Lithium Ion Battery Incident Kit / /

Transcription

1 TM Lithium Ion Battery Incident Kit

2 cellblockfcs.com 2

3 TM Revolutionizing the way the world safely handles, transports, and stores lithium-ion batteries and other dangerous goods cellblockfcs.com 3

4 THE PROBLEM In April 2016, bulk shipments of lithium-ion (LI) batteries in cargo holds were banned on international passenger flights because of their volatility. The impact was global. We know safety while flying is vital for both pilots and passengers. And we also know that shipping cargo and people separately, is expensive. Even more so when dangerous goods are involved. LI batteries can erupt when an internal short circuit occurs from damage, defect, exposure to high temperatures, or by overcharging. Heat radiating from one affected cell can create a domino effect referred to as thermal runaway. Minutes, even hours after a fire appears to be extinguished, a LI battery can reignite. THE SOLUTION In response to the ban, CellBlock Fire Containment Systems (CellBlock FCS) was born using postconsumer recycled glass (CellBlockEX) bound with cementitious materials, to manufacture precast fire containment panels. A 2.54cm (1 ) panel can tolerate direct heat in excess of 1100 C (2012 F) up to 6 hours with negligible heat transfer to the outside surface, surpassing ASTM E136 standards for non-combustibility and exceeding DOT requirements. In other words, if a LI battery fire occurred on board an aircraft, a plane would have enough time to make an emergency landing. Since March 20, 1991 more than 160 air/airport incidents involving lithium batteries carried as cargo or baggage have been recorded. SAFE. SIMPLE. EFFECTIVE. Numerous fire hazards exist in production, transportation, storage and operation. Companies need peace of mind knowing their people, products and profits are protected. And they want three things: safety, reliability and affordability. What began as a solution to the airline industry, has grown into a comprehensive line of fire containment products suitable for any business including panels, transportation and storage cases, bags, pads, drums and loose-fill. CellBlock FCS helps you safely handle, transport and store LI batteries and other dangerous goods from flammable liquids to flammable solids - with confidence. Located in Standish, Maine, CellBlock FCS provides you with peace of mind knowing you re using the safest, greenest, simplest and most effective products on the market cellblockfcs.com 4

5 MULTIPLE FIRE CONTAINMENT SOLUTIONS FOR MULTIPLE INDUSTRIES. PRODUCTS CellBlockEx is an environmentally friendly, mineral-based extinguishing agent used for fire containment, fire prevention, and as a filler. PAGE 6 CellBlockEX-lined hazardous material drums are ideal for transporting used, spent, damaged and prototype batteries. PAGE 9 CellBlock FCS panels and liner tiles are an ideal substrate for high temperature fire containment. PAGE 10 CellBlock transportation and storage cases allow for the safe transport of lithium-ion batteries and the devices containing them. PAGE 12 LIBIK (Lithium-Ion Battery Incident Kit) was designed for the airline industry to suppress PED thermal events in-flight. PAGE 15 ADDITIONAL INFORMATION Lithium-Ion Battery Air/Airport Incidents Characteristics of Combustible Metals CellBlockEX Extinguishing Tests Aggregates Comparison...21 CellBlockEX Technical Data Product Releases...23 How CellBlockEX Works cellblockfcs.com 5

