Chematic 1. Safety Data Sheet according to Regulation (EC) No. 453/2010 Date of issue: 07/05/2015 Revision date: : Version: 1.0
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1 Date of issue 07/05/2015 Revision date Version 1.0 SECTION 1 Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form Mixture Product name Chematic 1 Product code Type of product Mixture 1.2. Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Industrial/Professional use spec Use of the substance/mixture Industrial For professional use only Alkaline Concentrated Detergent Uses advised against 1.3. Details of the supplier of the safety data sheet Supplier Dober Chemical Corp Katherine's Crossing Woodridge, IL - US T F regulatory@dobergroup.com - Only Representative Experien Chemical Services (Europe) Limited YO7 9AN - United Kingdom T Emergency telephone number Emergency number / ChemTel SECTION 2 Hazards identification 2.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP]Show CLP information only Skin Irrit. 2 H315 Eye Dam. 1 H318 Full text of H-phrases see section 16 Adverse physicochemical, human health and environmental effects 2.2. Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP] Hazard pictograms (CLP) Signal word (CLP) Hazardous ingredients Hazard statements (CLP) Precautionary statements (CLP) Danger GHS05 Tetrasodium ethylene diaminetetraacetate, Sodium Hydroxide H315 - Causes skin irritation H318 - Causes serious eye damage P264 - Wash hands, forearms and face thoroughly after handling P280 - Wear protective gloves/protective clothing/eye protection/face protection P302+P352 - IF ON SKIN Wash with plenty of soap and water P305+P351+P338 - IF IN EYES Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P310 - Immediately call a POISON CENTER or doctor/physician P321 - Specific treatment (see First aid measures on this label) P332+P313 - If skin irritation occurs Get medical advice/attention P362+P364 - Take off contaminated clothing and wash it before reuse 08/05/2015 EN (English) 1/8
2 2.3. Other hazards SECTION 3 Composition/information on ingredients 3.1. Substance Not applicable 3.2. Mixture Name Product identifier % Classification according to Directive 67/548/EEC Tetrasodium ethylene diaminetetraacetate (CAS No) (EC no) (EC index no) Sodium Hydroxide (CAS No) (EC no) (EC index no) Undecan-1-ol, ethoxylated (CAS No) (EC no) Xn; R22 Xi; R C; R Not classified Name Product identifier Specific concentration limits Sodium Hydroxide (CAS No) (EC no) (EC index no) (0.5 =< C < 2) Xi;R36/38 (2 =< C < 5) C;R34 (C >= 5) C;R35 Name Product identifier % Classification according to Regulation (EC) No. 1272/2008 [CLP] Tetrasodium ethylene diaminetetraacetate (CAS No) (EC no) (EC index no) Sodium Hydroxide (CAS No) (EC no) (EC index no) Undecan-1-ol, ethoxylated (CAS No) (EC no) Acute Tox. 4 (Oral), H302 Eye Dam. 1, H Acute Tox. 4 (Dermal), H312 Skin Corr. 1A, H Acute Tox. 4 (Oral), H302 Eye Irrit. 2, H319 Name Product identifier Specific concentration limits Sodium Hydroxide (CAS No) (EC no) (EC index no) Full text of R- and H-phrases see section 16 (0.5 =< C < 2) Skin Irrit. 2, H315 (0.5 =< C < 2) Eye Irrit. 2, H319 (2 =< C < 5) Skin Corr. 1B, H314 (C >= 5) Skin Corr. 1A, H314 SECTION 4 First aid measures 4.1. Description of first aid measures First-aid measures general First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). Assure fresh air breathing. Allow the victim to rest. Rinse skin with water/shower. Remove/Take off immediately all contaminated clothing. Wash with plenty of soap and water. Wash contaminated clothing before reuse. If skin irritation occurs Get medical advice/attention. Specific treatment (see First aid measures on this label). Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention Most important symptoms and effects, both acute and delayed Symptoms/injuries after skin contact Causes skin irritation. Symptoms/injuries after eye contact Causes serious eye damage Indication of any immediate medical attention and special treatment needed SECTION 5 Firefighting measures 5.1. Extinguishing media Suitable extinguishing media Unsuitable extinguishing media Foam. Dry powder. Carbon dioxide. Water spray. Sand. Do not use a heavy water stream Special hazards arising from the substance or mixture 08/05/2015 EN (English) 2/8
