Exova Warringtonfire Holmesfield Road Warrington WA1 2DS United Kingdom T : +44 (0 1925 655116 F : +44 (0) 1925 655419 E : warrington@exova.com W: www.exova.com IMO Resolution MSC 61(67): Annex 1: Part 2 Smoke & Toxicity A Report To: Tarkett Sommer AB Document Reference: 190720 Date: 1 st April 2010 Issue No.: 1 Page 1 Registered Office: Exova (UK) Ltd, Lochend Industrial Estate, Newbridge, Midlothian EH28 8PL United Kingdom. Reg No.SC 70429 This report in issued in accordance with our terms and conditions, a copy of which is available on request.
Executive Summary Objective To determine the performance of the following product when tested in accordance with IMO Resolution MSC 61(67): Annex 1, Part 2. Generic Description Product reference of floor covering Thickness Weight per unit area or density or application rate Homogenous vinyl flooring Contract Plus 14.25mm 14.79kg/m 2 adhered to a calcium silicate based board utilising Casco Proff 3448 adhesive Individual components used to manufacture composite: Homogenous vinyl floor covering Contract Plus 2mm 3150g/m 2 Tackified acrylic emulsion Casco Proff 3448 N/A 3-5m 2 per litre Calcium silicate based board Promat - Brandschutzbauplatten; 12mm 870kg/m 3 Promatect-H Please see page 5 of this test report for the full description of the product tested Test Sponsor Summary of Test Results: Tarkett Sommer AB, Division Resiliant Flooring, Technical Centre, S-37281, Ronneby, Sweden. The specimens as tested achieved the criteria for smoke generation and toxicity for floor coverings as specified in the Resolution. Date of Test 22 nd February 2010 Signatories Responsible Officer J. Lucas-Cox * Principal Chemist Authorised C. Dean * Operations Manager * For and on behalf of Exova Warringtonfire. Report Issued: 1 st April 2010 This version of the report has been produced from a.pdf format electronic file that has been provided by Exova Warringtonfire to the sponsor of the report and must only be reproduced in full. Extracts or abridgements of reports must not be published without permission of Exova Warringtonfire. Document No.: 190720 Page No.: 2 of 10
CONTENTS PAGE NO. EXECUTIVE SUMMARY... 2 SIGNATORIES... 2 TEST DETAILS... 4 DESCRIPTION OF TEST SPECIMENS... 5 TEST RESULTS... 6 Appendix 1 Observations during test... 9 REVISION HISTORY... 10 Document No.: 190720 Page No.: 3 of 10
Test Details Purpose of test This test method, adopted by the International Maritime Organisation, specifies a procedure for qualifying smoke generation and toxic potency of products and thus their suitability for use in maritime construction. The tests were performed in accordance with the procedure specified in IMO Resolution MSC, 61(67) Annex 1, Part 2 as amended by MSC/Circ.916 dated 4 th June 1999 and revised by MSC/Circ.1008 dated 8 th June 2001, and it is advised that this report is read in conjunction with these documents. Scope of test IMO Resolution MSC 61(67) Annex 1, Part 2 (Ref.1) specifies that smoke generation tests should be conducted in accordance with ISO 5659: 1994, Part 2 (Ref.2). The Resolution also details a classification system based on the maximum specific optical density of smoke occurring during the test, averaged over three replicate tests, carried out in each of three test conditions. In addition, the Resolution specifies limits for seven toxic gases which must not be exceeded in any of the three test conditions. Fire test study group/egolf Instruction to test Certain aspects of some fire test specifications are open to different interpretations. The Fire Test Study Group and EGOLF have identified a number of such areas and has agreed Resolutions which define common agreement of interpretations between fire test laboratories which are members of the Groups. Where such Resolutions are applicable to this test they have been followed. The test was conducted on the 22 nd February 2010 at the request of Tarkett Sommer AB, the sponsor of the test. Conditioning specimens Exposed face Substrate of The specimens were received on the 5 th February 2010. Prior to test the specimens were conditioned to constant mass at a temperature of 23 ± 2 C and a relative humidity of 50 ± 5%. The decorative face of the specimens was exposed to the radiant heat of the test when the specimens were mounted in the test position. The floor covering was bonded to a nominally 12mm thick calcium silicate based board utilising Casco Proff 3448 adhesive. Provision of test specimens The flooring and adhesive specimens were supplied by the sponsor of the test. Exova Warringtonfire was not involved in any selection or sampling procedure. Exova Warringtonfire supplied the substrate and bonded the composite together. Document No.: 190720 Page No.: 4 of 10
Description of Test Specimens The description of the specimens given below has been prepared from information provided by the sponsor of the test. All values quoted are nominal, unless tolerances are given. General description Homogenous vinyl flooring adhered to a calcium silicate based board utilising Casco Proff 3448 adhesive Contract Plus Tarkett AB See Note 1 below 14.25mm (determined by Exova Warringtonfire) See Note 1 below 14.79kg/m 2 (determined by Exova Warringtonfire) Product reference Contract Plus Name of manufacturer Tarkett AB Generic type Homogenous vinyl flooring Thickness 2mm Weight per unit area 3150g/m 2 Colour reference 466 Flame retardant details See Note 2 below Trade name Casco Proff 3448 Generic type Tackified acrylic emulsion Name of manufacturer Casco Application rate 3-5m 2 per litre Trade name of floor covering Manufacturer of floor covering Overall thickness of floor composite Overall weight per unit area of floor covering Floor Covering Adhesive (floor covering to Application method V-notched trowel substrate) Flame retardant details The sponsor of the test has confirmed that no flame retardant additives were utilised in the production of this component. Substrate Product reference Promat - Brandschutzbauplatten; Promatect-H Generic type Calcium silicate based board Name of manufacturer Promat Overall thickness 12mm Overall density 870kg/m 3 Flame retardant details The substrate is inherently flame retardant Preparation details None See Note 2 below Brief description of manufacturing process of the floor covering Note 1 the sponsor was unable to provide this information Note 2 the sponsor was unwilling to provide this information Document No.: 190720 Page No.: 5 of 10
