: Anti-freeze Bitterment Agent

Transcription

1 0 SECTION 1: Identification 1.1. Product identifier Product form Product name Type of product UN-No. (ADR) Anti-freeze Bitterment Agent Date of issue:04/03/2015 Revision date: 20/11/2017 : Version: 2.0 : Mixtures : Anti-freeze Bitterment Agent : Liquid : Non Regulated Product code : Relevant identified uses of the substance or mixture and uses advised against Recommended use 1.3. Supplier's details Supplier Dober Chemical Corp Katherine's Crossing Woodridge, IL - US T F regulatory@dober.com Emergency telephone number : Aversive agent, bittering agent Emergency number : / ChemTel SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification according to the United Nations GHS Acute toxicity (oral) Category 4 Specific target organ toxicity (repeated exposure) Category 2 Full text of H statements : see section Label elements H302 H373 Labelling according to the United Nations GHS Hazard pictograms (GHS-UN) : Signal word (GHS-UN) Hazardous ingredients Hazard statements (GHS-UN) Precautionary statements (GHS-UN) GHS07 : Warning GHS08 : Ethylene Glycol; Denatonium Benzoate : H302 - Harmful if swallowed H373 - May cause damage to organs (kidneys) through prolonged or repeated exposure (oral) : P260 - Do not breathe fume, mist. P264 - Wash hands, forearms and face thoroughly after handling. P270 - Do not eat, drink or smoke when using this product. P301+P312 - IF SWALLOWED: Call a POISON CENTER or doctor if you feel unwell. P314 - Get medical attention if you feel unwell. P330 - Rinse mouth. P501 - Dispose of contents and container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation Other hazards SECTION 3: Composition/Information on ingredients 3.1. Substances Not applicable 3.2. Mixtures Name Product identifier % Classification according to the United Nations GHS Ethylene Glycol (CAS-No.) Acute Tox. 4 (Oral), H302 STOT RE 2, H373 Denatonium Benzoate (CAS-No.) Acute Tox. 4 (Oral), H302 Acute Tox. 4 (Inhalation), H332 20/11/2017 EN (English US) Chile 1/9

2 Full text of H-statements: see section 16 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : Never give anything by mouth to an unconscious person. : If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a poison center/doctor/physician if you feel unwell. Allow the victim to rest. : If skin irritation occurs: Get medical advice/attention. Remove affected clothing and wash all exposed skin area with mild soap and water, followed by warm water rinse. : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. : Drink plenty of water. Get medical advice/attention. Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention Most important symptoms and effects, both acute and delayed Symptoms/effects after inhalation Symptoms/effects after skin contact Symptoms/effects after eye contact Symptoms/effects after ingestion Potential Adverse human health effects and symptoms : Harmful if inhaled. : None under normal conditions. : None under normal conditions. : Harmful if swallowed. : Based on available data, the classification criteria are not met Indication of any immediate medical attention and special treatment needed SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media Unsuitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand. : Do not use a heavy water stream Special hazards arising from the substance or mixture 5.3. Advice for firefighters Firefighting instructions Protection during firefighting : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire-fighting water from entering environment. : Do not enter fire area without proper protective equipment, including respiratory protection. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures For non-emergency personnel Emergency procedures For emergency responders Protective equipment Emergency procedures : Evacuate unnecessary personnel. : Equip cleanup crew with proper protection. : Ventilate area Environmental precautions Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters Methods and material for containment and cleaning up Methods for cleaning up : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling : Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapor. No smoking Conditions for safe storage, including any incompatibilities Storage conditions Incompatible products Incompatible materials : Keep only in the original container in a cool, well-ventilated place. Keep container closed when not in use. : Oxidizing agent. Strong bases. Strong acids. : Sources of ignition. Direct sunlight. 20/11/2017 EN (English US) 2/9

