elative toxicity of the main active ingredients contained in pesticides for domestic use Rused for green spaces April 2015

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R elative of the main active ingredients contained in pesticides for domestic use used for green spaces April 2015

LAWNS AND PAVED SURFACES Relative of the main active ingredients contained in pesticides for domestic use 1 Active ingredient including human 2 Non targeted species 2 ingredient 3 INSECTICIDES Borax - - - Ants Imidacloprid High High European chafer beetle, japanese beetle, black turfgrass Ataenius, leatherjackets Ortho Home Defense Max Ant Traps (23372) Safer's Attack Ant Trap (24355) Knock Down Eco Ant Killer Bait (31203) Bayer Advanced season Long Grub Control Insecticide (29738) Insecticide soap - Low Low Ants, earwigs et chinch bugs Safer's Trounce Hose-End Lawn & Turf Insecticide (28680) Safer's Trounce Lawn & Turf Insecticide (28681) - 2 -

Active ingredient including human 2 Non targeted species 2 ingredient 3 Pyrethrins Low Low Ants, earwigs et chinch bugs Safer's Trounce Hose-End Lawn & Turf Insecticide (28680) Safer's Trounce Lawn & Turf Insecticide (28681) Spinosad Moderate Low Sod webworms Conserve 120 SC Domestic Naturalyte Insect Control Product (27285) Spinosad Insecticide (28602) HERBICIDES Acetic acid - - Low Low Dandelion and plantain in lawns, undesirable vegetation growing in paved surfaces EcoClear For Fast Acting Weed Control (26522) Scotts Ecosense Pathclear Fast Acting Grass & Weed Control Spray (28300) Grotek Elimaweed Weed & Grass Killer (28807) Amaizeingly Green Horticultural Vinegar (31459) Citric acid and Lactic acid - - - - Birds foottrefoil,black medick,wood sorel,red clover,white clover Bioprotec Lawn Herbicide Concentrate (30881) Bioprotec Lawn Herbicide Ready to Use (30883) - 3 -

Active ingredient including human 2 Non targeted species 2 ingredient 3 Corn gluten meal - - - - - - - Dandelion and crabgrass seeds Nutrite Pre-Emergent Weed Seed Germination Inhibitor (27727) Bioprotec Inhib (29144) Ferrous sulphate 4 - - High High Moss Greenleaf Moss Control (25250) Nurseryland Moss Control (25251) Iron (present as FeHEDTA) - - - - - Several species of broadleaf weeds, moss and algae NEU1173H Large Size (29538) Scotts Ecosense Weed B Gon Ready- To-Spray Weed Control (30145) Glufosinateammonium Low Low Undesirable vegetation growing in paved surfaces Wilson Wipe Out Fast Control Concentrate (23825) Wilson Total WipeOut Ready-To-Use (25300) Glyphosate Moderate Moderate Undesirable vegetation growing in paved surfaces Roundup Quik Stik Non-Selective Herbicide Tablets (23786) Glyphosate-Trimesium 480 LG Super Concentrate (26576) - 4 -

Active ingredient including human 2 Non targeted species 2 ingredient 3 Herbicide soap - Low Low Moss and lichen Safer's De-Moss Moss Killer (18418) Finalsan Concentrate (29017) Scotts Ecosense Moss B Gon Herbicidal Soap Concentrate Moss & Algae Killer (29303) Mixture of capric and pelargonic - - - Low - acids 4 Undesirable vegetation growing in paved surfaces Safer's Fast Acting Topgun Weed Killer Herbicide (22244) Safer's Fast Acting Superfast Patio Weed Killer RTU (23775) Sclerotinia minor IMI 344141 - - - - - Dandelion Sarritor Selective Biological Lawn Weed Killer (28546) Sodium chloride 4 - - - - - - Small ragweed Adios Ambros Domestic WSG (28712) 1 Active ingredients mentioned in this table are contained in pesticides for domestic use (federal government) and classes 4 and 5 (provincial government). 2 Source : SAgE pesticides. Québec : ministère de l Agriculture, des Pêcheries et de l alimentation / ministère du Développement durable, de l Environnement et de la Lutte contre les changements climatiques / Institut national de santé publique du Québec [www.sagepesticides.qc.ca] 3 The pesticide may contain one or more active ingredients other than mentioned. To learn more about the product, check the label on the Pest Management Regulatory Agency label search tool. 4 Source : PPDB (2009), The Pesticide Properties Database (PPDB) developed by the Agriculture & Environment Research Unit (AERU), University of Hertfordshire, funded by UK national sources and the EU-funded FOOTPRINT project (FP6-SSP-022704) (Pages consultées en mars 2015), [En ligne]. http://sitem.herts.ac.uk/aeru/ppdb/en/index.htm - 5 -

