MONO ENGINE OIL CF

Transcription

1 Date of issue: Revision date: supersedes: Version: 3.1 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form : Mixture Product name : MONO ENGINE OIL CF 40 Product code : Type of product : Lubricant Product group : Engine oil (lubricant) 1.2. Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Main use category Industrial/Professional use spec Use of the substance/mixture Function or use category : Engine oil (lubricant) : For professional use only : This oil should not be used for any other purpose than the intended use without expert advice. : Lubricants and additives Uses advised against 1.3. Details of the supplier of the safety data sheet Transnational Blenders B.V. (under license of 77 Lubricants) Wieldrechtseweg BG Dordrecht - Netherlands T +31 (0) info@tnb.nl Emergency telephone number Emergency number : +31 (0) Monday to Friday: 09:00-16:00 (CET) SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP]Mixture: SDS < 2015 : Show DPD information + CLP classification in section 2.1 Not classified Classification according to Directive 67/548/EEC [DSD] or 1999/45/EC [DPD] Not classified 2.2. Label elements Labelling according to Directive 67/548/EEC or 1999/45/EC Extra phrases : Safety data sheet available for professional user on request 2.3. Other hazards Other hazards not contributing to the classification : Flammable liquids. Repeated or prolonged contact may cause skin irritation. Spills of this product present a serious slipping hazard. SECTION 3: Composition/information on ingredients 3.1. Substance Not applicable 3.2. Mixture Name Product identifier % Classification according to Directive 67/548/EEC SN 500 substance with a Community workplace exposure limit (CAS No) (EC no) (EC index no) Not classified Not classified Classification according to Regulation (EC) No. 1272/2008 [CLP] EN (English) 1/8

2 Name Product identifier % Classification according to Directive 67/548/EEC Classification according to Regulation (EC) No. 1272/2008 [CLP] Mineral oil 1-5 Not classified Asp. Tox. 1, H304 Full text of R- and H-statements: see section 16 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). : Allow breathing of fresh air. Allow the victim to rest. : Remove affected clothing and wash all exposed skin area with mild soap and water, followed by warm water rinse. : Rinse immediately with plenty of water. Obtain medical attention if pain, blinking or redness persist. : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention Most important symptoms and effects, both acute and delayed Symptoms/injuries Symptoms/injuries after inhalation Symptoms/injuries after skin contact Symptoms/injuries after eye contact Symptoms/injuries after ingestion 4.3. Indication of any immediate medical attention and special treatment needed : Not expected to present a significant hazard under anticipated conditions of normal use. After adequate first aid, no further treatment is required unless symptoms reappear. : After adequate first aid, no further treatment is required unless symptoms reappear. : After adequate first aid, no further treatment is required unless symptoms reappear. : After adequate first aid, no further treatment is required unless symptoms reappear. : After adequate first aid, no further treatment is required unless symptoms reappear. SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media Unsuitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand. : Do not use a heavy water stream Special hazards arising from the substance or mixture 5.3. Advice for firefighters Firefighting instructions Protection during firefighting : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire-fighting water from entering environment. : Do not enter fire area without proper protective equipment, including respiratory protection. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures For non-emergency personnel Protective equipment Emergency procedures For emergency responders Protective equipment Emergency procedures : Eliminate all ignition sources if safe to do so. : Evacuate unnecessary personnel. : Equip cleanup crew with proper protection. Wear suitable protective clothing, gloves and eye/face protection. : Ventilate area Environmental precautions Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters Methods and material for containment and cleaning up For containment Methods for cleaning up 6.4. Reference to other sections See Heading 8. Exposure controls and personal protection. : Contain any spills with dikes or absorbents to prevent migration and entry into sewers or streams. : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials EN (English) 2/8

