SECTION 2: Hazards identification

Transcription

1 Page: 1 of 16 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1 Product identifier Trade name: REACH registration No.: xxxx - Normal Benzin - Super Plus - Super - Eurosuper - Ottokraftstoff unverbleit CAS-Number: EC-number: Relevant identified uses of the substance or mixture and uses advised against General use: Fuel 1.3 Details of the supplier of the safety data sheet Company name: Erdölbevorratungsverband Street/POB-No.: Jungfernstieg 38 Postal Code, city: Hamburg Germany WWW: Telephone: +49 (0) Telefax: +49 (0) Dept. responsible for information: Telephone: +49 (0) ebv-fuelssds@ebv-oil.org 1.4 Emergency telephone number Giftinformationszentrum Göttingen (GIZ-Nord) Telephone: +49 (0)551/ SECTION 2: Hazards identification 2.1 Classification of the substance or mixture Classification according to EC regulation 1272/2008 (CLP) Flam. Liq. 1; H224 Extremely flammable liquid and vapour. Skin Irrit. 2; H315 Causes skin irritation. Muta. 1B; H340 May cause genetic defects. Carc. 1A; H350 May cause cancer. Repr. 2; H361fd Suspected of damaging fertility. Suspected of damaging the unborn child. STOT SE 3; H336 May cause drowsiness or dizziness. Asp. Tox. 1; H304 May be fatal if swallowed and enters airways. Aquatic Chronic 2; H411 Toxic to aquatic life with long lasting effects.

2 Page: 2 of Label elements Labelling (CLP) Signal word: Danger Hazard statements: H224 Extremely flammable liquid and vapour. H304 May be fatal if swallowed and enters airways. H315 Causes skin irritation. H336 May cause drowsiness or dizziness. H340 May cause genetic defects. H350 May cause cancer. H361fd Suspected of damaging fertility. Suspected of damaging the unborn child. H411 Toxic to aquatic life with long lasting effects. Precautionary statements: P102 Special labelling Text for labelling: 2.3 Other hazards P201 P210 P261 P301+P330+P331 Keep out of reach of children. Obtain special instructions before use. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Avoid breathing vapours. IF SWALLOWED: rinse mouth. Do NOT induce vomiting. P302+P352 IF ON SKIN: Wash with plenty of water/soap. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308+P313 IF exposed or concerned: Get medical advice/attention. P310 Immediately call a POISON CENTER. P403+P233 P501 Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container to hazardous or special waste collection point. Contains Gasoline; Low boiling point naphtha - unspecified Contains benzene, toluene and methanol Restricted to professional users. Potentially explosive mixtures may form if adequate ventilation is not provided. Inhaling can lead to irritations of the respiratory tract and mucous membrane. Higher doses may lead to a narcotic effect. Special danger of slipping by leaking/spilling product. Results of PBT and vpvb assessment: This substance does not meet the PBT/vPvB criteria of REACH, Annex XIII.

3 Page: 3 of Substances SECTION 3: Composition / information on ingredients Chemical characterisation: Gasolines unleaded, like DIN EN 228. Ottokraftstoffe nach DIN Some product specifications contain biogenous components. CAS-Number: EC-number: UVCB substance - Information on ingredients: Ingredient Designation Content Classification REACH xxxx EC No CAS REACH xxxx EC No CAS EC No CAS EC No CAS EC No CAS REACH xxxx EC No CAS EC No CAS EC No CAS REACH xxxx EC No CAS Full text of H- and EUH-statements: see section 16. Gasoline; Low boiling point naphtha - unspecified <= 100 % Flam. Liq. 1; H224. Skin Irrit. 2; H315. Muta. 1B; H340. Carc. 1B; H350. Repr. 2; H361. STOT SE 3; H336. Asp. Tox. 1; H304. Aquatic Chronic 2; H411. Toluene < 30 % Flam. Liq. 2; H225. Skin Irrit. 2; H315. Repr. 2; H361d. STOT SE 3; H336. STOT RE 2; H373. Asp. Tox. 1; H304. Aquatic Chronic 3; H412. tert-butyl methyl < 15 % Flam. Liq. 2; H225. Skin Irrit. 2; H315. ether Ethanol < 10 % Flam. Liq. 2; H Methylpropan- 2-ol < 7 % Flam. Liq. 2; H225. Acute Tox. 4; H332. Eye Irrit. 2; H319. STOT SE 3; H335. Isobutanol < 7 % Flam. Liq. 3; H226. Skin Irrit. 2; H315. Eye Dam. 1; H318. STOT SE 3; H335, H336. Isopropyl alcohol < 5 % Flam. Liq. 2; H225. Eye Irrit. 2; H319. STOT SE 3; H336. Methanol < 3 % Flam. Liq. 2; H225. Acute Tox. 3; H301. Acute Tox. 3; H311. Acute Tox. 3; H331. STOT SE 1; H370. Benzene < 1 % Flam. Liq. 2; H225. Skin Irrit. 2; H315. Eye Irrit. 2; H319. Muta. 1B; H340. Carc. 1A; H350. STOT RE 1; H372. Asp. Tox. 1; H304.

