Ag, Cu, Ni Brazing Alloy ELECTRONIC COMPONENTS AND PACKAGING SECTION 1: Chemical product and company identification n 1.1 Product Identifier Product form Product Name : Article : Silver Brazing alloy, Silver Copper Nickel Brazing alloy 1.2. Relevant identified ue of the ubtance or mixture and ue advied againt 1.2.1 Relevant identified ue Indutrial/Profeional ue pec. : Indutrial For profeional ue only Ue of the ubtance/mixture : Brazing Function or ue category : Brazing agent 1.2.2 Ue advied againt No additional information available 1.3. Detail of the upplier of the afety data heet Coining, Inc. 15 Mercede Drive Montvale, NJ 07645 Tel: +1(201)7914020 www.coininginc.com martin.oud@ametek.com 1.4. Emergency Telephone Number Emergency Number SECTION 2: Hazard identification : CHEMTREC: 800-424-9300 for US/703-527-3887 outide US For Chemical Emergency, Spill, Leak, Fire, Expoure, or Accident, call CHEMTREC-Day of Night. 2.1. Claification of the Subtance or Mixture Claification GHS-US: Skin en. (cat 1) Carcinogenicity (cat 2) Specific Target Organ Toxicity-Repeated expoure (cat 1) Advere phyicochemical, human health and environmental effect No additional information available. 2.2. Label Element In Accordance with 29CFR1910.1200 (f)(4): Not regulated for labeling. Hazard Pictogram GHS-US: n Signal Word: Warning Hazard Statement H317 May caue allergic kin reaction
H351 H372 Supect of cauing cancer Caue damage to organ through prolonged or repeated expoure Precautionary Statement P261 Avoid breathing dut/fume/ga/mit/vapor/pray P270 Do not eat, drink or moke when uing thi product P273 Avoid releae to the environment P280 Wear protective glove/protective clothing/eye protection/face protection P362 Take off contaminated clothing and wah before reue. P501 Dipoe of content/container in accordance with local, regional, national and international regulation. 2.3. Other hazard No additional information available SECTION 3: Compoition/information on ingredient n 3.1. Subtance Not applicable 3.2. Mixture Name Product Identifier % Claification according to Regulation GHS-US Copper (CAS No) 7440-50-8 0.1-95 Solid, not claified Silver (CAS No) 7440-22-4 0.1-95 Solid, not claified Nickel (CAS No) 7440-02-0 0.1-20 Skin Sen. 1, H317 Carc. 2, H351 STOT RE 1, H372 Full text of H- and P-phrae: ee ection 16 SECTION 4: Firt aid meaure n 4.1. Decription of firt aid meaure Firt-aid meaure general Firt-aid meaure after inhalation Firt-aid meaure after kin contact Firt-aid meaure after eye contact Firt-aid meaure after ingetion : Never give anything by mouth to an unconciou peron. If you feel unwell, eek medical advice (how there label where poible). : When ymptom occur; go into open air and ventilate upected area. : Removal of olidified molten material from kin require medical aitance. Cool kin rapidly with cold water after contact with molten product : Rine cautiouly with water for everal minute. Remove contact lene, if preent and eay to do. Continue rining. : Rine mouth. Do NOT induce vomiting. 4.2. Mot important ymptom and effect, both acute and delayed Symptom/injurie : Under normal condition of ue not expected to preent a ignificant hazard. Under milling, or phyical alteration metal dut may be produced that caue irritation of the repiratory tract, kin, and may be harmful. Molten material may releae toxic and irritating fume. 2 / 12
Symptom/injurie after inhalation Symptom/injurie after kin contact Symptom/injurie after eye contact Symptom/injurie after ingetion Chronic ymptom : Not expected to be a primary route of expoure. The primary acute health hazard aociated with thi product would be the potential for expoure to fume during metal proceing operation. Inhalation of dut and fume can caue metal fume fever. Symptom can include a metallic or weet tate in the mouth, weating, hivering, headache, throat irritation, fever, chill, thirtine, mucle ache, nauea, vomiting, weakne, fatigue, and hortne of breath. : Skin contact i not conidered a potential route of expoure. The primary acute health hazard aociated with thi