Specifications for Fluorocarbon Refrigerants

AHRI Standard 700 with Addendum 0 Standard for Specifications for Fluorocarbon Refrigerants

WITH ADDENDUM, Specifications for Fluorocarbon Refrigerants June 0 AHRI Standard 700-0 with Addendum, Specifications for Fluorocarbon Refrigerants, adds refrigerant R-34ze to the scope Section and to Table A of AHRI Standard 700-0. The June 0 Addendum has been incorporated into the already published 0 version of AHRI Standard 700 to avoid confusion. Air-Conditioning, Heating, and Refrigeration Institute Wilson Blvd, Suite 500 Arlington, VA 0

New refrigerant to be added to Table A Reporting Units R-34ze(E) CHARACTERISTICS: Boiling Point ºC @.3 kpa -9.0 Boiling Point Range K Critical Temperature ºC 9.4 Isomer Content Isomer 0.3 R-34ze(Z) VAPOR PHASE Air and Other Non Condensables % by volume @ 5.0ºC LIQUID PHASE All Other Volatile Impurities Halogenated Unsaturated Volatile Impurities Chlorides % by volume or Visually clean to ppm by weight (as HCl) No visible turbidity. Scope. This standard specifies acceptable levels of contaminants (purity requirements) for fluorocarbon refrigerants (hereinafter referred to as refrigerants) regardless of source and lists acceptable test methods. These refrigerants are: R-; R-; R-3; R-; R-3; R-3; R-3; R-4; R-5; R-6; R-3; R-4; R-5; R-34a; R-4b; R-4b; R- 43a; R-5a; R-8; R-7ea; R-36fa; R-45fa; R-34yf; R-34ze(E); R-A; R-B; R-A; R-B; R- 3A; R-3B; R-4A; R-5A; R-6A; R-7A; R-7B; R-7C; R-7D; R-7E; R-7F; R-8A; R-9A; R-9B; R-4A; R-4B; R-4A; R-4B; R-4A; R-43A; R-44A; R-44B; R-45A; R-45B; R-46A; R- 47A; R-47B; R-48A; R-49A; R-40A; R-4A; R-4B; R-4A; R-4B; R-4C; R-4D; R-43A; R-44A; R-45A; R-46A; R-47A, R-48A, R-430A, R-434A, R-437A; R-438A; R-439A; R-4A; R-500; R-50; R-503; R- 507A; R-508A; R-508B; and R-509A as referenced in the ANSI/ASHRAE Standard 34 with Addenda. Price $.00 (M) $0.00 (NM) Printed in U.S.A. Copyright 0, by Air-Conditioning, Heating, and Refrigeration Institute Registered United States Patent and Trademark Office plastic extruder

IMPORTANT SAFETY DISCLAIMER AHRI does not set safety standards and does not certify or guarantee the safety of any products, components or systems designed, tested, rated, installed or operated in accordance with this standard/guideline. It is strongly recommended that products be designed, constructed, assembled, installed and operated in accordance with nationally recognized safety standards and code requirements appropriate for products covered by this standard/guideline. AHRI uses its best efforts to develop standards/guidelines employing state-of-the-art and accepted industry practices. AHRI does not certify or guarantee that any tests conducted under its standards/guidelines will be non-hazardous or free from risk. Note: This standard supersedes AHRI Standard 700-0 AHRI CERTIFICATION PROGRAMS PROVISIONS Scope of the Certification Programs The Reclaimed Refrigerant and Refrigerant Testing Laboratory Certification Programs are based on this standard. The Reclaimed Refrigerant Certification Program includes purity specifications for reclaimed refrigerants. The Refrigerant Testing Laboratory Certification Program includes verification for Refrigerant Testing Laboratories that perform testing of refrigerants to AHRI Standard 700. Certified Ratings The following ratings are verified by test for the Reclaimed Refrigerant Certification Program: a. (). b. Chloride (/fail). c. (). d. (% by volume or ). e. (/fail). f. Air and Other Non Condensables (% by volume). g. All Other Volatile Impurities () h. Halogenated Unsaturated Volatile Impurities (). The following contaminants are verified by test for the Refrigerant Testing Laboratory Certification Program: a. (). b. (% by volume or ). c. Air and Other Non Condensables (% by volume). d. All Other Volatile Impurities (). Price $.00 (M) $0.00 (NM) Printed in U.S.A. Copyright 0, by Air-Conditioning, Heating, and Refrigeration Institute Registered United States Patent and Trademark Office plastic extruder