4 Page: 4 of Description of first aid measures SECTION 4: First aid measures General information: If medical advice is needed, have product container or label at hand. First aider: Pay attention to self-protection! Take off immediately all contaminated clothing. Do not put any product-impregnated cleaning rags into your trouser pockets. In case of inhalation: Move victim to fresh air. If victim is at risk of losing consciousness, position and transport on their side. Immediately get medical attention. In case of breathing difficulties administer oxygen. In case of irregular breathing or respiratory arrest provide artificial respiration. Following skin contact: After contact with skin, wash immediately with soap and plenty of water. Take off immediately all contaminated clothing and wash it before reuse. In case of skin irritation, consult a physician. If the product penetrates the skin under high pressure, call a physician immediately. After eye contact: Immediately flush eyes with plenty of flowing water for 10 to 15 minutes holding eyelids apart. Remove contact lenses, if present and easy to do. Continue rinsing. Subsequently seek the immediate attention of an ophthalmologist. After swallowing: Do not induce vomiting. If swallowed or in the event of vomiting, risk of entering the lungs. In case of vomiting, position victim on their side. Keep airway open. Immediately get medical attention. Never give anything by mouth to an unconscious person. 4.2 Most important symptoms and effects, both acute and delayed May cause drowsiness or dizziness. May be fatal if swallowed and enters airways. Causes skin irritation. Causes serious eye damage. 4.3 Indication of any immediate medical attention and special treatment needed Where appropriate artificial ventilation. In the event of pulmonary irritation treat initially with dexamethasone - dosing aerosol. When swallowed and vomited immediately, aspiration into the lungs may occur resulting in chemical pneumonia or suffocation. Symptoms of poisoning may develop several hours following exposure. Victim should be under medical observation for at least 48 hours after exposure. Dangerous reactions with Disulfiram. 5.1 Extinguishing media SECTION 5: Firefighting measures Suitable extinguishing media: Foam, dry extinguishing powder (ABC-powder), water spray jet, carbon dioxide. Only in case of small fires: additionally: Sand, earth. Extinguishing media which must not be used for safety reasons: Full water jet

5 Page: 5 of Special hazards arising from the substance or mixture Extremely flammable liquid and vapour. With air, vapours form potentially explosive mixtures, which are heavier than air. Vapours may proceed on the ground over great distances and cause fire and backflashes. In case of fire may be liberated: Nitrogen oxides (NOx), sulphur oxides, carbon monoxide and carbon dioxide, carbon black. Formation of numerous unknown compounds is possible. 5.3 Advice for firefighters Special protective equipment for firefighters: Wear self-contained positive pressure breathing apparatus and fire fighter's clothing conforming to European standard EN 469. Additional information: Hazchem-Code: 3YE Heating will lead to pressure increase: Danger of bursting and explosion. Keep containers cool with water spray. In case of major fire and large quantities: Evacuate area. Fight fire remotely due to the risk of explosion. Use water spray jet to knock down vapours. Do not allow fire water to penetrate into surface or ground water. Fire residuals and contaminated extinguishing water must be disposed of in accordance with the regulations of the local authorities. SECTION 6: Accidental release measures 6.1 Personal precautions, protective equipment and emergency procedures Obtain special instructions before use. Avoid exposure. Do not breathe vapours. Eliminate all ignition sources if safe to do so. Avoid contact with the substance. Wear appropriate protective equipment. Take off immediately all contaminated clothing and wash it before reuse. Remove persons to safety. Provide adequate ventilation. Do not put any product-impregnated cleaning rags into your trouser pockets. 6.2 Environmental precautions Do not allow to penetrate into soil, waterbodies or drains. Danger of explosion! In case of release, notify competent authorities. In case of spills of large quantities: Danger to drinking water. 6.3 Methods and material for containment and cleaning up Additional information: clean up contamination/spills as soon as they occur. Remove from the water surface (e.g. skimming, sucking). Isolate leaked material using non-flammable absorption agent (e.g. sand, earth, vermiculit, diatomaceous earth) and collect it for disposal in appropriate containers in accordance with the local regulations (see section 13). Use only antistatically equipped (spark-free) tools. Unsuitable material for taking up: water. In case of greater quantities: Collect mechanically (use only explosion-proof equipment when pumping out). Soil (contaminated): Dispose of in accordance with the regulations. Remove all sources of ignition. Beware of reignition. Special danger of slipping by leaking/spilling product.