3 5.3. Advice for firefighters Firefighting instructions Protection during firefighting Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire-fighting water from entering environment. Do not enter fire area without proper protective equipment, including respiratory protection. SECTION 6 Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures For non-emergency personnel Emergency procedures For emergency responders Protective equipment Emergency procedures Evacuate unnecessary personnel. Equip cleanup crew with proper protection. Ventilate area Environmental precautions Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters Methods and material for containment and cleaning up Methods for cleaning up 6.4. Reference to other sections See Heading 8. Exposure controls and personal protection. Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials. SECTION 7 Handling and storage 7.1. Precautions for safe handling Precautions for safe handling Hygiene measures Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapour. No smoking. Wash hands, forearms and face thoroughly after handling Conditions for safe storage, including any incompatibilities Storage conditions Incompatible products Incompatible materials 7.3. Specific end use(s) Keep only in the original container in a cool, well-ventilated place incompatible materials. Keep container closed when not in use. Strong bases. Strong acids. SECTION 8 Exposure controls/personal protection 8.1. Control parameters Sodium Hydroxide ( ) Sources of ignition. Direct sunlight. Austria MAK (mg/m³) 2 mg/m³ Austria MAK Short time value (mg/m³) 4 mg/m³ Bulgaria OEL TWA (mg/m³) 2.0 mg/m³ Czech Republic Expoziční limity (PEL) (mg/m³) 1 mg/m³ Denmark Grænseværdie (kortvarig) (mg/m³) 2 mg/m³ Estonia OEL TWA (mg/m³) 1 mg/m³ Estonia OEL Ceiling (mg/m³) 2 mg/m³ Finland HTP-arvo (15 min) 2 mg/m³ Finland OEL Ceiling (mg/m³) 2 mg/m³ France VME (mg/m³) 2 mg/m³ Greece OEL TWA (mg/m³) 2 mg/m³ Greece OEL STEL (mg/m³) 2 mg/m³ Hungary AK-érték 2 mg/m³ Hungary CK-érték 2 mg/m³ Ireland OEL (15 min ref) (mg/m3) 2 mg/m³ Latvia OEL TWA (mg/m³) 0.5 mg/m³ Lithuania NRV (mg/m³) 2 mg/m³ Poland NDS (mg/m³) 0.5 mg/m³ 08/05/2015 EN (English) 3/8
4 Sodium Hydroxide ( ) Poland NDSCh (mg/m³) 1 mg/m³ Portugal OEL - Ceilings (mg/m³) 2 mg/m³ Slovakia NPHV (priemerná) (mg/m³) 2 mg/m³ Slovenia OEL TWA (mg/m³) 2 mg/m³ Slovenia OEL STEL (mg/m³) 2 mg/m³ Spain VLA-EC (mg/m³) 2 mg/m³ Sweden nivågränsvärde (NVG) (mg/m³) 1 mg/m³ Sweden takgränsvärde (TGV) (mg/m³) 2 mg/m³ United Kingdom WEL STEL (mg/m³) 2 mg/m³ Norway Gjennomsnittsverdier (Takverdi) (mg/m³) 2 mg/m³ Switzerland VME (mg/m³) 2 mg/m³ Switzerland VLE (mg/m³) 2 mg/m³ Canada (Quebec) PLAFOND (mg/m³) 2 mg/m³ Japan Exposure limits (ACGIH) TWA -,STEL C 2 mg/m3 USA - ACGIH ACGIH Ceiling (mg/m³) 2 mg/m³ USA - IDLH US IDLH (mg/m³) 10 mg/m³ USA - NIOSH NIOSH REL (ceiling) (mg/m³) 2 mg/m³ USA - OSHA OSHA PEL (TWA) (mg/m³) 2 mg/m³ 8.2. Exposure controls Personal protective equipment Hand protection Eye protection Skin and body protection Respiratory protection Other information Avoid all unnecessary exposure. Wear protective gloves/protective clothing/eye protection/face protection protective gloves Chemical goggles or safety glasses Wear suitable protective clothing Use a properly fitted, particulate filter respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator Do not eat, drink or smoke during use. SECTION 9 Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state Liquid Appearance Liquid. Colour Straw to Amber. Odour characteristic. Odour threshold ph > 11 Relative evaporation rate (butylacetate=1) Melting point Freezing point Boiling point Flash point Auto-ignition temperature Decomposition temperature Flammability (solid, gas) Vapour pressure Relative vapour density at 20 C NA Relative density Density g/ml Solubility Water Not available Log Pow Viscosity, kinematic 08/05/2015 EN (English) 4/8
