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Protection, prevention and environmental impact of fire in a tire storage SNCP experience feedback report Spray sprinkler system Recommendations on fire protection in tyre storage facilities using spray sprinkler system 05 Centre Français du Caoutchouc et des Polymères industriels 60, RUE AUBER 94408 VITRY SUR SEINE CEDEX TEL : 01 49 60 57 57 FAX : 01 45 21 03 50 N SIRET : 78435748500035 APE : 911 A SYNDICAT PROFESSIONNEL 53394 LOI DU 21 MARS 1884 Mél : info@lecaoutchouc.com - Internet : www.lecaoutchouc.com

Summary sheet Automatic fire ignition and extinguishing tests in tyre storage facilities. tyres stored on side, on tread and laced storage height up to 7.45 m ceiling height up to 12 m fire protection system using K11.2, K17 and K17 ESFR sprinklers Lessons learnt from the tests tyres do not ignite easily without an accelerating agent pyrolysis is slow to set in the heat release rate is low for the first 3 minutes, then increases rapidly the fire's kinetics, development and heat release rate are similar for the three types of storage configurations: on side, on tread and laced the automatic extinguishing system acts efficiently with less water on on-side storage the automatic extinguishing system acts in the same way on both types of storage: on tread and laced the first spray sprinkler head opens before the flames lick the ceiling extinguishing efficiency is affected by the clearance the fire does not spread to another island 2.4 m away with the sprinklers operating Copyright SNCP december 2007 Page 2

at the same flow, with all other conditions being equal, a K17 (242) spray sprinkler is more efficient than a K11.2 (160) with spray heads in control mode, the quantity of burnt tyres is high: up to 10,000 kg of burnt tyres with spray heads in control mode, the quantity of smoke emitted is considerable; visibility in the building is poor and hinders fire-fighting operations the smoke emitted would not have any reversible, irreversible or lethal effects on the exposed population (SNCP/REX/ENV/02 2007/S, SNCP/REX/ENV/03 2007/S, SNCP/REX/ENV/04 2007/VC) the release levels in the extinguishing water are compatible with the daily limits authorised for industrial facilities, whereas fire extinguishing water is a one-off release and limited in time (SNCP/REX/ENV/02 2007/S, SNCP/REX/ENV/03 2007/S, SNCP/REX/ENV/04 2007/VC) using a wetting additive and K17 ESFR heads at 1.8 bar in an existing system dramatically improves extinguishing efficiency suppression mode is obtained and the quantity of tyres burnt is very low (10 kg), for a storage height of 7.45 m use of an additive in a sprinkler system must be made during the wetting phase. The foaming phase degrades the sprinkler system's efficiency (ancillary result of the prep tests prior to the full-scale tests) Recommendations In existing storage facilities equipped with NFPA 13-compliant spray type sprinkler systems, both types of storage (on-tread and laced) can be used. The increased discharge coefficient of the spray type heads (K17 instead of K11.2) enhances extinguishing efficiency for a given storage height. By using an additive in its wetting phase and installing K17 ESFR heads in an existing system with spray heads delivering 36 l/min/m 2 of water density at ground level (with 1.8 bar pressure), storage height can be increased to 7.45 m while still achieving suppression mode. Copyright SNCP december 2007 Page 3

Experience feedback report Réf : SNCP/REX-INC/05-2007 Automatic fire ignition and extinguishing tests in tyre storage facilities. 1. Introduction Under the auspices of SNCP, a study group of tyre manufacturing, logistics and protection professionals met to further industry knowledge of fire hazard management in tyre storage facilities, specifically the performance of automatic water-based sprinkler systems. The members of this partnership the SNCP, Bridgestone, Goodyear-Dunlop, Hankook and Michelin, the logistic groups Afilog and Aliapur, and the manufacturer Tyco Fire & Building Products have put together ambitious specifications for significant extinguishing tests. These tests cover various configurations for storing tyres and various sprinkler types and characteristics. The Centre National de Prévention et Protection (CNPP Entreprise) in Vernon then performed the tests. The purpose of this experience feedback report is to present the main lessons learnt from analyses of the test results. Three tests were carried out by Michelin at Underwriters Laboratories in Chicago in 2002, paving the way for the CNPP tests and providing additional insight. Copyright SNCP december 2007 Page 4