3 SECTION 8: Exposure controls/personal protection 8.1. Control parameters EU IOELV TWA (mg/m³) 52 mg/m³ EU IOELV TWA (ppm) 20 ppm EU IOELV STEL (mg/m³) 104 mg/m³ EU IOELV STEL (ppm) 40 ppm EU Notes Possibility of significant uptake through the skin Austria MAK (mg/m³) 26 mg/m³ Austria MAK (ppm) 10 ppm Austria MAK Short time value (mg/m³) 52 mg/m³ Austria MAK Short time value (ppm) 20 ppm Austria OEL chemical category (AT) skin notation Belgium OEL chemical category (BE) Skin skin notation Bulgaria OEL TWA (mg/m³) 52 mg/m³ Bulgaria OEL TWA (ppm) 20 ppm Bulgaria OEL STEL (mg/m³) 104 mg/m³ Bulgaria OEL STEL (ppm) 40 ppm Croatia GVI (granična vrijednost izloženosti) (mg/m³) 52 mg/m³ Croatia Croatia Croatia GVI (granična vrijednost izloženosti) (ppm) KGVI (kratkotrajna granična vrijednost izloženosti) (mg/m³) KGVI (kratkotrajna granična vrijednost izloženosti) (ppm) 20 ppm 104 mg/m³ 40 ppm Croatia OEL chemical category (HR) skin notation Cyprus OEL TWA (mg/m³) 52 mg/m³ Cyprus OEL TWA (ppm) 20 ppm Cyprus OEL STEL (mg/m³) 104 mg/m³ Cyprus OEL STEL (ppm) 40 ppm Czech Republic Exposure limits (PEL) (mg/m³) 50 mg/m³ Czech Republic OEL chemical category (CZ) Potential for cutaneous absorption Denmark Limit (long-term) (mg/m³) 26 mg/m³ 10 mg/m³ (atomized) Denmark Limit (long-term) (ppm) 10 ppm Estonia OEL TWA (mg/m³) 52 mg/m³ (total concentration of aerosol and vapor) Estonia OEL TWA (ppm) 20 ppm (total concentration of aerosol and vapor) Estonia OEL STEL (mg/m³) 104 mg/m³ (total concentration of aerosol and vapor) Estonia OEL STEL (ppm) 40 ppm (total concentration of aerosol and vapor) Estonia OEL chemical category (ET) skin notation Finland HTP-arvo (8h) (mg/m³) 50 mg/m³ Finland HTP-arvo (8h) (ppm) 20 ppm Finland HTP-arvo (15 min) 100 mg/m³ Finland HTP-arvo (15 min) (ppm) 40 ppm Finland OEL chemical category (FI) Potential for cutaneous absorption France VME (mg/m³) 52 mg/m³ (indicative limit-vapor) France VME (ppm) 20 ppm (indicative limit-vapor) France VLE (mg/m³) 104 mg/m³ (indicative limit-vapor) France VLE (ppm) 40 ppm (indicative limit-vapor) France OEL chemical category (FR) Risk of cutaneous absorption Germany TRGS 900 Occupational exposure limit value (mg/m³) 26 mg/m³ (The risk of damage to the embryo or fetus can be excluded when AGW and BGW values are observed) 20/11/2017 EN (English US) 3/9

