Chlorine / Chlorine Dioxide Measurement liquisys S CCM 223 / 253

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Technical Information TI 214C/07/en 51502336 Chlorine / Chlorine Dioxide Measurement liquisys S CCM 223 / 253 Transmitter for free chlorine and chlorine dioxide Liquisys S CCM 223 Due to the modularity of its design, the Liquisys S CCM 223 / 253 transmitter can be adapted to a wide range of customer needs. The basic version, which provides simple measuring and alarm signalling functions, can be equipped with additional software and hardware modules to meet specific applications. Expansion modules can be retrofitted as required. Areas of application Drinking water Water treatment Cooling water Gas scrubbers Reverse osmosis Food processing Swimming pool water Features and benefits Transmitter in field or panel-mounted housing Universal application Switchable between chlorine and chlorine dioxide measurement ph compensation for free chlorine Easy handling Logical menu structure with plain text in 6 languages makes equipment configuration easy Large two-line display indicates measured value and temperature or ph/redox simultaneously Reliable operation Overvoltage protection acc. to EN 61000-4-5 Direct access for manual contact control Automatic controller shut-down if lower flow rate limit violated or total failure in sample current Basic unit expandable with: 2 or 4 contacts for use as: Limit contacts (for temperature also) P(ID) controller for chlorine and ph Timer for simple rinse processes Complete cleaning with Chemoclean Plus package: Manual ph compensation for Cl 2 Any current output configuration via table Automatic cleaning start in case of alarm or upper limit violation Live check of sensor Process monitoring Optional ph or redox measurement Automatic ph compensation for Cl 2 HART, PROFIBUS-PA or PROFIBUS-DP 2nd current output for temperature, ph or redox Current input for controller shut-down on lower flow rate limit violation or total failure in main flow or for feedforward control Endress +Hauser The Power of Know How

Details Liquisys S CCM 223 / 253 offers the right solution for all applications in drinking water and process water treatment. Features of the basic version (EK): Measuring the concentration of free chlorine or chlorine dioxide in standard or trace amount range The sensor is selected from the menu. The temperature is displayed but the reading can also be hidden. The EP version has an alternative feature that allows the display of the ph and redox measurements simultaneously. DPD reference measurement The CCS 140 / 141 sensors for free chlorine and the CCS 240 / 241 sensors for chlorine dioxide are zero-current-free and therefore require only single-point calibration. This is carried out by keying in a DPD reference measured value. E057 E080 - - - - Different alarms are required depending on the application and operator. Therefore the Liquisys S CCM 223 / 253 permits the independent configuration of the alarm contact and the error current for each individual error. Unnecessary or undesirable alarms can be suppressed in this way. on off yes no yes Timer 2.4 / 22 ma no yes no Up to four contacts can be used as limit contacts (also for temperature), to implement a P(ID) controller and for cleaning functions. Direct manual operation of the contacts (bypassing the menu) provides quick access to limit, control or cleaning contacts. If necessary, this helps to correct deviations very quickly. Instrument DATA SerNo E113 12345678 t on off on off Chemoclean The serial numbers of the instrument and the modules and the order code can be called up on the display. t The ES version provides additional functions: Measuring free chlorine with the amperometric sensor is ph-dependent, but not the DPD measurement used for calibration. Manual ph compensation means the instrument can also be used to measure a variable ph value with a slow rate of change. 20 ma 0 The current output is freely configurable by means of a table in order to display large measuring ranges and still achieve high resolution in certain ranges. This permits bilinear or quasilogarithmic curves, etc. 20 0 Cl 2 ph manu DPD t The live check issues an alarm when the sensor signal fails to change over a defined period of time. This detects blocking, passivation, separation from the real process, etc. The Process Check System uses adjustable time intervals to monitor whether the measured value is above or below the nominal value over an excessively long period of time. This detects in good time whether the level of disinfectant is dangerously low or high. Additional functions of the EP version: Cl 2/ClO2 ph/redox Option: additional measurement of ph value or redox potential in an instrument. This expansion stage also allows control of the ph value in the process. Cl 2 + ph auto DPD Automatic ph compensation means the instrument can also be used to measure a variable ph value which is subject to frequent changes. 2