3 SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling : Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapour Conditions for safe storage, including any incompatibilities Storage conditions Incompatible products Incompatible materials Storage temperature : 45 C Storage area Special rules on packaging 7.3. Specific end use(s) : Keep only in the original container in a cool, well ventilated place away from : Direct sunlight., Heat sources. Keep container closed when not in use. : Strong bases. Strong acids. SECTION 8: Exposure controls/personal protection 8.1. Control parameters : Sources of ignition. Direct sunlight. : Store away from heat. Store in a well-ventilated place. : Keep only in original container. Store in a closed container. SN 500 ( ) EU IOELV TWA (mg/m³) 5 mg/m³ 8 HRS EU IOELV STEL (mg/m³) 10 mg/m³ 15 min Austria MAK (mg/m³) 5 mg/m³ Belgium Limit value (mg/m³) 5 mg/m³ 8 HRS Belgium Short time value (mg/m³) 10 mg/m³ 15 MIN Bulgaria OEL TWA (mg/m³) 5 mg/m³ 8 HRS Czech Republic Expoziční limity (PEL) (mg/m³) 10 mg/m³ Czech Republic Expoziční limity (NPK-P) (mg/m³) 5 mg/m³ 8 HRS Denmark Grænseværdie (langvarig) (mg/m³) 1 Denmark Grænseværdie (kortvarig) (mg/m³) 2 mg/m³ Finland HTP-arvo (8h) (mg/m³) 5 mg/m³ 8 Hrs Greece OEL TWA (mg/m³) 5 mg/m³ 8 hrs Hungary AK-érték < 5 mg/m³ Hungary CK-érték 0 mg/m³ Ireland OEL (8 hours ref) (mg/m³) 5 mg/m³ 8 Hrs Italy OEL STEL (mg/m³) 10 mg/m³ Latvia OEL TWA (mg/m³) 5 mg/m³ 8 Hrs Lithuania IPRV (mg/m³) 3 mg/m³ 15 min Lithuania TPRV (mg/m³) 1 mg/m³ 8 Hrs Netherlands Grenswaarde TGG 8H (mg/m³) 5 mg/m³ 8 Hrs Poland NDS (mg/m³) 5 mg/m³ 8 hrs Poland NDSP (mg/m³) 10 mg/m³ 15 minutes Portugal OEL TWA (mg/m³) 5 mg/m³ 8 Hrs Portugal OEL STEL (mg/m³) 10 mg/m³ Romania OEL TWA (mg/m³) 5 mg/m³ 8 Hrs Romania OEL STEL (mg/m³) 10 mg/m³ 15 min Slovakia NPHV (priemerná) (mg/m³) 5 mg/m³ 8 hrs Spain VLA-ED (mg/m³) 5 mg/m³ 8 Hrs Spain VLA-EC (mg/m³) 10 mg/m³ 15 min Sweden nivågränsvärde (NVG) (mg/m³) 1 mg/m³ Sweden kortidsvärde (KTV) (mg/m³) 3 mg/m³ United Kingdom WEL TWA (mg/m³) 5 mg/m³ 8 Hrs Norway Grenseverdier (AN) (mg/m³) 1 mg/m³ Australia TWA (mg/m³) 5 mg/m³ 8 Hrs Canada (Quebec) VECD (mg/m³) 10 mg/m³ Canada (Quebec) VEMP (mg/m³) 5 mg/m³ EN (English) 3/8