product would be the potential for expoure to fume during metal proceing operation. Where poible allow molten material to olidify naturally. Removal of olidified molten material from kin require medical aitance. : Not expected to be a primary route of expoure. Dut generated from material cutting may caue a light irritation. Sliver may be generated, which could caue mechanical irritation or injure the eye. : Ingetion i not conidered a potential route of expoure. Silver: Chronic kin contact or ingetion of ilver dut, alt or fume can reult in a condition known a Argyria, a condition with bluih pigmentation of the kin and eye. Copper: Overexpoure to fume may caue metal fume fever (chill, mucle ache, nauea, fever, dry throat, cough, weakne, laitude); metallic or weet tate; dicoloration of kin and hair. Tiue damage of mucou membrane may follow chronic dut expoure. Nickel: May caue a form of dermatiti known a nickel itch. Intetinal irritation, which may caue diorder, convulion and aphyxia. 4.3. Indication of any immediate medical attention and pecial treatment needed If medical advice i needed, have product container or label at hand. SECTION 5: Fire fighting meaure 5.1. Extinguihing media Suitable extinguihing media Unuitable extinguihing media : Doe not burn. Ue extinguihing media appropriate for urrounding fire : None known. 5.2. Special hazard ariing from the ubtance or mixture Fire hazard : Dut, chip, or ribbon can be ignited more eaily, by an ignition ource, by improper machining, or by pontaneou combution if finely divided and damp 5.3. Advice for firefighter Firefighting intruction Protection during firefighting : Exercie caution when fighting any chemical fire. : Do not enter fire area without proper protective equipment, including repiratory protection. 3 / 12
SECTION 6: Accidental releae meaure 6.1. Peronal precaution, protective equipment and emergency procedure General meaure 6.1.1. For non-emergency peronnel Protective equipment Emergency procedure 6.1.2. For emergency reponder Protective equipment Emergency procedure 6.2. Environmental precaution Avoid releae to the environment : Handle in accordance with good indutrial hygiene and afety practice. : Ue appropriate peronal protection equipment (PPE) : Evacuate unneceary peronnel. : Equip cleanup crew with proper protection. : Ventilate area 6.3. Method and material for containment and clean up For containment Method for cleaning up 6.4 Reference to other ection See heading 8, expoure control and peronal protection. SECTION 7: Handling and torage 7.1. Precaution for afe handling Hygiene meaure 7.2. Condition for afe torage, including any incompatibilitie Storage condition Incompatible product 7.3. Specific end ue() : If metal i in molten form, allow cooling and collecting a a olid. If the metal i in olid form collect for remelting purpoe. : Clear up pill. Immediately and dipoe of wate afely. : Handle in accordance with good indutrial hygiene and afety procedure. Wah hand and other expoed area with mild oap and water before eating, drinking, or moking and again when leaving work. : Store in a dry, cool and well-ventilated place. : Strong acid. Strong bae. Strong oxidizer. Brazing. SECTION 8: Expoure control/peronal protection 8.1 Control parameter Copper (7440-50-8) Mexico OEL TWA (mg/m³) 0.2 mg/m³(fume), 1 mg/m³(dut and mit) Mexico OEL STEL (mg/m³) 2 mg/m³(fume), 2 mg/m³(dut and mit) USA ACGHI ACGIH TWA (mg/m³) 0.2 mg/m³ USA OSHA OSHA PEL (TWA) (mg/m³) 0.1 mg/m³(fume), 1 mg/m³(dut and mit) USA NIOSH NIOSH REL (TWA) (mg/m³) 0.1 mg/m³(fume), 1 mg/m³(dut and mit) USA IDLH US IDLH (mg/m3) 100 mg/m³ (dut, fume and mit) Alberta OEL TWA (mg/m³) 0.2 mg/m³ Britih Columbia OEL TWA (mg/m³) 1 mg/m³ 4 / 12
