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Transcription:

Page 1/5 1 Identification of substance Trade name: Product code: Manufacturer/Supplier: Information department: Emergency information: LIGHT GRAY PRIMER H.S. PM70099312 SEYMOUR OF SYCAMORE 917 Crosby Avenue Sycamore, IL 60178 (815)-895-9101, www.seymourpaint.com Health & Safety Department CHEMTEL 1-800-255-3924, 813-248-0585 if located outside the U.S. 2 Composition/Data on components Chemical Description: This product is a mixture of the substances listed below with nonhazardous additions. Dangerous components: 67-64-1 Acetone 15.78% 74-98-6 propane 12.56% 64742-89-8 VM&P Naptha 8.16% 13463-67-7 titanium dioxide 7.96% 106-97-8 n-butane 7.38% 1330-20-7 xylene (mix) 5.4% 14807-96-6 Talc (Mg3H2(SiO3)4) 5.18% 64-17-5 ethyl alcohol 3.9% 108-88-3 Toluene 3.72% 64742-47-8 Mineral Spirits 3.39% 123-86-4 n-butyl acetate 3.17% 110-19-0 isobutyl acetate 1.61% 1.18% 67-63-0 isopropyl alcohol 1.11% 108-65-6 PM acetate 1.08% Additional information: For the wording of the listed risk phrases refer to section 3. 3 Hazards identification Hazard description: Physical dangers: Effects of short-term overexposure: Effects of chronic overexposure: NFPA ratings (scale 0-4): Health = 1 Fire = 4 Reactivity = 3 HMIS-ratings (scale 0-4): Health= 1 Fire= 4 Physical Hazard= 3 Irritant Extremely flammable Danger! Extremely flammable liquid and vapor in a pressurized container. Vapors may cause flash fire. Keep away from heat, sparks, and flame. Extremely flammable. Irritating to eyes and respiratory system. Vapours may cause drowsiness and dizziness Keep out of the reach of children. Vapors cause irritation to the eyes, nose, throat, skin, and central nervous system. Symptoms may include dizziness, throat irritation, headache, fatigue,swelling of eyes, and nausea. May cause permanent brain and nervous system damage. Repeated overexposure can also damage kidneys, lungs, liver, heart, and blood. Intentional misuse by deliberately inhaling the contents may be harmful or fatal. 4 First aid measures After inhalation: After skin contact: After eye contact: If breathing is difficult, administer oxygen. Remove contaminated clothing. Wash exposed area with soap and water. Move to fresh air. Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor. (Contd. on page 2)

Page 2/5 After swallowing: Contact physician or poison control center. (Contd. of page 1) 5 Fire fighting measures Extinguishing agents: Protective equipment: CO2, sand, extinguishing powder, or water spray. Fight larger fires with water spray or alcohol resistant foam. No special measures required. 6 Accidental release measures Personal safety precautions: Wear protective equipment. Keep unprotected persons away. Environmental safety precautions: Measures for cleaning/ collecting: Do not allow product to reach sewage systems or ground water. Inform appropriate authorities in case of seepage into water course or sewage system. Do not flush with water or aqueous cleansing agents. Use diluted caustic solution. Soak up spills with inert absorbent material. Refer to section 13 for disposal information. 7 Handling and storage Fire/explosion protection: Do not spray on a naked flame or any incandescent material. Do not smoke. Protect from electrostatic charges. Storage requirements: Observe pressurized container storage regulations. Consult with your local authorities. Keep away from sources of heat and direct sunlight. Do not warehouse in subfreezing conditions. 8 Exposure controls and personal protection: Components with limit values that require monitoring at the workplace: 74-98-6 propane 1800 mg/m³, 1000 ppm 1800 mg/m³, 1000 ppm (4508) mg/m³, (2500) ppm 106-97-8 n-butane 1900 mg/m³, 800 ppm 1900 mg/m³, 800 ppm 1330-20-7 xylene (mix) 435 mg/m³, 100 ppm Short-term value: 655 mg/m³, 150 ppm Long-term value: 435 mg/m³, 100 ppm (o-, m-, & p-isomers) Short-term value: 651 mg/m³, 150 ppm Long-term value: 434 mg/m³, 100 ppm BEI 64-17-5 ethyl alcohol 1900 mg/m³, 1000 ppm 1900 mg/m³, 1000 ppm 1880 mg/m³, 1000 ppm 64742-47-8 Mineral Spirits 200 mg/m³ As total hydrocarbon vapor; Skin; (P) 123-86-4 n-butyl acetate 710 mg/m³, 150 ppm Short-term value: 950 mg/m³, 200 ppm Long-term value: 710 mg/m³, 150 ppm Short-term value: 950 mg/m³, 200 ppm Long-term value: 713 mg/m³, 150 ppm 110-19-0 isobutyl acetate 700 mg/m³, 150 ppm 700 mg/m³, 150 ppm 713 mg/m³, 150 ppm (Contd. on page 3)