CAL ENDRESS+HAUSER LIQUISYS S REL ALARM Versions Basic version (EK version) With Plus package (ES version) Full expansion (EP version) MEASUREMENT Manual ph compensation for free chlorine Optional ph value or redux measurement Measuring and alarm signalling CALIBRATION Read instrument DATA Linear CURRENT OUTPUT CURRENT OUTPUT simulation 1 programmable ALARM CONTACT (contact and error current) PROCESS CHECK SYSTEM for monitoring LIVE CHECK of sensor CURRENT OUTPUT programmable (table) Automatic ph compensation for free chlorine PROCESS CHECK SYSTEM and LIVE CHECK also for ph or redox Additional features Additional features Additional features Controlling Cleaning 2 CHANGEOVER CONTACTS for Measuring parameter limit Temperature limit P(ID) controller Timer for cleaning Additional features 2 further CHANGEOVER CONTACTS (total of 4) for Measuring parameter limit Temperature limit P(ID) controller Three-step controller Chemoclean cleaning (water and cleaning agent) Automatic cleaning start on alarm or upper limit violation Additional features External or automatic cleaning start on alarm upper limit violation ph or redox limit ph value control Additional features Controlled process 1 current input for flow monitoring in main flow feedforward control on chemical dosing Measuring and control system Complete measuring system with A full measuring system comprises: the Liquisys S CCM 223 or CCM 253 chlorine / chlorine dioxide transmitter a CCS 140 / 141 membrane-covered sensor for Cl 2 or CCS 240 / 241 for ClO 2 or an open sensor 963 for Cl 2 a flow assembly CCA 250 (not required for 963 sensor). Options: ph or redox electrode (e.g. CPS 31, CPS 12) INS proximity switch for flow monitoring (omitted with 963 sensor) CMK extension cable for chlorine measurement CYK 71 extension cable for ph/redox measurement if required MK extension cable for INS proximity switch VBC junction box. VBC junction box (only if connection length > standard length) Chlorine or chlorine dioxide sensor Transmitter Up to 4 relays Mounting points for ph or redox electrode 0.42 25.0 C mg/l Alarm contact Signal output 1: Chlorine / chlorine dioxide Flow assembly CCA 250 E Signal output 2: Temp., ph or redox (optional) Auxiliary 15 V output voltage Inductive proximity switch for flow monitoring Flow plummet Meas. water drain 2 digital inputs (e.g. for flow monitoring) Current input (e.g. for flow in main stream) Power supply (mains) Meas. water feed (sample flow) Sampling valve for DPD measurement Screw and calibration cap Main stream CM253S_E.CDR 3

Operation LCD-CL-E.CDR ENDRESS+HAUSER LIQUISYS S Liquid crystal display for indication of measured values, configuration data and current menu field 042 mg/l R242 ALARM CAL REL E Setpoint Field for user labelling Display of active contact and key for relay switchover in manual mode LED indicator for alarm function User interface: display and keys 4 main control keys for calibration and instrument configuration Key for switching between auto/manual relay modes LED indicators for switched limit outputs Complete overview at a glance The display simultaneously shows the current measured value and the temperature, i.e. the essential process data at a glance. Texts in the configuration menu help to set the instrument parameters. Intelligent and simple All instrument control functions are arranged in a logical menu structure. Each of the parameters can be easily selected and changed after keying in the access code. CALIBRATION Calibration of free chlorine or chlorine dioxide after DPD comparison measurement, calibration of ph or redox Display MEAS. VALUE TEMPERATURE Display of current temperature can be hidden; alternatively: display of ph value or redox potential Display of current fault (sequence according to prioritisation) SETUP 1 Sensor selection, flow monitoring in sample flow, function definition for digital input 1, measured value damping SETUP 2 Selection of ph or redox mode, ph compensation, correction of temperature measurement CURRENT INPUT Flow monitoring in main flow, controller feedforward control for flow in main flow CURRENT OUTPUT Definition of current output assignment, curve and simulation monitoring ALARM Customer-defined setting of errors effective at relay or error current (Plus package: automatic cleaning start on alarm) CHECK Setting of Process Check System and Live Check alarm RELAY The max. 4 relays can be configured as limit contacts, P(ID) controller, three-point step controller for Cl 2/ClO 2, timer or for chemical cleaning (Plus package: automatic cleaning start on upper/lower limit violation) Overview of Liquisys S CCM 223 / 253 menu. It describes the maximum expansion stage (see p. 2 Details ). SERVICE Selection of language version, display of software or hardware serial numbers, input of release codes CM2X3BEE.CDR 4