Manitoba OEL TWA (mg/m³) 0.2 mg/m³ New Brunwick OEL TWA (mg/m³) 0.2 mg/m³ Newfoundland & Labrador OEL TWA (mg/m³) 0.2 mg/m³ Nova Scotia OEL TWA (mg/m³) 0.2 mg/m³ Ontario OEL TWA (mg/m³) 0.2 mg/m³ Prince Edward Iland OEL TWA (mg/m³) 0.2 mg/m³ Québec VEMP (mg/m³) 0.2 mg/m³ Sakatchewan OEL STEL (mg/m³) 0.6 mg/m³ Sakatchewan OEL TWA (mg/m³) 0.2 mg/m³ Yukon OEL Stel (mg/m³) 0.2 mg/m³ Yukon OEL TWA (mg/m³) 0.2 mg/m³ Silver (7440-22-4) Mexico OEL TWA (mg/m³) 0.1 mg/m³ USA ACGHI ACGIH TWA (mg/m³) 0.1 mg/m³ USA OSHA OSHA PEL (TWA) (mg/m³) 0.01 mg/m³ Canada TLV- TWA (mg/m³) 0.1 mg/m³ Canada TLV-STEL (mg/m³) 0.3 mg/m³ Mexico OEL TWA (mg/m³) 1 mg/m³ USA ACGHI ACGIH TWA (mg/m³) 1.5 mg/m³ (inhalable fraction) USA OSHA OSHA PEL (TWA) (mg/m³) 1 mg/m³ USA NIOSH NIOSH REL (TWA) (mg/m³) 0.015 mg/m³ USA IDLH US IDLH (mg/m3) 10 mg/m³ Alberta OEL TWA (mg/m³) 1.5 mg/m³ Britih Columbia OEL TWA (mg/m³) 0.05 mg/m³ Manitoba OEL TWA (mg/m³) 1.5 mg/m³ (inhalable fraction) New Brunwick OEL TWA (mg/m³) 1 mg/m³ Newfoundland & Labrador OEL TWA (mg/m³) 1.5 mg/m³ Nova Scotia OEL TWA (mg/m³) 1.5 mg/m³ Nunavut OEL STEL (mg/m³) 2 mg/m³ Nunavut OEL TWA (mg/m³) 1 mg/m³ Northwet Territorie OEL STEL (mg/m³) 2 mg/m³ Northwet Territorie OEL TWA (mg/m³) 1mg/m³ Ontario OEL TWA (mg/m³) 1 mg/m³ (inhalable fraction) Prince Edward Iland OEL TWA (mg/m³) 1.5 mg/m³ (inhalable fraction) Québec VEMP (mg/m³) 1.0 mg/m³ Sakatchewan OEL STEL (mg/m³) 3 mg/m³ (inhalable fraction) Sakatchewan OEL TWA (mg/m³) 1.5 mg/m³ (inhalable fraction) Yukon OEL Stel (mg/m³) 3 mg/m³ Yukon OEL TWA (mg/m³) 1 mg/m³ 5 / 12
8.2. Expoure control Appropriate engineering control Peronal protective equipment : : Enure adequate ventilation, epecially in confined area. : Protective goggle. Inulated glove Hand protection : If material i hot, wear thermally reitant protective glove. Eye protection : During metal proceing, chemical goggle or afety glae. Repiratory protection : During metal proceing, wear approved mak. Other information : When uing, do not eat, drink or moke. SECTION 9: Phyical and chemical propertie 9.1. Information on bai phyical and chemical propertie Phyical tate : Solid Appearance : Preform, quare, ring, dic, wire Color : Metallic, ilvery or coppery Odor : Odorle Odor threhold : Not applicable ph : Neutral Relative evaporation rate (butylacetate=1) : Not applicable Melting point Freezing point Boiling point Flah point Self ignition temperature Decompoition temperature Flammability (olid, ga) Vapor preure Relative vapor preure at 20 C Relative denity Solubility : Inoluble Log Pow Log Kow Vicoity, kinematic Vicoity, dynamic Exploive propertie 6 / 12
Oxidizing propertie Exploive limit 9.2 Other information: No other information available. SECTION 10: Stability and reactivity 10.1 Reactivity : Hazardou reaction will not occur under normal condition. 10.2 Chemical tability : Stable under normal condition. Dut, chip or ribbon can be ignited more eaily, by an ignition ource, by improper machining, or by pontaneou combution if finely divided and damp. 10.3 Poibility of hazardou reaction : Hazardou polymerization will not occur. 10.4 Condition to avoid : High humidity, extremely high temperature. 10.5 Incompatible material : Strong acid. Strong bae. Strong oxidizer. 10.6. Hazardou decompoition product : Metal oxide. SECTION 11: Toxicological information 11.1 Information on toxicological effect Product: Acute toxicity : Not claified Irritation : Not claified Corroivity : Not claified Senitization : Not claified Repeated doe toxicity : Not claified Carcinogenicity : Not claified Mutagenicity : Not claified Toxicity for reproduction : Not claified 11.1 Information on toxicological effect Ingredient : LD50 and LC50 DATA: Silver (7440-22-4) LD50 oral rat >2000 mg/kg LD50 oral rat IARC Group National Toxicity Program (NTP) Statu >9000 mg/kg 2A Reaonably anticipated to be Human Carcinogen SECTION 12: Ecological information 12.1 Toxicity 7 / 12