6 TM / / A SAFE, SIMPLE SOLUTION FOR FIRE PREVENTION OR CONTAINMENT CellblockEX is a multi-functional environmentally friendly, non-combustible, mineral-based fire extinguishing agent comprised of recycled glass used for fire containment and prevention. Through a proprietary process, the post-consumer recycled glass is finely ground, mixed and formed into granules, then sintered and foamed in a rotary kiln to create lightweight spheres with a closed cellular pore structure. CellBlockEX s smooth spherical shape safely covers and encloses products and packaging and won t degrade when exposed to vibration or friction in the shipping process. Tested by the Material Testing Institute (MPA), in Dresden, Germany, the loose-fill can be used as a fire suppressant in industrial and residential construction to fill cavities from suspended ceilings, to cable shafts, lines and pipes. Used as a packaging filler, it can protect products from damage, vibrations and impacts. CellBlockEX is available in 50L bags. FEATURES BENEFITS Green, non-combustible and sustainable made from post-consumer recycled glass Green - 100% mineral-based, environmentally safe, reusable and harmless to health (does not contain Crystalline Silica) Tested by the Material Testing institute (MPA) Dresden Effectively binds liquids, gases and vapors absorbs approx. 200% of its own weight Displaces oxygen, absorbs energy and suffocates the fire Forms an impervious cocoon around the fire load Versatile - can be used as a fire suppressant, an absorption agent and a filler Insect, bacteria and mold resistant Multi-functional - suitable for class A, B, D and K fire loads including metal fires, lithium-ion battery fires and combustible liquids Low dust content and easily removable without the mess of water, halon, vermiculite, pumice or sand Unaffected by heat, moisture, and chemicals Lithium Ion Battery Incident Kit / / cellblockfcs.com 6

7 CELLBLOCKEX - FOR ALL OF YOUR FIRE CONTAINMENT NEEDS ALL-ROUND EXTINGUISHING AGENT CellBlockEX is suitable for use in industrial facilities, production operations, data processing centers, archives, warehouses, and for transportation. As an electrical insulator, the granulate is also idea for the energy sector (i.e. transformer station protection). It has a low dust content, tolerates frost and is easily removable. DANGEROUS GOODS PACKAGING The dangerous goods industry has to observe multiple regulations whether transporting over the road, in the air or by sea. CellBlockEX meets the fundamental requirements as a fire protection filler and exceeds DOT requirements for lithium-ion battery transport. LITHIUM-ION BATTERY FIRE PROTECTION There are increasing requirements for better fire protection during production, transportation, storage, disposal and recycling of lithium-ion batteries. CellBlockEX is ideal as a dry extinguishing agent and is especially well-suited for processes where the use of extinguishing water or foam is not possible. FIRE PREVENTION WITH CELLBLOCKEX Preventive fire protection encompasses steps taken in advance to counteract the outbreak and spread of fires. In technical fire protection, CellBlockEX can be used as a fire suppressing material by permanently filling cavities, suspended ceilings, cable shafts, lines and pipes cellblockfcs.com 7

8 Lithium Ion Battery Incident Kit / / cellblockfcs.com 8

9 Hazardous Materials Drums CELLBLOCK FCS HELPS YOU REDUCE YOUR SHIPPING COSTS AND YOUR CARBON FOOTPRINT CellBlock FCS steel drums represent a best-practice method for transporting used, spent, damaged and prototype batteries. Under our pending special permit we anticipate being able to ship various battery types in the same packaging and with hazard communication exceptions. Lined with 1.5 of CellBlockEX loose-fill in the perimeter and 4 in the base, these provide a higher level of safety than standard drums in Hazard Materials Regulations (HMR). The unique characteristics of CellBlockEX reduces the probability of ignition of flammable vapors and the release of toxic fumes. With CellBlockEX surrounding the batteries, the likelihood of fire, heat, or smoke being released from the packaging is greatly diminished. Drums are available in various sizes and can be customized based on customer needs. In addition to transport, these reusable containers may also be used for storage, effectively solving two problems in one package. Lid with pressure vents Steel outer drum CellBlockEX loose-fill Aluminum liner Perforated for venting CellBlockEX loose-fill FEATURES Prototype sizes: 55g, 30g, 20g and 15g Lid with pressure vents Steel outer drum Perimeter lined with 1.5 of CellBlockEX loose fill and 4 in the base Aluminum liner perforated for venting BENEFITS Best practice method for transporting used, spent and damaged batteries Provides a higher level of safety than standard drums in Hazardous Materials Regulations (HMR) Can be used for both transport and storage Reusable cellblockfcs.com 9

