SHS AS A TECHNOLOGY PLATFORM FOR SUSTAINABLE & COMPETETIV ADVANTAGE

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SHS AS A TECHNOLOGY PLATFORM FOR SUSTAINABLE & COMPETETIV ADVANTAGE Taastrup, 02.11.2012 Siegfried Schmidt, Global Applied Science Team, VDN Mars GmbH Europe

OVERVIEW Today s drying technology and it s energy usage SuperHeated Steam, as the drying medium of the future Energy demand to evaporate water Comparing SHS vs. air as heating medium SHS conveying Overview Status SHS drying Global petfood production with air & SHS drying Energy impact of implementing SHS applications in Mars dry factories Best way of energy recovery Mass balance of a typical extrusion line Example for vapour compression and the needed energy demand Conclusion

Drying of Food Drying is one of the oldest and most fundamental method for food preservation

Energy demand to evaporate *900 kt of water/year * Data s from 2010 Single Screw Extruder Air Conveying Specific Evaporative capacity 2,725 kj/kg = 0.757 kwh/kg Air Dryer to produce the total amount of dry product (globaly) on extruder lines we have in Minden Total need 2,452.5 TJ to evaporate 900kt of water to produce *3,500 kt of petfood per year

Air Drying vs. SHS Drying Advantage of air drying Product temperature during Drying is around 83 C Disadvantages of air drying: Exhaust of air drying is warm moist air at a temperature of > 80 C Low level of temperature, therefore less efficient in energy recovery Exhaust air is not condensable Bio filter is needed Moist exhaust air needs bio filter to reduce odours No way to reuse the water Fire and explosion risk by using high drying temperatures (> 135 C) Condensation risk in dryer entrance and dryer exit Condensation risk and energy losses by using air conveying Advantage of SHS drying: 15 to 20% less energy consumption comparing to air drying Steam, SuperHeated above 100 C, a non visible Gas which is capable to evaporate water. This gas is condensable. Due to high specific heat capacity and low viscosity, pasteurizing or sterilising of product is possible SHS (in our application) is a gas at nearly atmospheric pressure, no risk of safety SHS atmosphere nearly airless. No oxidation. SHS can also used for conveying without any risk of condensation, therefore no salmonella growth Disadvantages of SHS drying: Product temp. is 100 C or more.

Why Drying with SHS Thermodynamic advantages of SHS Drying vs. Air Drying: Overall heat transfer coefficient c and viscosity η T [ C] STEAM AIR H= m c ΔT RE = w dp ρ η 1-ε c [kj/(kg K)] 100 2.042 1.012 150 1.980 1.018 η [10-6 kg/ms] 100 12.27 21.94 150 14.18 24.07 not condensable As higher c value as higher drying rate As lower η value as better penetration condensable low temp. SHS high temp. SHS

SuperHeated Steam Conveying

SuperHeated Steam Conveying 150 C 120 C Infeed for steam by start-up Fan Steam temp. T4 Pressure P2 Heat exchanger Surface temp. T2 Energy recovery option Surface temp. T3 Cyclone Extruder head Flexible steam pipe Steam temp. T1 Pressure P1 Cutting head Pilot plant equipment constructed, implemented and evaluated on its impact on product safety, performance, characteristic and energy saving. Surface temp. T5 Surface temp. T6 Surface temp. T7 Surface temp. T8 Product temp. T9 Product 100 C Steam infeed Heated jacket rotary valve Steam outlet

Food safety and quality validation Necessary Food Safety features: 1. No condensation (temp. above 120 C) 2. Self-sanitization (prevents salmonella growth) 3. No cross-contamination (sliedly positive overpressure) 4. System operation (start, stop, die-plate change) Product Quality & energy recovery status: Palatability (Parity with current air conveying) Possible accumulation of volatiles (vapor pressure in the kibble is higher than in the system, therefore it should no risk) No temperature loss during Conveying A process steam used for conveying (flash off, etc.) can be recovered

SuperHeated Steam Drying

Energy demand to produce 1t of dry product Single Screw Extruder Air Conveying Specific Evaporative capacity 2,725 kj/kg = 0.757 kwh/kg Air Dryer to produce the 1t of dry product on a std. extrusion line in Minden Electr. energy cost: 10.9 ct/kwh Gas energy cost: 4,3 ct/kwh To produce 1t of finished product (7% moisture), we have to evaporate 17% moisture. 90.1kWh per 1 t

