International Journal of Mechanical and Materials Engineering (IJMME), Vol. (7), No., 54--60. BUANE, ISOBUANE AND HEIR MIXURES AS AN ALERANIVES O R-4a IN DOMESIC REFRIGERAOR M.A.Sattar, R Saidur, and H.H Masjuki Department of Mechanical Engineering University of Malaya 5060 Kuala Lumpur, Malaysia Email: sattar06@yahoo.com ABSRAC he present paper describes the experimental results on the performance of butane isobutene and their mixture as refrigerant in domestic refrigerator. ure butane, isobutene and mixture of propane, butane and isobutene were used as refrigerants. he performance of the refrigerator using hydrocarbons as refrigerants was investigated and compared with the performance of refrigerator when R-4a was used as refrigerant. he effect of condenser temperature and evaporator temperature on CO, refrigerating effect, condenser duty, work of compression and heat rejection ratio were investigated. he energy consumption of the refrigerator during experiment with hydrocarbons and R-4a was measured. he results show that the compressor consumed % and % less energy than that of HFC-4a at 8 C ambient temperature when iso-butane and butane was used as refrigerants respectively. he energy consumption and CO of hydrocarbons and their blends shows that hydrocarbon can be used as refrigerant in the domestic refrigerator. he CO and other result obtained in this experiment show a positive indication of using HC as refrigerants in domestic refrigerator. Keywords: Hydrocarbons, Butane, Iso-butane, Heat rejection ratio, Energy consumption. INRODUCION Natural ice was harvested, distributed and used in both commercial and home applications in the mid-800s to refrigerate food. he idea that cold could be produced by the forced evaporation of a volatile liquid under reduced pressure had been previously pursued by Willam Cullen in the eighteenth century. hese same volatile liquids could be condensed from a vapor state by application of cooling and compression was also known by the 800s. Combining these two ideas led to the development of what would ultimately become the dominant means of cooling, the vapor compression refrigerating system. Since the invention of the vapor compression refrigeration system in the middle of the 8 th century and its commercial application at the end of the 8 th century, the application of refrigeration has entered many fields. he application includes the preservation of food and medicine, airconditioning for comfort and industrial processing (Donald and Nagengast, 994). Chlorofluorocarbons (CFCs) and hydrochlorofluorocarbons (HCFCs) have many suitable properties, for example, nonflammability, low toxicity and material compatibility that have led to their common widespread use by both consumers and industries around the world, especially as refrigerants in air conditioning and refrigerating systems. Results from many researches show that this ozone layer is being depleted. he general consensus for the cause of this event is that free chlorine radicals remove ozone from the atmosphere, and later, chlorine atoms continue to convert more ozone to oxygen. he presence of chlorine in the stratosphere is the result of the migration of chlorine containing chemicals. he chlorofluorocarbons (CFCs) and hydrochloro-fluorocarbons (HCFCs) are a large class of chemicals that behave in this manner. (Radermacher and Kim, 996, Akash and Said, ). Since the discovery of the depletion of the earth s ozone layer caused mainly by CFC and HCFC and as a result of the 99 United Nations Environment rogram meeting, the phase out of CFC- and CFC-, used mainly in conventional refrigeration and air conditioning equipment, was expected by 996 (Lee and Su, ). he thermo physical properties of HFC-4a are very similar to those of CFC- and are also non-toxic environmentally safe refrigerant; the American Household Appliances Manufacturers have recommended HFC-4a as a potential replacement for CFC- in domestic refrigerators. However, while the ozone depletion potentials (ODs) of HFC-4a relative to CFC- are very low (<5.0-4 ), the global warming potentials (GWs) are extremely high (GW ) and also expensive. For this reason, the production and use of 54