10 Panels / Liner Tiles CELLBLOCK FCS GIVES YOU PEACE OF MIND Through a proprietary process, CellBlock FCS panels are made from environmentally friendly recycled glass aggregates (CellBlockEX), bound with multiple pozzolans and other additives. Panels consist of a core using three different grain sizes of postconsumer foamed glass ranging from 500 microns to 4 millimeters and are finished with a cementitious powder coating containing expanded glass and basalt fibers. CellBlock FCS is an ideal substrate for the construction of hightemperature fire containment shipping and storage containers, ballistic test chambers, fire corridors and floor underlayment. CellBlock s versatility allows it to meet the fire protection needs of multiple industries including manufacturing and production facilities, building construction, transportation of dangerous goods (land, sea and air), renewable energy storage, military applications (from storing drones to transporting trigger mechanisms) and for archival/museum safekeeping. Lightweight, environmentally friendly, durable and flexible, the panels can be used to line existing structures from walls to shelves and floors or manufactured as self-contained boxes, making them an ideal solution for every industry. Fire containment panels cellblockfcs.com 10

11 TIMESTAMP: 1:00 HOURS TIMESTAMP: 2:00 HOURS TIMESTAMP: 2:05 HOURS TIMESTAMP: 2:30 HOURS Infrared camera data FEATURES Available in two sizes: 2 x4 and 3 x5 Manufactured in four thicknesses: ½, 1, 2 and 4 depending on the structural loading and deflection requirements needed to safely contain fire or dangerous goods A 2.54cm (1 ) panel can tolerate direct heat in excess of 1100 C (2012 F) up to 6 hours with negligible heat transfer to the outside surface High insulating properties and low thermal conductivity: in 3 hour direct flame tests, backside of tile did not exceed 175 C (350 F) Strong and simultaneously light weight with 60 70% air by volume and densities as low as 640kg/m3 (45lbs/ft3) BENEFITS Green: 100% mineral-based, environmentally safe and reusable Can be manufactured in other sizes or assembled in box form Unaffected by heat, moisture, and chemicals Insect, bacteria and mold resistant Lightweight, durable and easy to install Exceeds DOT requirements for safe transport Surpasses ASTM e136 requirements for noncombustibility cellblockfcs.com 11

12 Transportation / Storage Cases CELLBLOCK FCS HELPS YOU DELIVER PEOPLE AND PRODUCTS TOGETHER Fabricated with CellBlock FCS panels, CellBlock transportation and storage cases allow for the safe transport of LI batteries and the devices containing them. Originally designed for the airline industry, both cases easily fit into an overhead compartment or cargo hold. Within the lid, CellBlockEX is packed into a burn-through fabric lining designed to release the recycled glass spheres, if and when a fire occurs. Once released, the beads form an impervious cocoon around the burning object displacing oxygen, absorbing smoke and heat while suffocating the fire. The inner box can be further compartmentalized with equipment dividers. Made from fire-resistant fabric and a CellBlockEX felt core, the reconfigurable walls provide padding plus an extra layer of insulation around a compromised device to limit the spread of heat and flames to neighboring devices. It s easy to use without the mess, volatility and ineffectiveness of water or halon, requires no assembly, and is reusable. Available with optional Fire-retardant equipment dividers Lithium Ion Battery Incident Kit / / cellblockfcs.com 12

13 FEATURES Large case dimensions: 76.2cm x 43.2cm x 25.4cm (30 x 17 x 10 ) Tare weight: 26.3kg (58lbs) Small case dimensions: 50.8cm x 43.2cm x 25.4cm (20 x 17 x 10 ) Tare weight: 18.1kg (40lbs) Ballistic strong - designed to safely contain and suppress fires during a thermal runaway incident without transferring heat to outside surfaces Disrupts thermal reaction - absorbs heat energy and cools the fire eradicating thermal runaway Binds liquids, gases, and fumes while creating an impervious layer over the fire load suppressing oxygen and suffocating the fire Can be equipped with cloud-enabled controls to monitor inside thermal activity and will send alerts if temperatures exceed normal ranges BENEFITS Can be manufactured in other sizes and requires no assembly Available in polished aluminum or powder coated with corporate colors and customized logos Versatile and multi-functional - suitable for LI battery fire containment, suppression of class A, B, D and K fires, containment and storing of flammable liquids, gases, solids and other dangerous goods Clean solution - safely contains fire and fumes without the mess of halon or water damage Green - reusable and environmentally friendly After a thermal runaway event, cases can be factoryinspected and recharged with CellBlockEX media for continued use cellblockfcs.com 13