Page 3/5 435 mg/m³, 100 ppm Short-term value: 545 mg/m³, 125 ppm Long-term value: 435 mg/m³, 100 ppm Short-term value: 543 mg/m³, 125 ppm Long-term value: 434 mg/m³, 100 ppm BEI 67-63-0 isopropyl alcohol 980 mg/m³, 400 ppm Short-term value: 1225 mg/m³, 500 ppm Long-term value: 980 mg/m³, 400 ppm Short-term value: 984 mg/m³, 400 ppm Long-term value: 492 mg/m³, 200 ppm Additional information: Protective hygienic measures: Breathing equipment: Protection of hands: Eye protection: 9 Physical and chemical properties: (Contd. of page 2) The International Agency for Research on Cancer has evaluated ethylbenzene and classified it as a possible human carcinogen based on sufficient evidence for carcinogenicity in experimental animals, but inadequate evidence for cancer in exposed humans. However, a two year rat and mouse gavage study by the National Toxicology Program on mixed xylene isomers including 17% ethylbenzene showed no evidence of carcinogenicity. Keep away from foodstuffs and animal feed. Wash hands after use. A respirator is generally not necessary when using this product outdoors or in large open areas. In cases of inadequate ventilation, a respiratory protective device should be worn to prevent overexposure. Use suitable respiratory protective device in case of insufficient ventilation. Due to missing tests, no glove material recommendation can be given.. Protective gloves. The glove material has to be impermeable and resistant to the substance. No glove recommendation can be given. Tightly sealed goggles General Information: Form: Aerosol Color: According to trade name description in section 1. Odor: Solvent Boiling point/boiling range: -44 C (-47 F) Flash point: -19 C (-2 F) Ignition temperature: 365.0 C (689 F) Auto igniting: Product is not self-igniting. Danger of explosion: Stable at normal temperatures. Can may burst when exposed to temperatures exceeding 120 degrees fahrenheit. In use, may form flammable/explosive vapour-air mixture. Lower Explosion Limit: 1.7 Vol % Upper Explosion Limit: 10.9 Vol % Vapor Pressure: 40 PSI, 2750 hpa Density: Not determined. Specific Gravity: Between 0.77 and 0.90 (Water equals 1.00) VOC content: 493.6 g/l / 4.12 lb/gl VOC in weight percent (less acetone): 49.3 % Solids content: 30.7 % 10 Stability and reactivity: Conditions to be avoided: Possibility of Hazardous Reactions: Do not allow the can to exceed 120 degrees Fahrenheit. Stable at normal temperatures. No dangerous reactions known. 11 Toxicological information: Primary effect on the skin: No irritant effect. Primary effect on the eye: Irritating effect. Sensitization: No sensitizing effects known. (Contd. on page 4)

Page 4/5 Additional toxicological information: Harmful (Contd. of page 3) 12 Ecological information Other information: Acquatic toxicity: This product does not contain any chloroflourocarbons (CFC's),chlorinated solvents, or heavy metals (lead, mercury, cadmium, etc.). No specific ecological data is available for this product. Harmful to aquatic organisms. Hazardous for water, do not empty into drains. 13 Disposal considerations DISPOSAL METHOD: Dispose of in accordance with local, state, and federal regulations. Do not puncture, incinerate, or compact. Partially empty cans must be disposed of responsibly. Do not heat or cut empty containers with electric or gas torches. Recommendation: Empty cans should be recycled. 14 Transport information: Hazard class: 2.1 Identification number: N/A Label 2.1 A/RID class: 2 5TF Gases UN-Number: 1950 IMDG Class: 2 Packaging group: II EMS Number: F-D,S-U Marine pollutant: No ICAO/IATA Class: 2.1 Propper shipping name: Aerosols, Flammable Consumer Commodity ORM-D 15 Regulations SARA Section 355 (extremely hazardous substances): None of the ingredients in this product are listed. SARA Section 313 (Specific toxic chemical listings): 1330-20-7 xylene (mix) TSCA (Toxic Substances Control Act): All ingredients are listed. PROPOSITION 65 Chemicals known to cause cancer: 108-88-3 Toluene PROPOSITION 65 Chemicals known to cause reproductive toxicity: 108-88-3 Toluene Canadian WHMIS: Class A, B5---Flammable Aerosols EPA: 1330-20-7 xylene (mix) D 110-19-0 isobutyl acetate D D IARC: Group 2B: The ingredient is possibly carcinogenic to humans. There is limited evidence of carcinogenicity. Group 3: The ingredient is unclassifiable as to its carcinogenicity to humans. 13463-67-7 titanium dioxide 3 1330-20-7 xylene (mix) 3 14807-96-6 Talc (Mg3H2(SiO3)4) 3 2B 67-63-0 isopropyl alcohol 3 (Contd. on page 5)

Page 5/5 (Contd. of page 4) ACGIH s: A1-designates a confirmed human carcinogen. A2-designates a suspected human carcinogen. A3-designates an animal carcinogen. A4-designates "not classifiable as a human carcinogen". 13463-67-7 titanium dioxide A4 1330-20-7 xylene (mix) A4 64-17-5 ethyl alcohol A4 110-19-0 isobutyl acetate A4 NIOSH: 13463-67-7 titanium dioxide 16 Other information This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. Contact: Craig Swafford, Regulatory Affairs. Email: cswafford@seymourpaint.com