Pb-Alloy Soldering Preform Lead, Tin, Silver, Indium, Antimony, Germanium ELECTRONIC COMPONENTS AND PACKAGING SECTION 1: Chemical product and company identification n 1.1 Product Identifier Product form Product Name : Article : High-Pb Soldering preform Tin, Silver, Indium, Antimony Lead-Soldering Alloy, 1.2. Relevant identified ue of the ubtance or mixture and ue advied againt 1.2.1 Relevant identified ue Indutrial/Profeional ue pec. : Indutrial For profeional ue only Ue of the ubtance/mixture : Soldering Function or ue category : Soldering agent 1.2.2 Ue advied againt No additional information available 1.3. Detail of the upplier of the afety data heet Coining, Inc. 15 Mercede Drive Montvale, NJ 07645 Tel: +1(201)7914020 www.coininginc.com martin.oud@ametek.com 1.4. Emergency Telephone Number Emergency Number SECTION 2: Hazard identification 2.1. Claification of the Subtance or Mixture Claification GHS-US: : CHEMTREC: 800-424-9300 for US/703-527-3887 outide US For Chemical Emergency, Spill, Leak, Fire, Expoure, or Accident, call CHEMTREC-Day of Night. Reproductive toxicity (Category 1A) (lead Chronic aquatic toxicity (Category 1) (lead) 2.2. Label Element In Accordance with 29CFR1910.1200 (f)(4): Not regulated for labeling. Hazard Pictogram GHS n Signal Word : Warning Hazard Statement H361 Supected of damaging fertility or the unborn child H373 May caue damage to organ through prolonged or repeated expoure H410 Very toxic to aquatic life with long lating effect Precautionary Statement P261 Avoid breathing dut/fume/ga/mit/vapor/pray P270 Do not eat, drink or moke when uing thi product
P273 Avoid releae to the environment P280 Wear protective glove/protective clothing/eye protection/face protection P362 Take off contaminated clothing and wah before reue. P501 Dipoe of content/container in accordance with local, regional, national and international regulation. 2.3. Other hazard No additional information available SECTION 3: Compoition/information on ingredient 3.1. Subtance Not applicable 3.2. Mixture n Name Product Identifier % Claification according to Regulation GHS-US Lead (CAS No) 7439-92-1 5-100 Repr. 1A, H361 Aquatic Chronic 1, H410 STOT RE 2, H373 Tin (CAS No) 7440-31-5 0-95 Solid Not Claified Silver (CAS No) 7440-22-4 0-5 Solid Not claified Indium (CAS No) 7440-74-6 0-97 Solid Not claified Antimony (CAS No) 7440-36-0 0-5 Solid Not claified Germanium (CAS No) 7440-56-4 0-1 Solid Not claified Full text of H- and P-phrae: ee ection 16 SECTION 4: Firt aid meaure 4.1. Decription of firt aid meaure Firt-aid meaure general Firt-aid meaure after inhalation Firt-aid meaure after kin contact Firt-aid meaure after eye contact Firt-aid meaure after ingetion : Never give anything by mouth to an unconciou peron. If you feel unwell, eek medical advice (how there label where poible). : When ymptom occur; go into open air and ventilate upected area. : Removal of olidified molten material from kin require medical aitance. Cool kin rapidly with cold water after contact with molten product : Rine cautiouly with water for everal minute. Remove contact lene, if preent and eay to do. Continue rining. : Rine mouth. Do NOT induce vomiting. 4.2. Mot important ymptom and effect, both acute and delayed Symptom/injurie Symptom/injurie after inhalation : Under normal condition of ue not expected to preent a ignificant hazard. Under milling, or phyical alteration metal dut may be produced that caue irritation of the repiratory tract, kin, and may be harmful. Molten material may releae toxic and irritating fume. : Not expected to be a primary route of expoure. The primary acute health hazard aociated with thi product would be the potential for expoure to fume during metal proceing operation. Inhalation of dut and fume can caue metal fume fever. Symptom can include a metallic or weet tate in the n 2 / 12