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15 Lithium Ion Battery Incident Kit CELLBLOCK FCS HELPS YOU PROTECT YOUR PEOPLE, PRODUCTS AND PROFITS Originally designed for airlines, the LIBIK will fit into an overhead compartment, while still accomodating the largest laptop. The outer bag is fabricated with layered fire-retardent materials that can handle temperatures up to 1648 C (3000 F). The lining consists of CellBlockEX loose-fill fire-suppressant media that is automatically released when exposed to high heat. Fire-retardant gloves and a blanket complete the kit. If a PED or tool gets overly hot, it can be placed into the LIBIK. CellBlockEX will immediately begin to absorb smoke, gases and flammable electrolyte while extinguishing the LI battery fire. This would preclude potentially diverting an aircraft in flight since the hazards would be fully contained. If there is no thermal event, the device can be returned to the passenger or retained for forensic analysis upon arrival. A complete solution without the mess of halon or water damage, the LIBIK represents a best-practice method for dealing with lithium-ion battery incidents on passenger flights FEATURES Standard Size: 22 x 17 x 5 Fire retardant fabrics Stitched with Kevlar Fire resistant Velcro Heat and flame resistant brass zipper Safely extinguishes fire and helps to consume fumes BENEFITS Safe storage of tools from PEDs to cordless drills and drones Lightweight / easy to carry Made from the same heat and flame resistant fabric used in firefighter and military apparel Handle temperatures up to 1648 C (3000 F) Can be customized with embroidered logo Sizes can be customized cellblockfcs.com 15

16 LITHIUM-ION BATTERY AIR/AIRPORT INCIDENTS SAFE BATTERY TRANSPORTATION AND STORAGE IS AT THE FOREFRONT OF EVERYTHING WE DO Lithium-ion battery incidents are on the rise. We re working hard to deliver effective solutions. Since March 20, 1991 more than 160 air/airport incidents involving lithium batteries carried as cargo or baggage have been recorded. headquarters_offices/ash/ash_programs/hazmat/ aircarrier_info/media/battery_incident_chart.pdf. Laptop with lithium-ion battery in carry-on baggage: Started burning in the overhead bin in the passenger cabin. Fire extinguished on the ramp. Prototype lithium battery shipped by a PHMSA Approval Holder. Fire discovered as ULD was being loaded for trans-atlantic cargo flight in Memphis. Two 12-volt non-spillable batteries packed together in same box. Package caught fire in air cargo sort facility cellblockfcs.com 16

17 Portable drill in checked baggage: Batterypowered drill accidentally activated in checked baggage. Drill/battery overheated and caused more than 20 suitcases to catch fire on the ramp right before loading on passenger flight. A passenger checked a toolbox as checked baggage. TSA screeners noticed smoke coming from the toolbox. The Port of Portland Fire Dept. (POPFD) was alerted and responded to the incident and closed the screening location. The violator paid a $10,000 Civil Penalty. Lithium-ion Batteries for remote control model cars: Shipment being returned to manufacturer in Korea caught fire in air cargo warehouse. Jet Blue Flight 721 During takeoff from JFK, smoke began pouring from an overhead bin in the passenger cabin. Passengers alerted flight attendants. As the plane returned to JFK for an emergency landing, flight attendants were able to put out the fire, discharging both Halon fire extinguishers. Additionally, water was applied to cloth embers that continued to burn after the Halon was used. One passenger complained of chest pains and needed assistance in exiting the aircraft. Both lithium metal and ion batteries were loosely packed with the equipment cellblockfcs.com 17