Electrical connection All connections to the panel-mounted instrument CCM 223 are made on terminal strips or by means of the BNC connector on the rear. On the field instrument CCM 253 all the wires are connected to terminals in the separate wiring compartment of the transmitter. In case of service, all the wiring can remain in place; only the modules are replaced. Dismantling the transmitter and rewiring are no longer necessary. Left: Liquisys S CCM 223 terminals on instrument rear; ph connection on EP version on BNC connector Right: instrument rear with replaceable electronics box (E) REAR223P.TIF E FELD2.CDR ANCL_E.CDR ph/ Redox ph Ref. Red. Sensor CCS 140 / 141 CCS 240 / 241 S PA/ PM optional gn 11 NTC bn 12 K K 90 A A rd bl A 91 Cl 2 ClO 2 41 42 43 Alarm* K Alternative sensor 963 rd 92 47 48 49 Relay 1* Signal output 1: Chlorine or chlorine dioxide 31 32 ma Cl 2 ClO 2 57 58 59 Relay 2* Signal output 2: Temperature, ph or redox (optional) 33 34 ma 51 52 53 Relay 3* With Chemoclean: Water 81 54 Digital input 1 (hold / cleaning) bk 10 50 V** Digital input 2 82 93 94 optional ma 55 56 23 24 Relay 4* With Chemoclean: Cleaner Current input 4... 20 ma bn bl Aux. voltage output 85 86 15 V = L L+ N L Power supply Electrical connection of Liquisys S CCM 223 / 253 Proximity switch INS ** Auxiliary output voltage term. 85/86 can be used *Contact position depicted: de-energised or error 5

CAL ENDRESS+HAUSER LIQUISYS S REL ALARM Dimensions ENDRESS+HAUSER LIQUISYS S CAL E REL ALARM 6 90 139 96 Dimensions of Liquisys S CCM 223 XM223-2D.CDR 11 157 E 6.5 70 247 115 70 154 170 Dimensions of XM253-2D.CDR 6

Installing the Liquisys S CCM 223 The panel-mounted instrument is mounted using the supplied tensioning screws.the total installation depth required is approx. 165 mm. Gasket (included in scope of supply) Installation cut-out acc. to DIN 43700 92 +0.5 33 57 90 96 92 +0.5 Installing the panel-mounted housing approx. max. 45 25 139 6 XM223MON.CDR Installing the 270 There are several installation options for the field instrument: Mounting on a square-tube post Mounting on round pipes Wall mounting using fastening screws. Weather protection cover CYY 101 (see Accessories) 300 320 ➀ ➁ CYY101.CDR When installing the instrument outdoors, you require weather protection cover CYY 101. This cover is compatible with all field instrument mounting options. To install the instrument to a square post (univeral upright post CYY 102 or upright post of suspension assembly holder CYH 101), proceed as follows: ➀ Install the weather protection cover to the upright post ➁ Attach the field instrument to the weather protection cover from the rear. 1495 60 60 Univeral upright post CYY 102 or identical upright post of suspension assembly holder CYH 101 (square pipe, see Accessories); installing weather protection cover and field instrument 120 150 YY101102.CDR 7

Installing the (continued) 90 70 8 30 157 8 M6 8 60 70 90 Post mounting kit for installing field housing on round pipes (horizontal or vertical, max. 60 mm; see Accessories) 70 90 6 MASTSATZ.CDR Mounting on round pipes (right with weather protection cover) XM253MAS.CDR Wall mounting; screws: 6mm rawl plug: 8mm 16 115 XM253WAN.CDR 8

