Dust Explosions. health & environmental sciences failure analysis & prevention

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health & environmental sciences failure analysis & prevention Dust Explosions Timothy Myers 9 Strathmore Road Natick, MA 01760 tmyers@exponent.com (508) 652-8572 December 7, 2016 A leading engineering & scientific consulting firm dedicated to helping our clients solve their technical problems.

2 Outline Combustible Dust Background Hazard Identification Dust Hazard Analysis Hazard Mitigation

Combustible Dust Background 3

4 Combustible Dusts - Effect of Particle Size Source: After Eckhoff, Dust Explosions in the Process Industries (2003).

5 Elements of a Flash Fire Combustible dust Small particle size Oxidizable Oxidizer (e.g. air) Ignition source Dispersion of dust

6 Organic and Metal Dust Flash Fires Organic Dust Metal Dust

7 Elements of a Dust Explosion Combustible dust Small particle size Oxidizable Oxidizer (e.g. air) Ignition source Dispersion of dust Confinement

Flash Fire vs. Explosion 8

Demonstration FM Global 9

10 Dust Concentration for Explosion Regime Source: After Eckhoff, Dust Explosions in the Process Industries (2003).

11 Dust Concentration Regimes Source: After Eckhoff, Dust Explosions in the Process Industries (2003).

History of Dust Explosions and Current Emphasis 12

13 First Reported Dust Explosion Mr. Giacomelli s Bakery Turin, Italy December 14, 1785 2 injuries Blew out windows and window frames Reported cause: grain flour dust ignited by lamp Source: Eckhoff, Dust Explosions in the Process Industries (2003).

Recent Dust Explosions 14

15 Recent U.S. Combustible Dust Incidents Year Facility State Dust Fatalities 1999 Gray Iron Casting Foundry MA Phenolic Resin 3 2002 Rubber Recycling Facility MS 2003 Rubber Drug Delivery Products Scrap Tire Grindings NC Polyethylene Dust 6 2003 Fiberglass Insulation Plant KY Phenolic Resin 7 2003 Automotive Wheel Foundry IN Aluminum Dust 1 2008 Sugar Refinery GA Sugar 14 2011 Metal Powder Manufacturer TN Iron Dust 5? 5

Combustible Dust National Emphasis Program Effective October 18, 2007 Reissued March 11, 2008 Outreach Targeted inspections NEP and other documents have listed OSHA regulations and NFPA Standards believed to apply to dust explosions 16

OSHA Combustible Dust NEP Results 17

Hazard Identification Test Methods 18

19 Testing Required by Standards NFPA 652 5.1 Responsibility. The owner/operator of a facility with potentially combustible dusts shall be responsible for determining whether the materials are combustible or explosible, and, if so, for characterizing their properties as required to support the DHA.

20 Testing Required by Standards NFPA 652 5.2* Screening for Combustibility or Explosibility. 5.2.1 The determination of combustibility or explosibility shall be permitted to be based upon either of the following: (1) Historical facility data or published data that are deemed to be representative of current materials and process conditions (2) Analysis of representative samples in accordance with the requirements of 5.4.1 and 5.4.3

Trough Test Is the Sample Combustible as a Dust Layer? 21 Flame held to one end of powder train Material combustible if flame propagates past heated zone In practice only some samples that are explosible are also combustible

Go/No-Go Test Is the Sample Explosible as a Dust Cloud 22 Explosion pressure measured in closed volume 2.5-kJ to 10-kJ chemical igniters typically used Material explosible if the pressure ratio (PR) is greater than 2 PP = P ee P iiiiiii P iiiiiiii

Additional Common Test Methods 23

Dust Hazard Analysis 24

25 Dust Hazard Analysis (DHA) NFPA 652 requires retroactive DHA for existing facilities within 3-year time period of the effective date of standard Some commodity specific standards using 5-year time period Next edition of 652 may extend time period Chapter 7 Provides details on DHA Methodology Material Evaluation Process Systems Building or Building Compartments NFPA 652 App. B, NFPA 651 App. F include an example DHAs

26 Dust Hazard Analysis (DHA) Multiple methodologies can be used Checklist, What-if, FMEA, HazOp, etc. Not intended to require PSM for all dusts Source: NFPA 652

Mitigation Strategies 27

Eliminating Sides of the Pentagon 28

29 NFPA Standards OSHA citations and many building codes reference NFPA Standards. NFPA Standards include both prescriptive requirements and performance-based equivalent options Mitigation options need to be determined on a process by process basis. Standards require formal dust hazard analysis. www.nfpa.org/??? i.e., www.nfpa.org/652

NFPA Standards for the Prevention of Dust Fires and Explosions NFPA 61 Standard for the Prevention of Fires and Dust Explosions in Agricultural and Food Processing Facilities NFPA 120 Standard for Fire Prevention and Control in Coal Mines NFPA 484 Standard for Combustible Metals NFPA 652 Standard on Fundamentals of Combustible Dust NFPA 654 Standard for the Prevention of Fire and Dust Explosions from the Manufacturing, Processing, and Handling of Combustible Particulate Solids NFPA 655 Standard for the Prevention of Sulfur Fires and Explosions NFPA 664 Standard of Fires and Explosions in Wood Processing and Woodworking Facilities 30

31 Related NFPA Standards and Practices NFPA 68 Standard on Explosion Protection by Deflagration Venting NFPA 69 Standard on Explosion Prevention Systems NFPA 70 National Electric Code NFPA 499 Recommended Practice for the Classification of Combustible Dusts and of Hazardous (Classified) Locations for Electrical Installations in Chemical Process Areas NFPA 505 Fire Safety Standard for Powered Industrial Trucks Including Type Designations, Areas of Use, Conversions, Maintenance, and Operations