TABLE OF CONTENTS SECTION PAGE Section. Purpose... Section. Scope... Section 3. Definitions... Section 4. Characterization of Refrigerants and Contaminants... Section 5. Sampling and Summary of Test Procedures... Section 6. Reporting Procedure...4 Section 7. Conformance Conditions...4 TABLES Table A. Table B. Table C. Characteristics of Single Component Refrigerants and their Maximum Allowable Levels of Contaminants...5 Characteristics of Zeotropic Blends (0 Series Refrigerants) and their Maximum Allowable Levels of Contaminants...8 Characteristics of Azeotropic Blends (500 Series Refrigerants) and their Maximum Allowable Levels of Contaminants...5 APPENDICES Appendix A. References - Normative...6 Appendix B. References - Informative...6 plastic extruder

SPECIFICATIONS FOR FLUOROCARBON REFRIGERANTS Section. Purpose. Purpose. The purpose of this standard is to establish purity specifications, to verify composition, and to specify the associated methods of testing for acceptability of fluorocarbon refrigerants regardless of source (new, reclaimed and/or repackaged) for use in new and existing refrigeration and air-conditioning products within the scope of AHRI... Intent. This standard is intended for the guidance of the industry including manufacturers, reclaimers, repackagers, distributors, installers, servicemen, contractors and users of fluorocarbon refrigerants... Review and Amendment. This standard is subject to review and amendment as technology advances or as additional data becomes available. This data can be submitted to AHRI for review. Section. Scope. Scope. This standard specifies acceptable levels of contaminants (purity requirements) for fluorocarbon refrigerants (hereinafter referred to as refrigerants) regardless of source and lists acceptable test methods. These refrigerants are: R-; R-; R-3; R-; R-3; R-3; R-3; R-4; R-5; R-6; R-3; R-4; R-5; R-34a; R-4b; R-4b; R- 43a; R-5a; R-8; R-7ea; R-36fa; R-45fa; R-34yf; R-A; R-B; R-A; R-B; R-3A; R-3B; R-4A; R-5A; R-6A; R-7A; R-7B; R-7C; R-7D; R-7E; R-7F; R-8A; R-9A; R-9B; R- 4A; R-4B; R-4A; R-4B; R-4A; R-43A; R-44A; R-44B; R-45A; R-45B; R-46A; R-47A; R-47B; R-48A; R-49A; R-40A; R-4A; R-4B; R-4A; R-4B; R-4C; R-4D; R-43A; R-44A; R-45A; R- 46A; R-47A, R-48A, R-430A, R-434A, R-437A; R-438A; R-439A; R-4A; R-500; R-50; R-503; R-507A; R-508A; R-508B; and R-509A as referenced in the ANSI/ASHRAE Standard 34 with Addenda. Section 3. Definitions All terms in this document follow the standard industry definitions in the current edition of ASHRAE Terminology of Heating, Ventilation, Air Conditioning and Refrigeration unless otherwise defined in this section. 3. "Shall" or "Should". "Shall" or "should" shall be interpreted as follows: 3.. Shall. Where "shall" or "shall not" is used for a provision specified, that provision is mandatory if compliance with the standard is claimed. 3.. Should. "Should" is used to indicate provisions which are not mandatory but which are desirable as good practice. Section 4. Characterization of Refrigerants and Contaminants 4. Characterization. Characterization of refrigerants and contaminants are listed in the following general classifications: 4... 4... Chloride 4..3. 4..4. High boiling residue 4.. Particulates/solids 4..6. Air and other Non-condensables 4..7. All other Volatile impurities 4..8. Halogenated Unsaturated Volatile Impurities plastic extruder

