H314 Full text of H-phrases see section 16 Adverse physicochemical, human health and environmental effects 2.2. Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP] Hazard pictograms (CLP) Signal word (CLP) Hazardous ingredients Hazard statements (CLP) Precautionary statements (CLP) Danger GHS05 GHS07 Tetrasodium ethylene diaminetetraacetate, Potassium Hydroxide H302 - Harmful if swallowed H314 - Causes severe skin burns and eye damage P260 - Do not breathe dust/fume/gas/mist/vapours/spray P264 - Wash hands, forearms and face thoroughly after handling P270 - Do not eat, drink or smoke when using this product P280 - Wear protective gloves/protective clothing/eye protection/face protection P301+P312 - IF SWALLOWED Call a POISON CENTER/doctor if you feel unwell P301+P330+P331 - IF SWALLOWED rinse mouth. Do NOT induce vomiting P303+P361+P353 - IF ON SKIN (or hair) Take off immediately all contaminated clothing. Rinse skin with water/shower P304+P340 - IF INHALED Remove person to fresh air and keep comfortable for breathing P305+P351+P338 - IF IN EYES Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P310 - Immediately call a POISON CENTER or doctor/physician P321 - Specific treatment (see First aid measures on this label) 08/05/2015 EN (English) 1/8
P330 - Rinse mouth P405 - Store locked up P501 - Dispose in a safe manner in accordance with local/national regulations 2.3. Other hazards SECTION 3 Composition/information on ingredients 3.1. Substance Not applicable 3.2. Mixture Name Product identifier % Classification according to Directive 67/548/EEC Potassium Hydroxide (CAS No) 1310-58-3 (EC no) 215-181-3 (EC index no) 019-002-00-8 Tetrasodium ethylene diaminetetraacetate (CAS No) 64-02-8 (EC no) 200-573-9 (EC index no) 607-428-00-2 10-30 Xn; R22 C; R35 10-30 Xn; R22 Xi; R41 Name Product identifier Specific concentration limits Potassium Hydroxide (CAS No) 1310-58-3 (EC no) 215-181-3 (EC index no) 019-002-00-8 (0.5 =< C < 2) Xi;R36/38 (2 =< C < 5) C;R34 (C >= 5) C;R35 Name Product identifier % Classification according to Regulation (EC) No. 1272/2008 [CLP] Potassium Hydroxide (CAS No) 1310-58-3 (EC no) 215-181-3 (EC index no) 019-002-00-8 Tetrasodium ethylene diaminetetraacetate (CAS No) 64-02-8 (EC no) 200-573-9 (EC index no) 607-428-00-2 10-30 Acute Tox. 4 (Oral), H302 Skin Corr. 1A, H314 10-30 Acute Tox. 4 (Oral), H302 Eye Dam. 1, H318 Name Product identifier Specific concentration limits Potassium Hydroxide (CAS No) 1310-58-3 (EC no) 215-181-3 (EC index no) 019-002-00-8 Full text of R- and H-phrases see section 16 (0.5 =< C < 2) Skin Irrit. 2, H315 (0.5 =< C < 2) Eye Irrit. 2, H319 (2 =< C < 5) Skin Corr. 1B, H314 (C >= 5) Skin Corr. 1A, H314 SECTION 4 First aid measures 4.1. Description of first aid measures First-aid measures general First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). Remove to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/physician. Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. Immediately call a POISON CENTER or doctor/physician. Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Rinse mouth. Do NOT induce vomiting. Call a POISON CENTER/doctor/physician if you feel unwell. Immediately call a POISON CENTER or doctor/physician. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/injuries Causes severe skin burns and eye damage. Symptoms/injuries after ingestion Swallowing a small quantity of this material will result in serious health hazard. 4.3. Indication of any immediate medical attention and special treatment needed SECTION 5 Firefighting measures 5.1. Extinguishing media Suitable extinguishing media Foam. Dry powder. Carbon dioxide. Water spray. Sand. Unsuitable extinguishing media Do not use a heavy water stream. 5.2. Special hazards arising from the substance or mixture 08/05/2015 EN (English) 2/8
