Presentation Title October 18, Physical Sciences Inc. 20 New England Business Center Andover, MA Outline

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Physical Sciences Inc. Standoff detection of trace level explosive residue using passive LWIR hyperspectral imaging B.R. Cosofret, T.E. Janov, M. Costolo, S. Chang, W.J. Marinelli, R. Moro, D. Brown, and J. Oxley 9 October 2009 20 New England Business Center Andover, MA 01810 Outline Program Overview Strategic Framework Technical Approach Technology Overview Summary of Test Results Next Steps, Challenges Speaker Name 1

Program Overview Ultimate goal: Develop sensor to attack terrorist networks Covert & Passive standoff detection of explosive residues on surfaces Goal of S&T efforts: Assess and demonstrate the capability to detect trace level explosive residue on surfaces using passive LWIR hyperspectral imaging Technical Objectives: Library signature development as a function of environmental conditions Demonstrate wide area detection from true standoff ranges (10-100m) Demonstrate detection and identification of explosives (, TNT, PETN, TATP, UN, AN, C4, dynamite) present at low surface densities Conduct sensor performance evaluation as a function of contamination loading, range, environmental conditions, surface types, interferents, vehicle speed Strategic Framework for Standoff Explosive Detection Speaker Name 2

Strategic Framework: Program Plan to Build an IED Concept Development Device structure Triggering mechanisms Explosives Acquisition Recruit personnel Identify sources Weaponization Modify UXO Build new Device Deployment Select target Recon target area Prep target site UXO UXO or explosives Build trigger Select CONOPs Device Packaging Concealment Identify targets CONOPs Triggers Packaging Concealment Move parts to assembly bldg Test trigger Build packaging Build concealment Integrate System Cache or deploy Assault Force movement PSYOPs movement Rehearse Attack Move and emplace IED Initiate attack Escape PSYOP dissemination Lessons learned Command Authority Finance Facilities Equipment Personnel Targets and Detection Methodology Residue Transfer Fugitive Emissions Speaker Name 3

Strategic Framework: How Low (Sensitivity) Do You Need To Go? Fabricating an IED contaminates its maker, who spreads detectable residues the trail to finding them High resolution imaging provides a richer target set Spatial discrimination & awareness of residues Fluorescent dye studies indicate spot concentrations that are exploitable with a passive LWIR hyperspectral imager Technology Overview Speaker Name 4

Technical Approach - Explosive Identification Detection & Identification Basis Molecular absorption spectroscopy Detect changes in reflectance of IR radiation from surfaces due to presence of explosive residue Characteristic explosive spectral finger prints in LWIR region (7 12 µm) Relative Absorbance 1.0 0.9 0.8 0.7 0.6 0.5 0.4 0.3 0.2 0.1 0.0 7.0 8.0 9.0 10.0 11.0 Wavelength (um) TATP Ammonium Nitrate Ammonium Perchlorate Potassium Nitrate Potassium Perchlorate Nitromethane Absorption Coefficient 0.015 0.01 0.005 Exploitable Absorption Features of Typical Homemade & Military Grade Explosives Tetryl TNT 0 7.0 8.0 9.0 10.0 11.0 12.0 Wavelength (um) Simplified Surface Reflection Model Background Radiance Reflection of Background Radiance (Path 1) Direct Thermal Emission from Contamination (Path 2) Reflected Thermal Emission from Contamination (Path 3) Thermal Emission from Surface (Path 4) Contamination Layer Surface Contamination detected as differential change in reflectance due to reflection/absorbance of background thermal radiation Model sensor signal as linear combination of radiances from each path Speaker Name 5

Combined Path Radiances Contaminant layer in thermodynamic equilibrium with surface (N S = N C ) N D = N Sε S + N B ( 1 ε S ) + 2αρ( N S N B )(1 ε S ) 1,000 950 0.012 0.010 Surface Radiance Background Radiance Reflected from Surface Background Radiance Modulated by Contaminant Layer and Reflected from Surface Radiance (W/(cm2 sr um)) 900 850 800 750 Surface Radiance (Ns) E = 1.0 Signal without Signal with Extinction 0.008 0.006 0.004 0.002 Extinction Coefficient (m2/mg) 700 0.000 7.0 8.0 9.0 10.0 11.0 Wavelength (um) 1 0.9 Reference Spectrum Extracted (Normalized) Background Target Differential Radiance Does not consider impact of atmospheric transmission Normalized Intensity 0.8 0.7 0.6 0.5 0.4 0.3 0.2 0.1 0 7.0 7.5 8.0 8.5 9.0 9.5 10.0 10.5 11.0 Wavelength (um) The SED System Adaptive Infrared Imaging Spectroradiometer (AIRIS) Real-Time Wide Area Detection of CWAs, TICs, & Bioaerosols Leverages standoff system developed for chemical weapon agents and toxic industrial chemicals Fabry-Perot Interferometer provides rapid sequential sampling of pre-programmed discrete spectra FPGA-based real time processor provides spatial-spectral detection Integrated advanced algorithms for on the move detection of chemical releases without a priori knowledge of background Simultaneously detects up to 4 materials using 20 spectral bands in 200ms Larger explosive databases possible in 10-30 seconds Speaker Name 6