32 Other US Standards and Practices FM Global Data Sheets 7-17 Explosion Protection Systems 7-73 Dust Collectors and Collection System 7-76 Prevention And Mitigation Of Combustible Dust Explosions And Fire Industry Specific Standards Building and Fire Codes

NFPA 652 Standard on the Fundamentals of Combustible Dust 33 New Standard - effective date September 7, 2015 Intended to cover fundamental topics that apply to all types of dusts Applies in addition to commodity specific standards

Relationship to Commodity Specific Standards Can follow commodity specific standard where it also covers requirement in 652 Requirements in 652 that are prohibited by commodity specific standard are prohibited Where a commodity specific standard does not address requirement, must follow 652 34

Alternate Protection Strategies 35

36 Alternate Protection Strategies Performance-Based Design Prescriptive Requirement Prescriptive Requirement Prescriptive Requirement Prescriptive Requirement Equivalent Design Risk Evaluation

37 Performance-Based Design Design Objectives - Life Safety - Structural Integrity -Mission Continuity -Fire Spread and Explosion Performance Criteria - Prevent Ignition - Limit Flame Propagation - Minimize Enclosure Damage Thresholds - Surfaces < MIT - Sparks < MIE - Overpressures < P es

Prescriptive Protection Methods 38

39 Areas of Guidance in NFPA Standards Dust Hazard Analysis Building construction Building explosion venting Equipment explosion protection Equipment isolation Bulk storage Material transfer systems Size reduction operations Segregation, separation, or detachment of hazard areas Items in bold apply retroactively Particle size separation Mixers and blenders Dryers Dust collection equipment Fire protection Housekeeping Management of change Control of ignition sources Employee training, inspection, and maintenance

40 Minimizing Dust Accumulations Dust accumulations can allow small event to become catastrophic Minimize escape of dust from equipment Operate equipment at negative pressure Maintain equipment seals Use dust collection systems in dust generation areas Frequent housekeeping to remove dust accumulations before they reach hazardous levels Do not neglect elevated surfaces or other difficult to reach areas

41 Combustible Dust Accumulation Thresholds Standard NFPA 484 (Metal) Combustible Dust Accumulation Threshold Color of underlying surfaces not discernible NFPA 654 (General) 1/32 over 5% or 1000 ft 2 NFPA 664 (Wood) 1/8 NFPA 499 (Electrical Classification Class II Division 1) NFPA 499 (Electrical Classification Class II Division 2) 1/8 Color of underlying surfaces not discernible

Dust Layer Accumulation Threshold Evaluation Methods in NFPA 654 42

43 Housekeeping Establish regular cleaning frequencies to maintain dust accumulations below hazard thresholds Consider quantifying material cleaned Using cleaning methods that minimize generation of clouds Vacuuming with vacuums approved for combustible dust and classified area Gentle sweeping Vigorous sweeping, blow down or steam should only be used after vacuuming and Elimination of ignition sources Use low supply pressure (<15 psig)

44 Ignition Source Control Sparks (friction, electrical, static electricity) Proper grounding, bonding Hot surfaces Hot work Open flames Heating systems Slipping belts Bearings Electrical Equipment (NFPA 499, 70)

45 Electrical Classification NFPA 499 Areas with combustible dust may be classified as Class II (dust) Division 1 or 2 by OSHA and NFPA 499 and 70 Classified electrical equipment should be used (NFPA 70 NEC) Classified industrial trucks (fork lifts) should be used (NFPA 505) Good housekeeping, prevention of dust releases and partitions, can reduce extent of classified areas

46 Unclassified Areas NFPA 499 Chapter 6 ) Electrical Classification Ignitable Dust Presence Class II, Division 1 or Zone 20/21 Class II, Division 2 or Zone 22 Unclassified Dust clouds during normal conditions or > 1/8 accumulation Dust clouds during abnormal conditions or color of underlying surfaces not discernible No visual dust clouds Color of underlying surfaces discernible The term normal does not necessarily mean the situation that prevails when everything is working properly. The term abnormal is used here in a limited sense and does not include a major catastrophe.

Explosion Protection 47

48 No Protection Source: Rembe

49 Deflagration (Explosion) Vents NFPA 68 provides equations for determining required explosion vent areas Vent reduces maximum overpressure Typically lower cost than explosion suppression systems Must vent to restricted outdoor area Flame Arresting and Particulate Retention (Flameless) vents can be used indoors

50 Undersized Vent Source: Rembe

51 Explosion Venting Source: Rembe

52 Deflagration Suppression NFPA 69 Detection of explosion Pressure rise Spark/flame detection Suppression Fast injection of chemical suppressants Can typically minimize explosion overpressure to a few psi Often used when explosion venting is not feasible Typically more expensive than venting Source: Plot from NFPA 654-2006.

53 Deflagration Suppression Slow Motion Source: Fike Corporation

54 Equipment Isolation NFPA 654 Prevent propagation of fire or deflagration between connected equipment Mechanical chokes Rotary valves Fast acting valves Flame front diverters Chemical suppressors

55 Explosion Isolation Source: Rembe

56 Summary Catastrophic dust explosions have placed an increased emphasis on the prevention and mitigation of dust explosions. Standards and guidelines provide guidance for the prevention and mitigation of dust fires and explosions. NFPA guidelines for preventing and mitigating explosions focus on: Hazard Identification Dust Hazard Analysis Mitigation Methods Housekeeping and dust collection Removal of ignition sources Explosion protection of equipment Maintenance and training

health & environmental sciences failure analysis & prevention Dust Explosions Timothy Myers 9 Strathmore Road Natick, MA 01760 tmyers@exponent.com (508) 652-8572 December 7, 2016 A leading engineering & scientific consulting firm dedicated to helping our clients solve their technical problems.