Copper (7440-50-8) LC50 fihe 1 EC50 Daphnia 1 EC50 other aquatic organim 1 LC50 fih 2 EC50 other aquatic organim 2 0.0068 (0.0068-0.0156)mg/l (Expoure time: 96 h-specie: Pimephale promela) 0.03mg/l (Expoure time: 48h-Specie: Daphnia magna [Static]) 0.0426 (0.0426-0.0535)mg/l (Expoure time:72 h-specie: Peudokirchneriella ubcapitate [Static]) 0.3mg/l (Expoure time: 96h pecie: Pimephale promela [Static]) 0.031(0.031-0.054) mg/l (Expoure time: 96 h - Specie: Peudokirchneriella ubcapitate [Static]) Silver (7440-22-4) LC50 fihe 1 EC50 Daphnia 1 LC50 fih 2 0.00155 (0.00155-0.00293)mg/l (Expoure time: 96 h-specie: Pimephale promela [Static]) 0.00024mg/l (Expoure time: 48h-Specie: Daphnia magna [Static]) 0.0062mg/l (Expoure time: 96h pecie: Oncorhynchu myki [flowthrough]) LC50 fihe 1 EC50 Daphnia 1 EC50 other aquatic organim 1 LC50 fih 2 EC50 Dahnia 2 EC50 other aquatic organim 2 100 mg/l (Expoure time: 96 h-specie: Brachydanio rerio]) 100 mg/l (Expoure time: 48h-Specie: Daphnia magna) 0.18 mg/l (Expoure time:72 h-specie: Peudokirchneriella ubcapitate) 1.3mg/l (Expoure time: 96h Specie: Cyprinu carpio [emi-tatic]) 1 mg/l (Expoure time: 48h-Specie: Daphnia magna [Static]) 0.174 (0.174-0.311 mg/l (Expoure time: 96 h - Specie: Peudokirchneriella ubcapitate [Static]) 12.2 Peritence and degradability Soldering and Brazing Alloy Peritence and degradability Not etablihed Copper (7440-50-8) Peritence and degradability Not readily biodegradable. 12.3 Bioaccumulative potential Brazing Alloy Bioaccumulative potential Not etablihed 8 / 12
12.4 Mobility in oil No additional information available. 12.5 Reult of PBT and vpvb aement No additional information available. 12.6 Other advere effect Other information : Avoid releae to the environment. SECTION 13: Dipoal information 13.1 Wate treatment method Wate dipoal recommendation : Dipoe of wate material in accordance with all local, regional, national and international regulation. SECTION 14: Tranport information 14.1. In Accordance with DOT : Not regulated for tranport. 14.2. In Accordance with IMDG : Not regulated for tranport. 14.3. In Accordance with IATA : Not regulated for tranport. 14.4. In Accordance with TDG : Not regulated for tranport. SECTION 15: Regulatory information 15.1. Safety, health and environmental regulation/legilation pecific for the ubtance or mixture 15.1.1. US Federal Regulation All ingredient are lited on the EPA TSCA Inventory. Copper/Copper Alloy SARA Section 311/312 Hazard Clae Delayed (chronic) health hazard n Copper (7440-50-8) Lited on the United State TSCA (Toxic Subtance Control Act) Inventory Lited on United State SARA Section 313 SARA Section 313 Emiion Reporting 1% Lited on the United State TSCA (Toxic Subtance Control Act) Inventory Lited on United State SARA Section 313 RQ (Reportable Quantity, Section 304 of EPA Lit of Lit): SARA Section 313 Emiion Reporting 1% 100 lb (only applicable if particle are <100 μm) 9 / 12
Silver (7440-22-4) Lited on the United State TSCA (Toxic Subtance Control Act) Inventory Lited on United State SARA Section 313 SARA Section 313 Emiion Reporting 1% 15.1.2. US State Regulation: U.S.-California Propoition 65 Carcinogen Lit Thi product can expoe you to chemical including nickel, which i known to the State of California to caue cancer. For more information go to www.p65warning.ca.gov Copper (7440-50-8) U.S. - Maachuett Right To Know Lit U.S. New Jerey Right to Know Hazardou Subtance Lit U.S. Pennylvania RTK (Right to Know) Lit- Environmental Hazard Lit U.S. Pennylvania RTK (Right to Know) Lit U.S. - Maachuett Right To Know Lit U.S. New Jerey Right to Know Hazardou Subtance Lit U.S. Pennylvania RTK (Right to Know) Lit- Environmental Hazard Lit U.S. Pennylvania RTK (Right to Know) Lit Special Hazardou Subtance U.S. Pennylvania RTK (Right to Know) Lit 15.1.3 Canadian Regulation All ingredient are lited on the Canadian Dometic Subtance Lit Copper/Copper Alloy WHMIS Claification Uncontrolled product according to WHMIS claification criteria Copper (7440-50-8) Lited on the Canadian DSL (Dometic Subtance Lit) Lited on the Canadian IDL (Ingredient Dicloure Lit) IDL Concentration 1% WHMIS Claification Uncontrolled product according to WHMIS claification criteria Lited on the Canadian DSL (Dometic Subtance Lit) 10 / 12