4 Germany TRGS 900 Occupational exposure limit value (ppm) Germany TRGS 900 chemical category skin notation Gibraltar Eight hours mg/m3 52 mg/m³ Gibraltar Eight hours ppm 20 ppm Gibraltar Short-term mg/m3 104 mg/m³ Gibraltar Short-term ppm 40 ppm Gibraltar OEL chemical category (GI) skin notation Greece OEL TWA (mg/m³) 125 mg/m³ (vapor) Greece OEL TWA (ppm) 50 ppm (vapor) Greece OEL STEL (mg/m³) 125 mg/m³ (vapor) Greece OEL STEL (ppm) 50 ppm (vapor) Hungary Exposure Limit Value 52 mg/m³ Hungary CK-érték 104 mg/m³ Hungary OEL chemical category (HU) Potential for cutaneous absorption Ireland OEL (8 hours ref) (mg/m³) 10 mg/m³ (particulate) 52 mg/m³ (vapour) Ireland OEL (8 hours ref) (ppm) 20 ppm (vapour) Ireland OEL (15 min ref) (mg/m3) 104 mg/m³ (vapour) Ireland OEL (15 min ref) (ppm) 40 ppm (particulate) Ireland OEL chemical category (IE) Potential for cutaneous absorption Italy OEL TWA (mg/m³) 52 mg/m³ Italy OEL TWA (ppm) 20 ppm Italy OEL STEL (mg/m³) 104 mg/m³ Italy OEL STEL (ppm) 40 ppm 10 ppm (The risk of damage to the embryo or fetus can be excluded when AGW and BGW values are observed) Italy OEL chemical category (IT) skin - potential for cutaneous absorption Latvia OEL TWA (mg/m³) 52 mg/m³ Latvia OEL TWA (ppm) 20 ppm Latvia OEL chemical category (LV) skin - potential for cutaneous exposure Lithuania IPRV (mg/m³) 25 mg/m³ (aerosol and vapor) Lithuania IPRV (ppm) 10 ppm (aerosol and vapor) Lithuania TPRV (mg/m³) 50 mg/m³ (aerosol and vapor) Lithuania TPRV (ppm) 20 ppm (aerosol and vapor) Lithuania OEL chemical category (LT) skin notation Luxembourg OEL TWA (mg/m³) 52 mg/m³ Luxembourg OEL TWA (ppm) 20 ppm Luxembourg OEL STEL (mg/m³) 104 mg/m³ Luxembourg OEL STEL (ppm) 40 ppm Luxembourg OEL chemical category (LU) Possibility of significant uptake through the skin Malta OEL TWA (mg/m³) 52 mg/m³ Malta OEL TWA (ppm) 20 ppm Malta OEL STEL (mg/m³) 104 mg/m³ Malta OEL STEL (ppm) 40 ppm Malta OEL chemical category (MT) Possibility of significant uptake through the skin Netherlands Grenswaarde TGG 8H (mg/m³) 52 mg/m³ (fume) 10 mg/m³ (droplets) Netherlands Grenswaarde TGG 15MIN (mg/m³) 104 mg/m³ Poland NDS (mg/m³) 15 mg/m³ Poland NDSCh (mg/m³) 50 mg/m³ Portugal OEL TWA (mg/m³) 52 mg/m³ (indicative limit value) Portugal OEL TWA (ppm) 20 ppm (indicative limit value) Portugal OEL STEL (mg/m³) 104 mg/m³ (indicative limit value) Portugal OEL STEL (ppm) 40 ppm (indicative limit value) 20/11/2017 EN (English US) 4/9