HFC-4a will be terminated in the near future (ashtoush et al.,, Sekhar et al., 5, Somchai and Nares, 5). Scientist and researcher are searching the environment benign refrigerant for the domestic refrigerator and freezer. Hydrocarbon especially propane, butane and isobutene are proposed as an environment benign refrigerant. Hydrocarbons are free from ozone depletion potential and have negligible global warming potential. Lee and Su () conducted an experiment study on the use of isobutene as refrigerant in domestic refrigerator. he performance was comparable with those of CFC- and HCFC- was used as refrigerant. Akash and Said () studied the performance of LG from local market (0%propane, 55% n-butane and 5% isobutene by mass) as an alternative refrigerant for CFC- in domestic refrigerator with masses of 50g, 80g and 00g. he result showed that a mass charge of 80g gave the best performance. Devotta et al., () selected HFC- 4a, HC-90, R-407C, R-40A, and three blends of HFC-, HFC-4a and HFC-5 and found that HFC- 4a offers the highest CO, but its capacity is the lowest and requires much larger compressors. he characteristics of HC-90 are very close to those of HCFC-, and compressors require very little modification. herefore, HC-90 is a potential candidate provided the risk concerns are mitigated as had been accomplished for refrigerators. Sekhar et al., (4) investigated an experiment to retrofit a CFC system to eco-friendly system using of HCFC4a/HC90/HC600a without changing the mineral oil and found that the new mixture could reduce the energy consumption by 4 to % and improve the actual CO by to 8% from that of CFC. Sekhar et al., (5) also investigated refrigerant mixture of HCFC4a/HC in two low temperature system (domestic refrigerator and deep freezer) and two medium temperature system (vending machine and walk in cooler) and found that the HCFC4a/HC mixture that contains 9% HC blend (by weight) has better performance resulting in 0-0% and 5-5% less energy consumption (than CFC) in medium and low temperature system respectively. Hydrocarbons (HCs) are an environmentally sound alternative for CFCs and HFCs. HCs as a refrigerant have been known and used since the beginning of this century. he development of the inert CFCs in the 90s put the HC technology in the background. CFCs have been applied since then in numerous refrigeration equipments (United Nations Environment rogramme, 99). here is currently little information on the application of hydrocarbon as refrigerant in the refrigerator without modification of the components. In this experiment a domestic refrigerator designed to work with HFC-4a were investigated without modification. he experiments were conducted with pure Butane, Iso-butane, HFC-4a and the mixture of propane, butane and isobutene. EXERIMENAL SEU AND ES ROCEDURE his section provides a description of the facilities developed for conducting experimental work on a domestic refrigerator. he technique of charging and evacuation of the system is also discussed here. Experimental data collection was carried out at ECL (Energy Conservations Laboratory), Mechanical Engineering Department, University of Malaya (UM). he schematic diagram of the test unit and apparatus is shown in the Figure.. Experimental Methodology he temperature of the refrigerant inlet/outlet of each component of the refrigerator was measured with copperconstantan thermocouples ( type). he thermocouple sensors fitted at inlet and outlet of the compressor, condenser, and evaporator are shown in Figure. Evaporator Condenser Expansion valve Compressor Service ort Service ort Data Logger Computer Data acquisition system -emperature sensor -ressure sensor Figure Schematic diagram of the test unit and apparatus hermocouples/emperature sensors were interfaced with a H data logger via a C through the GIB cable for data storage. emperature measurement is necessary to find out the enthalpy in and out of each component of the system to investigate the performance. he inlet and outlet pressure of refrigerant for each of the component is also necessary to find out their enthalpy at corresponding state. he pressure transducer was fitted at the inlet and outlet of the compressor and expansion valve as shown in Figure.he pressure transducers were fitted with the - joint and then brazed with the tube to measure the pressure at desired position. he range of the pressure transducer is - to + 9 bars. he pressure transducers have also been interfaced with computer via data logger to store data. A service port was installed at the inlet of 55
expansion valve and compressor for charging and recovering the refrigerant. he location of the service port is shown in Figure. he evacuation has also been carried out through this service port. A power meter was connected with compressor to measure the power and energy consumption.. System Evacuation Moisture combines in varying degree with most of the commonly used refrigerants and reacts with the lubricating oil and with other materials in the system, producing highly corrosive compound. he resulting chemical reaction often produces pitting and other damage on the valves seals, bearing journal, cylinder wall and other polished surface of the system. It may cause the deterioration of the lubricating oil and the formation of sludge that can gum up valves, clog oil passages, score bearing surface and