2. Test facilities 2.1 Test hall The tests were conducted at the CNPP in test hall no. 3, measuring 30 m long, 20 m wide and 24 m high. The test hall has metal walls and structural elements. Each of the hall's 4 facades is equipped with a rolling shutter (width: 4 m/height: 4.5 m). During the tests these doors were generally kept open at 40 50 cm from the ground to simulate air intake in a warehouse configuration. The roof of the test hall is equipped with a smoke extraction system:: four 5.2 m² louvered lateral openings, kept closed for the tests 1 central 25 m² opening, kept 50 100% open depending on the test 2.2 Extinguishing system A moveable 18 m x 15 m metal ceiling with an adjustable height of 9 12 m was installed in the centre of the test hall. The ceiling was equipped with a 3 m x 3 m main pipework grid fitted with spray sprinklers for the three CNPP tests 11 to 13.and with ESFR sprinklers for CNPP test 14. The additive, selected by comparative testing for CNPP test 14, is Silv-Ex type used at 0.3% concentration. 2.3 Tyre storage configurations There were 4 to 5 levels of tyre storage (5.95 m or 7.45 m high), covering a floor area of 14 pallets. The tyres were arranged on side, on tread, and/or laced. Copyright SNCP december 2007 Page 5

Two pallet designs was used, depending on the test: Monoblock pallet E4 folding pallet Outside width between tyres 1.30 m to 1.43 m 1.20 m to 1.35 m Inside width between uprights 1.24 m 1.05 m Outside length 1.93 m 2.35 m Inside length between uprights 1.74 m 2.20 m Height 1.55 m 2.20 m Spacing between pallets, measured at the base in both directions, varies from 1 to 27 cm depending on the tests (x in the diagram). x 2.4 Ignition system The fire ignition system consisted of cotton pellets, each soaked in 320 ml of fuel and enclosed in a plastic film bag (L = 15 cm, = 8 cm). Two igniters, each consisting of two pellets, were arranged at ground level at the intersection between pallets A20, A30, B20 and B30, in the free space between the pallets and positioned against the tyres. 1 2 3 4 D C B A 2,4 m 2.5 Instrumentation Stockage témoin 1 thermocouple per sprinkler head to detect its operating temperature 14 thermocouples in the storage 1 thermocouple at the top of the control storage area 2 thermocouples above the ignition point, close to the ceiling 5 thermocouples in a control angle iron placed against the ceiling above the ignition point 5 thermocouples in the roof s structural elements above the ceiling water pressure and flow rate; additive flow rate for test CNPP 14. 2.6 Video monitoring Each test was filmed by video cameras installed around the storage area. Copyright SNCP december 2007 Page 6

Appendices 1 to 4: The appendices contain additional data for each of the 4 spray sprinkler tests (ESFR for VG4-1) conducted at the CNPP: tables of parameters and results diagrams of open sprinkler heads and their opening times relative to ignition time 0 superimposed curves for temperature and water discharge Appendix 1 Test CNPP11 (VG3) Tyre storage Tyre configuration On tread Number of tyres per pallet 32 Nominal storage height 5.95 m Monoblock pallet levels 4 Nb of pallets on the ground 14 Total number of pallets 56 Spacing between pallets x = 5 cm Number of tyres stored 1 792 Storage configuration below ceiling Ignition point between heads 8, 9, 13 and 14 Extinguishing system configuration Ceiling height 10.5 m Sprinkler head height (deflectors) Clearance between deflectors and top of storage 4.25 m Head (deflector) to ceiling clearance 10.2 m 0.3 m Sprinkler type K11.2 spray Sprinkler K-factor K = 161 Sprinkler RTI 105 Operating temperature 141 C Sprinkler spacing 3 m x 3 m Sprinkler SIN TY 5251 Nominal sprinkler density 36 l.m -2.min -1 Sprinkler pressure 4.0 bar Nominal flow per sprinkler 324 l/min Extinguishing agent Water only Test conditions Test date 13/09/2005 Outside temperature 18 C Air intake Smoke extraction Natural; 4 facade doors open to 40 cm above ground Natural, central vent 100% open Avg temp at angle iron exceeds 400 C Conditions for ending test One of the ceiling structure temperatures exceeds 350 C Test results First sprinkler opened 4 min 54 s Total no. of sprinklers open 18 Last sprinkler opened 16 min 54 s Max temp 5 cm under ceiling 954 C Damage to test tyres No Max temp 30 cm under ceiling 851 C Avg max angle iron temp 420 C Time max temp attained 17 min 54 s Max ceiling framework temp 260 C Time max temp attained 19 min 15 s Total no. of pallets damaged 49 --- --- Equivalent no. of tyres burnt Extinguishing efficiency 994 tyres or 56 % of test stock Control mode not demonstrated for a sufficient time Copyright SNCP december 2007 Page 7

