Comparison of Oil Retention in R134a and CO 2 Climate Control Systems

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Comparison of Oil Retention in R134a and CO 2 Climate Control Systems Lorenzo Cremaschi Yunho Hwang,Ph.D. Reinhard Radermacher, Ph.D. CEEE University of Maryland

Objective: Introduction Research Overview Experimental Results Comparison Oil Retention Characteristics Conclusions 2

Experimental Test Facility for R134a 3

Experimental Test Facility for CO 2 P Exp. Valve P Mass Flow Meter DP DP Evaporator P Gas Cooler Oil Separators Indoor Loop Outdoor Loop Accumulator P P Electric motor Compressor 4 Torque Meter

Experimental Conditions Refrigerants : R134A, R22, R410A, CO 2 (Lee, 2003) Lubricants : Mineral, POE and PAG Oil Refrigerant mass flow rate: 14 to 45 g/s (steady state) Oil Circulation Ratio (OCR): 1 to 6 wt.% OCR[wt.%] = m! m! + m! oil oil ref 100 5

Oil Injection-Extraction Device 6

OCR < 0.5 wt.% Test Code: 1LS (without any injection) OCR = 0.5 " 6.5 wt.% Test Code: 1LS transitory R134a/POE Horizontal Suction line Flow Visualization OCR = 6.5 wt.% Test Code: 1LS with oil injection 7

Cumulative Oil Retention for R134a/POE : Condenser --- : MFR ref = 30 g/s : Liquid Line : MFR ref = 45 g/s : Evaporator : Suction Line 8

Cumulative Oil Retention for R134a/POE and R134a/PAG Ref. Mass Flow rate = 45 g/s : R134a/POE : Condenser --- : R134a/PAG : Liquid Line : Evaporator : Suction Line 9

Oil Distribution for R134a/POE Oil Retention Ratio [ % ] 40 30 20 10 Suction Line Condenser Liquid Line Evaporator OCR = 1 wt.% OCR = 5 wt.% 0 30 g/s 45 g/s 30 g/s 45 g/s Refrigerant Mass Flow Rate 10

Volume Ratio [%] Oil Distribution for CO2/PAG (Lee, 2003) 40 30 20 10 Suction Line Gas Cooler Oil Circulation Ratio= 5 wt.% Evaporator Oil Circulation Ratio=1 wt.% 0 MFR=14 g/s MFR=20 g/s MFR=14 g/s MFR=20 g/s *most of the oil is retained in the headers of the microchannel heat exchanger 11

Outlet Header Microchannel Evaporator CO2/PAG (Lee, 2003) ug Outlet Header ug Inlet Header 0.06 MFR=25 g/s X in =0.5 Microchannel Header ug Microchannel Volume Ratio 0.03 0 1 3 5 Oil Circulation Ratio [wt/%] 12

Effect of Change of Mixture Viscosity on Oil Retention Volume Kinetic Viscosity Ratio ν v ~ = ν liquid, film ref,vapor CO 2 /PAG area (vrf 1.3 1.6) Viscosity Ratio Factor (vrf) vrf = v ~ oil ref MO R22 v~ Re vapor 24 x 10 4 m flux 160 kg/m2 s 13

Oil Retention Data Comparison For R134a/POE systems, if the OCR increases from 0 to 5 wt.% the oil retention increases Up to 13 ml/m in the suction line Up to 2.1 ml/m in the evaporator Up to 1.4 ml/ m in the liquid line The Reynolds number in the suction line varied between 17,000 < Re g < 26,000 for R134a systems # CO 2 /PAG systems have lower oil retention in the microchannel since the increased mass flux promotes the oil transport. However, the oil is retained in the headers ( oil traps). # For CO 2 /PAG mixture the maximum oil retention in the suction line was 10 ml/m and the Reynolds number ranged from 12,000 < Re g < 35,000 during the experiments 14

Schematic Map for Oil Transport in the Suction Line of Air Conditioning Systems Poor Oil Transport Excellent Oil Transport 15

Characteristic Parameters for Oil Retention OR = f ( OCR,g,, µ D, σ, µ, ρ, ε,x) ρ v % ref ref, ref, film film film pipe G Gravity Re Solubility Pressure, Pipe relative surface roughness Temperature, ref-oil mixture Quality and miscibility oil-ref pair 16

Dimensionless Numbers for Oil Retention Refrigerant Reynolds Number: Re g = ρ gνg D = µ g G g µ D g Oil Circulation Ratio: OCR = m! oil m! + m! oil ref Mixture Viscosity Ratio: ν ~ = ν liquid, film ν ref,vapor Mixture Weber Number: We m = m 2 m G D ρ σ m 17

Oil Retention in the Fin and Tube Evaporator for R134a/PAG Fin-and Tube Evaporator MFRref = 45 g/s OCR = 2.4 wt.% Pin = 0.465 MPa Xin = 0.06 No. of Seg. = 224 18

R134a Pressure Drop Penalty Factor in the Evaporator and Suction Line PDPF[ ] = P P component( i ) OCR= x wt.% component( i ) OCR= 0wt.% - - - : Evaporator : Suction Line R134a/PAG R134a/POE 19

CO 2 and R134a Pressure Drop Penalty Factor in the Condenser/Gas Cooler Microchannel Gas Cooler(Lee, 2003) CO 2 /PAG Fin and Tube Condenser R410A/MO R134a/PAG R410A/POE 20

Conclusion & & & & Oil Retention (OR) increases when: & & & OCR (OCR = main independent variable!) Liquid Film Viscosity Refrigerant Mass flux G The oil retention volume ratio for R134a system is slightly less than that of CO 2 system, especially at low OCRs. R134a/POE and R134a/PAG mixtures have similar oil retention characteristics A very soluble refrigerant-oil mixture (such as R134a/PAG) promotes the oil transport even thought the viscosity of the pure oil is considerable. 21

Conclusion (cont) & & CO 2 /PAG Systems using micro channel HX suffered of & High oil retention in the evaporator and gas cooler & High Pressure drop penalty factor due to the oil retained When the OCR increased from 0 to 5 wt.% then the PDPF increases of about & 30% for R134a and 20% for CO 2 in the suction Line & 20% in the evaporator (R134a) & more than double that in CO 2 evaporator (microchannel HX) & 50% in the condenser (R134a) & 2.5 times in the gascooler (CO 2 microchannel HX) 22