produce other effect that reduce the life of the system. Moisture in the system may exist in solution or as free water. Free water can freeze into the ice crystals inside the metering device and in the evaporator tubes of system that operate below the freezing point of the water. his reaction is called freeze up. When freeze up occurs, the formation of ice within the orifice of the metering device temporarily stops the flow of the liquid refrigerant (Dossat and Horan, ). Evaporator pump is turned on the internal the pressure gauge shows the pressure inside the refrigerator system.. System Charging Yellow jacket digital electronic charging scale has been used to charge HCs, their blends and HFC-4a into the system. his is an automatic digital charging system that can charge the desired amount accurately and automatically. he mechanism of the charging is shown in the Figure. Evaporator Condenser Expansion valve Compressor Service ort = emperature sensor =ressure sensor Service ort Electronic control valve LCD display control module Cylinder latform Figure Schematic diagram of the charging system Condenser Compressor Service ort Service ort Vacuum pump he charging system consists of a platform, an LCD, an electronic controlled valve and charging hose. he refrigerant cylinder was placed on the platform which measures the weight of the cylinder. he LCD displays the weight and also acts as a control panel. One charging hose was connected with the outlet of the cylinder and inlet of the electronic valve and another one was connected with the outlet of electronic valve and inlet of the service port. Using this charging system refrigerants were charged into the system according to desired amount. =emperature sensor =ressure sensor.4 est Unit Figure Schematic diagram of the evacuation system o get rid of the detrimental effect of moisture Yellow jacket 4cfm vacuum pump was used to evacuate the system. his supervac system evacuates the system fast and better which is deep enough to get rid of contaminant that could cause system failure. he evacuation system which is shown in the Figure consists of a vacuum pump, a pressure gauge and hoses. he hoses were connected with the service port to remove the moisture from the system as shown in the Figure. When the he test unit was a Samsung refrigerator and designed to work with R-4a refrigerant. he refrigerator s performance with no load and closed door condition has been investigated. he specification of the refrigerator is shown in able. 56
able echnical specifications of refrigerator freezer test unit SECIFICAIONS Freezer Capacity (liter) 80 Fresh Food Compartment 0 Capacity (liter) ower Rating (W) 60 Current rating (A) 0.9 Voltage (V) 0 Frequency (Hz) 50 No of door Refrigerant type Defrost system.5 est rocedure 4a(CFCHF) Auto Defrost he system was evacuated with the help of vacuum pump to remove the moisture and charged with the help of charging system. he pressure transducers and thermocouples fitted with the system were connected with the data logger. he data logger was interfaced with the computer and software has been installed to operate the data logger from the computer and to store the data. he data logger was set to scan the data from the temperature sensor and pressure sensor at an interval of 5 minutes within 4 hours. A power meter was connected with the refrigerator and interfaced with the computer and power meter software was installed. he power meter stores the instantaneous power and cumulative energy consumption of the refrigerator at an interval of one minute within 4 hours in the computer. he pressures and temperatures of the refrigerants from the data logger were used to determine the enthalpy of the refrigerant with the help of REFRO7 software. All equipments and test unit was installed inside the environment control chamber where the temperature and humidity was controlled. he dehumidifier has been used to maintain desired level of humidity at the control chamber. he unit can maintain humidity from 60% to 90% with an accuracy of ±5%. he humidity has been maintained at 60% RH for all experimental work. he temperature inside the chamber was maintained at 5 C and 8 C. When the temperature and humidity inside the chamber was at steady state, the experiments were started. he experiment has been conducted on the domestic refrigerator at no load and closed door conditions. RESULS AND DISCUSSIONS he comparison of the performance parameter of the refrigerants and energy consumption by the refrigerator is discussed in this section. he comparison of energy consumption and performance is given below for each of the refrigerants.. Energy Consumption by the Compressor. he energy consumption by the compressor during 4 hours was measured and stored in computer. he test was