SVENSK STANDARD SS-EN ISO 5398-4:2007 Fastställd 2007-08-07 Utgåva 1 Läder Kemisk bestämning av kromoxidinnehåll Del 4: Kvantifiering med induktivt kopplad plasma optisk emissionspektrometer (ICP-OES) (ISO 5398-4:2007) Leather Chemical determination of chromic oxide content Part 4: Quantification by inductively coupled plasma optical emission spectrometer (ICP-OES) (ISO 5398-4:2007) ICS 59.140.30 Språk: engelska Publicerad: september 2007 Copyright SIS. Reproduction in any form without permission is prohibited.

Provläsningsexemplar / Preview Europastandarden EN ISO 5398-4:2007 gäller som svensk standard. Detta dokument innehåller den officiella engelska versionen av EN ISO 5398-4:2007. The European Standard EN ISO 5398-4:2007 has the status of a Swedish Standard. This document contains the official English version of EN ISO 5398-4:2007. Upplysningar om sakinnehållet i standarden lämnas av SIS, Swedish Standards Institute, telefon 08-555 520 00. Standarder kan beställas hos SIS Förlag AB som även lämnar allmänna upplysningar om svensk och utländsk standard. Postadress: SIS Förlag AB, 118 80 STOCKHOLM Telefon: 08-555 523 10. Telefax: 08-555 523 11 E-post: sis.sales@sis.se. Internet: www.sis.se

Provläsningsexemplar / Preview EUROPEAN STANDARD NORME EUROPÉENNE EUROPÄISCHE NORM EN ISO 5398-4 August 2007 ICS 59.140.30 English Version Leather - Chemical determination of chromic oxide content - Part 4: Quantification by inductively coupled plasma - optical emission spectrometer (ICP-OES) (ISO 5398-4:2007) Cuir - Dosage chimique de l'oxyde de chrome - Partie 4: Quantification par plasma à couplage inductif - spectromètre d'émission optique (ICP-OES) (ISO 5398-4:2007) Leder - Chemische Bestimmung des Chromoxidgehaltes - Teil 4: Bestimmung durch induktiv gekoppeltes Plasma/optisches Spektrometer (ICP-OES) (ISO 5398-4:2007) This European Standard was approved by CEN on 28 July 2007. CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such national standards may be obtained on application to the CEN Management Centre or to any CEN member. This European Standard exists in three official versions (English, French, German). A version in any other language made by translation under the responsibility of a CEN member into its own language and notified to the CEN Management Centre has the same status as the official versions. CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland and United Kingdom. EUROPEAN COMMITTEE FOR STANDARDIZATION COMITÉ EUROPÉEN DE NORMALISATION EUROPÄISCHES KOMITEE FÜR NORMUNG Management Centre: rue de Stassart, 36 B-1050 Brussels 2007 CEN All rights of exploitation in any form and by any means reserved worldwide for CEN national Members. Ref. No. EN ISO 5398-4:2007: E

EN ISO 5398-4:2007 (E) Provläsningsexemplar / Preview Contents Page Foreword... iii Introduction... iv 1 Scope...1 2 Normative references...1 3 Terms and definitions...1 4 Principle...2 5 Sampling and sample preparation...2 6 Reagents...2 6.1 Wet oxidation method...2 6.2 ICP OES...2 7 Apparatus...2 8 Methods...3 8.1 Preparation of analytical solution...3 8.2 Measurement of the aqueous solution...3 9 Calculation and expression of results...4 10 Test report...5 Annex A (informative) Determination of water and other volatile matter...6 ii

Provläsningsexemplar / Preview EN ISO 5398-4:2007 (E) Foreword This document (EN ISO 5398-4:2007) has been prepared by Technical Committee CEN/TC 289 "Leather", the secretariat of which is held by UNI, in collaboration with the International Union of Leather Technologists and Chemists Societies (IULTCS). This European Standard shall be given the status of a national standard, either by publication of an identical text or by endorsement, at the latest by February 2008, and conflicting national standards shall be withdrawn at the latest by February 2008. According to the CEN/CENELEC Internal Regulations, the national standards organizations of the following countries are bound to implement this European Standard: Austria, Belgium, Bulgaria, Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland and the United Kingdom. iii

EN ISO 5398-4:2007 (E) Provläsningsexemplar / Preview Introduction ISO 5398 has been split into four parts, each describing methods suitable for the determination of the chromic oxide content in leather. The different techniques have been described to reflect the variations in industrial practice compared with the more sensitive analytical equipment available for test laboratories. Variations also exist in the range of chromic oxide that the methods are deemed suitable to quantify. ISO 5398-4 describes a technique that is suitable for determining chromium more precisely than those described in ISO 5398-1 and ISO 5398-2. It requires the use of sophisticated analytical equipment, such as inductively coupled plasma and atomic absorption spectroscopy. iv