North Unopened sprinklers Open sprinklers Sprinkler covered with soot Temperatures / Open sprinkler heads Avg angle iron temp 30 cm below ceiling. 5 cm below ceiling Total no. open heads No. open discharging heads (*) (**) (*) Emergency supply in service (**) Time (min.) Copyright SNCP december 2007 Page 8

Appendix 2 Test CNPP12 (VG3-1) Tyre storage Tyre configuration On tread Number of tyres per pallet 32 Nominal storage height 5.95 m Monoblock pallet levels 4 Nb of pallets on the ground 14 Total number of pallets 56 Spacing between pallets x = 5 cm Number of tyres stored 1 792 Storage configuration below ceiling Ignition point between heads 8, 9, 13 and 14 Extinguishing system configuration Ceiling height 10.5 m Sprinkler head height (deflectors) Clearance between deflectors and top of storage 4.25 m Head (deflector) to ceiling clearance 10.2 m 0.3 m Sprinkler type K17 (*) spray Sprinkler K-factor K = 242 Sprinkler RTI 105 Operating temperature 141 C Sprinkler spacing 3 m x 3 m Sprinkler SIN TY 7251 Nominal sprinkler density 36 l.m -2.min -1 Sprinkler pressure 1.8 bar Nominal flow per sprinkler 324 l/min Extinguishing agent Water only Test conditions Test date 21/09/2005 Outside temperature 17 C Air intake Smoke extraction Natural; 4 facade doors open to 40 cm above ground Natural, central vent 100% open Avg temp at angle iron exceeds 400 C Conditions for ending test One of the ceiling structure temperatures exceeds 350 C Test results First sprinkler opened 4 min 11 s Total no. of sprinklers open 20 Last sprinkler opened 32 min 05 s Max temp 5 cm under ceiling 491 C Damage to test tyres No Max temp 30 cm under ceiling 360 C Avg max angle iron temp 95 C Time max temp attained 25 min 30 s Max ceiling framework temp 66 C Time max temp attained 27 min 00 s Total no. of pallets damaged 48 --- --- Equivalent no. of tyres burnt Extinguishing efficiency (*): Sole parameter different from VG3 695 tyres or 39 % of test stock Control mode achieved Copyright SNCP december 2007 Page 9

Unopened sprinkler Open sprinklers Sprinklers with lodgement North Temperatures / open sprinkler heads Avg angle iron temp 30 cm below ceiling. 5 cm below ceiling Total no. open heads No. open discharging heads (*) Time (min.) (*) Copyright SNCP december 2007 Page 10

Appendix 3 Test CNPP13 (VG6-2) Tyre storage Tyre configuration Laced Number of tyres per pallet 32 to 48 Nominal storage height 5.95 m Monoblock pallet levels 4 Nb of pallets on the ground 14 Total number of pallets 56 Spacing between pallets x = 5 cm Number of tyres stored 2 294 Storage configuration below ceiling Ignition point between heads 8, 9, 13 and 14 Extinguishing system configuration Ceiling height 10.5 m Sprinkler head height (deflectors) Clearance between deflectors and top of storage 4.25 m Head (deflector) to ceiling clearance 10.2 m 0.3 m Sprinkler type K17 spray Sprinkler K-factor K = 242 Sprinkler RTI 105 Operating temperature 141 C Sprinkler spacing 3 m x 3 m Sprinkler SIN TY 7251 Nominal sprinkler density 36 l.m -2.min -1 Sprinkler pressure 1.8 bar Nominal flow per sprinkler 324 l/min Extinguishing agent Water only Test conditions Test date 30/09/2005 Outside temperature 15 C Air intake Smoke extraction Natural; 4 facade doors open to 40 cm above ground Natural, central vent 100% open Avg temp at angle iron exceeds 400 C Conditions for ending test One of the ceiling structure temperatures exceeds 350 C Test results First sprinkler opened 4 min 12 s Total no. of sprinklers open 18 Last sprinkler opened 12 min 37 s Max temp 5 cm under ceiling 565 C Damage to test tyres No Max temp 30 cm under ceiling 628 C Avg max angle iron temp 86 C Time max temp attained 11 min 20 s Max ceiling framework temp 92 C Time max temp attained 17 min 45 s Total no. of pallets damaged 45 --- --- Equivalent no. of tyres burnt Extinguishing efficiency 543.5 tyres or 24% of test stock Control mode achieved Copyright SNCP december 2007 Page 11