Identification of the refrigerant and volatile impurities shall be carried out by gas chromatography (GC). Section 5. Sampling and Summary of Test Procedures 5. Referee Test. The referee test methods for the various contaminants are summarized in the following paragraphs. Detailed test procedures are included in Appendix C to AHRI Standard 700. If alternative test methods are employed, the user shall be able to demonstrate that they produce results at least equivalent to the specified referee test method. 5. Refrigerant Sampling.. 5.. Sampling Precautions. Special precautions should be taken to ensure that representative samples are obtained for analysis. Sampling shall be done by qualified personnel following accepted sampling and safety procedures. Refrigerants with critical temperatures near or below ambient temperature cannot be reliably sampled for both liquid and vapor phase without special handling. 5.. Cylinder Preparation. Place a clean, empty sample cylinder with the valve open in an oven at C for one hour. Remove it from the oven while hot, immediately connect it to an evacuation system and evacuate it to less than 56 kpa. Close the valve and allow it to cool. Weigh the empty cylinder. 5..3 Vapor Phase Sampling. A vapor phase sample shall be obtained for determining the non condensables. The source temperature shall be measured and recorded at the time the sample is taken. Non condensable gases, if present, will concentrate in the vapor phase of the refrigerant; care must be exercised to eliminate introduction of either air or liquid phase refrigerant during the sample transfer. Since R-, R-3, R-3, R-4b, and R-45fa have normal boiling points near or above room temperature, non condensable determination is not required for these refrigerants. 5..3. Special Handling for Low Critical Temperature Refrigerant. A vapor phase sample is required to determine non condensables and volatile impurities, including other refrigerants. The vapor phase sample is obtained by regulating the sample container temperature to 5 K or more above the refrigerant critical temperature. 5..4 Liquid Phase Sampling. A liquid phase sample is required for all tests listed in this standard except the test for non condensables. 5..4. Liquid Sampling. Accurate analysis requires that the sample cylinder, at ambient temperature, be filled to at least 60% by volume; however, under no circumstances should the cylinder be filled to more than 80% by volume. This can be accomplished by weighing the empty cylinder and then the cylinder with refrigerant. When the desired amount of refrigerant has been collected, close the valve(s) and immediately disconnect the sample cylinder. NOTE: Care should be taken to ensure that all connections and transfer lines are dry and evacuated to avoid contaminating the sample. 5..4. Special Handling for Low Critical Temperature Refrigerant. A liquid phase sample is required for all testing except non condensables and volatile impurities, including other refrigerants. The liquid phase sample is obtained by regulating the sample cylinder temperature to ºC below the critical temperature of the refrigerant. NOTE: If free water is present in the sample, cooling to below 0 ºC may result in the formation of ice. Clathrates may form at temperatures above 0 ºC with some fluorocarbon refrigerants. 5..4.3 Record Weight. Check the sample cylinder for leaks and record the gross weight.

5.3 Refrigerant Identification. The required method shall be gas chromatography as described in Appendix C with the corresponding gas chromatogram figures as illustrated in Informative Appendix D to AHRI Standard 700. The chromatogram of the sample shall be compared to known standards. 5.4 Content. 5.4. Method. The Coulometric Karl Fischer Titration, as described in Appendix C, shall be used for determining the water content of refrigerants. This method can be used for refrigerants that are either a liquid or a gas at room temperature. For all refrigerants, the sample for water analysis shall be taken from the liquid phase of the container to be tested. 5.4. Limits. The value for water content shall be expressed in parts per million (ppm) by weight and shall not exceed the maximum specified in Tables A, B, and C. 5.5 Conductivity. (Alternative to Chloride and Tests). 5.5. Method. A refrigerant may be tested for conductivity as an indication of the presence of acids, metal chlorides, and any compound that ionizes in water. This alternative procedure is intended for use with new or reclaimed refrigerants, however, significant amounts of oil can interfere with the test results. 5.5. Limits. The value for conductivity shall be converted to and expressed in calculated as HCl and shall be compared with the maximum acidity value specified (see in Tables A, B, and C). If the conductivity is above this amount, then the Chloride and Tests shall be conducted. If the conductivity is not greater than this amount, then the Chloride and Tests may be omitted. 5.6 Chloride. 5.6. Method. The refrigerant shall be tested for chloride as an indication of the presence of hydrochloric acid and/or metal chlorides. The referee procedure is intended for use with new or reclaimed refrigerants; however, high boiling residue in excess of the amounts in Tables A, B, and C can interfere with the test results. The test method shall be that described in Appendix C to AHRI Standard 700. The test will show noticeable turbidity at chloride levels of about 3 ppm or greater by weight. 5.6. Limits. The results of the test shall not exhibit any sign of turbidity. Report the results as "" or "fail." 5.7. 5.7. Method. The acidity test uses the titration principle to detect any compound that is soluble in water and ionizes as an acid. The test method shall be that described in Appendix C to AHRI Standard 700. This test may not be suitable for determination of high molecular weight organic acids; however, these acids will be found in the high boiling residue test outlined in. The test requires a 0 to 0 gram sample and has a detection limit of 0. ppm by weight calculated as HCl. 5.7. Limits. The value for acidity shall be expressed in as HCl and shall not exceed the limits in Tables A, B, and C... Method. High boiling residue shall be determined by either volume or weight. The volume method measures the residue from a standard volume of refrigerant after evaporation. The gravimetric method is described in Appendix C to AHRI Standard 700. Oils and/or organic acids will be captured by these methods.. Limits. The value for high boiling residue shall be expressed as a percentage by volume or weight and shall not exceed the maximum percent specified in Tables A, B, and C. 3