Symptom/injurie after kin contact Symptom/injurie after eye contact Symptom/injurie after ingetion Chronic ymptom mouth, weating, hivering, headache, throat irritation, fever, chill, thirtine, mucle ache, nauea, vomiting, weakne, fatigue, and hortne of breath. : Skin contact i not conidered a potential route of expoure. The primary acute health hazard aociated with thi product would be the potential for expoure to fume during metal proceing operation. Where poible allow molten material to olidify naturally. Removal of olidified molten material from kin require medical aitance. : Not expected to be a primary route of expoure. Dut generated from material cutting may caue a light irritation. Sliver may be generated, which could caue mechanical irritation or injure the eye. : Ingetion i not conidered a potential route of expoure. Lead: Expoure can reult in laitude (weakne, exhaution), inomnia; facial pallor; anorexia, weight lo, malnutrition; contipation, abdominal pain, colic; anemia; gingival lead line; tremor; encephalopathy; kidney dieae; hypertenion. Tin: Ha been hown to increae incidence of arcoma in animal tet. Chronic expoure to tin dut and fume may reult in "tannoi", a mild form of pneumoconioi. Silver: Chronic kin contact or ingetion of ilver dut, alt or fume can reult in a condition known a Argyria, a condition with bluih pigmentation of the kin and eye. Antimony: Expoure to dut and fume may reult in irritation eye, kin, noe, throat, mouth; cough; dizzine; fainting; dypnea (breathing difficulty); nauea, vomiting, diarrhea, tomach cramp; inomnia; anorexia; unable to mell properly. 4.3. Indication of any immediate medical attention and pecial treatment needed If medical advice i needed, have product container or label at hand. SECTION 5: Fire fighting meaure 5.1. Extinguihing media Suitable extinguihing media Unuitable extinguihing media : Doe not burn. Ue extinguihing media appropriate for urrounding fire : None known. 5.2. Special hazard ariing from the ubtance or mixture Fire hazard 5.3. Advice for firefighter Firefighting intruction Protection during firefighting SECTION 6: Accidental releae meaure : Dut, chip, or ribbon can be ignited more eaily, by an ignition ource, by improper machining, or by pontaneou combution if finely divided and damp : Exercie caution when fighting any chemical fire. : Do not enter fire area without proper protective equipment, including repiratory protection. 6.1. Peronal precaution, protective equipment and emergency procedure General meaure 6.1.1. For non-emergency peronnel Protective equipment : Handle in accordance with good indutrial hygiene and afety practice. : Ue appropriate peronal protection equipment (PPE) 3 / 12