carried out at 5 C and 8 C ambient temperatures. he refrigerator consumes more energy at 8 C ambient temperature than at 5 C ambient temperature for all refrigerants as shown in the able. he energy consumption by the refrigerator is presented in the able. able Energy consumption by compressor at 5 C and 8 C ambient temperature Refrigerant used Room temperature, 5 C Energy consumption, Room temperature, 8 C Energy consumption, kwh/day kwh/day HFC4a.077.54 Isobutane..8 Butane.97.99 M.66.758 M.55.579 he compressor consumes % and % less energy when Butane and Iso-butane was used than that of HFC-4a at 8 C as shown in the able. he compressor consumes % and 4% more energy than that of HFC- 4a when mixture and mixture was used as refrigerant at 8 C.. Effect of Evaporator and Condenser emperature on Co-efficient of erformance he CO of the domestic refrigerator using R-4a as a refrigerant was considered as benchmark and the CO of butane, iso-butane and their blend were compared. he CO versus evaporator temperature is plotted at 5 C and 8 C ambient temperatures in the same graph. he results displayed in Figures 4 and 5 show a progressive increase in CO as the evaporating temperature increases. he CO of the domestic refrigerator is plotted against condenser temperature of the refrigerator and shown in Figures 6 and 7. he result displayed in Figures 6 and 7 shows that CO increases as the temperature of 57
the condenser decrease. he CO of the refrigerator when isobutene and butane was used is better than that of R-4a. his is because the enthalpy of the isobutene and butane is higher than that of the R-4a at same condition. CO.5 s=8ºc CO 4 0 s=5ºc.5 6 60 58 56 54 5 Figure 7 Effect of condenser temperature on CO at 8 C ambient temperature. Effect of Evaporator emperature on Refrigerating Effect and Compressor Work. Figure 4 Effect of evaporator temperature on CO at 5 C ambient temperature CO 0 s=8ºc Figure 5 Effect of evaporator temperature on CO at 8 C ambient temperature he refrigerating effect is the main purposes of the refrigeration system. he liquid refrigerant at low pressure side enters the evaporator. As the liquid refrigerant passes through the evaporator coil, it continually absorbs heat through the coil walls, from the medium being cooled. During this, the refrigerant continues to boil and evaporate. Finally the entire refrigerants have evaporated and only vapor refrigerant remains in the evaporator coil. he liquid refrigerant still colder than the medium being cooled, therefore the vapor refrigerants continue to absorb heat. he refrigerating effect versus evaporator temperature is shown in Figures 8 and 9.he Figures show that the refrigerating effect increases as the temperature of the evaporator decreases. he refrigerant effect when pure butane, isobutene and their blends were used is higher than that of R-4a because the enthalpy of the pure HCs and their blends are higher than that of HFC4a at same condition. CO.5.5 s=5ºc 6 60 58 56 54 5 50 Figure 6 Effect of condenser temperature on CO at 5 C ambient temperature Refrigerating effect, kj/kg 00 s=5ºc Figure 8 Effect of evaporator temperature on refrigerating effect at 5 C ambient temperature 58
Refrigerating effect, kj/kg 50 50 50 00 s=8ºc Figure 9 Effect of evaporator temperature on refrigerating effect at 8 C ambient temperature he evaporator temperature versus work of compression is shown in Figures 0 and. he Figures show that the work of compression increases as the temperature of the evaporator decreases. his is due to the fact that when the temperature of the evaporator decreases the suction temperature also decreases. At low suction temperature, the vaporizing pressure is low and therefore the density of suction vapor entering the compressor is low. Hence the mass of refrigerant circulated through the compressor per unit time decreases with the decreases in suction temperature for a given piston displacement. he decreases in the mass of refrigerant circulated increases in work of compression. he work of compression when HCs and their blends are used is higher than that of R- 4a as shown in Figures 0 and. Compressor work,kj/kg Compressor work,kj/kg 80 60 s=5ºc 40 0 00 80 60 40 Figure 0 Effect of evaporator temperature on compressor work at 5 C ambient temperature 80 s=8ºc 60 40 0 00 80 60 40 Figure Effect of evaporator temperature on compressor work at 8 C ambient temperature.4 Effect of evaporator emperature on Condenser Duty for Different Refrigerants he evaporator temperature versus condenser duty is shown in Figures and. he Figures show that the condenser duty increases as the temperature of the evaporator decreases. As work of compression increases the heat added to the hot refrigerant during compression increases so the condenser requires more heat to