Shyam Enterprises 9 PACKAGE UNIT 59
Reaction Distillation Unit The Unit has been designed to suit the customers requirement of combination of versatile reaction/distillation or combination for pilot plant work. This has a flexibility of working at atmospheric pressure as well as under vacuum. Typical unit has a reaction vessel fitted in a Metal Heating/Cooling bath having facility for heating and cooling both by means of Heating/Cooling Fluids as a media. The Standard system is equipped with stirrer having mechanical seal,a packed column on the side neck of the vessel, reflux divider, coil type condenser and or receiver system having a product, cooler, vent, drain and vacuum valves, Options of or speed variator by machanical variator or electronic variator can be provide. Receiver System is equipped with Product Cooler, Vent / Vacuum Valve and Drain Valve. The above units are available in 10 Ltr.//50 Ltr./100 Ltr./200 Ltr. Capacity with Spherical Reactor and up to 500 Ltr. capacity with Cylindrical Reactor. CONDENSER REFLUX DIVIDER FLAME PROOF MOTOR WITH GEAR BOX PACKED Reactor Vessel Capacity 10 Ltr. 50 Ltr. 100 Ltr. 200 Ltr. Packed Column in mm 50 x 1000 80 x 1000 100 x 1000 150 x 1000 150 x 1000 Condenser HTA Product Cooler HTA in M 2 in M 2 0.20 0.10 0.35 0.20 0.50 0.20 1.50 0.35 1.50 0.35 Receiver Capacity 2 Ltr.x 2 nos. 5 Ltr.x 2 nos. 10 Ltr.x 2 nos. x 2 nos. x 2 nos. Optional Items : Heating mantle instead of jacketed heating / cooling bath. Simple Drain Valve instead of flush bottom valve. MS PTFE lined stirrer instead of glass stirrer. Variable frequency drive for variable speed. Addition Vessel 2 Ltr. 5 Ltr. 10 Ltr. Catalogue Reference SERDU 10 SERDU 20 SERDU 50 SERDU 100 SERDU 200 ADDITIONAL VESSEL CHUCK & SEAL ASSY. WITH MECH. SEAL DIP PIPE PTFE FLUSH BOTTOM JACKETED HEATING/ COOLING BATH LINE Fractional Distillation Unit : This unit is typically used for only Distillation and Fractionation under vacuum or at atmospheric pressure. Typical unit has distillation vessel fitted in a Metal Heating / Cooling bath and with a Packed column above Reflux divider and coil condensors are fitted on the packed column. Condensed material is either taken back to the vessel or to the receiver via product cooler. The above units are available in 10 Ltr. / /50 Ltr./100 Ltr./200 Ltr. capacity Spherical Vessels and upto 500 Ltr. Capacity with Cylindrical Vessel. CONDENSER REFLUX DIVIDER Reactor Vessel Capacity 10 Ltr. 50 Ltr. 100 Ltr. 200 Ltr. Packed Column in mm 50 x 1000 80 x 1000 100 x 1000 150 x 1000 150 x 1000 Condenser HTA Product Cooler HTA in M 2 in M 2 0.20 0.10 0.35 0.20 0.50 0.20 1.50 0.35 1.50 0.35 Receiver Capacity 2 Ltr.x 2 nos. 5 Ltr.x 2 nos. 10 Ltr.x 2 nos. x 2 nos. x 2 nos. Addition Vessel 2 Ltr. 5 Ltr. 10 Ltr. Catalogue Reference SEFDU 10 SEFDU 20 SEFDU 50 SEFDU 100 SEFDU 200 ADDITIONAL VESSEL PACKED Optional Items : Heating mantle instead of jacketed heating / cooling bath. Simple Drain Valve instead of flush bottom valve. DIP PIPE PTFE LINE 60 JACKETED HEATING/ COOLING BATH FLUSH BOTTOM
Bromine Recovery Plant Bromine being a highly reactive material, finds wide applications in many Chemical Industries like, Organic Intermediates, Dyestuffs, Agrochemical, Fire retardants etc. Bromine can be recovered from Ž Industrial Bromides (NaBr, KBr, HBr.) Ž Bittern Aqueous Bromide solution is reacted with chlorine vapour in reaction column. The Chlorine liberates elemental bromine from the dissolved bromide. This is stripped out by live steam feed from the bottom of column. Crude bromine is then distilled to get Bromine purity of minimum 99.5%. The solution is not always so simple though, as feeds are often containmated with organic material from process. These organic impurities have to be removed by pre-treatment before feeding to the plant. Typical plant consists of stripping column, Heat Exchangers Phase Separator, Purification Column collection pot, Reboiler, Scrubber with associated Glass Piping and Fittings. All wefted components are made from Borosilicate glass and PTFE which are corrosion resistant even at elevated temperature. SCRIBBER STRPPING STEAM CONDENSOR CRUDE BROMINE CHLORNE GAS TO EFFLUENT PLANT CLEAR ACIDIC TREATED FEED LIQUOR CONDENSOR REBOILER CONDENSOR PURE BROMINE PURFICATION PURE BROMINE Sulphuric Acid Dilution Unit : The dilution chamber illustrated in figure has the capability of diluting acid of any concentration to produce