Direct measurement of the aerosol absorption and extinction cross section for a variety of chemical and biological simulants in the LWIR Kristan P. Gurton Rachid Dahmani David Ligon Army Research Laboratory, Adelphi MD Burt Bronk Air Force Research Laboratory at SBCCOM Edgewood Chemical Biological Center Aberdeen Proving Grounds, MD
Report Documentation Page Form Approved OMB No. 0704-0188 Public reporting burden for the collection of information is estimated to average 1 hour per response, including the time for reviewing instructions, searching existing data sources, gathering and maintaining the data needed, and completing and reviewing the collection of information. Send comments regarding this burden estimate or any other aspect of this collection of information, including suggestions for reducing this burden, to Washington Headquarters Services, Directorate for Information Operations and Reports, 1215 Jefferson Davis Highway, Suite 1204, Arlington VA 22202-4302. Respondents should be aware that notwithstanding any other provision of law, no person shall be subject to a penalty for failing to comply with a collection of information if it does not display a currently valid OMB control number. 1. REPORT DATE 01 OCT 2005 2. REPORT TYPE N/A 3. DATES COVERED - 4. TITLE AND SUBTITLE Direct measurement of the aerosol absorption and extinction cross section for a variety of chemical and biological simulants in the LWIR 5a. CONTRACT NUMBER 5b. GRANT NUMBER 5c. PROGRAM ELEMENT NUMBER 6. AUTHOR(S) 5d. PROJECT NUMBER 5e. TASK NUMBER 5f. WORK UNIT NUMBER 7. PERFORMING ORGANIZATION NAME(S) AND ADDRESS(ES) Army Research Laboratory, Adelphi MD 8. PERFORMING ORGANIZATION REPORT NUMBER 9. SPONSORING/MONITORING AGENCY NAME(S) AND ADDRESS(ES) 10. SPONSOR/MONITOR S ACRONYM(S) 12. DISTRIBUTION/AVAILABILITY STATEMENT Approved for public release, distribution unlimited 11. SPONSOR/MONITOR S REPORT NUMBER(S) 13. SUPPLEMENTARY NOTES See also ADM001851, Proceedings of the 2003 Joint Service Scientific Conference on Chemical & Biological Defense Research, 17-20 November 2003., The original document contains color images. 14. ABSTRACT 15. SUBJECT TERMS 16. SECURITY CLASSIFICATION OF: 17. LIMITATION OF ABSTRACT UU a. REPORT unclassified b. ABSTRACT unclassified c. THIS PAGE unclassified 18. NUMBER OF PAGES 9 19a. NAME OF RESPONSIBLE PERSON Standard Form 298 (Rev. 8-98) Prescribed by ANSI Std Z39-18
In situ measurement of the mass normalized extinction and absorption coefficients for chemical and biological simulants using flow-through aerosol photoacoustics
Aerosol spectroscopy using flow-through photoacoustics Aerosol in IR window with fresh air flush chopper laser Aerosol chamber Aerosol filter holder/substrate Modulated IR laser Flow meter Dosimetric measurement Electret Acoustic dampeners Inner cavity Electret microphone Vacuum pump Acoustic dampeners spectrophone Aerosol flow out IR detector Aerosol out IR detector
Typical spectrophone calibration using Isopropanol vapor 10000 Extinction = scatter + absorption For a calibration gas extinction = absorption 1000 Absorption (1/km) 100 10 1 0 2 4 6 8 Electret Signal (mv)
Measured size distributions for silicone oil SF-96, bacillus subtilis endospores, and Kaolin clay aerosol 1.E+05 1.E+04 Particle 1.E+03 Count (au) 1.E+02 1.E+01 SF-96 Bacillussubtilis(new) Kaolin 1.E+00 0.1 1 10 100 AerodynamicDiameter (um)
Comparison of the extinction and absorption cross-sections for aerosolized silicone oil SF-96, grade 50 1 0.1 mass normalized coefficient (m^2/gram) 0.01 Extinction(FTIRmeasured) Extinction(Mietheory) Absorption(Mietheory) ext (m^2/gram) abs (m^2/gram) 0.001 9 10 11 wavelength(um)
Comparison of the extinction and absorption cross-sections for aerosolized bacillus subtilis endospores 1 0.1 mass normalized coeffcient (m^2/gr) 0.01 0.001 absorption (Mie theory) extinction (Mie theory) extinction (FTIR measured) ext (m^2/gram) abs (m^2/gram) 9 10 11 wavelength (um)
Comparison of the extinction and absorption cross-sections for Kaolin clay aerosol 1 0.1 mass normalized coefficient (m^2/gram) 0.01 0.001 extinction (FTIR measured) extinction (Mie theory) absorption (Mie theory) ext (m^2/gram) abs (m^2/gram) 9 10 11 wavelength (um)
Future -Consider additional chemical and biological simulants, including other naturally occurring background aerosols. -Extend photoacoustic study to incorporate MIR wavelengths by introducing a new tunable CO laser system, i.e., 5-6 µm. -Begin to investigate the utility of a new/novel technique termed Single particle emission spectroscopy. coherent IR source (1-5 watts) ZnSe lens ZnSe photoelastic modulator spherical-void (or ring) electrodynamic trap Gold plated Off-axis parabola Cold shield background held at 77 K Levitated 1-30um particle LN2 cooled MCT IR detector Holograp hic notch filter