Tri-Mer Packed Bed Tower Scrubbers

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Tri-er Packed Bed Tower Scrubbers for gaseous emissions NOx, Cl 2, SO 2, others acid fumes, including H 2 SO 4, HCl, HNO 3, and HF odor control single and multi-stage units combination systems for hot and cold gases Systems can incorporate particulate control, gas quench, venturis, cartridge filters, and carbon systems.

Design Criteria: V/F Series Tri-er packed bed scrubbers are versatile, reliable systems that serve the widest variety of processes. They are used and specified worldwide. Tri-er packed scrubbers are highly recommended for the efficient removal of inorganic gases, odors and fumes, and are particularly appropriate where gas streams have extreme ph. They are well-suited for use as primary or secondary systems in conjunction with thermal oxidizers, and are also used in a series where there are multiple-contaminant gas streams. Optimum system performance is achieved with systems that combine intimate gas/liquid mixing and low pressure drop. There are four broad categories of information which influence the design of these systems. CF Air flow through the scrubber, based on cubic ft/min. This is determined by the process to be handled by the scrubber, through information provided by customer and Tri-er analysis. System capacities of heavy service V/F systems range to 100,000 cfm and above. Configuration Internal vs. external recirculation system, fan location in relation to tower, duct sizes, inlet and outlet plus location of pump systems, tower access service ports, service platform requirement. aterials of Construction Determined by application; because most contaminants involve corrosive gases and fumes, material must be able to withstand continuous contact with high and low ph gases and scrubbing solutions. Standard construction materials include: polypropylene, fiberglass and PVC. Optional materials include high alloy metals such as stainless, Hastelloy and Inconel. Also duallaminate structures incorporating FRP over PVC, PP, PVDF and Teflon liners are available. Operational Efficiency Removal efficiency of scrubber: inlet vs. outlet requirement, based on mass emission in lbs/hr. in vs. lbs/hr. out. Factors to consider in calculating removal efficiency are: 1. contaminant flow composition 2. contaminant solubility 3. chemistry that will react with contaminants 4. reaction speed 5. HTU (height transfer unit) factors required for specified removal efficiency 6. liquid-to-gas ratio 7. velocity Producing a Practical System Design Using the information gathered under the efficiency requirement section above, and other factors specific to the site, Tri-er engineers determine the optimum tower diameter, packing depth, recirculation flow rate, and mist eliminator requirement in microns. These calculations form the basis for a layout similar to illustration on the facing page. External recirculation tank farm. Typical upper level access platform interfaced with existing structure. Packed column with redundant pump and fans incorporating breech-fitted stack assembly. Dual fan set up prior to installation of duct. 2

A B C Scrubber body, manufactured standard in 6" intervals, from 12" through 16' diameter. Outlet from the scrubber (Note: Can also exhaust vertically) ist eliminator B D E ist eliminator access door Recirculation liquid distribution nozzle system A F Recirculation piping system C G Recirculation pumps: single or redundant, as shown. ANSI-style pump shown is standard; vertical sump design is also available. D H (Optional) recirculation system basket strainer for prevention of pump damage and nozzle plugging. Y-strainers recommended with smaller units. Basket strainers for systems above 8,000 cfm. E I Liquid flow meter. eter can be line-mounted for smaller units; self-powered for larger systems. Electrically-powered units also available. P J Packing media. Tri-Packs 2" diameter is recommended for most applications; other options are available. F K L Packing support grid Scrubber inlet (Can be round or rectangular) J Recirculation tank. Illustrations shows internal recirculation sump; external recirculation sumps can be recommended for applications such as multi-stage scrubbers incorporating NO x control and other applications. I O Liquid sump should hold (at minimum) a 1.5X recirculation flow rate. K N Recirculation sump level control system G L O Clear packing removal portal P Clear packing fill door H Tri-er V/F Series Packed Bed Towers Are Available in the Following aterials of Construction: Polypropylene Fiberglass PVC N 3