Global Dry Petfood Production/Year Raw material moisture 280 kt/y (Estimation 2010) Dry raw material 3,220 kt/y Process water 900 kt/y 900 kt/y Evaporated water in exhaust air flow 3,500 kt/y Wet raw material 4,400 kt/y 27% moisture Extrusion Wet kibbles after extrusion Air drying Kibbles after drying 8% moisture Finished product

Dry raw materials 3,220 kt/y Future Global Dry Petfood Production/Year Raw mat moisture 280 kt/y Process water ** 900 kt/y 900 kt/y evaporated water contains latent heat of > 2016 TJ/Y reuse of latent heat leads to CO 2 reduction of 164 kt/y* *[as natural gas (type H) combustion] Wet raw material 4,400 kt/y 27% moisture 3,500 kt/y Wet kibbles after extrusion Extrusion SHS Drying ** reuse of condensate as process water has to be validated Kibbles after drying 8% moisture Finished product

Optimized SHS Drying Process Heat exchanger Exhaust steam outlet Recirculation fan Cyclone Heat exchanger Exhaust steam Extruder head Recirculation fan SHS conveying SuperHeated Steam dryer

Energy Recovery Recovery by condensation By condensing the 120 C SHS 95% of the energy can be recovered by condensation. That means, cooling water is needed and we will end up with a huge amount of water (condensate), which has 95 C and the 50 C warm cooling water after cooling. Total amount of water after condensation 2,483 kg/h condensate at 95 C 29,6 m³/h Water 60 C Recovery by Vapour compression Vapour compression can compress the exhaust SHS from 1,02 bar at 120 C up to 10 bar at 180 C. This steam can be used as primary energy to operate the SHS dryer after reaching stable conditions The output of the heat exchanger is 130 C Water at 10bar. Enough energy for additional recovery Theoretical efficiency >70 %

Mass Balance Diagram of an SHS Dryer Heat exchanger 1,668 kwh/h Cold water at 15 C Product infeed Product moisture: 24 % Product amount : 13,583 kg/h Amount of water: 3,260 kg/h Dry matter : 10,323 kg/h Product temp.: 100 C SHS dryer 2,483 kg/h Fan Product outlet 2,483 kg/shs/h at 120 C Condenser Condensate at 50 C Hot water at 95 C Product moisture: 7 % Amount of product: 11,100 kg/h Amount of water: 777 kg/h Dry matter: 10,323 kg/h Product temp.: 110 C Ambient air at 15 C Product cooler Finished product at 35 C

Single Screw Extruder Influence on Different Process Configurations Air Conveying Specific Evaporative capacity 2,725 kj/kg = 0.757 kwh/kg Air Dryer Energy demand per t of finished product 7.29 /t product 100% SHS Conveying Specific Evaporative capacity 2,380 kj/kg = 0.661 kwh/kg Air Dryer 6,35 /t product 87% SHS Conveying Specific Evaporative capacity 2,426 kj/kg = 0.673 kwh/kg 6.47 /t product 88% SHS Dryer Maximum saving without energy recovery 12%

Mass balance of an identified vapour compressor Outlet steam 1,100 kg/h Inlet steam 900 kg/h Pressure:0.8MPaG 175 Pressure:0.05MPaG 110

SuperHeated Steam drying combined with Vapour Compression for energy recovery 3035 kg/h Exit water 130 C at 8 bar ag 120 C 160 C 120 C 160 C Heat Exchanger 1,7 MWh/h Recirculation Fan 1.87 MWh/h for heat exchanging Exhaust Steam 3035 kg/h Compressed vapour 175 C at 8 bar ag out Oxygen content =/< 1%!! 2483 kg/h Exhaust vapour 120 C at 0.5 bar ag in Pressure increase from 20 mbar ag to 500 mbar ag SuperHeated Steam Dryer The energy demand to compress exhaust steam at 1kg/h from 120 C at 0,5 bar ag to 175 C at 8 bar ag is ~ 0.14KWh/kg Drain: 110 kg/h Steam for injection: 552 kg/h, Drain: 110 kg/h Water injection: 662 kg/h Power 444 kw

Conclusion 1. This type of drying process is suitable for drying petfood. 2. No change in product quality. 3. Energy saving is possible. 4. No exhaust flow, no odours. 5. Condensate from drying and conveying can be used in the factory instead of fresh water. Has to be validated 6. No Fire and explosion risk. 7. SHS that constantly circulated is capable of creating a close loop sterile/aseptic system. 8. Vapour compression can deliver a up scalable process to recover energy theoretical estimated to ~ 70%

Next steps Energy saving by using vapour compression (existing technologies?) does that technology can handle our steam (quality of steam) feasibility, reliability and all the cost (investment operation and maintenance) when is that technology available?

Thanks!