AIRIS-WAD Technology Overview High speed tunable bandpass filter coupled to infrared focal plane array Detection of nerve and blister agents Intended deployment on vehicles, rotorcraft, and aircraft Built to be qualified to MIL-STD-810F for Shock, Vibration, Drop, and Temperature and MIL-STD-461/462 for EMI Dugway Simulant Release 32 o x 32 o FOV direct imaging Detections overlaid on thermal infrared image of scene using a real-time processor Color coded target identification Data acquired and processed at 5 per second 10 meter spatial resolution at 5 km range for smaller release detection Archival data storage Cold Filter Imaging Lens Interferometer IR Camera Ground Airborne Focal Plane Array Cold Shield Summary of Experimental Program Speaker Name 7

Detection on Non-Porous Real World Surfaces Feasibility Assessment Detection on a variety of non-porous metal surfaces demonstrated Semi-quantitative approach Inability to detect on exterior glass surfaces not yet understood Could be related to IR coatings used on auto glass 5 m 5 m SF-96 R134a TNT Thumb Smudge of Comp B Detection Capability as a Function of Range Detection demonstrated to 20 meters using 5 m Ranges to 100 meters possible depending on humidity and concentration levels Optics optimization required to align spatial resolution with CONOPS At 20 meters detected spot is only 2x2 pixels ATR could flag operators Zoom lens needed Automobile Trunk Lid 15 m 20 m SF-96 R134a TNT Speaker Name 8

Quantitative Performance Assessment Sample Preparation: Technical Approach Explosive material is dissolved in a solvent (methanol) and injected into a Sono-Tek Accumist ultrasonic nozzle via syringe pump Nozzle is stationary and motion of the deposition target (substrate) is actuated via a computer-controlled x-y stage (NEAT 300) Compressed air injected into the diffuser area of the nozzle Aids in evaporation of solvent Carries the droplets to the substrate surface Gravimetric analysis to determine efficiency and accuracy of method Results indicate a coating uniformity of 2.2% Mass (g) 0.0210 0.0200 0.0190 0.0180 0.0170 0.0160 Conclusion: Method yields accurate and uniform explosive deposits 0.0150 Al Foil AN + Foil 0 1 2 3 4 5 6 7 8 9 10 Sample Detection Sensitivity Measurements: Data acquired with AIRIS-WAD (8 11 µm coverage) Speaker Name 9

on controlled Al surfaces: Black Anodized and Polished Al Range = 5 m x x x x x µg/cm 2 Polished Al Fraction of Detected Pixels 1.00 0.90 0.80 0.70 0.60 0.50 0.40 0.30 0.20 0.10 0.00 Detection of Concentrations at 5 meter range Black Al Polished Al concentration (µg/cm 2 ) ITAR Information Conclusions: detection demonstrated in complex scenes at 5 m range observed at low concentrations on polished Al surface High probability of detection (P d > 90%) for low surface densities No false alarm pixels on controlled Al surfaces: Black, Polished Al, and Painted Steel Range = 10 m x x x x x x x x x x µg/cm 2 Black Al Fraction of Detected Pixels 1.00 0.90 0.80 0.70 0.60 0.50 0.40 0.30 0.20 0.10 0.00 Detection of Concentrations at 10 meter range concentration (µg/cm 2 ) Black Al Polished Al Painted Steel ITAR Information Conclusions: detection demonstrated in complex scenes at 10 m range on surfaces with a range of emissivities No false alarm pixels Speaker Name 10

on controlled Al surfaces: Black, Polished Al, and Painted Steel Range = 20 m x x x x x x x x x x µg/cm 2 Painted Steel Fraction of Detected Pixels 1.00 0.90 0.80 0.70 0.60 0.50 0.40 0.30 0.20 0.10 0.00 Detection of Concentrations at 20 meter range concentration (µg/cm 2 ) Black Al Polished Al Painted Steel ITAR Information Conclusions: Detection demonstrated in complex scenes at 20 meters range observed at low concentrations on various emissivity surfaces Extended Range Detection 37 meters Detection Car with Aluminum plates at 37 m standoff 3 surface loadings on polished Aluminum Speaker Name 11

7.5 10.5 µm vs. 8 11 µm Spectral Coverage Enables use of stronger absorption features Additional spectral bands allow multi-band correlation using Automated Target Recognition Algorithm Conclusion: Expect 3x 4x improvement in detection sensitivity with a system capable of 7.5 10.5 micron spectral coverage In addition, the system would be capable of detecting HMEs MODTRAN calculation of atmospheric transmission - 30m range - Boston weather - 25C, 60% RH HME Detections using early generation PAIRIS (7.5 10.5 micron spectral coverage) HME Detection - Urea Nitrate UN primary IR signature below 8 microns Employ PAIRIS (lower performance than AIRIS-WAD, easier to modify) Polished Aluminum Test Plates 3 contamination loadings Conclusion: Successfully demonstrated detection on all 3 concentration levels at 5 m standoff range Speaker Name 12

Challenges and Next Steps Library signature generation as a function of environmental conditions signature robustness Development of next generation detection algorithms for improved sensitivity and detection statistics (P d and P fa ) Evaluation of sensor performance (ROC curves) as a function of contamination loading, range, environmental conditions, surface types, interferents, vehicle speed, etc. Impact on signal from surface emissivity, extent of cloud cover, and sky obscuration Variation in sensitivity due to surface porosity, chemical permeability, and roughness Engineering development to align sensor with CONOPs Adjustable FOV for increased spatial resolution at long standoff ranges Integration with other sensors for a system of systems approach Speaker Name 13