Emergency procedure 6.1.2. For emergency reponder Protective equipment Emergency procedure 6.2. Environmental precaution Avoid releae to the environment : Evacuate unneceary peronnel. : Equip cleanup crew with proper protection. : Ventilate area 6.3. Method and material for containment and clean up For containment Method for cleaning up 6.4 Reference to other ection See heading 8, expoure control and peronal protection. SECTION 7: Handling and torage 7.1. Precaution for afe handling Hygiene meaure 7.2. Condition for afe torage, including any incompatibilitie Storage condition Incompatible product 7.3. Specific end ue() : If metal i in molten form, allow cooling and collecting a a olid. If the metal i in olid form collect for remelting purpoe. : Clear up pill. Immediately and dipoe of wate afely. : Handle in accordance with good indutrial hygiene and afety procedure. Wah hand and other expoed area with mild oap and water before eating, drinking, or moking and again when leaving work. : Store in a dry, cool and well-ventilated place. : Strong acid. Strong bae. Strong oxidizer. Soldering. Die-attach SECTION 8: Expoure control/peronal protection 8.1 Control parameter Mexico OEL TWA (mg/m³) 0.15mg/m³( dut and fume) USA ACGHI ACGIH TWA (mg/m³) 0.05 mg/m³ USA OSHA OSHA PEL (TWA) (mg/m³) 50 μg/m³ USA NIOSH NIOSH REL (TWA) (mg/m³) 0.050 mg/m³ USA IDLH US IDLH (mg/m3) 100 mg/m³ Alberta OEL TWA (mg/m³) 0.05 mg/m³ Britih Columbia OEL TWA (mg/m³) 0.05 mg/m³ Manitoba OEL TWA (mg/m³) 0.05 mg/m³ New Brunwick OEL TWA (mg/m³) 0.05 mg/m³ Newfoundland & Labrador OEL TWA (mg/m³) 0.05 mg/m³ Nova Scotia OEL TWA (mg/m³) 0.05 mg/m³ Nunavut OEL STEL (mg/m³) 0.45 mg/m³ Nunavut OEL TWA (mg/m³) 0.15 mg/m³ Northwet Territorie OEL STEL (mg/m³) 0.45 mg/m³ Northwet Territorie OEL TWA (mg/m³) 0.15 mg/m³ 4 / 12
Ontario OEL TWA (mg/m³) 0.05 mg/m³ (deignated ubtance regulation) Prince Edward Iland OEL TWA (mg/m³) 0.05 mg/m³ Québec VEMP (mg/m³) 0.05 mg/m³ Sakatchewan OEL STEL (mg/m³) 0.15mg/m³ Sakatchewan OEL TWA (mg/m³) 0.05mg/m³ Yukon OEL Stel (mg/m³) 0.45mg/m³( dut and fume) Yukon OEL TWA (mg/m³) 0.15mg/m³( dut and fume) Tin (7440-31-5) Mexico OEL TWA (mg/m³) 2 mg/m³ Mexico OEL STEL (mg/m³) 4 mg/m³ USA ACGHI ACGIH TWA (mg/m³) 2 mg/m³ USA NIOSH/OSHA NIOSH REL (TWA) (mg/m³) 2 mg/m³ USA IDLH US IDLH (mg/m3) 100 mg/m³ Alberta OEL TWA (mg/m³) 2 mg/m³ Britih Columbia OEL TWA (mg/m³) 2 mg/m³ Manitoba OEL TWA (mg/m³) 2 mg/m³ New Brunwick OEL TWA (mg/m³) 2 mg/m³ Newfoundland & Labrador OEL TWA (mg/m³) 2 mg/m³ Nova Scotia OEL TWA (mg/m³) 2 mg/m³ Ontario OEL TWA (mg/m³) 2 mg/m³ Prince Edward Iland OEL TWA (mg/m³) 2 mg/m³ Québec VEMP (mg/m³) 2 mg/m³ Sakatchewan OEL STEL (mg/m³) 4 mg/m³ Sakatchewan OEL TWA (mg/m³) 2 mg/m³ Silver (7440-22-4) Mexico OEL TWA (mg/m³) 0.1 mg/m³ USA ACGHI ACGIH TWA (mg/m³) 0.1 mg/m³ USA OSHA OSHA PEL (TWA) (mg/m³) 0.01 mg/m³ Canada TLV- TWA (mg/m³) 0.1 mg/m³ Canada TLV-STEL (mg/m³) 0.3 mg/m³ Indium (7440-74-6 ) Mexico PEL (mg/m³) 0.1 mg/m³ Mexico TLV-STEL (mg/m³) 0.3 mg/m³ USA ACGHI TLV- TWA (mg/m³) 0.1 mg/m³ USA OSHA OSHA PEL (mg/m³) 0.1 mg/m³ Canada TLV- TWA (mg/m³) 0.1 mg/m³ Canada TLV-STEL (mg/m³) 0.3 mg/m³ Antimony (7440-36-0) Mexico PEL (mg/m³) Not etablihed Mexico TLV-TWA (mg/m³) 0.5 mg/m³ 5 / 12
Mexico TLV-STEL (mg/m³) Not etablihed USA ACGHI ACGHI- TWA (mg/m³) 0. 