Technical data General specifications Manufacturer Endress+Hauser Product designation Liquisys S CCM 223 / Input Measured variables free chlorine or chlorine dioxide, temperature, ph or redox (optional) Cl 2 /ClO 2 measurement Display and measuring range 0... 5 mg/l or 0... 20 mg/l, respectively Application measuring range 0.05... 20 mg/l for sensors CCS 140 / 240 0.01... 5 mg/l for sensors CCS 141 / 241 0.05... 5 mg/l for sensor 963 Temperature compensation range 2... 45 C ph compensation range for free chlorine ph 4... 9 Reference point for nominal slope 25 C / ph 7.2 Cl 2 /ClO 2 signal input Sensors CCS 140 / 141 / 240 / 241 0... 5000 na Sensor 963 100... 500 µa Temperature measurement Temperature sensor (with CCS 140 / 141 / 240 /241) NTC, 10 kω at 25 C Display range 0... 50 C ph and redox measurement ph measuring range ph 3.5... 9.5 Redox measuring range 0... 1500 mv Zero point adjustment ±100 mv Slope adjustment 38... 65 mv/ph Digital inputs 1 and 2 Voltage Current drain Current input Current range Load 10... 50 V DC max. 10 ma 4... 20 ma, galvanically isolated, passive voltage drop 5.2 V = load 260 Ω at 20 ma Output Signal outputs Cl 2 /ClO 2 or temperature/ph/redox (optional) Current range 0 / 4... 20 ma, galvanically isolated, active; error current 2.4 / 22 ma Min. distance 0 / 4... 20 ma signal min. 10 % of respective measuring span Load max. 500 Ω Max. resolution 700 digits/ma Transfer range Cl 2 /ClO 2 0... 20 mg/l for sensors CCS 140 / 240 0... 5 mg/l for sensors CCS 141 / 241 and 963 Temperature transfer range 0... 50 C ph transfer range ph 4... 9 Redox transfer range 0... 1500 mv Isolation voltage max. 350 V rms / 500 V DC Overvoltage protection acc. to EN 61000-4-5:1995 Auxiliary voltage output Output voltage Output current Contact outputs (floating changeover contacts) Switching current with resistive load (cos ϕ = 1) Switching current with inductive load (cos ϕ = 0.4) Switching voltage Switching power with resistive load (cos ϕ = 1) Switching power with inductive load (cos ϕ = 0,4) Limit contactor Pickup/dropout delay 15 V ± 0.6 V max. 10 ma max. 2 A max. 2 A max. 250 V AC, 30 V DC max. 500 VA AC, 60 W DC max. 500 VA AC, 60 W DC 0... 7200 s Controller Function (adjustable) Controller response Controller gain K p 0.01... 20.00 Integral action time T n 0.0... 9999 min Derivative action time T v 00... 999.9 min Period length of pulse-length controller 0.5... 999.9 s Max. frequency of pulse-frequency controller 60... 180 min 1 Motor run time for three-point step controller 10... 999 s Neutral zone for three-point step controller 0... 40 % pulse-length / pulse-frequency controller three-point step controller for Cl 2 /ClO 2 P, PI, PD, PID 9

Technical data (continued) Output (continued) Accuracy Alarm Function (selectable) Alarm threshold adjustment range Alarm delay Monitoring time lower limit violation Monitoring time upper limit violation Cl 2 /ClO 2 measurement Measured value resolution CCS 140 / 240 / 963 Measured value resolution CCS 141 / 241 Measurement deviation 1 of display (ph, T = const) Reproducibility Measurement deviation 1 of Cl 2 /ClO 2 signal output steady / fleeting contact Cl 2 /ClO 2 / ph / redox / temperature: total measuring range 0... 2000 min (s) 0... 2000 min 0... 2000 min 0.01 mg/l 0.001 mg/l max. 0.5 % of measured value ± 4 digits max. 0.2 % of measuring range max. 0.75 % of current output range Deviation for Cl 2 /ClO 2 measurement with sensor 963 Measurement deviation 1 of display (ph, T = const.) max. 1 % of measuring range ± 4 digits Temperature measurement Measured value resolution 0.1 C Measurement deviation 1 of display ±0.3 K Measurement deviation 1 of temperature signal output max. 1.25 % of current output range ph and redox measurement ph measured value resolution ph 0.01 Redox measured value resolution 1 mv Measurement deviation 1 of display ph ph 0.03 Measurement deviation 1 of redox display 3 mv Measurement deviation 1 of ph signal output max. 1.25 % of current output range Measurement deviation 1 of redox signal output max. 1.25 % of current output range Ambient conditions Ambient temperature (nominal operating conditions) 10... +55 C Ambient temperature (limit operating conditions) 20... +60 C Storage and transport temperature 25... +65 C Relative humidity (nominal operating conditions) 10... 95 %, non-condensing Ingress protection of panel-mounted unit IP 54 (front panel), IP 30 (housing) Ingress protection of field housing IP 65 Electromagnetic compatibility interference emission and interference immunity acc. to EN 61326:1997 / A1:1998 Physical data Dimensions of panel-mounted unit (H W D) 96 96 145 mm Installation depth approx. 165 mm Dimensions of field housing (H W D) 247 170 115 mm Weight of panel-mounted unit max. 0.7 kg Weight incl. field housing max. 2.3 kg Display LC display, two lines, five- and nine-digit with status indicators Materials Housing of panel-mounted unit Front membrane Field housing polycarbonate polyester, UV-resistant ABS PC Fr Power supply Supply voltage 100 / 115 / 230 V AC +10 / 15 %, 48... 62 Hz 24 V AC/DC +20 / 15 % Power consumption max. 7.5 VA Fuse protection fine-wire fuse, medium time-lag 250 V / 3.15 A 1 acc. to IEC 60746-1, at nominal operating conditions Subject to modifications. 10