18 CHARACTERISTICS OF COMBUSTIBLE METALS Temperature Temperatures of 1,000 C and up can be expected from most metal fires. Light metals burn at 2,000-3,200 C and the heavy metal zircon burns at over 4,660 C. These high temperatures trigger chemical reactions that do not correspond to our usual experiences. Therefore, special care should be taken when extinguishing, since there is a risk of death. UV Radiation The high temperatures are also responsible for emitting a large proportion of UV radiation. The eyes should also be protected. Inflammability The inflammability of metals is largely dependent on their form of appearance. The larger the surface of the metal relative to its volume, the easier it is for combustion (oxidation) to take place. For example, fine iron powder can be ignited very easily. For some light metals, contact with water is sufficient to cause inflammation. Aluminum powder and magnesium powder can be ignited with the flame of a gas burner. Light metals (Reaction with water already in cold condition) Light metals (No reaction with water in cold condition) Non-noble heavy metals Noble heavy metals Many light metals (density less than 5 kg/dm³) react on contact with water and form hydrogen gas (H2), which produces a highly explosive oxyhydrogen mixture with the oxygen present in the air and ignites by the resulting heat of the reaction. These metals reach very high temperatures (2,000-3,200 C) in the event of a fire and therefore represent a particular danger. These can also be ignited under certain conditions, e.g. iron chips Don t burn Lithium, Sodium, Potassium, Rubidium, Cesium, Calcium, Strontium, Barium Beryllium, Magnesium, Aluminum, Titanium e.g. iron, lead, zircon Silver, gold, platinum Sodium (Na) Potassium (K) Aluminum (Al) Lithium (Li) Magnesium (Mg) cellblockfcs.com 18

19 CELLBLOCKEX EXTINGUISHING TESTS LITHIUM-ION BATTERIES EXTINGUISHING TEST Coverage with approx. 20 cm CellBlockEX No flames visible after 60 seconds Fire was extinguished after 10 minutes Cooled down after 6-12 hours Suffocates the fire Absorbs heat energy SODIUM FIRE EXTINGUISHING TEST Coverage with approx. 10 cm CellBlockEX No flames visible after 10 seconds Fire was extinguished after 10 minutes Cooled down after 6-12 hours Suffocates the fire Absorbs heat energy MAGNESIUM FIRE EXTINGUISHING TEST Coverage with approx. 30 cm CellBlockEX No flames visible after 10 seconds Fire was extinguished after 10 minutes Cooled down after 6-12 hours Suffocates the fire Absorbs heat energy Lithium Ion Battery Incident Kit / / cellblockfcs.com 19

20 HOW CELLBLOCKEX WORKS Suffocation Effect Covering a fire load with CellBlockEX granulate displaces oxygen and separates it from the fuel, suffocating the fire. Cooling Effect Due to its specific thermal capacity, CellBlockEX absorbs heat, thereby cooling the fire, and disrupting the thermal reaction. Isolation Effect Like glass, CellBlockEX melts at a high temperature. The granulates absorb heat in the form of melting energy, and cools the fire while forming an impervious layer over the fire load, preventing a reaction with oxygen. Even difficult to control metal fires, such as sodium or magnesium, can be extinguished with CellBlockEX. Gas Tightness Due to the CellBlockEX grain shape, very dense sphere packing is achieved. The supply of oxygen is impeded by the packed bed, and the formation of combustible gases is prevented. Sorbency of Liquids The special granulate mixture combined with the porous, large grain surface, effectively binds liquids. Fire Gas Filtering Just like liquids, gases and vapors accumulate on the large surface area of the CellBlockEX granulate and are bound for disposal. CELLBLOCKEX IS AN ENVIRONMENTALLY FRIENDLY, MINERAL-BASED FIRE EXTINGUISHING AGENT cellblockfcs.com 20