5.9 Particulates and Solids. 5.9. Method. A measured amount of sample shall be placed in a Goetz bulb under controlled temperature conditions. The particulates/solids shall be determined by visual examination of the Goetz bulb prior to the evaporation of refrigerant. For details of this test method, refer to Part 3 of Appendix C to AHRI Standard 700. 5.9. Limits. Visual presence of dirt, rust or other particulate contamination is reported as "fail." 5. Non Condensables. 5.. Method. A vapor phase sample shall be used for determination of non condensables. Non condensable gases consist primarily of air accumulated in the vapor phase of refrigerants where the solubility of air in the refrigerant liquid phase is extremely low and air is not significant as a liquid phase contaminant. The presence of non condensable gases may reflect poor quality control in transferring refrigerants to storage tanks and cylinders. The test method shall be gas chromatography with a thermal conductivity detector as described in Appendix C to AHRI Standard 700. 5.. Limits. The maximum level of non condensables in the vapor phase of a test sample shall not exceed the maximum at 5.0 C as shown in Tables A, B, and C. 5. Volatile Impurities Including Other Refrigerants. 5.. Method. The amount of volatile impurities including other refrigerants in the subject refrigerant shall be determined by gas chromatography as described in Appendix C to AHRI Standard 700. 5.. Limits. The test sample shall not contain more than of volatile impurities including other refrigerants as shown in Tables A, B, and C. 5... Halogenated Unsaturated Volatile Impurities. The test sample of a saturated fluorinated refrigerant shall not contain more than of halogenated unsaturated volatile impurities, unless listed individually in 5... 5... Individual Listed Volatile Impurities. Tables A, B and C list specific volatile impurities and their maximum allowable concentrations in. Section 6. Reporting Procedure 6. Reporting Procedure. The source (manufacturer, reclaimer or repackager) of the packaged refrigerant shall be identified. The refrigerant shall be identified by its accepted refrigerant number and/or its chemical name. Maximum allowable levels of contaminants are shown in Tables A, B, and C. Test results shall be tabulated in a similar manner. Section 7. Conformance Conditions 7. Conformance. While conformance with this standard is voluntary, conformance shall not be claimed or implied for products or equipment within the standard's Purpose (Section ) and Scope (Section ) unless such product claims meet all of the requirements of the standard and all of the testing and rating requirements are measured and reported in complete compliance with the standard. Any product that has not met all the requirements of the standard cannot reference, state, or acknowledge conformance to the standard in any written, oral, or electronic communication. 4

Table A. Characteristics of Single Component Refrigerants and their Maximum Allowable Levels of Contaminants Reporting Units Reference Section R- R- R-3 R- R-3 R-3 R-3 R-4 CHARACTERISTICS : ºC @.3 kpa 3.7-9.8-80 -.8-8.00-5.7 47.60 3.60 Boiling Point K 0.3 0.3 0.3 0.3 0.3 Boiling Point Range 0.3 ºC 98.0.0 8.9 96.0 6. 78. 4. 45.7 Critical Temperature Isomer Content Isomer 0- R-3a 0-30 R-4a VAPOR PHASE Air and Other Non Condensables LIQUID PHASE % by volume @ 5.0ºC 5. 5.4 0 0 All Other Volatile Impurities 5. % by volume or Halogenagted Unsaturated Volatile Impurities 5... Visually clean to 5.9 (as HCl) 5.7 Chloride 3 No visible turbidity 5.6 3 Boiling points, boiling point ranges and critical temperatures, although not required, are provided for informational purposes. Since R-, R-3, R-3, R-4b, and R-45fa have normal boiling points near or above room temperature, non condensable determinations are not required for these refrigerants. Recognized chloride level for /fail is about 3 ppm. Not Applicable Refrigerant data compiled from Refprop 7.0. 5