5.3. Advice for firefighters Firefighting instructions Protection during firefighting Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire-fighting water from entering environment. Do not enter fire area without proper protective equipment, including respiratory protection. SECTION 6 Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures 6.1.1. For non-emergency personnel Emergency procedures 6.1.2. For emergency responders Protective equipment Emergency procedures Evacuate unnecessary personnel. Equip cleanup crew with proper protection. Ventilate area. 6.2. Environmental precautions Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters. Avoid release to the environment. 6.3. Methods and material for containment and cleaning up Methods for cleaning up 6.4. Reference to other sections See Heading 8. Exposure controls and personal protection. Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials. SECTION 7 Handling and storage 7.1. Precautions for safe handling Precautions for safe handling Hygiene measures Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapour. Do not breathe dust/fume/gas/mist/vapours/spray. Avoid contact during pregnancy/while nursing. Do not eat, drink or smoke when using this product. Wash hands, forearms and face thoroughly after handling. 7.2. Conditions for safe storage, including any incompatibilities Technical measures Storage conditions Incompatible products Incompatible materials 7.3. Specific end use(s) Comply with applicable regulations. Keep only in the original container in a cool, well-ventilated place. Keep container closed when not in use. Strong bases. Strong acids. SECTION 8 Exposure controls/personal protection 8.1. Control parameters Potassium Hydroxide (1310-58-3) Sources of ignition. Direct sunlight. Austria MAK (mg/m³) 2 mg/m³ Bulgaria OEL TWA (mg/m³) 2.0 mg/m³ Czech Republic Expoziční limity (PEL) (mg/m³) 1 mg/m³ Denmark Grænseværdie (kortvarig) (mg/m³) 2 mg/m³ Estonia OEL TWA (mg/m³) 2 mg/m³ Finland HTP-arvo (15 min) 2 mg/m³ Finland OEL Ceiling (mg/m³) 2 mg/m³ France VLE (mg/m³) 2 mg/m³ Greece OEL TWA (mg/m³) 2 mg/m³ Greece OEL STEL (mg/m³) 2 mg/m³ Hungary AK-érték 2 mg/m³ Hungary CK-érték 2 mg/m³ Ireland OEL (15 min ref) (mg/m3) 2 mg/m³ Poland NDS (mg/m³) 0.5 mg/m³ Poland NDSCh (mg/m³) 1 mg/m³ Portugal OEL - Ceilings (mg/m³) 2 mg/m³ 08/05/2015 EN (English) 3/8
Potassium Hydroxide (1310-58-3) Spain VLA-EC (mg/m³) 2 mg/m³ Sweden nivågränsvärde (NVG) (mg/m³) 1 mg/m³ Sweden takgränsvärde (TGV) (mg/m³) 2 mg/m³ United Kingdom WEL STEL (mg/m³) 2 mg/m³ Norway Gjennomsnittsverdier (Takverdi) (mg/m³) 2 mg/m³ Switzerland VME (mg/m³) 2 mg/m³ Canada (Quebec) PLAFOND (mg/m³) 2 mg/m³ Japan Exposure limits (ACGIH) TWA -,STEL C 2 mg/m3 USA - ACGIH ACGIH Ceiling (mg/m³) 2 mg/m³ USA - NIOSH NIOSH REL (ceiling) (mg/m³) 2 mg/m³ 8.2. Exposure controls Personal protective equipment Hand protection Eye protection Skin and body protection Respiratory protection Other information Avoid all unnecessary exposure. Wear protective gloves/protective clothing/eye protection/face protection protective gloves Chemical goggles or face shield Wear suitable protective clothing Wear appropriate mask Do not eat, drink or smoke during use. SECTION 9 Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state Liquid Colour Colorless to Pale Yellow. Odour odourless. Odour threshold ph 12 Relative evaporation rate (butylacetate=1) Melting point Freezing point Boiling point Flash point Auto-ignition temperature Decomposition temperature Flammability (solid, gas) Non flammable Vapour pressure Relative vapour density at 20 C Relative density Density 1.37 g/ml Solubility Water 100 % Log Pow Viscosity, kinematic Viscosity, dynamic Explosive properties Oxidising properties Explosive limits 9.2. Other information SECTION 10 Stability and reactivity 10.1. Reactivity Thermal decomposition generates Corrosive vapours. 10.2. Chemical stability Not established. 08/05/2015 EN (English) 4/8