TREES, SHRUBS AND GARDENS Relative of the main active ingredients contained in pesticides for domestic use 1 Active ingredient including human 2 Non targeted species 2 ingredient INSECTICIDES Acetamiprid Low Low Aphids, leafhoppers, leaf miners and whiteflies Acetamiprid RTU Insecticide (27126) Bacillus thuringiensis kurstaki - - - - Caterpillars Safer's BTK Biological Insecticide (24536) Bioprotec Eco (27251) Calcium sulphide or calcium polysulphide - - Mealybugs, mites, scale insects Green Earth Lime Sulphur Concentrate (7386) Lime Sulphur (27978) Carbaryl Low Low A number of insects Wilson Rose Doctor Insecticide- Fungicide (10565) King PTV Potato, Tomato & Vegetable Dust for Bugs and Blight (29619) - 6 -

Active ingredient including human 2 Non targeted species 2 ingredient Insecticide soap - Low Low A number of insects Safer's Insecticidal Soap (14668) Scotts Ecosense Bug-B-Gon Insecticidal Soap Ready-To-Spray Concentrate (29272) Malathion Low Low A number of insects Wilson 50% Malathion Liquid Insecticide-Miticide (9802) Mineral oil - - Mealybugs, mites, scales and spider mites Green Earth Horticultural Oil Insect Spray (21348) Liquid Insecticide oil spray for Dormant Trees (25307) Permethrin Moderate Low Aphids and caterpillars Pyrethrins Low Low A number of insects Bio-Environmental Permethrin Water-Based Insecticide (22804) Pyrocide Aqueous Plant Spray Insecticide (15181) K-G House & Garden Insect Killer I (17953) Safer's Trounce Yard and Garden Insecticide Concentrate (20564) Silicon dioxyde, present as diatomaceous earth - - - - - - A number of insects Wilson Antout Ant Killer Dust (21936) Knock Down Eco Crawling Insect Control & Killer Bait Powder (31048) - 7 -

Active ingredient including human 2 Non targeted species 2 ingredient Spinosad Moderate Low Caterpillars, gypsy moths and thrips Conserve 120 SC Domestic Naturalyte Insect Control Product (27285) Spinosad Insecticide(28602) FUNGICIDES Bacillus subtilis QST 713 - - - - - - - Botrytis blight, leaf spot and powdery mildew Bayer Advanced Natria Disease Control Concentrate (28628) Bayer Advanced Natria Disease Control Ready to Use (28629) Calcium sulphide or calcium polysulphide - - Apple scab and black spot Green Earth Lime Sulphur Concentrate (7386) Lime Sulphur (27978) Captan Low Low Black spot, bulb rot, damping off and powdery mildew Gardal Rose, Flower, & Evergreen Dust (14851) Wilson Bulb and Soil Dust (14852) King Home & Garden Fruit Tree and Garden Spray (9986) Copper present as tribasic copper sulphate High Low Anthracnose and black spot Wilson Garden Doctor Insecticide/Fungicide (17424) Green Earth Bordo Copper Spray (17482) - 8 -

Active ingredient including human 2 Non targeted species 2 ingredient Folpet Low Low Sulphur High High Anthracnose, black spot and powdery mildew Leaf spot, powdery mildew and rust Wilson Rose Doctor Insecticide- Fungicide (10565) Safer's Defender Garden Fungicide Ready to Use (19061) Green Earth Garden Fungicide Ready to Use (21880) King Eco-Way Fruit Tree & Garden Fungicide Spray or Dust (29572) HERBICIDES Dichlobenil High High Mixture of capric and pelargonic - - - Low - acids 3 Napropamide High High Undesirable vegetation Undesirable vegetation Undesirable vegetation Casoron Granular Herbicide (20233) Safer's Fast Acting Topgun Weed Killer Herbicide (22244) Safer's Topgun Weed Killer (23254) Granular Weed Preventer (28731) Wilson WeedStop Granular Herbicide (29049) Trifluralin High Low Undesirable vegetation Biobarrier Root Control System (Domestic) (28780) - 9 -

