High Efficiency, Residential Gas- Fired Adsorption Heat Pump Water Heater Development

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High Efficiency, Residential Gas- Fired Adsorption Heat Pump Water Heater Development Moonis Ally Oak Ridge National Laboratory Hot Water Forum Water Heating, Distribution, and Use Efficiency American Council for an Energy-Efficient Economy (ACEEE) Session 4 B: Gas Heat Pump Water Heater Research and Development Nashville, TN February 22-24, 2015

Recent Heat Pump Work at ORNL Design and Development of Integrated Heat Pump (IHP) Concept and reduction to practice Collaborative R&D with multinational corporations and manufacturers Wide range of products brought to the marketplace Seeking partnership with industry on new products 2 Presentation name

Conventional Heat Pump and Water Heater ED Indoor Coil WH Outdoor Coil RV Compressor 3 Presentation name

Integrated Heat Pump TXV Indoor Coil Water Coil WH VS VS Outdoor Coil VS Pump RV HX VS Compressor 4 Presentation name

AS-IHP Concept (early ORNL concept) Full integration to heat, cool, ventilate, dehumidify, and heat water as needed AS-IHP concept, in dehumidification/ventilation/wh mode, shown at right - many modes possible H or C/ventilation/WH Dedicated water heating Dedicated dehumidification and/or humidification Ventilation air pre-treatment; H in winter, C & dehumidify in spring/summer/fall Lab prototype constructed and tested Lab prototype air handler ref/air HX water/air HX blower Possible AS-IHP packaging approach 5 Presentation name Presentation_name

Industry CRADA Collaborations are Delivering Additional Equipment Solutions to the Market Commercial Gas HP Ground-Source IHP Gas-Fired Absorption HPWH CO 2 HPWH GE Heat Pump Water Heater Residential Gas HP 6 Presentation name

Ripple effects of General Electric-ORNL heat pump water heater CRADA Began production in Louisville KY Feb 2012 (created ~1,000 jobs) 62% energy savings compared to a conventional electric storage water heater, pays for itself in < 3 yr 7 Presentation name Heat Pump Water Heater

After CRADA with ORNL, ClimateMaster Launches Trilogy 40 Q-Mode (1 st AHRI Rating > 40 EER) Heating, cooling, 100% of water heating (not just a desuperheater) 55-65% energy savings vs. minimum efficiency (SEER 13) equipment 30-35% savings vs. state-of-the-art two-stage GHP with desuperheater Separate Units [Water Heating; Heating/Cooling] Single Unit [Water Heating; Heating/Cooling] 8 Presentation name

The Trilogy 40 Q-Mode Ground Source IHP With rated efficiencies as high as 42.1 EER, the Trilogy 40 series is the first geothermal heat pump ever certified by the Air Conditioning, Heating, and Refrigeration Institute (AHRI) to exceed 40 EER at ground-loop (GLHP) conditions. The Trilogy 40 utilizes variable-speed technology to provide an extremely wide range of heating and cooling capacities In addition, patent-pending Q-Mode technology produces year-round domestic hot water on demand, even when space conditioning is not required. 9 Presentation name

Pushing the Envelope at ORNL on Adsorption Technology Old applications Adsorption ice maker for Fishing boat Solar refrigerator 100 kw chiller ISAAC solar Icemaker In Kenya ORNL Pushing the envelope Gas domestic hot water COP ~ 1.0 Challenge: increase COP to 1.5 Application of Adsorption technology for domestic/commercial hot water production Adsorbent beds (generators) 10 Presentation name

The Case for Sorption HPWH Elec. WH 0.92 kw t Θ = 0.31 Gas WH 0.92 kw t Θ = 0.92 Elec. HPWH 2.76 kw t Θ = 0.92 3 kw t 1 kw e 3 kwt (at Source) 1 kw e 3 kw t (at Source) Θ = Energy to make HW 1 kw t Thermal Energy at Source 1 kw t AdHPWH COP =1.5 1.5 kw t 0.5 kw t Surr. 1.38 kw t Θ = 1.38 2 kw t (surr.) A Sorption HPWH holds promise in advancing WH tech. Focus on AdHPWH for domestic WH 11 Presentation name

Water Heaters Affected by New Standards, Effective April 2015 New, higher energy efficiency standards for residential hot water heaters are due to kick in April 2015, cutting the energy use of all sizes and types of water heaters significantly, and dramatically changing the home hot water landscape. The new regulations will require electric water heaters to use 47% less energy, and gas water heaters to be 30% more efficient. There are a variety of products that can comply with the 2015 standards In larger sized units industry facing some headwinds Ref: CONTRACTOR: The online resource for mechanical contracting http://contractormag.com/residential-plumbing/new-efficiency-standards-residential-waterheaters-are-horizon 12 Presentation name

