APAC Innovation Summit 2016 Series Advanced Materials & Printed Electronics November 22, Hong Kong Electoactive Fluorinated Polymers for Organic Electronics & Haptics Atsushi MIYABO Vice President and Director, Arkema K.K. General Manager, Arkema Kyoto Technical Center
The new Arkema: a global producer of specialty chemicals 7,500m sales* 19,000 employees worldwide Worldwide presence in 50 countries 137 industrial sites 13 R&D centers * 2014 pro forma 2
Leadership positions POSITION MAIN PLAYERS #1 SPECIALTY POLYAMIDES #1 #1 #3 #2 #2 #2 #3 #3 #3 PVDF THIOCHEMICALS ORGANIC PEROXIDES FLUOROGASES PMMA HYDROGEN PEROXIDE ACRYLIC MONOMERS COATINGS ADHESIVES High Performance Materials Industrial Specialties Coating Solutions Among the first 3 leaders (WW) on 90% of sales 3
Innovation: promises for 2015 New transparent and rigid biosourced polyamides for smartphones and tablets Development of the Kepstan PEKK polymer of the extreme New generation flame-retardant adhesives for aircraft interior Genius-Fix: high green strength, very fast cure grab adhesive Flexible electronics 3D printing New hydrophilic membranes for water treatment 4
Ferroelectric Materials Ferroelectric Materials are : Piezoelectric Stress & Strain Voltage & Current Pyroelectric Temperature variation Voltage & Current Crystals (rochelle salt,tryglycine sulfate (TGS) ) Ceramics (PZT, BaTiO 3 ) Fluorinated Polymers (PVDF and derivatives)
Piezotech, an Arkema Group Company Designs & Produces Fluorinated Electroactive Polymers & Inks for Organic Electronics Fluorinated Polymers Organic Electronics Piezoelectric Pyroelectric Ferroelectric Relaxor Sensors Energy Harvesting Memories Actuators MEMS. Flexibility Low Cost Large Areas Printed Electronic
7 Piezotech Road Map : Electroactive Polymers Monomers (Arkema) VF2 VF3 Ferroelectric Copolymers VF2-VF3 Relaxor Terpolymers VF2-VF3-Y Advanced Materials Ferroelectric Materials Powder, inks Relaxor Materials Inks, Powder Applications Piezo cables, piezo fibers, sheets Printed electronics Printed sensors, speakers, memories actuators OTFT Actuators, Electrocaloric, Energy harvesting
Key Assets VF2 VF3 Arkema, world leader in VF2 and PVDF. Only producer present on the three continents Arkema World leader in fluorinated monomers and gases Large volume process for VF3 Relaxor Terpolymers VF2-VF3-Y Patented process & products for relaxor terpolymers Ferroelectric Copolymers VF2-VF3 Product range development to sustain Printed electronic Dedicated R&D & Pilot facilities for product development Strong Partnerships : Private & Academics Relaxor Materials Inks, Powder, films Semi industrial production line launched Synergy with electronic development High quality Formulations & Inks
Piezotech Product Range Piezotech FC: P(VDF-TrFE) Copolymers Printable Polymers with Piezoelectric and Pyroelectric Properties for Sensors & Memories Piezotech RT: Relaxor Terpolymers High Dielectric and Electromechanical Polymers for Actuators & Dielectrics Piezotech Inks A Range of Inks based on Piezotech Polymers adapted to printing Process : Spin-coat, Slot-Die, R2Roll
Copolymers & Terpolymers Piezotech FC Piezotech RT Composition P(VDF-TrFE) P(VDF-TrFE-X) Properties Applications Ferrroelectric, Piezoelectric, Pyroelectric Sensors (IR, P, US) Actuators (small deformations) Memories Energy Harvesting Relaxor, Electrostrictive, High permitivity, Electrocaloric Processing Film & Printing Film & Printing Poling Yes No Driving Voltage Moderate High Actuators (large deformations) High-k Dielectrics (OTFT) Solid-state Cooling
Sensors Ultrasound Infra Red Pressure Courtesy Irlynx Arkema-CEA Resonnator & Filters Fibers & Textiles Courtesy Suez Shock Detection MIT Courtesy Schneider Electrics Microphones, fingertips etc
Smart Textiles Actuator Sensor Processing unit unit Interconnections supply Energy storage Antenna Energy harvesting Sensors : Temperature, Blood Pressure, Impact, IR Energy harvesting
Piezotech RT& FC : Haptic Devices Haptic in Wearables Haptic in Large Surfaces HAPPINESS H2020 Project CEA, Bosch, INRIA, University of Glasgow, Walter pack, Gaiker
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