Illicit Discharge Detection and Elimination: Field and Laboratory Assessment Protocols

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Illicit Discharge Detection and Elimination: Field and Laboratory Assessment Protocols Presented At: A Workshop for Stormwater Program Managers Kansas City, KS July 20-21, 2004 Presented By:

Top Problems in Identifying Inappropriate Discharge Sources Source Related Periodic nature Illegal dumping / one-time dischargers Illegal connections Inflow/infiltration from sanitary sewers After-hours discharges Infrastructure Related Accessibility (building, stream, outfall, traffic) Complexity of network Natural influences (tidal, groundwater) Size of drainage basin Multiple sources w/in system Program Related - Accuracy of mapping - Timeliness of complaint - Insufficient staffing - Insufficient expertise - Slow laboratory analysis - Unreliable equipment - Use of unreliable indicators Source: Ft. Worth DEM

Conditions Driving Program Setup No Suspected Discharges broader stream assessment program Isolated Problems confined subwatersheds, reaches, or specific industries where history of suspect discharges exist Severe Problems recognize that IDDE program will need significant commitment (staff, equipment, budget) for improvements to be realized

Field and Lab Protocol 1. Pre-Screening Prioritization 2. Outfall Reconnaissance Inventory (ORI) 3. Post-Screening Prioritization 4. Detailed Field Sampling / Lab Analysis

Outfall Reconnaissance Inventory (ORI) Map, Mark & Photograph Outfalls Assign unique ID to each outfall Physically mark each outfall Use a GPS unit to record outfall locations Take a photograph

May need to work back up floodplain to find outfall

Look, Look! Signs of flow! Hone Your Detective 2002 Skills

Look, Look! Signs of flow! Cross-Train Your Staff 1964

Outfall Reconnaissance Inventory (ORI) Record Basic Characteristics Dimensions Material Whether or not outfall is flowing

Outfall Reconnaissance Inventory (ORI) Physical Indicators Odor Color Turbidity Floatables Deposits/Stains Vegetation Pipe Benthic Growth

Outfall Reconnaissance Inventory (ORI) Simple Monitoring at Flowing Outfalls ph Temperature Ammonia

Outfall Reconnaissance Inventory (ORI) Take flow sample at outfalls with likely problems Deal with major problems immediately Photo Source: R. Frymire

Hotspot Site Investigation Site Data and Basic Classification Vehicle Operations Outdoor Material Waste Management Physical Plant Turf / Landscaping Areas Stormwater Infrastructure

What the ORI Cannot Do Misses a significant number of discharges, and can sometimes lead to a false positive as well (Pitt, 2001) Detect intermittent flows that leave no trace Quantify impacts definitively (no direct measure of relative problem) Define sources (except for some obvious indicators)

Quick and Dirty ORI Exercise (Pardon the pun!)

Look at each photo and answer the following: 1. Is the outfall a closed pipe or open drainage? 2. What material is the pipe made of? (RCP, CMP, PVC, HDPE, Steel, Other?) 3. Is there flow present? 4. What is the color of the flow? 5. Are floatables present? If so, what kind? 6. Is there any outfall damage? 7. Are there any deposits or stains? 8. Is there any abnormal vegetation in or around the outfall? 9. Should a water sample be collected at this outfall? 10. Do you see anything else?

Source: R. Frymire

Source: Fort Worth DEM

Post-Screening Prioritization ORI, combined with other existing data, can help determine: Extent of the problem If problems are clustered Indicators of intermittent discharges Relative ranking of problem outfalls

Factors to Consider Fraction flowing (from ORI) Number with physical indicators, and severity Indicators at dry outfalls Other existing monitoring data In-stream goals History of complaints

Detailed Field Sampling / Lab Analysis More detailed sampling that includes: Sampling to ID problem outfalls not apparent from physical indicators alone Source identification Potential intermittent monitoring

Forensics Run chemical tests Choose specific indicators depending on local fingerprints or based on land use in area

Key Features for Ideal Indicators Distinguishes a particular source Tight statistical distribution Precise measurement Safe Relatively inexpensive Simple to conduct

Key Lab Considerations Equipment cost Staff training Number of samples Safety Disposal

Flow Chart to Identify Illicit Discharges in Residential Drainage Areas

Benchmark Concentrations to Identify Industrial Discharges Benchmark Concentration Notes Ammonia (mg/l) Potassium (mg/l) Color (Units) Conductivity ( S/cm) Hardness (mg/l as CaCO 3 ) ph (Units) Turbidity (NTU) 50 20 500 2,000 10 2,000 5 1,000 Existing Flow Chart Parameter Concentrations higher than the benchmark can identify a few industrial discharges Existing Flow Chart Parameter Excellent indicator of a broad range of industrial discharges Supplemental parameter that identifies a few specific industrial discharges Identifies a few industrial discharges May be useful to distinguish between industrial sources Identifies a few industrial discharges May be useful to distinguish between industrial sources Only captures a few industrial discharges High ph values may also indicate an industrial discharge but residential wash waters can have a high ph as well Supplemental parameter that identifies a few specific industrial discharges

Chemical Fingerprint Library Shallow Groundwater Spring Water Tap water Irrigation Sewage Septic Tank Discharge Common Industrial Discharges Commercial Car Wash Commercial Laundry

Fingerprints of Major Sources Sewage E. Coli Detergents (various) High Ammonia/ Potassium Ratio Wash Water Detergents (various) Tap Water Fluoride Sometimes Hardness Septage E. Coli Fluorescence High Ammonia/Potassium Shallow Groundwater Hardness, ph

Special Indicators for Intermittent Discharges Optical brightener monitoring Toxicity testing Outfall damming Take a sample from the pool

Finding and Fixing Move up the pipe Use smoke or dye testing once narrowed Use enforcement or repair

Most Wanted List Look up reference for common types of illicit discharges (e.g., sewage, wash water, spills) General overview of indicators, detection methods, source tracing, removal, and prevention Possible case study approach

Most Wanted List Cont d

Most Wanted List Cont d

Quick and Dirty ORI Exercise (Pardon the pun!)

Look at each photo and answer the following: 1. Is the outfall a closed pipe or open drainage? 2. What material is the pipe made of? (RCP, CMP, PVC, HDPE, Steel, Other?) 3. Is there flow present? 4. What is the color of the flow? 5. Are floatables present? If so, what kind? 6. Is there any outfall damage? 7. Are there any deposits or stains? 8. Is there any abnormal vegetation in or around the outfall? 9. Should a water sample be collected at this outfall? 10. Do you see anything else?

Source: R. Frymire

Source: R. Frymire

Source: R. Frymire