Test Results Test procedure A 75mm x 75mm specimen was mounted horizontally inside a smoke chamber of the design specified in ISO 5659 Part 2, 25mm below a cone shaped, radiant electric heater capable of producing a uniform irradiance of 50kW/m 2 on the specimen surface. A premixed propane/air pilot flame of length 30mm may be applied 10mm above the specimen surface. Three replicate specimens are tested in each of the following three test conditions: 1. Irradiance of 25kW/m 2 in the presence of pilot flame. 2. Irradiance of 25kW/m 2 in the absence of pilot flame. 3. Irradiance of 50kW/m 2 in the absence of pilot flame. The attenuation of a light beam passing through the evolved smoke is measured and the results are reported in terms of the maximum Specific Optical Density attained during the test, given by the equation: Ds = (V/(A*L)*log 10 (100/T) Where: V = total volume of the chamber (m 3 ) A = exposed area of the specimen (m 2 ) L = optical length (m) of smoke measurement T = % light transmitted. Test duration is a minimum of ten minutes. This period is extended by a further ten minutes if the maximum Specific Optical Density has not been reached. The sampling of the fire effluent created in the chamber during the test for the analysis of the concentration of the seven different gases for which criteria are given is conducted using a variety of methods as defined in the internal operating procedure. In all cases, the sample is taken from the geometric centre of the chamber and sample lines are kept as short as possible. For the analysis of oxides of nitrogen and carbon monoxide, continuous measurements are made throughout the duration of the test. Carbon monoxide (CO) is determined continuously using a pre-calibrated nondispersive infra-red analyser. The values reported are those averaged over a 3 minute period of maximum smoke obscuration. Oxides of Nitrogen (NO x ) are determined continuously using a chemiluminesence analyser. Again, the values reported are those averaged over a 3 minute period of maximum smoke obscuration. Document No.: 190720 Page No.: 6 of 10
For the other gases, single point analysis is conducted. The gases are absorbed into aqueous media and analysed remotely. Two types of media are used; 0.1M sodium hydroxide solution and 0.3% Hydrogen Peroxide solution. The gases are sampled over a two minute period of maximum smoke density by bubbling the gases through the media using a fritted funnel Dreschel bottle arrangement. Hydrogen Cyanide (HCN) is determined from gases absorbed into a solution of sodium hydroxide and analysed using ion chromatography. Hydrogen Fluoride (HF), Hydrogen Chloride (HCl), Hydrogen Bromide (HBr) and Sulphur Dioxide (SO 2 ) are absorbed into a solution of 0.3% hydrogen peroxide and are also analysed by ion chromatography. Test Results GAS Limit (ppm) Condition 1 Reading (ppm) Condition 2 Condition 3 Carbon Monoxide CO 1450 206 244 373 Hydrochloric Acid HCl 600 238 491 233 Hydrogen Bromide HBr 600 ND ND ND Hydrogen Fluoride HF 600 ND ND ND Hydrogen Cyanide HCN 140 ND ND ND Nitrous Fumes NO x 350 1 ND 1 Sulphur Dioxide SO 2 200 ND ND ND Averaged Specific Optical Density Key: ND indicates non-detected. 500 208 233 310 Observations recorded during the tests are detailed in Appendix 1 of this report. Summary of Results The specimens as tested achieved the criteria for smoke generation and toxicity for floor coverings as specified in the Resolution. Document No.: 190720 Page No.: 7 of 10
Validity This report is valid for a period for fifteen years from the date of test. This report may only be reproduced in full. Extracts or abridgements shall not be published without permission of Exova Warringtonfire. The tests results relate only to the specimens of the product in the form in which they are tested, they are not intended to be the sole criterion for assessing the potential fire hazard of the product in use. Small differences in the composition or thickness of the product may significantly affect the performance during the test and may therefore invalidate the test results. Care should be taken to ensure that any product which is supplied or used is fully represented by the specimens that were tested. The quantity of each specific toxic gas species generated is dependant upon the fire model used and the burning behaviour of the specimen during each individual fire test. The quantitative determination of combustion products therefore relates only to the specimens tested under the conditions stated and when combustion occurs as described in this test report. References 1. International Maritime Organisation Resolution MSC 61(67) 1996; The International Code for Application of Fire Test Procedures, Annex 1, Part 2: Smoke and Toxicity Test. 2. ISO 5659 Plastics - Smoke Generation - Part 2 1994: Determination of Optical Density by a Single Chamber Test. Document No.: 190720 Page No.: 8 of 10
Appendix 1 Observations during test 25kW/m² In The Presence Of A Pilot Flame 25kW/m² In The Absence Of A Pilot Flame 50kW/m² In The Absence Of A Pilot Flame Specimen No. 1 2 3 4 5 6 7 8 9 Colour of smoke produced Expansion distance towards heater (mm) Ignition time in seconds (if applicable) Extinction time in seconds (if applicable) Dark Dark Dark Dark Dark Dark Dark Dark Dark 30 30 30 30 30 30 30 30 30 28 33 36 100 80 87 14 15 13 270 250 300 330 320 300 450 340 480 0 = Did Not Occur * = Did Not Re-ignite N/A = Not Applicable Document No.: 190720 Page No.: 9 of 10
Revision History Issue No : Issue Date : Revised By: Approved By: Reason for Revision: Issue No : Issue Date : Revised By: Approved By: Reason for Revision: Document No.: 190720 Page No.: 10 of 10