Lited on the Canadian IDL (Ingredient Dicloure Lit) IDL Concentration 0.1% WHMIS Claification Cla D Diviion 2 Subdiviion B Toxic material cauing other toxic effect 15.2 Chemical afety aement No chemical afety aement ha been carried out. SECTION 16: Other information Other information GHS Full Text Phrae: Thi ha been etablihed in accordance with the SDS requirement of the OSHA Regulation 29 CFR 1910.1200 Acute Tox.1 (Inhalation: dut, mit) Acute toxicity (inhalation: dut, mit) Category 1 Acute Tox.2 (Dermal) Acute toxicity (dermal) Category 2 Acute Tox.3 (Oral) Acute toxicity (oral) Category 2 Aquatic Acute 1 Hazardou to the aquatic environment-acute Hazard Category 1 Aquatic Chronic 1 Hazardou to the aquatic environment-chronic Hazard Category 1 Aquatic Chronic 3 Hazardou to the aquatic environment-chronic Hazard Category 3 Carc.2 Carcinogenicity Category 2 Eye Irrit. 2 Seriou eye damage/eye irritation Category 2 Flam. Sol. 1 Flammable olid Category 1 Pyr. Sol. 1 Pyrophoric olid Category 1 Skin Corr. 1A Skin corroion/irritation Category 1A Skin Sen. 1 Skin enitization Category 1 STOT RE 1 Specific target organ toxicity (repeated expoure) Category 1 STOT Se 3 Specific target organ toxicity (ingle expoure) Category 3 H228 H250 H300 H310 H314 H317 H319 H330 H335 H351 H372 H400 H410 Flammable olid Catche fire pontaneouly if expoed to air Fatal if wallowed Fatal in contact with kin Caue evere kin burn and eye damage May caue an allergic kin reaction Caue eriou eye irritation Fatal if inhaled May caue repiratory irritation Supected of cauing cancer Caue damage to organ through prolonged or repeated expoure Very toxic to aquatic life Very toxic to aquatic life with long lating effect n 11 / 12
H412 P261 P270 P273 P280 P501 Harmful to aquatic life with long lating effect Avoid breathing dut/fume/ga/mit/vapor/pray Do not eat, drink or moke when uing thi product Avoid releae to the environment Wear protective glove/protective clothing/eye protection/face protection Dipoe of content/container in accordance with local, regional, national and international regulation. Key/Legend ACGIH = American Conference of Governmental Indutrial Hygienit; ADG = Autralian Code for the tranport of Dangerou Good by Road and Rail; ADR/RID = European Agreement of Dangerou by Road/Rail; AS = Standard Autralia; DFG = Deutche Forchunggemeinchaft; DOT= Department of Tranportation; DSL = Dometic Subtance Lit; EEC = European Economic Community; EINECS = European Inventory of Exiting Commercial Chemical Subtance; ELINCS = European Lit of Notified Chemical Subtance; EU = European Union; HMIS = Hazardou Material Identification Sytem; IARC = International Agency for Reearch on Cancer; IATA = International Air Tranport Aociation; IDLH= Immediately Dangerou to Life or Health; IMO = International Maritime Organization; MAK = Maximum Concentration Value in the Workplace; NDSL = Non-Dometic Subtance Lit; NFPA = National Fire Protection Aociation; NIOSH = National Intitute for Occupational Safety & Health ; NTP = National Toxicology Program; OSHA=Occupational Safety and Health Adminitration; PEL= Permiible Expoure Limit; REL= Recommended Expoure Limit; STEL = Short-term Expoure Limit; TDG = Tranportation of Dangerou Good; TLV = Threhold Limit Value; TSCA = Toxic Subtance Control Act; TWA Time weighted Average. Thi information i baed on our current knowledge and i intended to decribe the product for the purpoe of health, afety and environmental requirement only. It hould not therefore be contrued a guaranteeing any pecific property of the product. STATEMENT OF LIABILITY-DISCLAIMER To the bet of the COINING, INC knowledge, the information and recommendation contained in thi publication are reliable and accurate a of the date prepared. However, accuracy, uitability, or completene are not guaranteed, and no warranty, guarantee, or repreentation, expreed or implied, i made by COINING, INC. a to the abolute correctne or ufficiency of any repreentation contained in thi and other publication; COINING, INC. aume no reponibility in connection therewith; nor can it be aumed that all acceptable afety meaure are contained in thi and other publication, or that other or additional meaure may not be required under particular or exceptional condition or circumtance. Data may be changed from time to time. 12 / 12