Two distinct projects funded by BTO, U.S. Department of Energy Commercial Gas-Fired Absorption Heat Pump Water Heater -Working pair is ammonia-water -Prototype system is essentially complete -Next step is to demonstrate that target goals are achieved with prototype by mid 2015. Residential Gas-Fired Adsorption Heat Pump Water Heater (AdHPWH) -Working pair is ammonia-activated carbon (AC) -AdHPWH system, model, components is nearly complete -Next step is to build a 2-3 kw prototype and demonstrate 80% of target goal of EF>1.0 by the standard rating procedure for storage water heaters. 13 Presentation name

US Market/Environmental Impact In 2010, residential water heating accounted for (3.02 x 10 15 kj, or 8.4 x 10 11 kwh) of primary energy use (2011 Building Energy Data Book, Table 2.1.5). When fully deployed, the AdWH may provide up to 0.47 x 10 15 kj or 1.3 x 10 11 kwh of primary energy savings, equivalent to 24 million tons of CO 2 emission reductions annually (2011 Building Energy Data Book, Table 1.4.8), eliminating the need for HFC refrigerants with significantly higher ODP and GWP. Developed market for AdHPWH is about 15% of residential water heating market 14 Presentation name

Participation in IEA Annex 43/Research Program The U.S through the Oak Ridge National Laboratory became a participant in Annex 43 Fuel Driven Sorption Heat Pumps in March 2014 The program of research is the development, demonstration, and promotion of gas-fired heat pumping technology for the commercial and residential markets with COP >1 with working materials having 0 GWP and 0 ODP Research is conducted under the directive of the U.S Department of Energy, Office of Energy Efficiency and Renewable Energy (EERE), Buildings Technology Program (BTO) 15 Presentation name

Water Heater Shipment Projections All Water Heater Industry Shipments: U.S Electric Storage and Gas Storage units dominate sales Mike Parker; ACEEE Hot Water Forum May 2011 Ref: http://www.aceee.org/files/pdf/conferences/hwf/2011/plenary%20-%20mike%20parker.pdf 16 Presentation name

Objectives : Residential Gas-fired Adsorption Heat Pump Water Heater - To develop an adsorption heat pump water heater (AdHPWH) at an installed cost low enough to enable widespread residential market adoption 3 to 5 kw capacity Provide hot water at 50-60 C Ambient temperature range -10 C to 37 C EF>1.0 as determined by the standard rating procedure for storage water heaters. Industry collaborators to be determined. Currently, In-house R&D at ORNL 17 Presentation name

R&D Status Residential Gas-fired Adsorption Heat Pump Water Heater -Established technical feasibility of AdHPWHs with EF>1.0 using working materials that have 0 GWP and 0 ODP -Identified possible working pairs -Established process constraints and acceptable cost for the manufacturer -Developed a model for parametric analysis -Quantified system size based on cycle times, adsorption capacity, and capacity Currently developing a prototype 18 Presentation name

What s been done: Large Scale Mycom Europe markets large capacity (100kW) adsorption chillers (see above) Chilled water at 15 C (59 F) with a heat source temperature of 68 C (154.4 F) with 27 C (80.6 F) cooling water inlet temperature zeolite-water working pairs. Ref: http://www.ppiway.com/brands-solutions/eco-max/products-services/adsorption-chillers Hong Kong s 1 st zero carbon bldg. houses an ECO- MAX adsorption chiller in a trigeneration system (below, right) providing power, heat and cooling Tri-generation packages have capacity ~200kW to 2MW. ECO-MAX chillers integrate solar hot water collectors and concentrators to produce the source heat (at least 130 F, or 54.4 C) for the adsorption chiller. In tri-generation systems (above), hot water in the range of 51.7 C (125 F) to 93.3 C (200 F) can be produced 19 Presentation name

What s been done: Smaller systems Vaillant: 10 kw prototype Zeolite-water, gasfired Space heating and WH 135% eff. relative to condensing furnaces 5-25 kw over next several years Adsorption Heat Pumps from Vaillant and Viesmann under widespread field tests in Germany (Wessing and Wackertapp 2011) Inititive Gaswärmepumpe: by 2011, 51 installations across Germany; gas-fired systems included absorption & adsorption Results seem to suggest 120% - 140% WH efficiency improvement relative to condensing furnaces. Ref: Wessing, W., and Wackertapp, Hans. (2011). Potential of the gas-heat-pumps, EFE-ja 1_228_01, Nov 15, 2011. 20 Presentation name