05mg/m³ USA NIOSH/OSHA TWA (mg/m³) 0.5 mg/m³ USA IDLH IDLH (mg/m³) 50 mg/m³ Canada TLV- TWA (mg/m³) 0.5 mg/m³ Canada TLV-STEL (mg/m³) 1.5 mg/m³ Germanium (7440-56-4) Mexico PEL/TLV-STEL (mg/m³) Not etablihed USA-NIOSH PEL/TLV-STEL (mg/m³) Not etablihed Canada PEL/TLV-STEL (mg/m³) Not etablihed 8.2. Expoure control Appropriate engineering control Peronal protective equipment : : Enure adequate ventilation, epecially in confined area. : Protective goggle. Inulated glove Hand protection Eye protection Repiratory protection Other information : If material i hot, wear thermally reitant protective glove. : During metal proceing, chemical goggle or afety glae. : During metal proceing, wear approved mak. : When uing, do not eat, drink or moke. SECTION 9: Phyical and chemical propertie 9.1. Information on bai phyical and chemical propertie Phyical tate : Solid Appearance : Preform, quare, ring, dic Color : Metallic Odor : Odorle Odor threhold : Not applicable ph : Neutral Relative evaporation rate (butylacetate=1) : Not applicable Melting point Freezing point Boiling point Flah point Self ignition temperature 6 / 12
Decompoition temperature Flammability (olid, ga) Vapor preure Relative vapor preure at 20 C Relative denity Solubility Log Pow Log Kow Vicoity, kinematic Vicoity, dynamic Exploive propertie Oxidizing propertie Exploive limit : Inoluble 9.2 Other information No other information available SECTION 10: Stability and reactivity 10.1 Reactivity Hazardou reaction will not occur under normal condition. 10.2 Chemical tability Stable under normal condition. Dut, chip or ribbon can be ignited more eaily, by an ignition ource, by improper machining, or by pontaneou combution if finely divided and damp. 10.3 Poibility of hazardou reaction Hazardou polymerization will not occur. 10.4 Condition to avoid Direct unlight. Extremely high or low temperature. 10.5 Incompatible material Strong acid. Strong bae. Strong oxidizer. 10.6. Hazardou decompoition product Metal oxide. SECTION 11: Toxicological information 11.1 Information on toxicological effect - Product Acute toxicity Irritation Corroivity Senitization Repeated doe toxicity Carcinogenicity : Not claified : Not claified : Not claified : Not claified : Lead can caue potential harm to the developing fetu : Lead i claified a poible carcinogen 7 / 12
Mutagenicity Toxicity for reproduction : Not claified : No pecific data available 11.2 Information on toxicological effect Ingredient() ATE US (oral) ATE US (dut, mit) 500 mg/kg body weight 1.50mg/l/4h Silver (7440-22-4) LD50 oral rat >2000 mg/kg Antimony (7440-36-0) LD50 oral rat 100 mg/kg SECTION 12: Ecological information 12.1 Toxicity LC50 fihe 1 EC50 Daphnia 1 LC50 fih 2 0.44mg/l (Expoure time: 96 h-specie: Cyprinu carpio [emi-tatic]) 600 μg/l (Expoure time: 48 h - Specie: water flea) 1.17 mg/l (Expoure time: 96h pecie: Oncorhynchu myki [flowthrough]) Silver (7440-22-4) LC50 fihe 1 EC50 Daphnia 1 LC50 fih 2 0.00155 (0.00155-0.00293)mg/l (Expoure time: 96 h-specie: Pimephale promela [Static]) 0.00024mg/l (Expoure time: 48h-Specie: Daphnia magna [Static]) 0.0062mg/l (Expoure time: 96h pecie: Oncorhynchu myki [flowthrough]) 12.2 Peritence and degradability Soldering Alloy Peritence and degradability Not etablihed 12.3 Bioaccumulative potential Soldering Alloy Bioaccumulative potential Not etablihed 12.4 Mobility in oil No additional information available. 12.5 Reult of PBT and vpvb aement 8 / 12
