MaxiCoking Technology Breakthrough Technology for Improved Existing Delayed Coker Performance

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MaxiCoking Technology Breakthrough Technology for Improved Existing Delayed Coker Performance Foam Reduction in petroleum Cokers, US Patent 6,117,308: A method of producing petroleum coke in a petroleum coking system comprising the steps of (a) adding a fluid to live coking drum while warming a second drum so that additional vapor is provided in the live drum and (b) reducing pressure loss in the live drum by regulating the addition of the fluid based upon a target pressure for the live drum and by regulating the flow of warm-up vapor from the live drum to the second drum based upon a target pressure for second drum. Constant Pressure System PC LCGO/ Naphtha DE Constant coking drum pressure operation. Constant drum vapor velocity; eliminates foam formation & foam expansion in drum during coking operation. Provides additional vapor for drum warm up process.

Constant Pressure System Detail Drawing Superheated Steam Naphtha /LCGO FO FO FO Quench water PRC 1- Set at the drum overhead pressure 2- Minimum liquid flow rate is require, 10gpm Drum Overhead Line Overhead Vapor

Drum Warming in Petroleum Cokers, Patent No. 6,764,593B1: The new warm-up system operates to provide additional hot vapor material for warming the empty drum. Further, the new warm up system operates to more effectively preserve the temperature and motive pressure of the warm-up vapor. Thus, a drum switchover temperature of 700 + ºF can be consistently achieved. Moreover, the desired warm-up temperature is achieved in a shorter period of time. Constant Pressure System LCGO/ Naphtha Hot Vapor 830 ºF, 18 psig New Warm-Up System 825 ºF, 17.82 psig 830 ºF, 35 psig WARMING UP Condensate Drum Faster warm-ups. Drum warm up time is measurably reduced to provide additional on-stream time. Reduction of foam & condensate formation during drum warm-up as slop production, poor fractionator performance as recycle production and after drum switching as front foam production Eliminate Antifoam Silicon usage.

New Drum Warm Up System Detail Drawing Drums warm up line connection options: Point A Point B Option 1 Top Collar TO Top Collar Option Drum top head Flange TO Drum top head flange Option 3 PSV Header TO PSV Header Point A Hot Vapor New Warm-Up System Point B 830 ºF, 35 psig WARMING UP Condensate Drum

Alternative Foam Carry Over Option : The new warm-up system operates to provide an alternative foam carry over place during warm up and quenching process, which saves the or Blowdown Systems. During the warm up of drum B and steam purging process of drum A, if the foam expansion level be noticed, we will increase the set pressure of PC A by 10-20 psig more than operation pressure, so the foams/fines will be pushed into the empty drum B via the new warm up live which is already open. During water quenching, the PC A will controls the quench water flow. LCGO/ Naphtha PC A PC B Hot Vapor Quench water FC 830 ºF, 18 psig New Warm-Up System 825 ºF, 17.82 psig 830 ºF, 35 psig WARMING UP Empty drum will become an alternative option for foam carrying over during warm up process and quenching instead System or Blowdown System.

Shorter coking cycle will reduces the Blowdown system loading: A coker unit of 21,300 BPSD vacuum bottom feed rate at 32 psig coking drum pressure and 925 F heater outlet has produced 836 short tones of coke per drum in 16 hour coking cycle. Comparison of Blowdown vapor feed rate at shorter cycle of 12 and 10 hour will indicate the less Blowdown vapor feed rate loading ( assuming the coker feed properties and operation conditions are the same); please refer to below chart. Coking Cycle Coking Cycle Coking Cycle 16 hour 12 hour 10 hour Coker Feed Rate, BPSD 21,500 21,500 23,000 Coke Product, Shot tons per drum 836 627 523 Quench cycle, hour 6 6 6 Lb/hr Lb/hr Lb/hr Steam 100,320 75,240 62,760 Wax Tailings 10,032 7,524 6,276 Non condensibles 334 251 209 Lt. Slop 7,524 5,643 4,707 Total Blowdown Vapor Feed 118,210 88,658 73,952 OVHD Cooler, BTU/hr 1,529,880 1,147,410 957,090 Bottom Reboiler, BTU/hr 145,069,207 108,801,905 90,755,018 Reduces the Blowdown loading rate by 33% at same current coker throughput OR Increases the coker throughput by 33% at the same current Blowdown load

US CokerTech engineers and management have more than 35 years Delayed Coker operation and design experience. Our services include the following: We access the latest Delayed Coker equipment specification and simulation programs to evaluate the pumps, compressor, vessels, heat exchangers, fractionator, heaters, and PSVs, etc. We are implementing our own latest patented technologies. We are capable to evaluate your coker system and make recommendations for modification; and to apply the latest patented technology. This would allow to increased capacity, liquid recovery and to operate more efficiently and reliably over time. Our competitive fees are lump sum; including use of our technologies.