5 Viscosity, dynamic Explosive properties Oxidising properties Explosive limits 9.2. Other information SECTION 10 Stability and reactivity Reactivity Chemical stability Possibility of hazardous reactions Conditions to avoid Direct sunlight. Extremely high or low temperatures Incompatible materials Strong acids. Strong bases Hazardous decomposition products Fume. Carbon monoxide. Carbon dioxide. SECTION 11 Toxicological information Information on toxicological effects Acute toxicity Tetrasodium ethylene diaminetetraacetate ( ) LD50 oral rat 1658 mg/kg Sodium Hydroxide ( ) LD50 dermal rabbit Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity Reproductive toxicity Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Aspiration hazard Potential adverse human health effects and symptoms 1350 mg/kg Causes skin irritation. ph > 11 Causes serious eye damage. ph > 11 Based on available data, the classification criteria are not met. SECTION 12 Ecological information Toxicity Tetrasodium ethylene diaminetetraacetate ( ) LC50 fishes 1 41 mg/l (Exposure time 96 h - Species Lepomis macrochirus [static]) EC50 other aquatic organisms mg/l (Exposure time 72 h - Species Desmodesmus subspicatus) LC50 fish mg/l (Exposure time 96 h - Species Pimephales promelas [static]) Sodium Hydroxide ( ) EC50 Daphnia 1 40 mg/l Persistence and degradability Chematic 1 Persistence and degradability 08/05/2015 EN (English) 5/8
6 Undecan-1-ol, ethoxylated ( ) Persistence and degradability Bioaccumulative potential Chematic 1 Bioaccumulative potential Undecan-1-ol, ethoxylated ( ) Bioaccumulative potential Mobility in soil Results of PBT and vpvb assessment Other adverse effects Additional information Avoid release to the environment SECTION 13 Disposal considerations Waste treatment methods Waste disposal recommendations Dispose in a safe manner in accordance with local/national regulations. Ecology - waste materials Avoid release to the environment. SECTION 14 Transport information In accordance with ADR / RID / IMDG / IATA / ADN UN number UN-No. (ADR) 1719 UN-No. (IMDG) 1719 UN-No.(IATA) 1719 UN-No.(ADN) 1719 UN-No. (RID) UN proper shipping name Proper Shipping Name (ADR) Proper Shipping Name (IMDG) Proper Shipping Name (IATA) Proper Shipping Name (ADN) Proper Shipping Name (RID) Caustic Alkali Liquids, N.O.S. CAUSTIC ALKALI LIQUID, N.O.S. CAUSTIC ALKALI LIQUID, N.O.S. CAUSTIC ALKALI LIQUID, N.O.S. Caustic Alkali Liquids, N.O.S Transport hazard class(es) ADR Transport hazard class(es) (ADR) 8 Danger labels (ADR) 8 IMDG Transport hazard class(es) (IMDG) 8 Danger labels (IMDG) 8 08/05/2015 EN (English) 6/8
7 IATA Transport hazard class(es) (IATA) 8 Hazard labels (IATA) 8 ADN Transport hazard class(es) (ADN) 8 Danger labels (ADN) 8 RID Transport hazard class(es) (RID) 8 Danger labels (RID) Packing group Packing group (ADR) Packing group (IMDG) Packing group (IATA) Packing group (ADN) Packing group (RID) Environmental hazards Dangerous for the environment Marine pollutant Other information II II II II II No No No supplementary information available SECTION 15 Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture EU-Regulations Contains no substances with Annex XVII restrictions Chematic 1 is not on the REACH Candidate List Contains no REACH candidate substance Contains no REACH Annex XIV substances National regulations Listed on the United States TSCA (Toxic Substances Control Act) inventory 08/05/2015 EN (English) 7/8
8 Germany Water hazard class (WGK) 3 - strongly hazardous to water Chemical safety assessment No chemical safety assessment has been carried out SECTION 16 Other information Other information None. Full text of R-, H- and EUH-phrases Acute Tox. 4 (Dermal) Acute toxicity (dermal), Category 4 Acute Tox. 4 (Oral) Acute toxicity (oral), Category 4 Eye Dam. 1 Serious eye damage/eye irritation, Category 1 Eye Irrit. 2 Serious eye damage/eye irritation, Category 2 Skin Corr. 1A Skin corrosion/irritation, Category 1A Skin Irrit. 2 Skin corrosion/irritation, Category 2 H302 Harmful if swallowed H312 H314 H315 H318 H319 R22 R35 R41 C Xi Xn Harmful in contact with skin Causes severe skin burns and eye damage Causes skin irritation Causes serious eye damage Causes serious eye irritation Harmful if swallowed Causes severe burns Risk of serious damage to eyes Corrosive Irritant Harmful Dober SDS EU To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. 08/05/2015 EN (English) 8/8
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