No additional information available. 12.6 Other advere effect Other information SECTION 13: Dipoal information 13.1 Wate treatment method : Avoid releae to the environment. EURLW Code : According to the European Wate Catalogue, Wate Code are not product pecific, but application pecific. Wate code hould be aigned by the uer baed on the application for which the product wa ued. Wate dipoal recommendation SECTION 14: Tranport information 14.1. In Accordance with DOT : Not regulated for tranport. 14.2. In Accordance with IMDG : Not regulated for tranport. 14.3. In Accordance with IATA : Not regulated for tranport. 14.4. In Accordance with TDG : Not regulated for tranport. SECTION 15: Regulatory information : Dipoe of wate material in accordance with all local, regional, national and international regulation. 15.1. Safety, health and environmental regulation/legilation pecific for the ubtance or mixture 15.1.1. US Federal Regulation All ingredient are lited on the EPA TSCA Inventory. n Lited on the United State TSCA (Toxic Subtance Control Act) Inventory Lited on United State SARA Section 313 SARA Section 313 Emiion Reporting 0.1% Silver (7440-22-4) Lited on the United State TSCA (Toxic Subtance Control Act) Inventory Lited on United State SARA Section 313 SARA Section 313 Emiion Reporting 1% Antimony (7440-36-0) Lited on the United State TSCA (Toxic Subtance Control Act) Inventory Lited on United State CERCLA 500 lb final RQ (no reporting of releae of thi hazardou ubtance i required if the diameter of the piece of the olid metal releaed i >100 μm ); 2270 kg final RQ (no reporting of releae of thi hazardou ubtance i required if the diameter of the piece of the olid metal releaed i >100 μm ). 9 / 12
15.1.2. US State Regulation: U.S.-California-Propoition 65 Carcinogen lit U.S.-California-Propoition 65 Carcinogen lit U.S.-California-Propoition 65 Carcinogen lit U.S.-California-Propoition 65 Carcinogen lit WARNING: Thi product contain chemical known to the State of California to caue cancer. WARNING: Thi product contain chemical known to the State of California to caue birth defect. WARNING: Thi product contain chemical known to the State of California to caue (Female) reproductive harm. WARNING: Thi product contain chemical known to the State of California to caue (Male) reproductive harm. U.S. - Maachuett Right To Know Lit U.S. New Jerey Right to Know Hazardou Subtance Lit U.S. Pennylvania RTK (Right to Know) Lit Environmental Hazard Lit U.S. Pennylvania RTK (Right to Know) Lit Tin (7440-31-5) U.S. - Maachuett Right To Know Lit U.S. New Jerey Right to Know Hazardou Subtance Lit U.S. Pennylvania RTK (Right to Know) Lit 15.1.3 Canadian Regulation All ingredient are lited on the Canadian Dometic Subtance Lit Lited on the Canadian DSL (Dometic Subtance Lit) Lited on the Canadian IDL (Ingredient Dicloure Lit) IDL Concentration 0.1% WHMIS Claification Cla D Diviion Subdiviion B A-Very Toxic material cauing other toxic effect Tin (7440-31-5) Lited on the Canadian DSL (Dometic Subtance Lit) Lited on the Canadian IDL (Ingredient Dicloure Lit) IDL Concentration 1% WHMIS Claification Uncontrolled product according to WHMIS claification criteria 10 / 12
15.2 Chemical afety aement No chemical afety aement ha been carried out. SECTION 16: Other information Other information GHS Full Text Phrae: Thi Safety Data Sheet ha been etablihed in accordance with the SDS requirement of the OSHA Regulation 29 CFR 1910.1200 Acute Tox.1 (Inhalation: dut, mit) Acute toxicity (inhalation: dut, mit) Category 1 Acute Tox.2 (Dermal) Acute toxicity (dermal) Category 2 Acute Tox.3 (Oral) Acute toxicity (oral) Category 2 Aquatic Acute 1 Hazardou to the aquatic environment-acute Hazard Category 1 Aquatic Chronic 1 Hazardou to the aquatic environment-chronic Hazard Category 1 Aquatic Chronic 3 Hazardou to the aquatic environment-chronic Hazard Category 3 Carc.2 Carcinogenicity Category 2 Eye Irrit. 