Table A. Characteristics of Single Component Refrigerants and their Maximum Allowable Levels of Contaminants (continued) CHARACTERISTICS : Reporting Units Reference Section R-5 R-6 R-3 R-4 R-5 R-34a R-4b ºC @.3 kpa -38.9-78.0 7.8 -.0-48. -6. 3.0 Boiling Point K 0.3 0.3 0.3 0.3 0.3 0.3 0.3 Boiling Point Range Critical Temperature ºC 80.00 9.9 83.7.3 66.00. 0 06.8 Isomer Content Isomer VAPOR PHASE Air and Other Non Condensables LIQUID PHASE % by volume @ 5.0ºC 5. 0-8 R-3a+ R-3b 0-5 R-4a 0- R-34 0-0.ea R-4, R-4a 5.4 0 0 All Other Volatile Impurities 5. 0.9 Halogenated Unsaturated Volatile Impurities 5... See footnote 4 % by volume or % by weight Visually clean to (as HCl) 5.9 5.7 Chloride 3 No visible turbidity 5.6 3 Boiling points, boiling point ranges and critical temperatures, although not required, are provided for informational purposes. Since R-, R-3, R-3, R-4b, and R-45fa have normal boiling points near or above room temperature, non condensable determinations are not required for these refrigerants. Recognized chloride level for /fail is about 3 ppm. 4 Up to 5000 ppm R-34yf is acceptable as a halogenated unsaturated volatile impurity in R-34a Not Applicable Refrigerant data compiled from Refprop 7.0. 7

Table A. Characteristics of Single Component Refrigerants and their Maximum Allowable Levels of Contaminants (continued) Reporting Units Reference Section R-4b R-43a R-5a R-8 R-7ea R-36fa R-45fa CHARACTERISTICS : Boiling Point ºC @.3 kpa º -9.0-47. -4.0-36.8-6.5 -. 4.9 K 0.3 0.3 0.3 0.3 0.3 Boiling Point Range -- -- ºC 37. 7.70 3.3 7.00.7 4.9 54. Critical Temperature Isomer Content Isomer VAPOR PHASE Air and Other Non Condensables LIQUID PHASE % by volume @ 5.0ºC 5. 0-0.ea R-4, R-4a.0 0- R-43 -- -- -- R-45ca, R-45cb, R-45ea, 5.4 5 0 All Other Volatile Impurities % by volume or 5. Halogenated Unsaturated Volatile Impurities Visually clean to (as HCl) 5... 5.9 5.7 3.0 Chloride 3 No visible turbidity 5.6 3 Boiling points, boiling point ranges and critical temperatures, although not required, are provided for informational purposes. Since R-, R-3, R-3, R-4b, and R-45fa have normal boiling points near or above room temperature, non condensable determinations are not required for these refrigerants. Recognized chloride level for /fail is about 3 ppm Not Applicable Refrigerant data compiled from Refprop 7.0. R-34yf -9.4 94.8 7

Table B. Characteristics of Zeotropic Blends (0 Series Refrigerants) and their Maximum Allowable Levels of Contaminants Reporting Units Reference Section R-A R-B R-A R-B R-3A R-3B CHARACTERISTICS : Refrigerant Components R-/ 5a/4 R-/ 5a/4 R-5/ 90/ R-5/ 90/ R-90/ /8 R-90/ /8 Nominal Comp 53/3/34 6//8 60.0/.0/38.0 38.0/.0/60.0 5/75/0 5/56/39 Allowable Comp 5-55/- 3.5/33-35 59-63/9.5- /7-9 58.0-6.0/-./36.0-.0 36.0-.0/-./58.0-6.0 3-5./73-77/8-3-5./54-58/37-4 ºC @.3 kpa -33.3-49.0-47.0-47.8-49. Bubble Point -34.9 ºC @.3 kpa -6.4-8.8-46.9-44.7-44.3-46.8 Dew Point ºC 5.3 3.5 76.00 83.00 87.00 79.70 Critical Temperature VAPOR PHASE Air and Other Non Condensables % by volume @5.0ºC 5. LIQUID PHASE 5.4 All Other Volatile Impurities Chloride % by volume or % by weight Visually clean to (as HC) No visible turbidity 5. 5.9 5.7 5.6 Bubble points, dew points and critical temperatures, although not required, are provided for informational purposes. Recognized chloride level for /fail is about 3 ppm. Not Applicable Refrigerant data compiled from Refprop 7.0. R-4A R-5/ 43a/34a 44/5/4 4-46/5-53/-6-46. -45.5 7. 8

