Moisture in the Atmosphere. GEOG/ENST 2331 Lecture 9 Ahrens: Chapter 4

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Moisture in the Atmosphere GEOG/ENST 2331 Lecture 9 Ahrens: Chapter 4

Last lecture! Atmospheric mechanics! PGF, gravity, Coriolis effect, friction! Geostrophic winds! Cyclones and anticyclones

Moisture in the Atmosphere! Hydrologic cycle! Changes of phase! Humidity! Adiabatic processes! Humidity and comfort

Hydrologic Cycle Ahrens: Figure 5.1

Phases of water Ahrens: Fig. 4.3

Changes of phase! Evaporation! Liquid molecules break free to become gaseous! Surrounding material becomes cooler! Condensation! Gaseous molecules pull together to form a liquid! Surrounding material becomes warmer

Saturation and equilibrium Water exposed to a gas (or vacuum) will evaporate into it Water vapour will bond together and condense Saturation is the point at which the evaporation and condensation rates are equal A&B: Figure 5-2

More changes of phase! Freezing! Melting! Sublimation! Solid to gas! Deposition! Gas to solid! Sometimes also called sublimation

Ahrens: Fig. 2.3

Lecture outline! Hydrologic cycle! Humidity! Absolute and specific humidities! Vapour pressure! Saturation! Dew point temperature! Adiabatic processes! Humidity and comfort

Water vapour indices! Absolute Humidity! Indicates the density of water vapor expressed as a concentration (typically g/m 3 )! Specific Humidity! Represents a given mass of water vapor per mass of air as a ratio (typically g/kg)! Vapour pressure! The amount of pressure exerted by water molecules in the air (typically mb or hpa)! Also called the partial pressure of water vapour

Saturation vapour pressure! Water vapor pressure at equilibrium! Dependent on temperature and pressure! Increases non-linearly with temperature! Similar to saturation specific humidity Ahrens: Active Fig. 4.10

Relative Humidity! Indicates the amount of water vapour in the air relative to the saturation point RH = = Vapour pressure Saturation vapour pressure Specific humidity Saturation specific humidity! Dependent on specific humidity, temperature, and pressure

Ahrens: Active Fig. 4.11

Dew point temperature! Another index of moisture (not temperature)! Temperature at which the vapour pressure would equal the saturation vapour pressure! High vapour pressure means high dew point! If the air cools to this temperature, it will become saturated! If T = T d then RH = 100%

Dew Point Temperature A&B: Figure 5-9

Methods of Achieving Saturation! Cool the air to the dew point! Add water vapour to the air! Mix cold air with warm air! If the warm air has higher specific humidity

Achieving saturation A&B: Figure 5-9

Dew! At night the ground cools quickly! Emission of IR! Air above the ground cools due to conduction! Reaches dew point temperature! Condensation begins

Frost! Like dew, but with a dew point temperature below 0 C (frost point temperature)! Deposition into ice crystals rather than condensation! Frozen dew: dew point is above 0 C, but temperature drops below after condensation

Lecture outline! Hydrologic cycle! Humidity! Adiabatic processes! Dry adiabatic cooling! Humidity and comfort

Temperature change! Diabatic process: adds or removes energy from a system! Heat transfers! Adiabatic process: changes temperature without adding or removing heat

Diabatic processes! Mixing! Advection! Warm, moist air moves over a cool surface! Radiation! Night-time cooling

Adiabatic processes! Changes in pressure cause changes in temperature! If the pressure drops, a parcel of air will expand and cool down! If the pressure rises, a parcel of air will be compressed and warm up

What is a parcel of air?! A volume of air with distinct properties! No fixed dimensions or shape! Creates a mental picture for visualizing atmospheric conditions! I talk about a cubic metre of air on occasion a blob of air

Dry adiabatic cooling Parcels expand and cool at the dry adiabatic lapse rate of 1 o C/100 m (10 C/km) A&B: Figure 5-15

Adiabatic warming Descending air warms at exactly the same rate Ahrens: Figure 6.2

Lecture outline! Hydrologic cycle! Humidity! Adiabatic processes! Humidity and comfort! Humidex

It is not the heat, it is... the Humidity! Dry heat! Sweat evaporates readily! Body cools down easily! High humidity! Sweat does not evaporate! Body cannot shed heat

Even when it is cold?! Dry cold! Sweat evaporates readily! But the body does not sweat much! High humidity! Sweat condenses in clothing! Damp clothing provides much less insulation

Humidex Ahrens: Fig. 4.19

Summary! Three important humidity indices:! Vapour pressure, relative humidity, dew point temperature! Adiabatic processes! Rising air expands and cools! Sinking air is compressed and warms! Humidex! Interesting but not so important

Coming up! Atmospheric stability! Saturated lapse rates! Ahrens: Chapter 6