remove. It is found from the Figures and that the condenser duty when butane, isobutene and their blends were used is better then that of HFC-4a. Condenser duty,kj/kg 50 50 50 s=5ºc Figure Effect of evaporator temperature on condenser duty at 5 C ambient temperature Condenser duty,kj/kg 50 50 50 s=8ºc Figure Effect of evaporator temperature on condenser duty at 8 C ambient temperature.5 Heat Rejection Ratio for Different Refrigerant he condenser must reject both the energy absorbed by the evaporator and the heat of compression added by the compressor. A term often used to relate the rate of heat flow at the condenser to that of the evaporator is the heatrejection ratio. Heat rejection ratio at the condenser temperature is shown in Figures 4 and 5. he heat rejection in the condenser depends on the refrigerating effect and the work done by the compressor. he hot vapor refrigerant consists of the heat absorbed by the evaporator and the heat of compression added by the mechanical energy of the compressor motor. It is found from Figures 4 and 5 that the heat rejection ratio for butane, iso-butane and their blends is better than that of HFC-4a. 59
Heat rejection ratio.5.. 0.9 0.7 s=5ºc 50 5 54 56 58 60 6 Figure 4 Effect of condenser temperature on heat rejection ratio at 5 C ambient temperature Heat rejection ratio.5.4... s=8ºc 50 5 54 56 58 60 6 Figure 5 Effect of condenser temperature on heat rejection ratio at 8 C ambient temperature 4 CONCLUSIONS his project invested an ozone friendly, energy efficient, user friendly, safe and cost-effective alternative refrigerant for HFC4a in domestic refrigeration systems. After the successful investigation on the performance of HCs and blends of HCs as refrigerants the following conclusions can be drawn based on the results obtained. he co-efficient of performance for the HCs and blends of HCs is comparable with the coefficient of performance of HFC4a. he energy consumption of the pure HCs and blends of HCs is about similar to the energy consumption of refrigerator when HFC4a is used as refrigerant. he compressor consumes % and % less energy when Butane and Isobutane was used than that of HFC-4a at 8 C ambient temperature. HCs and mixture of HCs offer lowest inlet refrigerant temperature of evaporator. So for the low temperature application HCs and blends of HCs is better than HFC-4a. he domestic refrigerator was charged with 40g of HFC4a and 70g of HCs and blends of HCs. his is an indication of better performance of HCs as refrigerants. he experiment was performed on the domestic refrigerator purchased from the market, the components of the refrigerator was not changed or modified. his indicates the possibility of using HCs as an alternative of HFc-4a in the existing refrigerator system. Chemical and thermodynamics properties of hydrocarbon meet the requirement of a good refrigerant. Some standards allow the use HCs as refrigerant if small amount of refrigerant is used. he final conclusion is that butane and isobutene can be used in the existing refrigerator-freezer without modification of the components. REFERENCES [] Donald B, Nagengast B, 994. Heat and Cold mastering the great indoors. ASHRAE, Inc. 79 ullie Circle NE Atlanta, GA 09. ISBN-884-7-6. [] Radermacher R, Kim K, 996. Domestic refrigerator: recent development, International journal of refrigeration 9, 6-69. [].Akash B. A, Said S.A,. Assessment of LG as a possible alternative to R- in domestic refrigerators. Energy conversion and Management 44, 8-88. [4] Lee Y. S, Su C. C, Experimental studies of isobutene (R600a) as refrigerant in domestic refrigeration system. Applied hermal Engineering () 507-59. [5] ashtoush B, ahat M, Shudeifat M. A,. Experiment study of new refrigerant mixtures to replace R in domestic refrigerator. Applied hermal Engineering, 495-506. [6] Sekhar S. J, Lal D.M, 5. HFC4a/HC600a/HC90 mixture a retrofit for CFC system, International journal of refrigeration 8, 75-74. [7] Somchai Wongwises, Nares Chimres, 5. Experimental study of hydrocarbon mixtures to replace HFC-4a in a domestic refrigerator, Energy conversion and management 46, 85-00. [8] Devotta, S. Wagmare A. V., Sawant N. N., Domkundwar B.M.,. Alternatives to HFC- for air conditioners, Applied hermal Engineering, 70-75. [9] Sekhar S.J, Lal D.M, Renganarayanan S., 4. Improved energy efficiency for CFC domestic refrigerators with ozone-friendly HFC4a/HC refrigerant mixture, International Journal of thermal Science 4, 07-4. [0] United Nations Environment rogramme, 99. Study on the otential for Hydrocarbon Replacements in Existing Domestic and Small Commercial Refrigeration Appliances. UNIED NAIONS UBLICAION ISBN 9-807-765-0 [] Dossat RJ, Horan J,. rinciple of refrigeration. rentice Hall, New Jersey, USA. Fifth edition, ISBN 0--0770- pp-454 60