Table B. Characteristics of Zeotropic Blends (0 Series Refrigerants) and their Maximum Allowable Levels of Contaminants (continued) CHARACTERISTICS : Refrigerant Components Nominal Comp Allowable Comp Bubble Point Reporting Units ºC @.3 kpa Reference Section R-5A R-/5a/ 4b/C38 45/7/5.5/4.5 43-47/6-8/4.5-6.5/4-44.5-3.9 R-6A R-/ 600a/4b 55/4/4 53-57/3-5/ -4-3.7 R-7A R-3/5/ 34a 0// 8-/38-4/ 38-4 -45.3 R-7B R-3/5/ 34a /70/0 8-/68-7/ 8- -46.8 R-7C R-3/5/ 34a 3/5/5-5/3-7/50-54 -43.6 R-7D R-3/5/ 34a 5/5/70 3-7/3-7/68-7 -39.5 R-7E R-3/5/ 34a 5/5/60 3-7/3-7/58-6 -4.9 R-7F R- 3/5/34 a 30.0/30.0/4 0.0 8.0-3.0/8.0-3.0/38.0-4.0-46. -4.5-3.5-38.9-4.5-36.6-3.9-3 -39.7 Dew Point ºC @.3 kpa ºC 6.0 6.5 8.30 75.00 86.00 9. 88.50 83.0 Critical Temperature VAPOR PHASE Air and Other Non Condensables LIQUID PHASE % by volume @5.0ºC 5. 5.4 All Other Volatile Impurities % by volume or Visually clean to 5. 5.9 5.7 Chloride No visible turbidity 5.6 Bubble points, dew points and critical temperatures, although not required, are provided for informational purposes. Recognized chloride level for /fail is about 3 ppm. Not Applicable Refrigerant data compiled from Refprop 7.0. 9

Table B. Characteristics of Zeotropic Blends (0 Series Refrigerants) and their Maximum Allowable Levels of Contaminants (continued) Reporting Units Reference Section R-8A R-9A R-9B R-4A R-4B R-4A R-4B CHARACTERISTICS : Refrigerant Components R-5/ 43a/ R-/ 4/4b R- /4/4b R-3/5 R-3/5 R-70/ /5a R-70/ /5a Nominal Comp 7/46/47 60/5/5 65/5/ 50/50 45/55 /87.5/ 3/94/3 Allowable Comp 5-9/45-47/ 45-49 58-6/3-7/4-6 63-67/3-7/ 9-48.5-5/ 49.5-5 44-46/54-56 -/87.5-89.5/- -3/94-96/ -3 ºC @.3 kpa -44.6-34.7-35.6-5.4-5.3-39.5-4.6 Bubble Point ºC @.3 kpa -44. -6.4-7.9-5.4-5.6-36.6 -.0 Dew Point ºC 83. 6.9 6.9 7. 70.80 99. 96.00 Critical Temperature VAPOR PHASE Air and Other Non Condensables LIQUID PHASE % by volume @ 5.0ºC 5. 5.4 All Other Volatile Impurities % by volume or % by weight Visually clean to (as HC) 5. 5.9 5.7 Chloride No visible turbidity 5.6 Bubble points, dew points and critical temperatures, although not required, are provided for informational purposes. Recognized chloride level for /fail is about 3 ppm. Not Applicable Refrigerant data compiled from Refprop 7.0.

Table B. Characteristics of Zeotropic Blends (0 Series Refrigerants) and their Maximum Allowable Levels of Contaminants (continued) CHARACTERISTICS : Refrigerant Components Reporting Units Reference Section R-4A R-/8/ 4b R-43A R-8/ 34a/600a R-44A R-/4/ 600a/4b R-44B R-/4/ 600a/4b R-45A R-/5a R-45B R-/5a R-46A R-34a/ 4/600 Nominal Comp 70/5/5 9/88/3 5/8.5/ 4.0/6.5 50.0/39.0/ /9.5 8.0/8.0 5.0/75.0 59.0/39.5/ Allowable Comp Bubble Point ºC @.3 kpa 68-7/3-7/4-6 -38.0 8-/86-90/-3-30.6 49.0-53.0/ 6.5-3/ 3.5-4.5/ 5.5-7.0-34.0 48.0-5.0/ 37.0-4/ -.0/ 8.5-.0-3.9 8-83.0/ 7.0-9.0-37.5 4.0-6.0/ 74.0-76.0-7.7 58.0-59.5/ 39.0-4/.3-.6-3.4 ºC @.3 kpa -8.7-7.9 - -4.3-34.7-6. -.8 Dew Point ºC 7. 98.50.7 0.0.3 8. Critical Temperature VAPOR PHASE Air and Other Non Condensables % by volume @ 5.0ºC 5. LIQUID PHASE 5.4 All Other Volatile Impurities Chloride % by volume or % by weight Visually clean to (as HC) No visible turbidity 5. 5.9 5.7 5.6 Bubble points, dew points and critical temperatures, although not required, are provided for informational purposes. Recognized chloride level for /fail is about 3 ppm. Not Applicable Refrigerant data compiled from Refprop 7.0.

