Power-to-Cold using vacuum ice slurry technology in the scope of German WindNODE project

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Institute of Air-handling and Refrigeration (ILK Dresden) Power-to-Cold using vacuum ice slurry technology in the scope of German WindNODE project IEA SHC Task 53 Solar Cooling Workshop, 12.04.2018

Challenges in Air-Conditioning and Refrigeration Phase down of HFC refrigerants Kigali amendment of Montreal Protocol Limited choice of alternative refrigerants Continuously growing energy/electricity consumption for cooling AC becoming fundamental for survival in even more regions because of climate change Urban heat island effects in cities and metropolitan areas Transition to renewable electricity generation more volatile energy sources volatile prices (1 h, 15 min) Storage becomes crucial

Why cold thermal energy storage? Cooling/Refrigeration mostly driven by electricity ~16 % of electricity consumption in Germany for cooling 40 60 % of electricity consumption in warmer climates Cold thermal stores useful energy Integration of renewables needs storage, Power-to-Cold

Cold thermal energy storage why? Thermal storage for decoupling of cooling demand & cooling generation Efficiency increase of cold generation at favorable re-cooling / condensation conditions (day-night temperature difference)

Comparison of cold storage technologies Sensible heat storage Uses temperature difference (6/12 C 25 kj/kg ~ 7 kwh/m³) Very small difference usable Leads to very big tanks Stratification issues Latent heat storage Uses latent heat of fusion Water / Ice (333 kj/kg ~ 93 kwh/m³) High storage density Melting point close to application temperature T.Urbaneck Calmac

Ice slurry generation by direct evaporation How does it work? Method to generate ice & to create a pumpable water/ice mixture by direct evaporation of the refrigerant water under vacuum conditions Evaporation near triple point of water (611 Pa, 0 C) Evaporation at low temperature difference Storage as a single substance binary mixture of water / water ice

Ice generation by direct evaporation Chilled water from chiller 3...6 C Condensate reflux Water vapour condenser Evaporator Ice generation at water surface Chilled water to chiller 8...12 C Water vapour centrifugal compressor Water reflux Heat of evaporation (6.1 mbar; 0.01 C) h V = 2500 kj/kg Heat of fusion h fus = 333.5 kj/kg Water (liquid, 0 C) 1 000 g 1.0002 l Water vapour 118 g 24 244 l Ice slurry Ice: 882 g / 0.962 l Charging pump Ice Slurry

Pumpable Ice Slurry generated by vacuum freezing

Integration of vacuum ice cold thermal storage in chilled water system

Comparison of ice generation technologies 0 C evaporating refrigerant water (R718) Stuttgart University

Installations Vacuum ice slurry cold storage Zwickau, Germany Charging capacity: 50 kw Storage capacity: 350 kwh Discharging capacity: 100 kw Load management at local chilled water network Göttingen, Germany Charging capacity: 180 kw Storage capacity: 1 MWh Discharging capacity: 350 kw Load management at local chilled water network

Ice slurry storage within SINTEG showcase WindNODE BMWi Funding program "Smart Energy Showcases - Digital Agenda for the Energy Transition" (SINTEG) Showcases demonstrating the future of energy provision & management 5 showcases (model regions) in Germany

Vacuum ice slurry project within SINTEG/WindNODE Demonstrating vacuum ice slurry technology for Power-to-Cold applications Main goals 1. High capacity demonstrator: 500 kw 0 (@ 0 C) 2. Lower ice temperature (-5 C) for easier integration into industrial cooling systems e.g. food processing and refrigerated storage 3. Integration in ICT platform a. coordinating flexibility options b. securing grid stability with high shares of volatile renewables

Applications of vacuum ice slurry technology Energy storage in direct / indirect combination with volatile renewables Cooling of industrial processes / food processing / batch processes (breweries, diaries, bakeries, cheese maturing, dehumidification of air) Enhanced district cooling systems decentralised storage for higher peak capacity (without changing tubes or installing additional chillers) centralised storage use of off-peak electricity ice slurry for cold transportation reduced pipe size and pumping power Cold storage for demand side management or for integration of higher shares of renewable electricity Open new applications for thermally driven chillers (co- / trigeneration, concentrated solar) Combined desalination and cold generation High efficiency snow generation at any ambient temperature (sport events and facilities)

Solar thermal cooling for refrigerated warehouses Highly efficient cold generation with high temperature solar heat and double effect water/libr absorption chillers (chilled water @ 4 6 C) Ice slurry generation with low electrical input (small temperature lift) Cooling of refrigerated warehouse using ice slurry as coolant (thermal energy carrier) with constant temperature (0 C or down to -5 C with using additives) cold water 3...6 C Solar thermally driven cold generation Concentrating solar thermal energy + absorption cold water 8...12 C water vapour condenser 0 C condensate return evaporator ice generation at free surface centrifugal compressor ice slurry ice slurry storage 0 6 C 6 C 2 C 0 C ice slurry ice water mixture (slurry) charging pump in operation during charging of storage water return discharge pump

Summary 7 times higher energy density than chilled water storage ~30 % higher efficiency than block ice storage Flexible operation; 0 100 % discharging Cheap storage medium (PCM) Pumpable storage medium Sustainable, using water (R718) as refrigerant

ILK Dresden Mathias Safarik Department of Applied Energy Engineering Bertolt-Brecht-Allee 20; 01309 Dresden; Germany Tel.: +49 351 4081-700 E-Mail: ice@ilkdresden.de