5 Portugal OEL - Ceilings (mg/m³) 100 mg/m³ (aerosol only) Portugal OEL chemical category (PT) A4 - Not Classifiable as a Human Carcinogen skin - potential for cutaneous exposure indicative limit value Romania OEL TWA (mg/m³) 52 mg/m³ Romania OEL TWA (ppm) 20 ppm Romania OEL STEL (mg/m³) 104 mg/m³ Romania OEL STEL (ppm) 40 ppm Romania OEL chemical category (RO) skin notation Slovakia NPHV (priemerná) (mg/m³) 52 mg/m³ Slovakia NPHV (priemerná) (ppm) 20 ppm Slovakia NPHV (Hraničná) (mg/m³) 104 mg/m³ Slovakia OEL chemical category (SK) Potential for cutaneous absorption Slovenia OEL TWA (mg/m³) 52 mg/m³ Slovenia OEL TWA (ppm) 20 ppm Slovenia OEL STEL (mg/m³) 104 mg/m³ Slovenia OEL STEL (ppm) 40 ppm Slovenia OEL chemical category (SL) Potential for cutaneous absorption Spain VLA-ED (mg/m³) 52 mg/m³ (indicative limit value) Spain VLA-ED (ppm) 20 ppm (indicative limit value) Spain VLA-EC (mg/m³) 104 mg/m³ Spain VLA-EC (ppm) 40 ppm Spain OEL chemical category (ES) skin - potential for cutaneous absorption Sweden nivågränsvärde (NVG) (mg/m³) 25 mg/m³ (the limit value applies to the combined concentration of vapor and aerosol-aerosol and vapor) Sweden nivågränsvärde (NVG) (ppm) 10 ppm (the limit value applies to the combined concentration of vapor and aerosol-aerosol and vapor) Sweden kortidsvärde (KTV) (mg/m³) 104 mg/m³ (aerosol and vapor) Sweden kortidsvärde (KTV) (ppm) 40 ppm (aerosol and vapor) Sweden OEL chemical category (SE) skin notation United Kingdom WEL TWA (mg/m³) 10 mg/m³ (particulates) 52 mg/m³ (vapour) United Kingdom WEL TWA (ppm) 20 ppm (vapour) United Kingdom WEL STEL (mg/m³) 104 mg/m³ (vapour) 30 mg/m³ (calculated-particulate) United Kingdom WEL STEL (ppm) 40 ppm (vapour) United Kingdom WEL chemical category Potential for cutaneous absorption Norway TWA (AN) (mg/m³) 20 mg/m³ (equal to the standard for nuisance dust-dust) 52 mg/m³ (total sum of limit values for both vapor and dust) Norway TWA (AN) (ppm) 52 ppm (total sum of limit values for both vapor and dust-total dust and vapor) Norway TWA (Korttidsverdi) (mg/m3) 104 mg/m³ (value from the regulation-dust) Norway TWA (Korttidsverdi) (ppm) 40 ppm (value from the regulation) Norway OEL chemical category (NO) skin notation Switzerland VME (mg/m³) 26 mg/m³ Switzerland VME (ppm) 10 ppm Switzerland VLE (mg/m³) 52 mg/m³ Switzerland VLE (ppm) 20 ppm Switzerland OEL chemical category (CH) skin notation Australia TWA (mg/m³) 10 mg/m³ (particulate) 52 mg/m³ (vapour) Australia TWA (ppm) 20 ppm (vapour) Australia STEL (mg/m³) 104 mg/m³ (vapour) Australia STEL (ppm) 40 ppm (vapour) Canada (Quebec) PLAFOND (mg/m³) 127 mg/m³ (mist and vapour) Canada (Quebec) PLAFOND (ppm) 50 ppm (mist and vapour) USA - ACGIH ACGIH TWA (ppm) 25 ppm (vapor fraction) 20/11/2017 EN (English US) 5/9

6 USA - ACGIH ACGIH STEL (mg/m³) 10 mg/m³ (inhalable particulate matter, aerosol only) USA - ACGIH ACGIH STEL (ppm) 50 ppm (vapor fraction) China OEL TWA 20 mg/m³ China OEL STEL 40 mg/m³ China Catalogue of Occupational Hazard Factors Category 3 - Chemicals Indonesia OEL STEL (mg/m³) 100 mg/m³ (aerosol) Japan Exposure limits (ACGIH) TWA (-),STEL (C 100 mg/m3 (H)) A4 Korea ISHA Hazardous Substances Subject to Control - Organic Compounds Korea ISHA Ceiling (mg/m³) 100 mg/m³ (mist and vapor) Korea ISHA Ceiling (ppm) 40 ppm (mist and vapor) Singapore OEL STEL (mg/m³) 127 mg/m³ Singapore OEL STEL (ppm) 50 ppm Taiwan OEL TWA (mg/m³) 10 mg/m³ (mist) Taiwan OEL STEL (mg/m³) 15 mg/m³ (mist) Taiwan OEL Ceilings (mg/m³) 127 mg/m³ (vapor) Taiwan OEL Ceilings (ppm) 50 ppm (vapor) Vietnam OEL TWA (mg/m³) 10 mg/m³ (particulate) Vietnam OEL STEL (mg/m³) 20 mg/m³ (particulate) 8.2. Appropriate engineering controls Other information : Do not eat, drink or smoke during use Individual protection measures, such as personal protective equipment (PPE) Hand protection Eye protection Respiratory protection : Wear protective gloves. : Chemical goggles or safety glasses : Use a properly fitted, particulate filter respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator 8.4. Exposure limit values of other components SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Appearance Color : Colorless. Odor : Sweet. Odor threshold ph ph solution Relative evaporation rate (butyl acetate=1) Relative evaporation rate (ether=1) Melting point Freezing point Boiling point : > 176 C Flash point : 111 C Auto-ignition temperature Decomposition temperature Flammability (solid, gas) : Non flammable Vapor pressure Vapor pressure at 50 C Relative vapor density at 20 C Relative density Relative density of saturated gas/air mixture 20/11/2017 EN (English US) 6/9