Unopened sprinklers Open sprinklers Sprinklers with lodgement North Temperatures / Open sprinkler heads Avg angle iron temp 30 cm below ceiling 5 cm below ceiling Total no. Open heads No. open discharging heads (*) Time (min.) (*) Copyright SNCP december 2007 Page 12

Appendix 4 Test CNPP14 (VG4-1) Tyre storage Tyre configuration On tread Number of tyres per pallet 28 to 32 Nominal storage height 7.45 m Monoblock pallet levels 5 Nb of pallets on the ground 14 Total number of pallets 70 Spacing between pallets x = 5 cm Number of tyres stored 2 080 Storage configuration below ceiling Ignition point between heads 13 and 14 Extinguishing system configuration Ceiling height 12 m Sprinkler head height (deflectors) Clearance between deflectors and top of storage 4.25 m Head (deflector) to ceiling clearance 11.7 m 0.3 m Sprinkler type K17 ESFR Sprinkler K-factor K = 242 Sprinkler RTI 26 Operating temperature 74 C Sprinkler spacing 3 m x 3 m Sprinkler SIN TY 7226 Nominal sprinkler density 36 l.m -2.min -1 Sprinkler pressure 1.8 bar Nominal flow per sprinkler 324 l/min Extinguishing agent Water + 0.3% additive Test conditions Test date 28/10/2005 Outside temperature 16 C Air intake Natural; 4 facade doors open to 50 cm above ground Smoke extraction Natural, central vent 50 % open Avg temp at angle iron exceeds 400 C Conditions for ending test One of the ceiling structure temperatures exceeds 350 C Test results First sprinkler opened 3 min 30 s Total no. of sprinklers open 1 Last sprinkler opened 3 min 30 s Max temp 5 cm under ceiling 87 C Damage to test tyres No Max temp 30 cm under ceiling 65 C Avg max angle iron temp 23 C Time max temp attained 3 min 55 s Max ceiling framework temp 16 C Time max temp attained --- Total no. of pallets damaged 8 --- --- Equivalent no. of tyres burnt Extinguishing efficiency 1 tyre or 0.1% of test stock Suppression mode achieved Copyright SNCP december 2007 Page 13

Unopened sprinklers Open sprinklers North Temperatures / open sprinkler heads Avg angle iron temp 30 cm below ceiling 5 cm below ceiling Total no. Open heads No. Open discharging heads (*) Time (min.) (*) Copyright SNCP december 2007 Page 14

Appendix 5 : Summary table of CNPP and UL full-scale tests to optimise storage in existing warehouses Test series involving existing warehouses: to optimise the storage capacity of existing warehouses to allow sprinkler-protected sites to be used as warehouses by controlling the effectiveness of automatic protection Copyright SNCP december 2007 Page 15