6 Page: 6 of Reference to other sections Refer additionally to section 8 and Precautions for safe handling SECTION 7: Handling and storage Advices on safe handling:provide adequate ventilation, and local exhaust as needed. Avoid spraying or spilling the product during use. Avoid breathing vapours. Avoid exposure. Do not get in eyes, on skin, or on clothing. Wear appropriate protective equipment. Do not eat, drink or smoke when using this product. Wash hands thoroughly after handling. Take off immediately all contaminated clothing and wash it before reuse. Guarantee sufficient ventilation during and after use, in order to prevent vapour accumulation. When handling large quantities, supply emergency spray. Precautions against fire and explosion: Keep away from sources of ignition - No smoking. Take precautionary measures against static discharge. Use only explosion-protected equipment/instruments. Do not weld. In partially filled containers explosive mixtures may form. 7.2 Conditions for safe storage, including any incompatibilities Requirements for storerooms and containers: Keep container tightly closed and in a well-ventilated place. Keep away from sources of ignition and heat. Protect from direct sunlight. Qualified materials: steel, HD polyethylene, polypropylene, Fluororubber (Viton), admitted spare canister. Only trained personnel may be allowed to enter storage area. Do not stack cans too high. Max. 3 barrels. Hints on joint storage: Do not store together with oxidizing agents. Further details: Keep locked up and out of the reach of children. 7.3 Specific end use(s) No information available.

7 Page: 7 of Control parameters Occupational exposure limit values: SECTION 8: Exposure controls/personal protection CAS No. Designation Type Limit value Toluene Europe: IOELV: STEL 384 mg/m³; 100 ppm Europe: IOELV: TWA 192 mg/m³; 50 ppm Great Britain: WEL-STEL 384 mg/m³; 100 ppm Great Britain: WEL-TWA 191 mg/m³; 50 ppm Ireland: 15 minutes 384 mg/m³; 100 ppm Ireland: 8 hours 192 mg/m³; 50 ppm tert-butyl methyl Europe: IOELV: STEL 367 mg/m³; 100 ppm ether Europe: IOELV: TWA mg/m³; 50 ppm Great Britain: WEL-STEL 367 mg/m³; 100 ppm Great Britain: WEL-TWA mg/m³; 50 ppm Ireland: 15 minutes 367 mg/m³; 100 ppm Ireland: 8 hours mg/m³; 50 ppm Ethanol Great Britain: WEL-TWA 1920 mg/m³; 1000 ppm Ireland: 15 minutes 1000 ppm Methylpropan-2-ol Great Britain: WEL-STEL 462 mg/m³; 150 ppm Great Britain: WEL-TWA 308 mg/m³; 100 ppm Ireland: 15 minutes 450 mg/m³; 150 ppm Ireland: 8 hours 300 mg/m³; 100 ppm Isobutanol Great Britain: WEL-STEL 231 mg/m³; 75 ppm Great Britain: WEL-TWA 154 mg/m³; 50 ppm Ireland: 15 minutes 225 mg/m³; 75 ppm Ireland: 8 hours 150 mg/m³; 50 ppm Isopropyl alcohol Great Britain: WEL-STEL 1250 mg/m³; 500 ppm Great Britain: WEL-TWA 999 mg/m³; 400 ppm Ireland: 15 minutes 400 ppm Ireland: 8 hours 200 ppm Methanol Europe: IOELV: TWA 260 mg/m³; 200 ppm Great Britain: WEL-STEL 333 mg/m³; 250 ppm Great Britain: WEL-TWA 266 mg/m³; 200 ppm Ireland: 8 hours 260 mg/m³; 200 ppm Benzene Europe: BOELV: TWA 3.25 mg/m³; 1 ppm Great Britain: WEL-TWA 3.25 mg/m³; 1 ppm Ireland: 8 hours 3 mg/m³; 1 ppm