sulfuric acid of any desired concentration. The system consist of Dilution Chamber, Heat Exchanger, Receiver & Circulation of dilute acid Pump (Optional) with associated Glass Pipelines, Valves & Fittings. Dilution Chambers is used for diluting concentrated Sulphuric acid to the desired concentration and the Heat Exchanger is used for bringing down the temperature of dilute acid to desired temperature (When the concentrated acid mixed with water, large amounts of heat are released. ) The Heat Exchanger is either of Shell and Tube type or Coil Type. The acid should be added slowly to cold water to limit the buildup of heat H 2SO4 DILUTE H 2SO4 DILUTION CHAMBER WATER COOLING WATER OUTLET SHELL AND TUBE HEAT EXCHANGER COOLING WATER DILUTE ACID ACID CIRCULATION 61
Gas Absorber - Adiabatic Type Hydrogen Chloride is very soluble in water but it's absorption is complicated by the high heat of solution and the high partial pressure over warm concentrated solutions. In practice, the basic problem in making concentrated solutions is one of efficient heat removal. In this type of absorber, the heat of absorption is removed by evaporation of water and acid in the column. The vapour being condensed is diluted with 'makeup' therefore mostly removed via condenser. Concentration and cooling of the liquid phase is assisted by evaporation of water to maintain the vapour/liquid equilibrium in the lower part of the packed section. The arrangement of the absorber is common to all sizes in the range. The gas is introduced into the column at a point below the packed section and rises counter current to a down comer stream of acid. 'Makeup' water enters above the condenser and in ert gases are vented from the head of the column. The hot concentrated products is passed through an acid cooler before flowing to a storage tank. ADAPTOR 'MAKE' WATER IN COOLENT IN COOLENT OUT HEAT EXCHANGER COOLENT IN PACKED GAS IN COOLENT OUT HEAT EXCHANGER COOLENT IN ADAPTOR Gas Absorber - Falling Film Type Hyderogen chloride feed gas is being allowed to enter from the inlet provided on the upper end of ABSORBER. This gas falls down along with the water inside the vertical parallel glass tubes. This arrangement provides more effective absorption as cooling of dilute acid and absorption of hydrogen chloride gas are taking place simultaneously. It has got more solubility in water at lower temperature. In this way ABSORBER work as a number of water cooled wetted wall columns in parallel. The basic principle involved is falling film absorption which have : Ž ability to absorb large loadings of gas flow. Ž capacity to produce strong acid with minimum vent losses. since absorption is effected at a low temperature. ABSORBER consists of a vertical Shell and Tube Heat Exchanger incorporating economical design considerations. Compactness and light weight are the additional features. Area of Application Hydrogen Chloride Gas Absorption. HCI GAS AT AMBIENT TEMP FALLING FILM ABSORBER COOLANT OUT COOLANT IN URI SCRUBBER Hydrogen Chloride Gas / Sulphur Dioxide Gas Absorption Hydrogen Chloride Gas/Chlorine Gas Absorption MAKE UP TO FINAL STORAGE Hydrogen Chloride Gas/ Sulphur Dioxide / Cl2 Absorption Hydrogen Bromide Gas Absorption TANK WATER / 30% HCI RECIRCULATION 62
HCl Gas Generation Unit (Sulphuric Route) : 'Shyam' Supplies Various Dry HCl gas generation plant based on dif ferent capacities ranging from 5kg./hr. to 300 kg./hr. 30% HCl and 98% Sulphuric acid are fed to the Mixing Zone by the metering pump or from Overhead tank through Rotameter depending upon the customer requirement and site height availability. The HCl and H2SO4 feed are mixed prior to entry into the Reaction zone (Falling Film Tubular Heat Exchanger). The spent Sulphuric acid from the bottom of the Falling Film Tubular Exchanger is cooled in the Heat Exchanger, prior to discharge. The Liquid Cooler uses cooling water for cooling duty. The HCl gas generated in the Falling Film Tubular Heat Exchanger comes in contact with Conc. H2SO4 in the Drying Zone (Dehydrating packed column) Initial drying of the HCl gas takes place in this section. HCl gas from the top of the Dehydrating column is passed through Sulphuric Acid trap to minimize the moisture content in HCl Gas. There are no moving parts in the entire system. The utility requirements as well as floor space requirements for the Plant are minimum. All the wetted parts of the system are fabricated from corrosion resistant materials (glass/ptfe) for the process conditions envisaged. 