Choice of Refrigerant Refrigerant ODP GWP H 2 Methanol 0.16 2.8 CO 2 0 1 H 2 O 0 0 NH 3 0 0 Refrigerant -10 C<Evap.<+4 C Evap. >5 C Cond. 55-65 C Ads. 55-65 C Des. >100 C ΔH kj kg -1 (25 C) Water No Yes Yes Yes Yes 2443 Ammonia Yes Yes Yes Yes Yes 1165 21 Presentation name

Adsorbents Best Performance with Two-Bed Configuration at Driving Temperature of 100 C Samples Heat Pumping q H (MJ m -3 ) KOH-AC (monolithic) 237 1.50 SRD1352/2 (granular) 128 1.41 FM10/700 (fibre) 97 1.47 C-2132 (powder) 110 1.50 SRD1352/2 (compacted) 152 1.50 The best performance for heating application with a 2-bed system reported by (Tamainot-Telto, Metcalf et al. 2009) is summarized in above Table. COP Best Performance with Two-Bed Configuration at Driving Temperature of 200 C Samples Heat Pumping q H (MJ m -3 ) COP KOH-AC (monolithic) 594 1.70 SRD1352/2 (granular) 287 1.70 FM10/700 (fibre) 235 1.69 (powder) AX-21 AX-21 265 1.80 (compacted) 208C 208C 132 1.62 All 5 types of carbons considered have almost the same COP, but the KOH-AC (monolithic) type yields twice the heat, q H = 237 MJ m -3 than the other types of carbons. Increasing the driving temperature from 100 C to 200 C by a factor of 1.28 (in terms of absolute temperature) essentially doubles the heat delivered, but increases the COP by 25% only. We select a driving temperature of about 200 C as acceptable to produce HW at ~60 C Ref: Tamainot-Telto, Z., S. J. Metcalf, et al. (2009). "Carbon-ammonia pairs for adsorption refrigeration applications: ice making, air conditioning and heat pumping." International Journal of Refrigeration 32: 1212-1229. 22 Presentation name

What COPs can we expect? 2 2 Dead Mass = 0.05 e evap = 1 1.8 Dead Mass = 0.15 e 1.5 evap = 0.9 1.6 1.4 e evap =1 e evap = 0.9 1.2 COP WH 1 0.5 e evap = 0.5 COP WH 1 0.8 0.6 0.4 e evap = 0.5 0.2 COP WH 0-20 -10 0 10 20 2 1.8 1.6 1.4 1.2 1 0.8 0.6 0.4 0.2 T OAT,in [C] Dead Mass absorber = Dead Mass desorber =0.25 0-20 -10 0 10 20 T OAT,in [C] e evap = 1 e evap = 0.9 e evap = 0.5 COP WH 2.5 2.4 2.3 2.2 2.1 2 1.9 1.8 1.7 1.6 1.5 1.4 1.3 1.2 1.1 1 0-20 -10 0 10 20 Carnot COP =9.7 T OAT,in [C] T OAT,in = -20 o C Parameter: T OAT,in in 10 o C intervals e evap = 1 0.9 0 0.1 0.2 0.3 DeadMass ads T OAT,in = 30 o C 23 Presentation name

Dead Mass strongly limits COP 1.6 1.4 COP WH 1.2 1 0.8 0.6 Effect of e evap on COP T OAT,in as parameter in 10 o C steps Dead Mass (abs/des) = 0.25 T OAT,in = 30 o C 0.4 T OAT,in = -20 o C 0.2 0 0 0.2 0.4 0.6 0.8 1 e evap 24 Presentation name

U.S Consumer Sentiment Consumers are interested ---- but remain skeptical about ----- efficient models ENERGY STAR ranking is a significant selling point Cost-conscious consumers want efficiency rebates and incentives About 26% of consumers are skeptical about claims of utility bill savings Consumers willing to pay a modest premium for energy efficiency Consumer skepticism is reinforced by inexperienced installers Consumers are increasingly relying on on-line information to research products The single greatest factor in decision-making is the cost of purchase and installation Source: NEEA Report # 12-234, January 16, 2012 25 Presentation name

26 Presentation name Thank You! allymr@ornl.gov 865-576-8003