10.3. Possibility of hazardous reactions Not established. 10.4. Conditions to avoid Direct sunlight. Extremely high or low temperatures. 10.5. Incompatible materials Strong acids. Strong bases. 10.6. Hazardous decomposition products Fume. Carbon monoxide. Carbon dioxide. Thermal decomposition generates Corrosive vapours. SECTION 11 Toxicological information 11.1. Information on toxicological effects Acute toxicity Oral Harmful if swallowed. ATE CLP (oral) Potassium Hydroxide (1310-58-3) LD50 oral rat LD50 oral 759.797 mg/kg bodyweight 214 mg/kg 284 mg/kg Tetrasodium ethylene diaminetetraacetate (64-02-8) LD50 oral rat 1658 mg/kg Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity Reproductive toxicity Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Aspiration hazard Potential adverse human health effects and symptoms SECTION 12 Ecological information 12.1. Toxicity Ecology - water Causes severe skin burns and eye damage. ph 12 Serious eye damage, category 1, implicit ph 12 Based on available data, the classification criteria are not met. Harmful if swallowed. Harmful to aquatic life. Tetrasodium ethylene diaminetetraacetate (64-02-8) LC50 fishes 1 41 mg/l (Exposure time 96 h - Species Lepomis macrochirus [static]) EC50 other aquatic organisms 1 1.01 mg/l (Exposure time 72 h - Species Desmodesmus subspicatus) LC50 fish 2 59.8 mg/l (Exposure time 96 h - Species Pimephales promelas [static]) 12.2. Persistence and degradability Chematic 82EURO Persistence and degradability Not established. 12.3. Bioaccumulative potential Chematic 82EURO Bioaccumulative potential Not established. Potassium Hydroxide (1310-58-3) Log Pow 0.65 12.4. Mobility in soil 12.5. Results of PBT and vpvb assessment 08/05/2015 EN (English) 5/8
12.6. Other adverse effects Additional information Avoid release to the environment SECTION 13 Disposal considerations 13.1. Waste treatment methods Waste disposal recommendations Ecology - waste materials SECTION 14 Transport information In accordance with ADR / RID / IMDG / IATA / ADN 14.1. UN number UN-No. (ADR) 1719 UN-No. (IMDG) 1719 UN-No.(IATA) 1719 UN-No.(ADN) 1719 UN-No. (RID) 1719 Dispose in a safe manner in accordance with local/national regulations. Dispose in a safe manner in accordance with local/national regulations. Avoid release to the environment. 14.2. UN proper shipping name Proper Shipping Name (ADR) Proper Shipping Name (IMDG) Proper Shipping Name (IATA) Proper Shipping Name (ADN) Proper Shipping Name (RID) Caustic Alkali Liquids, N.O.S. CAUSTIC ALKALI LIQUID, N.O.S. CAUSTIC ALKALI LIQUID, N.O.S. CAUSTIC ALKALI LIQUID, N.O.S. Caustic Alkali Liquids, N.O.S. 14.3. Transport hazard class(es) ADR Transport hazard class(es) (ADR) 8 Danger labels (ADR) 8 IMDG Transport hazard class(es) (IMDG) 8 Danger labels (IMDG) 8 IATA Transport hazard class(es) (IATA) 8 Hazard labels (IATA) 8 08/05/2015 EN (English) 6/8
ADN Transport hazard class(es) (ADN) 8 Danger labels (ADN) 8 RID Transport hazard class(es) (RID) 8 Danger labels (RID) 8 14.4. Packing group Packing group (ADR) Packing group (IMDG) Packing group (IATA) Packing group (ADN) Packing group (RID) 14.5. Environmental hazards Dangerous for the environment Marine pollutant Other information II II II II II No No No supplementary information available SECTION 15 Regulatory information 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture 15.1.1. EU-Regulations Contains no substances with Annex XVII restrictions Chematic 82EURO is not on the REACH Candidate List Contains no REACH candidate substance 0,1 % / SCL. Contains no REACH Annex XIV substances. 15.1.2. National regulations Germany Water hazard class (WGK) 3 - strongly hazardous to water 15.2. Chemical safety assessment No chemical safety assessment has been carried out SECTION 16 Other information Other information None. Full text of R-, H- and EUH-phrases Acute Tox. 4 (Oral) Acute toxicity (oral), Category 4 Eye Dam. 1 Serious eye damage/eye irritation, Category 1 Skin Corr. 1A H302 H314 H318 Skin corrosion/irritation, Category 1A Harmful if swallowed Causes severe skin burns and eye damage Causes serious eye damage 08/05/2015 EN (English) 7/8
R22 R35 R41 C Xi Xn Harmful if swallowed Causes severe burns Risk of serious damage to eyes Corrosive Irritant Harmful Dober SDS EU To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. 08/05/2015 EN (English) 8/8