8 Page: 8 of 16 Biological limit values: CAS No. Designation Type Limit value Parameter Sampling Benzene Europe: BLV, blood Europe: BLV, urine 28 µg/l benzene end of exposure or end of shift 46 µg/g creatinine Phenylmercapturic end of exposure or acid end of shift DNEL/DMEL: Information about Gasoline; Low boiling point naphtha - unspecified: DNEL Short-term, workers, inhalative: 1300 mg/m³ / 15 min DNEL Short-term, workers, inhalative: 1110 mg/m³ / 15 min DNEL Long-term, workers, inhalative: 840 mg/m³ / 8h DNEL Short-term, consumers, inhalative: 1200 mg/m³ / 15 min DNEL Short-term, consumers, inhalative: 640 mg/m³ / 15 min DNEL Long-term, consumers, inhalative: 180 mg/m³ / 8h Information about Ethanol: DNEL Long-term, workers, inhalative: 950 mg/m³ DNEL Long-term, workers, dermal: 343 mg/kg DNEL Long-term, consumers, inhalative: 114 mg/m³ DNEL Long-term, consumers, dermal: 206 mg/kg*d DNEL Long-term, consumers, oral: 87 mg/kg*d Information about benzene: DNEL Long-term, workers, inhalative: 3,24 mg/m³ *8h 8.2 Exposure controls Personal protection equipment Provide for good room ventilation, suctioning/venting. In enclosed areas: Withdraw by suction. Natural ventilation is adequate outside and in open halls. Occupational exposure controls Respiratory protection: Respiratory protection must be worn whenever the WEL levels have been exceeded. Use filter type A (= against vapours of organic substances) according to EN (Vapours up to 0.1 Vol.-%: A1, up to 0.5 Vol.-% A2, up to 1 Vol.-% A3.) Wear self-contained breathing apparatus if circumstances are indefinite or oxygen content is below 17%. (Control of breathing air: Test tube Auer Benzin A, BNZ, Gasolin 30, QL). Hand protection: Protective gloves according to EN 374. Glove material: Short term effect: Nitrile rubber (0.35 mm; max. 4h). In case of prolonged exposure: Fluororubber (Viton) (0.4 mm). Breakthrough time: >= 480 min. Unsuitable materials: natural rubber, butyl caoutchouc (butyl rubber), PVC, leather, textile material. Observe glove manufacturer's instructions concerning penetrability and breakthrough time. Eye protection: Tightly sealed goggles according to EN 166. In case of increased risk, additionally Face protection shield. Body protection: Use antistatic protection clothing and protection boots.

9 Page: 9 of 16 General protection and hygiene measures: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Avoid breathing vapours. Do not get in eyes, on skin, or on clothing. Contaminated work clothing should not be allowed out of the workplace. When using do not eat or drink. Wash hands thoroughly after handling. When handling large quantities, supply emergency spray. Do not put any product-impregnated cleaning rags into your trouser pockets. SECTION 9: Physical and chemical properties 9.1 Information on basic physical and chemical properties Appearance: Odour: Odour threshold: Physical state at 20 C and kpa: liquid Colour: colourless up to yellow characteristic ph value: Melting point/freezing point: Initial boiling point and boiling range: C (CONCAWE 2010) Flash point/flash point range: <= -40 C Evaporation rate: Flammability: Extremely flammable liquid and vapour. Explosion limits: LEL (Lower Explosion Limit): 0.60 Vol-% UEL (Upper Explosive Limit): 8.00 Vol-% Vapour pressure: at 38 C: Summer: 45,0-60,0 kpa - winter: kpa (DIN EN ) at 50 C: Vapour density: Density: at 15 C: 720,0_775 kg/m³ (DIN ISO 3675/12185) Water solubility: at 20 C: low Partition coefficient: n-octanol/water: approx log P(o/w) Based on the n-octanol/water partition coefficient accumulation in organisms is possible. Auto-ignition temperature: Decomposition temperature: Viscosity, kinematic: Explosive properties: Oxidizing characteristics: 9.2 Other information Ignition temperature: >= 210 C at 20 C: approx. 0.5 mm²/s Vapours can form explosive mixtures with air.