V/F Series Capacities ODEL NUBER AXIU CF TOWER DIAETER (FEET and INCHES) STANDARD RECIRCULATION FLOW RANGE IN GALS/IN (Consult Tri-er for exact flow requirement based on application) APPROXIATE HEIGHT WITH STD. RECIRCULATION AND 5-0 PACKING (All dimensions for reference only, not for construction) V/F 12 390 1-0 4-7 10-6 V/F 18 880 1-6 9-15 11-0 V/F 24 1,570 2-0 16-25 11-6 V/F 30 2,450 2-6 25-40 11-6 V/F 36 3,530 3-0 35-58 13-0 V/F 42 4,810 3-6 48-78 14-0 V/F 48 6,280 4-0 62-100 14-6 V/F 54 7,950 4-6 80-128 15-6 V/F 60 9,815 5-0 98-158 15-6 V/F 66 11,880 5-6 118-190 16-0 V/F 72 14,135 6-0 140-226 17-0 V/F 78 16,590 6-6 166-265 17-0 V/F 84 19,240 7-0 192-307 17-6 V/F 90 22,090 7-6 220-354 17-0 V/F 96 25,130 8-0 252-402 18-0 V/F 102 28,370 8-6 284-454 18-0 V/F 108 31,808 9-0 318-508 19-0 V/F 114 35,440 9-6 354-568 19-0 V/F 120 39,270 10-0 392-628 19-0 V/F 126 43,300 10-6 432-692 19-6 V/F 132 47,516 11-0 475-760 19-6 V/F 138 51,934 11-6 519-830 20-0 V/F 144 56,550 12-0 565-904 21-0 V/F 150 61,360 12-6 614-982 22-0 V/F 156 66,366 13-0 664-1060 22-6 V/F 162 71,570 13-6 716-1145 23-0 V/F 168 76,970 14-0 770-1232 23-0 V/F 174 82,565 14-6 825-1320 25-0 V/F 180 88,360 15-0 884-1412 26-0 V/F 186 94,345 15-6 944-1509 27-0 V/F 192 100,530 16-0 1005-1608 28-0 4 Elevation estimates incorporate a minimum recirculation sump capacity of 1.5x the recirculation flow rate indicated. Elevation assumes a rectangular inlet configuration for gas dispersion, and a round outlet for external fan location. aximum cfm capacity must be confirmed by manufacturer. Efficiency requirement may dictate a lower cfm than indicated.

Tri-er s VTB Series Packed Bed Scrubbers Light Duty Integrated Fan System SERIES TOWER D FAN SIZE STD FAN HP AX. CF STD. RECIRC. RATE/GP VTB 14 8 1/2 550 6 gpm A Top-mounted exhaust blower with motor assembly VTB 18 10 2 VTB 24 12 3 880 1,570 9 gpm 16 gpm B C D E ist eliminator Spray header and nozzles Tri-Packs tower packing Packing support grid A VTB 36 18 7 1 /2 VTB 48 22 10 VTB 60 27 15 VTB 72 33 20 3,530 6,280 9,815 14,135 35 gpm 62 gpm 93 gpm 140 gpm F G H I J Tank access (optional) Recirculation tank extension (optional required with vertical pump option) Recirculation liquor Liquid flowmeter Horizontal recirculation pump L C D B 1. Standard material of construction PVC or polypropylene. 2. Inlet pressure typically limited to 3 w.g. 3. Standard packing depth 3-0. 4. Unit outlet integrated with top-mounted blower. 5. Consult Tri-er Corporation for exact fan and pump horsepower. 6. Horizontal magnetic pump is standard with model VTB 14-8 through VTB 48-22. VTB 60-27 and 72-33 may use ANSI style. 7. Vertical sump style pumps are also available. K L Scrubber inlet connection Horizontal fan discharge 8,000 cfm VTB units constructed of black polypropylene ready to ship. Packing fill and cleanout ports E N Y strainer (optional) K F O Steel sub base O I H G This compact system incorporates the exhaust blower into the packed bed tower as a unified vertical structure. VTB series applications range to 14,135 cfm. J N 5

Design Criteria: V/F and VTB Series Control Panels All Tri-er scrubber packages are available with electrical control panels, which can incorporate the following features: Panel-mounted flowmeters, ph controls, flow indicators, ORP conductivity controls, alarms and auxiliaries. PLC options. ost customers specify a dedicated PLC control interface for scrubber operation. Auxiliary loop tie-ins can be made to specific plant processes, so that system chemistry is activated automatically. This provides the user with maximum control and flexibility. UL stamped panel assemblies are available from Tri-er. Control screens Tri-er CRT operator screens depict system status in full detail, in a form most useful to plant personnel. Valve positions, liquid and air flow conditions, ph, reduction or oxidation potential and other required parameters are available at-a-glance. System alarms and other process interrupt functions are detailed through the CRT. Pre-wiring Skid-mounted: Tri-er electrical systems are available completely pre-wired prior to shipment. Larger systems: available pre-wired to terminal boxes specific to each piece of equipment. This greatly simplifies field wiring. ulti-stage scrubber pump room. Piping Piping connecting the recirculation tank, pumping system and spray header assemblies is part of the Tri-er package. These piping assemblies come in packages that which have been set up and tested at Tri-er's headquarters. V/F series scrubbers are specified for heavy duty applications such as steel pickling, plating, anodizing and other metal finishing operations generating corrosive fumes and gases. They are most effective for applications involving inorganic compounds with high solubility or chemically reactive characteristics. V/F units are used throughout the semiconductor industry. The V/F series is a design incorporating the recirculating tank, inlet transition, packed bed section, mist eliminator and a remote mounted exhaust blower. V/F units occupy a modest footprint and can be easily used as a scrubber for single or multiple tank chemical processes. aterials of Construction Standard alternatives include polypropylene, fiberglass and PVC. Capacities Capacities range from 100 cfm to over 100,000 cfm in various models. Catwalk Access V/F and VTB Series Packed Bed Systems are available with optional catwalk access platform facilities. Recirculation Tank V/F and VTB series units have recirculation tanks which incorporate a horizontal or vertical-style pump. Piping between the spray header assembly and pump is included in the package. 6