Active ingredient including human 2 Non targeted species 2 ingredient Ferric phosphate MOLLUSCICIDES - - - - - - - Slugs and snails Sluggo Slug and Snail Bait for Gardens (26102) Scotts Ecosense Slug B Gon Slug and Snail Bait (28375) Ferric sodium EDTA - - - Slugs and snails Safer's Slug & Snail Killer (28775) Metaldehyde Moderate - Slugs and snails King Slug & Snail Pellets (28287) Wilson SlugOut Meal (25908) Silicon dioxyde, present as diatomaceous earth - - - - - - Slugs Wilson Antout Ant Killer Dust (21936) Progreen S.D. Insect Dust (28746) 1 Active ingredients mentioned in this table are contained in pesticides for domestic use (federal government) and classes 4 and 5 (provincial government). 2 Source : SAgE pesticides. Québec : ministère de l Agriculture, des Pêcheries et de l alimentation / ministère du Développement durable, de l Environnement et de la Lutte contre les changements climatiques / Institut national de santé publique du Québec. [www.sagepesticides.qc.ca] 3 Source : PPDB (2009), The Pesticide Properties Database (PPDB) developed by the Agriculture & Environment Research Unit (AERU), University of Hertfordshire, funded by UK national sources and the EU-funded FOOTPRINT project (FP6-SSP-022704) (Pages consultées en mars 2015), [En ligne]. http://sitem.herts.ac.uk/aeru/ppdb/en/index.htm - 10 -

LEGEND This symbol is used to describe pesticides with very high risk to human health or the environment. These pesticides should be used in last resort and all necessary prevention measures must be taken to avoid all form of exposure and minimized risk for the environment. This symbol is used to describe pesticides with high risk to human health or the environment. These pesticides should be used in last resort and all necessary prevention measures must be taken to avoid all form of exposure and minimized risk for the environment. This symbol is used to describe pesticides with moderate risk to human health or the environment. Users should take all necessary prevention measures to avoid all form of exposure and minimized risk for the environment. This symbol is used to describe pesticides with slight risk to human health or the environment. Although these pesticides can normally be used without adverse s, users should take all necessary prevention measures to avoid all form of exposure and minimized risk for the environment. This symbol is used to describe pesticides with low risk to human health or the environment. These pesticides should be used in first place. Although these pesticides can normally be used without adverse s, users should take all necessary prevention measures to avoid all form of exposure and minimized risk for the environment. Source : SAgE pesticides. Québec : ministère de l Agriculture, des Pêcheries et de l alimentation / ministère du Développement durable, de l Environnement et de la Lutte contre les changements climatiques / Institut national de santé publique du Québec. [www.sagepesticides.qc.ca] - 11 -

Mammals including human Severity of the s criteria Indicator values LD 50 oral (mg/kg) 5 > 5-50 > 50-300 > 300-2000 > 2000 LD 50 dermal (mg/kg) 50 > 50-200 > 200-1000 > 1000-2000 > 2000 LC 50 inhalation (mg/l) 0,05 > 0,05-0,5 > 0,5-1 > 1-5 > 5 Dermal irritation Severe to extreme irritant Moderate irritant Slight irritant Little or no irritant Ocular irritation Severe to extreme irritant Moderate irritant Slight irritant Little or no irritant Sensitization Yes Potential No s criteria Severity of the s Indicator values Carcinogenicity Human carcinogen Probable human carcinogen Geno Genotoxic for humans Endocrine disruption Reproductive s Development Confirmed human s Confirmed human s Evidence of endocrine disruption Suspected human s Suspected human s Possible human carcinogen Potential genotoxic for humans Potential of endocrine disruption Confirmed animal s Confirmed animal s Data inadequate for assessment of human carcinogenic potential Suspected animal s Suspected animal s No or inadequate data No or inadequate data No or inadequate data No or inadequate data Not likely to be carcinogen to humans No evidence of human geno No evidence of endocrine disruption No No - 12 -

Non-target species Bird criteria LD 50 (mg/kg) < 10 10 50 50-500 500-2000 Symbol > 20000 Freshwater fish and aquatic invertebrate criteria LC 50 (µg/l) Symbol < 100 100-1000 1000-10 000 10 000-100 000 > 100 000 Honey bee criteria LD 50 (µg/bee) < 2 2-11 > 11 Symbol - 13 -

Persistence in soil Environmental persistence potential criteria DT 50 (jours) Persistence potential < 30 Low 30-90 Moderate 90 High potential potential criteria GUS* Index potential < 1,8 Low 1,8-2,8 Moderate 2,8 High *Groundwater Ubiquity Score - 14 -