10 Page: 10 of Reactivity SECTION 10: Stability and reactivity Extremely flammable liquid and vapour. If containers are open, product will slowly oxidize on contact with air Chemical stability Stable under recommended storage conditions Possibility of hazardous reactions 10.4 Conditions to avoid 10.5 Incompatible materials Heating will lead to pressure increase: Danger of bursting and explosion. In case of warming: Risk of fire/danger of spontaneous combustion. Potentially explosive vapour/air mixtures may form. Keep away from heat sources, sparks and open flames. Protect from direct sunlight. Oxidizing agents 10.6 Hazardous decomposition products No hazardous decomposition products when regulations for storage and handling are observed. Thermal decomposition: 11.1 Information on toxicological effects SECTION 11: Toxicological information Acute toxicity: LD50 Rat, oral: > 5000 mg/kg (OECD TG 401) LC50 Rat, inhalative: > 5 mg/l (OECD TG 403) LD50 Rabbit, dermal: > 2000 mg/kg (OECD TG 402)

11 Page: 11 of 16 Toxicological effects: Other information: Symptoms Acute toxicity (oral): Based on available data, the classification criteria are not met. Acute toxicity (dermal): Based on available data, the classification criteria are not met. Acute toxicity (inhalative): Based on available data, the classification criteria are not met. Skin corrosion/irritation: Skin Irrit. 2; H315 = Causes skin irritation. Information about Gasoline; Low boiling point naphtha - unspecified: Specific symptoms in animal studies (Rabbit): irritant (OECD TG 404) Serious eye damage/irritation: Lack of data. Sensitisation to the respiratory tract: Lack of data. Skin sensitisation: Based on available data, the classification criteria are not met. Information about Gasoline; Low boiling point naphtha - unspecified: test result for Sensitisation (Guinea pig): negative (OECD TG 406) Germ cell mutagenicity/genotoxicity: Muta. 1B; H340 = May cause genetic defects. Contents of benzene >=0,1 % Carcinogenicity: Carc. 1A; H350 = May cause cancer. Contents of benzene >=0,1 % Reproductive toxicity: Repr. 2; H361fd = Suspected of damaging fertility. Suspected of damaging the unborn child. Contents of toluene or n-hexane >=3 % Information about Methanol Contents of Methanol >= 0.3 %. May damage fertility or the unborn child. Effects on or via lactation: Lack of data. Specific target organ toxicity (single exposure): STOT SE 3; H336 = May cause drowsiness or dizziness. symptoms: CNS disorders. Specific target organ toxicity (repeated exposure): Based on available data, the classification criteria are not met. NOAEL Rat, dermal: 3750 mg/kg/28d (OECD TG 410) NOAEC chronic inhalation toxicity: 1400 mg/m³ (OECD TG 453) Aspiration hazard: Asp. Tox. 1; H304 = May be fatal if swallowed and enters airways. Oral or inhalative ingestion causes nephrotoxic effects in rats. Toxic effect on blood building organs. Product contains benzene, which induces leukaemia. Information about Gasoline; Low boiling point naphtha - unspecified: Neurotoxicity: Exposure to high level can produce depression of central nervous system in humans or in experimental animals. immunotoxicity: Gasoline exposure does not affect the immune system in experimental animals at Concentration > mg/[m3]. In case of inhalation: Headache, intoxication, nausea, drowsiness, dizziness, shortage of breath, Cough. If higher concentrations occur: CNS disorders, unconsciousness, narcosis, apnea. In case of ingestion: gastrointestinal complaints, diarrhoea, Cough, shortness of breath, fever. After contact with skin: Has degreasing effect on the skin.