Table B. Characteristics of Zeotropic Blends (0 Series Refrigerants) and their Maximum Allowable Levels of Contaminants (continued) Reporting Units Referenc e Section R-47A R-47B R-48A R-49A R-40A R-4A R-4B CHARACTERISTICS : Refrigerant Components Nominal Comp R-5/ 34a/600 46.6/50.0/3.4 R-5/34a/ 600 79.0/8.3/.7 R-90/ /5a /96.0/.5 R-5/34a/ E70 77.0/9.0/4.0 R-34a/ 4b 88.0/.0 R- 5/34a 58.0/4.0 R- 5/34 a 85.0/5. 0 Allowable Comp Bubble Point ºC @.3 kpa 45.5-47.7/ 49.0-5/ 3.0-3.5-38.0 78.0-80.0/7.3-9.3/.-.8-44.9 -.0/ 95.0-97.0/.0-3.0-4. 76.0-78.0/ 8.0-0.0/ 3.0-5.0-4.6 88.0-89.0/ -.0-5.0 57.0-59.0/ 4-43.0 -.8 84.0-86.0/ 4.0-6.0-45.7 Dew Point ºC @.3 kpa -3.9-4 -. -36.0-4. -35.5-4.6 ºC 89.90 75. 96.70 79. 5.4 78.50 69.00 Critical Temperature VAPOR PHASE Air and Other Non Condensables LIQUID PHASE All Other Volatile Impurities Chloride % by volume @ 5.0ºC ppm by weight % by volume or % by weight Visually clean to ppm by weight (as HC) No visible turbidity Bubble points, dew points and critical temperatures, although not required, are provided for informational purposes. Recognized chloride level for /fail is about 3 ppm. Not Applicable Refrigerant data compiled from Refprop 7.0. 5. 5.4 5. 5.9 5.7 5.6 0

Table B. Characteristics of Zeotropic Blends (0 Series Refrigerants) and their Maximum Allowable Levels of Contaminants (continued) Reporting Units Referenc e Section R-4A R-4B R-4C R-4D R-43A R-44A R-45A R-46A CHARACTERISTICS : Refrigerant Components R-5/34a/ 600a R- 5/34a/ 600a R-5/ 34a/600 a R- 5/34a/ 600a R-34a/ 7ea R-5/34a /600a/600/ 60a R-3/34a/ 7ea R- 5/34a/6 00/60a Nominal Comp 85.// 3.4 55.0/4.0/ 3.0 8.0/ 5.0/3.0 65./3/ 3.4 5.5/47.5 5/47.0/ 0.9//0.6 8.5/69.5/.0 5./93.0/. 3/0.6 Allowable Comp 84.- 86./-.5/3.0-3.5 54.0-56.0/4-43.0/.5-3. 8-83.0/4.0-6.0/.5-3. 64.0-66.0/3-3.5/3.0-3.5 5-53.5/46.5-48.5 49.5-5/ 46.0-48.0/ 0.7-/0.8-./0.4-0.7 8.0-9.0/ 69.0-70.0/ -.5 4.- 6./9.0-94.0/.-.4/0.4-0.7 Bubble Point ºC @.3 kpa -46.5-4 -45.3-43. -4. -39. -38. -8.5 Dew Point ºC @.3 kpa -44. -35.6-4.3-38.4-3.5-33.3-3.3-6.7 7.70 85.70 76. 79.6 99.00 87.50 93.90 0. Critical Temperature ºC VAPOR PHASE Air and Other Non Condensables LIQUID PHASE All Other Volatile Impurities Chloride % by volume @ 5.0ºC % by volume or No visible turbidity 5. 5.4 5. 5.6 0 Bubble points, dew points and critical temperatures, although not required, are provided for informational purposes. Recognized chloride level for /fail is about 3 ppm. Not Applicable Refrigerant data compiled from Refprop 7.0. 3