Accessories Mounting accessories Type Features Order code Weather protection cover CYY 101 Universal upright post CYY 102 Post mounting kit For mounting on field housing, for outdoor operations Dimensions (H W D): 320 300 270 mm Material: SS 304 Square pipe fopr mounting field housing Dimensions (H W D): 1495 60 60 mm Material: SS 304 Kit for mounting field housing to horizontal or vertical pipes ( max. 60 mm) Material: SS 304 CYY 101-A CYY 102-A 50086842 Assemblies Type Features Applications CCA 250 Flow assembly for bypass installation, suitable for mounting a sensor CCS 140 / 141 for free chlorine or CCS 240 / 241 for chlorine dioxide and a ph and redox electrode; with flow setting and optical monitoring, optionally monitoring by proximity switch drinking water swimming pool water process water Sensors Type Features Applications CCS 140 CCS 141 CCS 240 CCS 241 Membrane-covered amperometric sensor for free chlorine in measuring range 0.05... 20 mg/l Membrane-covered amperometric trace sensor for free chlorine in measuring range 0.01... 5 mg/l Membrane-covered amperometric sensor for chlorine dioxide in measuring range 0.05... 20 mg/l Membrane-covered amperometric trace sensor for chlorine dioxide in measuring range 0.01... 5 mg/l drinking water swimming pool water processing water Cable extension Type Features Order code VBC CMK CYK 71 MK Junction box for extending measuring cable connection between sensor cable and transmitter, ingress protection IP 65 Special measuring cable for sensors CCS 140 / 141 and CCS 240 / 241 for cable extension between transmitter and junction box VBC For ph/redox electrodes or conductivity sensors with temperature sensor. Consisting of one coaxial conductor of low-noise quality and four auxiliary cores (0.75 mm²) with common screen, outside diameter 7.2 mm. Minimum length 5 m. Two-core signal line with additional screen and PVC insulation. Preferably for transmission of output signals of transmitters or input signals of controllers and for temperature measurement. 50005181 50005374 50085333 50000662 11

Product structure Chlorine / chlorine dioxide transmitter Liquisys S CCM 223 / CCM 253 Version EK Measurement of free chlorine / chlorine dioxide ES Measurement of free chlorine / chlorine dioxide with extended features EP Measurement of chlorine / chlorine dioxide with extended features, in addition ph or redox measurement (switchable) Power supply 0 230 V AC 1 115 V AC 5 100 V AC 8 24 V AC/DC Measurement output 0 Chlorine or chlorine dioxide 1 Chlorine or chlorine dioxide and temperature (alternatively ph or redox with EP version) 3 PROFIBUS-PA 4 PROFIBUS-DP 5 Chlorine or chlorine dioxide with HART 6 Chlorine or chlorine dioxide with HART and temperature (alternatively ph or redox with EP version) Contacts 05 No additional contacts 10 2 contacts (limit / P(ID) / timer) 15 4 contacts (limit / P(ID) / Chemoclean / three-point step controller for Cl 2 /ClO 2 ) 16 4 contacts (limit / P(ID) / timer / three-point step controller for Cl 2 /ClO 2 ) 20 2 contacts with current input (limit / P(ID) / timer) 25 4 contacts with cleaning, current input (limit / P(ID) / Chemoclean / three-point step controller for Cl 2 /ClO 2 ) 26 4 contacts with timer, current input (limit / P(ID) / timer / three-point step controller for Cl 2 /ClO 2 ) CCM 223- complete order code CCM 223 CCM 253- complete order code CCM 253 Endress+Hauser GmbH+Co. Instruments International P.O. Box 2222 D-79574 Weil am Rhein Germany Tel. (0 76 21) 975-02 Fax (07621) 9 75-3 45 http://www.endress.com info@ii.endress.com Endress +Hauser The Power of Know How TI 214C/07/en/09.00 Printed in Germany / CV 5 / DT (51502336)