7 Specific gravity / density Relative gas density Solubility Log Pow Log Kow Viscosity, kinematic Viscosity, kinematic (calculated value) (40 C) Explosive properties Oxidizing properties Explosion limits LEL UEL : Completely Miscible with Water Other information SECTION 10: Stability and reactivity Reactivity Chemical stability Stable under normal conditions Possibility of hazardous reactions None under normal use Conditions to avoid Direct sunlight. Extremely high or low temperatures Incompatible materials Oxidizing agent. Strong acids. Strong bases Hazardous decomposition products fume. Carbon monoxide. Carbon dioxide. SECTION 11: Toxicological information Information on toxicological effects Acute toxicity (oral) Acute toxicity (dermal) Acute toxicity (inhalation) ATE UN (oral) Denatonium Benzoate ( ) LD50 oral rat LD50 oral rat LD50 dermal rat : Oral: Harmful if swallowed mg/kg body weight 584 mg/kg 4700 mg/kg mg/kg Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitization Germ cell mutagenicity Carcinogenicity Reproductive toxicity Specific target organ toxicity single exposure Specific target organ toxicity repeated exposure Aspiration hazard : May cause damage to organs (kidneys) through prolonged or repeated exposure (oral). Potential Adverse human health effects and symptoms : Based on available data, the classification criteria are not met. 20/11/2017 EN (English US) 7/9

8 SECTION 12: Ecological information Toxicity Aquatic acute Aquatic chronic LC50 fish ml/l (Exposure time: 96 h - Species: Oncorhynchus mykiss [static]) EC50 Daphnia mg/l (Exposure time: 48 h - Species: Daphnia magna) NOEC chronic crustacea 4.2 mg/l Log Pow Persistence and degradability Anti-freeze Bitterment Agent Persistence and degradability Not established Bioaccumulative potential Anti-freeze Bitterment Agent Bioaccumulative potential Log Pow Not established. See section 12.1 on ecotoxicology Mobility in soil Anti-freeze Bitterment Agent Mobility in soil Log Pow See section 12.1 on ecotoxicology Other adverse effects Ozone Other adverse effects Other information : : Avoid release to the environment. SECTION 13: Disposal considerations Disposal methods Ecology - waste materials SECTION 14: Transport information In accordance with IMDG / IATA / UN RTDG : Avoid release to the environment. UN RTDG IMDG IATA UN number Not regulated for transport Proper Shipping Name Non Regulated Non Regulated Non Regulated Transport hazard class(es) Not applicable Not applicable Not applicable Not applicable Not applicable Not applicable Packing group Not applicable Not applicable Not applicable Environmental hazards Dangerous for the environment : No Dangerous for the environment : No Marine pollutant : No No supplementary information available Dangerous for the environment : No Special precautions for user - UN RTDG No data available - IMDG No data available 20/11/2017 EN (English US) 8/9

9 - IATA No data available Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable SECTION 15: Regulatory information Safety, health, and environmental national regulations specific for the product SECTION 16: Other information Date of issue : 04/03/2015 Revision date : 20/11/2017 Other information : None. Full text of H-phrases: H302 Harmful if swallowed H332 Harmful if inhaled H373 May cause damage to organs through prolonged or repeated exposure SDS UN To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. 20/11/2017 EN (English US) 9/9