Packing The standard random dump section of the wet scrubber system incorporates ultra high efficiency TRI-PACKS tower packing, originally engineered for use with Tri-er s TRI-NOx ULTI-CHE system. ist Eliminator Efficiency ist eliminator systems are available in rigid chevron blade style and/or layered pad designs. Selection depends on the efficiency required and scrubber size. Typical mist eliminator efficiencies are based on 99% on 15 micron size droplets. Lower or higher efficiency rates are possible and will be recommended by Tri-er engineering, where applicable. Inlet vs. Outlet Performance It is critical, when calculating the efficiency of a V/F or VTB series scrubber, to know the inlet load of the contaminant being removed. This data should be provided to Tri-er in the form of a mass emission number, relating to lbs per hour of contaminant to be removed. Tri-er engineers will use of HTU (height transfer unit) and NTU factors to calculate the necessary packing depth. Also using this inlet load information, Engineering will calculate the liquid-to-gas ratio for optimum pump sizing for recirculation rates. Tri-er Corp. uses conservative calculations in the design of systems to assure reliable, long-term performance under a wide range of operating conditions. any competitive systems are designed to operate with velocities more than 20% higher than a Tri-er system, and recirculation flow rates less than 50%. Use of these under-sized systems on industrial applications often results in failure to meet operating permit requirements. For the system owner, this means the choice will be to significantly modify, or replace, the equipment. Tri-er's conservative engineering approach serves our customers predictably and well, because systems meet stack efficiency and other operational requirements from the first day they're on-line. Dual stage HCl scrubber with fiberglass columns and catwalks. ulti-stage external recirculation system. ulti-stage scrubber system (Tri-NOx ) constructed of polypropylene and fiberglass, with catwalk access. Dual pump back-up on multi-stage system. ANSI design. Pumps Pumps for the V/F series scrubber systems are offered in two categories: 1. ANSI horizontal units 2. Vertical submerged head units Blowers are available in belt-driven and direct drive versions. Exhaust Blowers In the Tri-er standard design, materials of construction include polypropylene, PVC or FRP. The inlet cone is laminar flow-molded; its bell-shaped design insures smooth air entry, with minimal system effect loss. The impeller design is backwardly inclined, flat blade (or air foil wheel). Wheels are available in Class 2, 3 or 4 categories, depending on pressure requirements. aterials of construction for fan impellers are mild steel with FRP coating, stainless steel, and special alloys such as Hastelloy. Standard arrangements include one and nine. Vibration isolation is available for the inlet and outlet duct; spring isolation is available for the fan base. The fan discharge depends on stack requirements and fan position. The fan package is then mated to the appropriate scrubber and tested. 7

Design Options Single-Stage Vertical Flow These units are applied to inorganic scrubbing applications requiring between 3 and 16 feet. of packing. This includes a multitude of chemical processes, metal finishing and semiconductor applications. This also includes certain odor control systems (such as light inputs of ammonia or sulfur-based compounds) that are accommodated with a single-stage process. Two-Stage Vertical Flow These systems use two independent columns, operating in series. Columns can operate with identical chemistry, or more typically, use two different chemical processes. An example is ammonia combined with other acids, which requires one stage for primary removal using sulfuric acid, and a second stage operating as a caustic scrubber. This design can be used in many other applications that require dual chemistries to destroy contaminants, and is common throughout Tri-er's design portfolio. ulti-stage Scrubbers (NO x ) In this equipment design, Tri-er incorporates three or more scrubber stages. The best known application for this design is the Tri-NO x ulti- Chem process, which handles NO x, (NO+NO 2 ) in any ratio. The primary application of the Tri-NO x ulti-chem process is the removal of NO x from gas streams where other contaminants co-mingle with NO x. This situation makes other types of NO x removal technology impractical, because they use catalytic devices to remove the NO x, and gas streams containing particulate or other inorganic/organic matter can readily poison the catalyst and destroy the system. Single stage V/F series packed scrubber with dual pumps and containments pan constructed of UV-stabilized polypropylene. Fiberglass-constructed, two-stage HCl scrubber with dual fans and catwalk assembly. In contrast, the Tri-NO x ulti-chem system is not vulnerable to catalytic poisoning. This feature makes the Tri-NO x ulti-chem system an excellent system for processes such as hazardous waste incinerators, calcinators, and rotary kilns; also for a wide variety of chemical nitrations and metal finishing operations which emit inorganic and organic material in concert with NO x. Tri-NOx ulti-chem plant constructed of black, UV-stabilized polypropylene with external recirculation systems and catwalk access assembly. Tri-er CORPORATION Quality Design/Build Services Since 1960 1400 onroe St. P.O. Box 730 Owosso, I 48867-0730 Phone (989) 723-7838 FAX (989) 723-7844 www.tri-mer.com salesdpt@tri-mer.com 2003 Tri-er Corp.