Table B. Characteristics of Zeotropic Blends (0 Series Refrigerants) and their Maximum Allowable Levels of Contaminants (continued) CHARACTERISTICS : Refrigerant Components Nominal Comp Allowable Comp Reporting Units Referen ce R-47A R- 3/5/43 a/34a 5.0/5.0/ 0.0/50.0 3.0-7.0/3.0-7.0/8.0-.0/48.0-5.0 R-48A R- 5/43a/ 90/600a 77.5/0.0/0.6/.9 76.5-78.5/9.0- /0.4-0.7/.7-.0 R-430A R-5a/600a 76.0/4.0 75.0-77.0/3.0-5.0 R-434A R-5/ 43a/ 34a/600a 63./8.0/6.0/.8 6.-64./7.0-9.0/5.0-7.0/.6-.9 R-437A R-5 / 34a / 600 / 60 9.5/78.5/.4/0. 6 7.7-0.0/77.8-80.0/.-/0.4-0.7 R-438A R-3 / 5 / 34a / 600 / 60a 8.5 / 45.0 / 44. /.7 / 0.6 7.0-9.0 / 43.5-46.5 / 4.7-45.7 / -.8 / 0.4-0.7 R-439A R-3 / 5 / 600a 50.0 / 47.0 / 3.0 49.0-5 / 46.0-48.0 /.5-3.5 ºC @.3 kpa -43.0-43.0 Bubble Point -48.3-7.6-45. -3.9-5.0 ºC @.3 kpa -36.3-36.4 Dew Point -47.5-7.4-4.4-9. -5.7 84. 7.0 Critical Temperature ºC 85.3 69.0 7.0 75.6 95.3 VAPOR PHASE Air and Other Non Condensables LIQUID PHASE All Other Volatile Impurities High Boiling Residue Chloride % by volume @ 5.0ºC % by volume or Visually clean to (as HC) No visible turbidity 5. 5.4 5. 5.9 5.7 5.6 0 Bubble points, dew points and critical temperatures, although not required, are provided for informational purposes. Recognized chloride level for /fail is about 3 ppm. Not Applicable R f i t d t il d f R f 7 0 R-4A R-90 / 34a / 5a 0.6 /.6 / 97.8-0.7 / -. / 97.3-98.3-5.5-4.3.9 4

Table C. Characteristics of Azeotropic Blends (500 Series Refrigerants) and their Maximum Allowable Levels of Contaminants Reporting Units Reference Section R-500 R-50 R-503 R-507A R-508A R-508B CHARACTERISTICS : Refrigerant Components R-/5a R-/5 R-3/3 R-5/43a R-3/6 R-3/6 Nominal Comp 73.8/6. 48.8/5../59.9 50/50 39/6 46/54 Allowable Comp 7.8-74.8/ 5.-7. 44.8-/ 47.-55. 39-4/ 59-6 49.5-5/ 48.5-5 37-4/ 59-63 44-48/ 5-56 ºC @.3 kpa -33.6-45. -87.80-46.7-87. -87.00 Bubble Point ºC @.3 kpa -33.6-45.0-87.80-46.7-87. -87.00 Dew Point ºC. 80.0 8.4 70.60.8.8 Critical Temperature VAPOR PHASE Air and Other Non Condensables % by volume @ 3.9ºC 5. LIQUID PHASE 5.4 All Other Volatile Impurities % by volume or % by weight 5. Visually clean to 5.9 5.7 Chloride No visible turbidity 5.6 Bubble points, dew points and critical temperatures, although not required, are provided for informational purposes. Recognized chloride level for /fail is about 3 ppm. Not Applicable Refrigerant data compiled from Refprop 7.0. R-509A R-/8 44/56 4-46/ 56-60 -49.8-48. 68.60 5

APPENDIX A. REFERENCES NORMATIVE A Listed here are all standards, handbooks, and other publications essential to the formation and implementation of the standard. All references in this appendix are considered as part of this standard. A. ANSI/ASHRAE Standard 34-0 Designation and Safety Classification of Refrigerants, 0, with Addenda, American National Standards Institute/American Society of Heating, Refrigerating and Air-Conditioning Engineers, Inc., 5 West 43rd Street, 4th Floor, New York, New York 036 U.S.A., 79 Tullie Circle N.E., Atlanta, GA 3039, U.S.A. A.. Appendix C Analytical Procedures for AHRI Standard 700-008, Specification for Fluorocarbon Refrigerants, Air-Conditioning, Heating, and Refrigeration Institute, 008, Wilson Blvd., Suite 500, Arlington, VA 0; U.S.A. A..3 Appendix D Gas Chromatograms for AHRI Standard 700-008, Specification for Fluorocarbon Refrigerants, Air-Conditioning, Heating, and Refrigeration Institute, 008, Wilson Blvd., Suite 500, Arlington, VA 0; U.S.A. A..4 ASHRAE Terminology of Heating, Ventilating, Air Conditioning and Refrigeration, Second Edition, American Society of Heating, Refrigerating and Air-Conditioning Engineers, 99, 79 Tullie Circle N.E., Atlanta, GA 3039-305; U.S.A. APPENDIX B. REFERENCES INFORMATIVE B Listed here are standards, handbooks and other publications which may provide useful information and background but are not considered essential. References in this appendix are not considered part of the standard. B. U.S. Code of Federal Regulations, Title, Part 8, Protection of Stratospheric Ozone, 0, Office of the Federal Register, National Archives and Records Administration, 800 North Capitol Street, NW, Washington, DC 0, U.S.A. 6