12 Page: 12 of Toxicity Aquatic toxicity: SECTION 12: Ecological information Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Information about Gasoline; Low boiling point naphtha - unspecified: Acute effects: algae toxicity freshwater species: EL50 Pseudokirchneriella subcapitata (green algae): 3.1 mg/l/72h (OEDC 201, based on: growth rate) (source: CONCAWE 1995o) NOELR Pseudokirchneriella subcapitata (green algae): 0.5 mg/l/72h (OEDC 201, based on: growth rate) (source: CONCAWE 1996a) fish toxicity freshwater species: LC50 Oncorhynchus mykiss: 10 mg/l/96h (OEDC 203) (source: CONCAWE 1995a, 1996a,b) LC50 Pimephales promelas (fathead minnow): 8.2 mg/l/96h (EPA ) (source: PPSC 1995a) Invertebrate toxicity: freshwater species EC50 Daphnia magna (Big water flea): 4.5 mg/l/48h (OEDC 202, based on: Mobility) (source: CONCAWE 1995h, 1996j,k) Bacterial toxicity: freshwater species LL50 Tetrahymena pyriformis: mg/l/72h (Method: QSAR PETROTOX) (source: Redman et al. 2010b) Long-term effects: freshwater species NOEL Daphnia magna (Big water flea): 2.6 mg/l/21d (OEDC 211, based on: reproduction) (source: Springborn Laboratories Inc. 1999d) 12.2 Persistence and degradability Further details: 12.3 Bioaccumulative potential Information about Gasoline; Low boiling point naphtha - unspecified: Inherently biodegradable (Solano-Serena, F. et al (1999)). Hydrolysis is not expected to occur. (Neely, W.B., Blau, G.E. (1985)) Environmental distribution like calculation model (PETRORISK): Air: % Water: 5.83 % Soil: 0.34 % Sediment: 0.81 % (source: Redman et al., 2010a) Partition coefficient: n-octanol/water: approx log P(o/w) Based on the n-octanol/water partition coefficient accumulation in organisms is possible Mobility in soil 12.5 Results of PBT and vpvb assessment This substance does not meet the PBT/vPvB criteria of REACH, Annex XIII.

13 Page: 13 of Other adverse effects General information: Discharge into the environment must be avoided. Formation of an oil film on water impairs the oxygen exchange and may cause significant adverse effects in the aquatic environment Waste treatment methods Product Waste key number: Recommendation: SECTION 13: Disposal considerations * = Wastes of liquid fuels: Petrol * = Evidence for disposal must be provided. Delivery to an approved waste disposal company. Incinerate according to applicable local, state and federal regulations. Contaminated packaging Recommendation: Completely emptied packages can be recycled. Additional information Discharge into the environment must be avoided. Handle empty containers with care. Incineration may cause explosion UN number ADR/RID, IMDG, IATA-DGR: UN UN proper shipping name ADR/RID: IMDG, IATA-DGR: 14.3 Transport hazard class(es) ADR/RID: Class 3, Code: F1 IMDG: Class 3, Subrisk - IATA-DGR: Class Packing group ADR/RID, IMDG, IATA-DGR: II 14.5 Environmental hazards Marine pollutant: SECTION 14: Transport information UN 1203, Motor fuel (for spark ignition engines) UN 1203, MOTOR SPIRIT yes