30% HCI TANK H 2SO 4TANK CONC. 98% H 2SO4 DRYING ZONE 30% HCI MIXING ZONE TI MIST ELIMINATOR TI CWR SPENT HCI CWS SULPHURIC ACID TRAP DRY HCI GAS SPENT SULPHURIC ACID OUTLET HCl Gas Generation Unit (Boiling Route) HCI TO REACTOR 'Shyam Supplies Various Dry HCl gas generation plant based on dif ferent capacities ranging from 5kg./hr. to 300 kg./hr. 30% HCl is fed to the unit continuously by the Pump or through Overhead tank depending upon the customer requirement and site height availability. 20-21% Azeotropic HCl/Water mixture is formed into Thermosyphon Reboiler by boiling 30% HCl. By product 20-21% spent Hydrochloric acid is continuously discharged from the bottom of the stripping column. The 20% spent HCl is cooled by an acid cooler prior to discharge into an intermediate spent acid storage tank. HEAT EXCHANGER BRINE IN BRINE IN CONC.HCl LIQUOR 30% HCI BRINE OUT BRINE OUT AZEOTROPIC DISTILLATION The condensation system at top of column consists of : TP 1. Cooling Water Condenser 2. Chilled Water Condenser 3. Chilled Brine Condenser SPENT HCI CONDE. STEAM HCI REBOILER Chilled Brine is to be provided to remove the moisture from the HCl gas. If chilled Brine is not available, Sulphuric acid trap is to be provided to remove the moisture from the gas generated. The Product Dry HCl gas is discharged at atmospheric pressure and goes to downstream equipment. All the wefted parts of the system are fabricated from corrosion resistant materials (Glass/PTFE) for the process conditions envisaged. CONC.HCI LIQUOR TANK CONC. HCI SPENT HCI TANK SPENT HCI 20% HCI FOR DISPOSAL 63
Distillation Assembly on Glass Lined Reactor The type of Typical unit is mounted on a Vapour nozzle of Glasslined Reactor. The assembly has a Glass Packed Column to enhance Distillation. Reflux Divider and Reflux Condenser with twin receiver system is to facilitate working under vacuum or at atmospheric pressure. Receiver System is equipped with Product Cooler. Vent/Vacuum Valve and Drain Valve. PTFE LINE HEAT EXCHANGER HEAT EXCHANGER OUTLET SHELL & TUBE HEAT EXCHANGER REFLUX DIVIDER PACKED FEED PIPE REFLUX LINE LINE LINE LINE DIP PIPE RECEIVING FLASK VESSEL HOLDER PTFE RECEIVING FLASK PTFE REACTOR REACTOR OPTION - I OPTION - II 64
Shyam Enterprises Rotary Film Evaporators 65
Rotary Film Evaporators Shyam offers the complete range of Rota Evaporators and its accessories and spares. The basic function of the Rota Evaporator is gentle evaporation and concentration that is thin film evaporation under vacuum. A standard model of Super Rota consists of Evaporating flask, receiving flask, Vapor Tube and Facility for dual, reflux and product collection along with parameters specified in the table. Available with the Evaporating Flask Capacities of 10, 20, 50, 100 liter. A completely self contained Transportable Model Can be operated continuously in atmospheric pressure and in batch in vacuum Six Glass Assemblies are available for different Process needs. Can also be offered tailor made glass assemblies as per clients, process requirements. Digital indication of the bath temperature and flask RPM and vapor temperature. Temperature control for bath are set with digital temperature controller. Efficient glass condenser with large heat transfer area to minimise distillation losses. Manual Bath Lowering in case of power failure. Insulated bath ensures user safety from the burn. Add versatility and enhance safety with the help of Optional accessories like Anti Bump device and Supercoat coating on the glass parts. Flame proof and GMP models are also available. Model Shyam Rota 10 Shyam Rota 20 Shyam Rota 50 Shyam Rota 100 Evaporating Flask Capacity 10 20 50 100 Rotation Speed (RPM) 20-90 20-90 20-90 20-90 Rotation Speed Setting Hand / Motor Lift Motorized Motorized Motorized Motorized 2 Condensing Surface (Cm) 5000 6000 10000 25000 Heating Capacity (W) 3000 4000 6000 8000 Temperature Range (Heating Bath Water) 30-90 30-90 30-90 30-90 Temperature Range (Heating Oil Bath) 30-150 30-150 30-150 30-150 Receiving Flask Capacity 5 10 20 50 Bath Temperature Indication Digital Digital Digital Digital Heating Bath Temperature Control Supply Voltage (V / Hz.) 230 v / 50 Hz. 230 v / 50 Hz. 440 v / 50 Hz. 440 v / 50 Hz. Supply Power (W) 3400 4400 7500 9500 Drive AC, 3 Phase AC, 3 Phase AC, 3 Phase AC, 3 Phase 66