2 Seriou eye damage/eye irritation Category 2 Flam. Sol. 1 Flammable olid Category 1 Pyr. Sol. 1 Pyrophoric olid Category 1 Skin Corr. 1A Skin corroion/irritation Category 1A Skin Sen. 1 Skin enitization Category 1 STOT RE 1 Specific target organ toxicity (repeated expoure) Category 1 STOT Se 3 Specific target organ toxicity (ingle expoure) Category 3 H228 H250 H300 H310 H314 H317 H319 H330 H335 H351 H372 H400 H410 H412 P261 P270 Flammable olid Catche fire pontaneouly if expoed to air Fatal if wallowed Fatal in contact with kin Caue evere kin burn and eye damage May caue an allergic kin reaction Caue eriou eye irritation Fatal if inhaled May caue repiratory irritation Supected of cauing cancer Caue damage to organ through prolonged or repeated expoure Very toxic to aquatic life Very toxic to aquatic life with long lating effect Harmful to aquatic life with long lating effect Avoid breathing dut/fume/ga/mit/vapor/pray Do not eat, drink or moke when uing thi product n 11 / 12
P273 P280 P501 Avoid releae to the environment Wear protective glove/protective clothing/eye protection/face protection Dipoe of content/container in accordance with local, regional, national and international regulation. Key/Legend ACGIH = American Conference of Governmental Indutrial Hygienit; ADG = Autralian Code for the tranport of Dangerou Good by Road and Rail; ADR/RID = European Agreement of Dangerou by Road/Rail; AS = Standard Autralia; DFG = Deutche Forchunggemeinchaft; DOT= Department of Tranportation; DSL = Dometic Subtance Lit; EEC = European Economic Community; EINECS = European Inventory of Exiting Commercial Chemical Subtance; ELINCS = European Lit of Notified Chemical Subtance; EU = European Union; HMIS = Hazardou Material Identification Sytem; IARC = International Agency for Reearch on Cancer; IATA = International Air Tranport Aociation; IDLH= Immediately Dangerou to Life or Health; IMO = International Maritime Organization; MAK = Maximum Concentration Value in the Workplace; NDSL = Non-Dometic Subtance Lit; NFPA = National Fire Protection Aociation; NIOSH = National Intitute for Occupational Safety & Health ; NTP = National Toxicology Program; OSHA=Occupational Safety and Health Adminitration; PEL= Permiible Expoure Limit; REL= Recommended Expoure Limit; STEL = Short-term Expoure Limit; TDG = Tranportation of Dangerou Good; TLV = Threhold Limit Value; TSCA = Toxic Subtance Control Act; TWA Time weighted Average. Thi information i baed on our current knowledge and i intended to decribe the product for the purpoe of health, afety and environmental requirement only. It hould not therefore be contrued a guaranteeing any pecific property of the product. STATEMENT OF LIABILITY-DISCLAIMER To the bet of the COINING, INC knowledge, the information and recommendation contained in thi publication are reliable and accurate a of the date prepared. However, accuracy, uitability, or completene are not guaranteed, and no warranty, guarantee, or repreentation, expreed or implied, i made by COINING, INC. a to the abolute correctne or ufficiency of any repreentation contained in thi and other publication; COINING, INC. aume no reponibility in connection therewith; nor can it be aumed that all acceptable afety meaure are contained in thi and other publication, or that other or additional meaure may not be required under particular or exceptional condition or circumtance. Data may be changed from time to time. 12 / 12