21 AGGREGATES COMPARISON CellBlockEX Perlite Vermiculite Expanded Clay EPS Thermal conductivity coefficient 0.07 W/mK (all granular sizes) ca W/mK W/mK W/mK depending on grain and type W/mK Granular strength high very low very low very high very low Water absorption low 5-7 vol.-% very high vol.-% greatly variable very high vol.-% greatly variable low to high water absorption 5-15 vol.-% depending on granular form and firing process very low 1-2 vol.-% Granular structure regular as per grading curve 11 sizes mm greatly variable (no defined granular structure) change through conveying and mixing processes greatly variable (no defined granular structure) change through conveying and mixing processes sand 0-4 mm (crushed beads) round grain equigranular Bulk density low, e.g. 2-4 mm = 190kg/m mm = 140kg/m 3 very low kg/m 3 depending on grain low kg/m 3 depending on grain high 1-4 mm = kg/m mm = kg/m 3 very low kg/m 3 Binder required low due to ball shape, granular structure and low water absorption high due to irregular granular structure and high water absorption high due to irregular granular structure and high water absorption high with crushed beads low with round grain high through low inherent strength Compressive strength high very low severe abrasion very low severe abrasion high very low yes no no no in part Recycling product ( Blue Angel award) cellblockfcs.com 21

22 TECHNICAL DATA Fire extinguishing agent class D MPA No Fire rating class (DIN ) non combustible (A1) Grain size [mm] 1-4 Particle size [mesh #] 18-5 Dry loose bulk density [kg/m³] 240 ± 30 [lb/ft³] 15 ± 1.9 Particle density 1) [kg/m³] 360 ± 60 Crushing resistance 2) according to DIN EN [lb/ft³] 22 ± 3.7 [N/mm²] 1.5 [PSI] 217 Oversize [M.-%] 10 Undersize [M.-%] 15 ph value 8-11 Moisture content [M.-%] < 0.5 Color Thermal conductivity Main Component CE according DIN EN Thermal capacity creamy white [W/(m K)] 0.07 [BTU-in/hr-ft²- F] silicon dioxide [kj/(kg K)] 0.7 [BTU/lb- F] Porosity approx. [%] 85 1) Apparent (relative) density according to EN ) Values according to DIN V on request Raw Glass Material CellBlockEX Beads Glass Powder cellblockfcs.com 22

23 2018 PRODUCT RELEASES CellBlock FCS is developing several new products scheduled for launch in PED-PAD: FIRE-SUPPRESSION PILLOWS WITH CELLBLOCKEX TECHNOLOGY These fire suppression PED-Pads are designed for the technology sector in repair lab environments. When the pillow is placed over a compromised PED (Personal Electronic Device), the inner CellBlockEX loose-fill will be released, covering the burning object, extinguishing the fire and absorbing most of the smoke and fumes. Multiple sizes will be available for order by late 2017 or early ULDs WITH CELLBLOCKEX TECHNOLOGY CellBlock high-temperature fire containment ULDs are in the final design stages. These transport units are constructed from a high-grade aluminum frame and lined with CellBlock FCS panels designed to withstand high temperatures for extended periods of time. The outer walls are insulated with CellBlockEX loose-fill to help absorb smoke and fumes. STORAGE CABINETS WITH CELLBLOCKEX TECHNOLOGY These storage units are constructed from powder-coated steel and CellBlock FCS panels. The interior shelves contain CellBlockEX loose-fill, which will be released if a thermal event occurs and will work to suppress the flame and help control smoke and fumes. The cabinets may also be equipped with digital cloud-based monitoring technology. Recommended for the storage of lithium-ion batteries or PEDs in a laboratory, office or retail environment. POUR-IN-PLACE HIGH-TEMP UNDERLAYMENT WITH CELLBLOCKEX TECHNOLOGY Our proprietary concrete underlayment can be used under any type of flooring and provides over an hour of fire and heat protection from temperatures in excess of 1093 C (2000 F). The self-leveling formula is designed to simply be mixed with water and poured 1 thick. The resulting surface will be similar to CellBlockFCS solid panels. Sold in 42.6 kg (94 lb.) bags cellblockfcs.com 23

24 TM Lithium Ion Battery Incident Kit cellblockfcs.com 234 Northeast Road Unit # 5, Standish, Maine cellblockfcs.com