14 Page: 14 of Special precautions for user Land transport (ADR/RID) Warning board: ADR/RID: Kemmler-number 33, UN number UN 1203 Hazard label: 3 Special provisions: Limited quantities: EQ: Contaminated packaging - Instructions: Contaminated packaging - Special provisions: Special provisions for packing together: Portable tanks - Instructions: Portable tanks - Special provisions: Tank coding: Tunnel restriction code: Sea transport (IMDG) EmS: ADR664 1 L E2 P001 IBC02 R001 BB2 MP19 T4 TP1 LGBF D/E Special provisions: 243 Limited quantities: Excepted quantities: Contaminated packaging - Instructions: Contaminated packaging - Provisions: - IBC - Instructions: IBC - Provisions: - Tank instructions - IMO: - Tank instructions - UN: F-E, S-E 1 L E2 P001 IBC02 T4 Tank instructions - Provisions: TP1 Stowage and handling: Category E. Properties and observations: Immiscible with water. Segregation group: none Air transport (IATA) Hazard label: Excepted Quantity Code: Passenger and Cargo Aircraft: Ltd.Qty.: Passenger and Cargo Aircraft: Cargo Aircraft only: Special provisions: Emergency Response Guide-Code (ERG): 3H Flamm. liquid E2 Pack.Instr. Y341 - Max. Net Qty/Pkg. 1 L Pack.Instr Max. Net Qty/Pkg. 5 L Pack.Instr Max. Net Qty/Pkg. 60 L A Transport in bulk according to Annex II of Marpol and the IBC Code

15 Page: 15 of 16 SECTION 15: Regulatory information 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture National regulations - Great Britain Hazchem-Code: 3YE National regulations - EC member states Volatile organic compounds (VOC): 100 % by weight = 775 g/l Labelling of packaging with <= 125mL content Signal word: Danger Hazard statements: H224 Extremely flammable liquid and vapour. H304 May be fatal if swallowed and enters airways. H336 May cause drowsiness or dizziness. H340 May cause genetic defects. H350 May cause cancer. H361fd Suspected of damaging fertility. Suspected of damaging the unborn child. Precautionary statements: P102 Keep out of reach of children. P201 Obtain special instructions before use. P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P261 Avoid breathing vapours. P301+P330+P331 IF SWALLOWED: rinse mouth. Do NOT induce vomiting. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308+P313 IF exposed or concerned: Get medical advice/attention. P310 Immediately call a POISON CENTER. P403+P233 Store in a well-ventilated place. Keep container tightly closed. Further regulations, limitations and legal requirements: Use restriction according to REACH annex XVII, no.: 3 Directive 2012/18/EU on the control of major-accident hazards involving dangerous substances [Seveso-III-Directive]: annex I, part 1: P5a, E2, 34a Chemical Safety Assessment For the following substances of this mixture a chemical safety assessment has been carried out: Gasoline; Low boiling point naphtha - unspecified

16 Page: 16 of 16 Further information SECTION 16: Other information Wording of the H-phrases under paragraph 2 and 3: H224 = Extremely flammable liquid and vapour. H225 = Highly flammable liquid and vapour. H226 = Flammable liquid and vapour. H301 = Toxic if swallowed. H304 = May be fatal if swallowed and enters airways. H311 = Toxic in contact with skin. H315 = Causes skin irritation. H318 = Causes serious eye damage. H319 = Causes serious eye irritation. H331 = Toxic if inhaled. H332 = Harmful if inhaled. H335 = May cause respiratory irritation. H336 = May cause drowsiness or dizziness. H340 = May cause genetic defects. H350 = May cause cancer. H361 = Suspected of damaging fertility or the unborn child. H361fd = Suspected of damaging fertility. Suspected of damaging the unborn child. H361d = Suspected of damaging the unborn child if inhaled. H370 = Causes damage to organs. H372 = Causes damage to organs through prolonged or repeated exposure. H373 = May cause damage to central nervous system through prolonged or repeated exposure via inhalation. H411 = Toxic to aquatic life with long lasting effects. H412 = Harmful to aquatic life with long lasting effects. Literature: - CONCAWE Dossier 'Liquified Petroleum Gas', 92/102 (Madouplein 1, B-1030 Brussels, Belgium) - CONCAWE Report 01/54 (Environmental Classification of Petroleum Substances - Summary data and Rationale) - CONCAWE Report 01/53 (Classification and of Labelling of Petroleum Substances Directive) Reason of change: Changes in section 8: occupational exposure limit values Date of first version: 5/6/2013 Department issuing data sheet Contact person: see section 1: Dept. responsible for information For abbreviations and acronyms, see: ECHA Guidance on information requirements and chemical safety assessment, chapter R.20 (Table of terms and abbreviations). The information in this data sheet has been established to our best knowledge and was up-to-date at time of revision. It does not represent a guarantee for the properties of the product described in terms of the legal warranty regulations.