Syndicat National du Caoutchouc et des Polymères Fire Prevention and Protection Committee Summary table of CNPP and UL full-scale tests to optimise storage in existing warehouses Test series involving existing warehouses: to optimise the storage capacity of existing warehouses to allow sprinkler-protected sites to be used as warehouses by controlling the effectiveness of automatic protection Tests date Test objectives UL 1 17/3/02 Test low value (24 l/min/m2) required by NFPA Rule 13 - Table 12.4.2(b) on tread storage UL 2 23/3/02 Test the capacity of an 18 l/min/m2 density sprinkler system with wetting agent additive on side tyres stored 7.3m high. UL 3 28/3/02 Test the improvement achieved when wetting agent is added to a 24 l/min/m2 density sprinkler system (achieve control under UL1 test conditions) CNPP 11 (VG 3) 13/9/05 Test NFPA rule (Table 12.4.2 (a), 5) with 4.25 m clearance, which corresponds to a 10.5 m-high warehouse (under NFPA 13, clearance limit is 3.1 m) CNPP 12 (VG 3-1) 21/9/05 Find a solution for improving operating conditions with storage having the same characteristics as in test VG3 by increasing spray head K-factor. CNPP 13 (VG 6-2) 30/9/05 Test the protection characteristics of test VG 3-1 with on-tread storage (NFPA 13 does not allow on-tread storage with spray sprinklers) CNPP 14 (VG 4-1) 28/10/05 Test wetting agent additive with K17 ESFR heads on 7,5 m high storage. Storage arra Type of storage on tread on side on tread on tread on tread laced on tread Storage height (m) 6,1 7,3 6,1 5,95 5,95 5,95 7,45 Ceiling height (m) 8,2 8,5 8,2 10,5 10,5 10,5 12 Clearance (m) 1,8 0,9 1,8 4,25 4,25 4,25 4,25 Number of pallets on floor 3x5 + 3 2x5 + 3 4x3 + 1 3x4 +2 3x4 +2 3x4 +2 3x4 +2 Number of pallet levels 4 4 4 4 4 4 5 Number of tyres 2592 3276 1872 1792 1792 2294 2080 Sprinkler Sprinkler type spray spray spray spray spray spray ESFR SIN number TY 5251 TY 7251 TY 7251 TY 7226 K-factor 11.2 / 161 11.2 / 161 11.2 / 161 11.2 / 161 16.8 / 242 16.8 / 242 17 / 242 Operating temperature ( C) 141 141 141 141 141 141 74 RTI 105 105 105 105 105 105 26 Water Wetting additive (%) 0 3 (Cold Fire) 3 (Cold Fire) 0 0 0 0.3 (SilvEx) Actual head pressure (bar) 1,8 1,1 1.1 then 1.8 4 1,8 1,8 1,8 Flow per head (l/min) 324 324 324 324 Water density at floor (l/min/m2) 24 18,4 18.4 then 24 36 36 36 36 Fire Location of ignition below heads between 4 heads between 4 heads between 4 heads between 4 heads between 4 heads between 4 heads between 2 heads Overall assessment of test results Control mode not Unsatisfactory control Controlled Controlled with 24 l/min/m2 demonstrated for a sufficient Controlled Controlled Suppressed time Findings Opening time 1st head 3'12" 3'31" 2'56" 4'54" 4'11" 4'12" 3'30" main Number of heads open 18 13 18 18 20 18 1 Max. angle iron temp ( C) 678 311 334 420 95 86 23 Max ceiling gas temperature ( C) 772 604 617 954 491 628 87 Mass burned (kg,% test storage) unknown unknown unknown 9900 kg/56% 6900 kg/38% 5400 kg/24% 10kg/0.05% Lessons learned from test The dual water density requirements of 24 l/min/m2 for 465 m2 and 36 l/min/m2 for 280 m2 should be respected. Control mode is achieved. Control mode achieved with 24 l/min/m2 Clearance is an important factor. The 3 m limit must be respected. Control mode is achieved. Control mode is achieved. Suppression mode is achieved. Note: The roof structure temperature exceeds 500 C at about 13', reaches 630 C at 16', and declines after the 18th head opens. Under these temperature criteria, control is unsatisfactory. Using a wetting agent additive with 18 l/min/m² density sprinkler protection allows tyres to be stored on side to a height of 7.3 m Using a wetting agent additive provides protection for this type of storage with a water density of 24 l/min/m² (in cases where the dual density required by the rule is unavailable). Note: The fire is under control for 15 minutes, after which it regains strength, probably when a pallet section collapses. Because the test was halted for safety reasons, it was not possible to learn whether control would have been regained. Using 16.8K instead of 11.2K heads provides better control and allows for greater clearance. The droplets are probably larger and penetrate hot gases more easily. Fire containment of laced tyre storage is similar to fire containment on tread tyre storage. Storage can be increased in a warehouse protected by spray sprinklers at 36 l/min/m2 by: - adding a wetting agent - using K17 ESFR heads. The test did not allow the influence of either of these 2 modifications to be determined.