4 SN 500 ( ) USA - ACGIH ACGIH TWA (mg/m³) >= mg/m³ USA - OSHA OSHA PEL (TWA) (mg/m³) 5 mg/m³ Mineral oil EU IOELV TWA (mg/m³) 5 mg/m³ EU IOELV STEL (mg/m³) 10 mg/m³ Belgium Limit value (mg/m³) 5 mg/m³ 8 Hrs Belgium Short time value (mg/m³) 10 mg/m³ 15 Min Bulgaria OEL TWA (mg/m³) 5 mg/m³ 8 Hrs Czech Republic Expoziční limity (PEL) (mg/m³) 10 mg/m³ Czech Republic Expoziční limity (NPK-P) (mg/m³) 5 mg/m³ 8 Hrs Denmark Grænseværdie (kortvarig) (mg/m³) 1 mg/m³ Finland HTP-arvo (15 min) 5 mg/m³ 8 Hrs Greece OEL TWA (mg/m³) 5 mg/m³ 8 Hrs Hungary CK-érték 5 mg/m³ Ireland OEL (8 hours ref) (mg/m³) 5 mg/m³ 8 Hrs Latvia OEL TWA (mg/m³) 5 mg/m³ 8 Hrs Lithuania IPRV (mg/m³) 1 mg/m³ 8 Hrs Lithuania TPRV (mg/m³) 3 mg/m³ 15 Min Netherlands Grenswaarde TGG 8H (mg/m³) 5 mg/m³ 8 Hrs Portugal OEL TWA (mg/m³) 5 mg/m³ 8 Hrs Portugal OEL STEL (mg/m³) 10 mg/m³ Romania OEL TWA (mg/m³) 5 mg/m³ 8 Hrs Romania OEL STEL (mg/m³) 10 mg/m³ 15 Min Slovakia NPHV (priemerná) (mg/m³) 5 mg/m³ 8 Hrs Spain VLA-ED (mg/m³) 5 mg/m³ 8 Hrs Spain VLA-EC (mg/m³) 10 mg/m³ 15 Min Sweden nivågränsvärde (NVG) (mg/m³) 1 mg/m³ Sweden kortidsvärde (KTV) (mg/m³) 3 mg/m³ United Kingdom WEL TWA (mg/m³) 500 mg/m³ Norway Grenseverdier (AN) (mg/m³) 1 mg/m³ USA - OSHA OSHA PEL (TWA) (mg/m³) 5 mg/m³ 8.2. Exposure controls Personal protective equipment Hand protection Eye protection Skin and body protection Respiratory protection : Avoid all unnecessary exposure. Protective clothing. Gloves. Safety glasses. : Wear protective gloves : Chemical goggles or safety glasses : Wear suitable protective clothing : Wear appropriate mask Other information : Do not eat, drink or smoke during use. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Appearance : Characteristics. Colour : light brown. Odour : Characteristics. Odour threshold ph EN (English) 4/8

5 Relative evaporation rate (butylacetate=1) Melting point Freezing point : -9 C Boiling point Flash point : 220 C Auto-ignition temperature Decomposition temperature Flammability (solid, gas) Vapour pressure Relative vapour density at 20 C Relative density Density Solubility Log Pow Viscosity, kinematic Viscosity, dynamic Explosive properties Oxidising properties Explosive limits : Non flammable. : 896,9 C : insoluble in water. : 146 C 9.2. Other information Other properties : See Product Data Sheet for detailed information. SECTION 10: Stability and reactivity Reactivity Chemical stability Not established Possibility of hazardous reactions Not established Conditions to avoid Direct sunlight. Extremely high or low temperatures Incompatible materials Strong acids. Strong bases Hazardous decomposition products fume. Carbon monoxide. Carbon dioxide. SECTION 11: Toxicological information Information on toxicological effects Acute toxicity SN 500 ( ) LD50 oral (rat) Mineral oil LD50 oral (rat) LD50 dermal (rabbit) LC50 inhalation (rat) (Vapours - mg/l/4h) Irritation Corrosivity Sensitisation Repeated dose toxicity Carcinogenicity Mutagenicity Toxicity for reproduction Potential adverse human health effects and symptoms 5000 mg/kg > 5000 mg/kg > 5000 mg/kg > 5000 mg/l/4h : Based on available data, the classification criteria are not met EN (English) 5/8

6 SECTION 12: Ecological information Toxicity SN 500 ( ) LC50 fish 1 Mineral oil LC50 fish 1 LC50 other aquatic organisms 1 16 mg/l 96 Hrs 16 mg/l 0,1 mg/l Persistence and degradability MONO ENGINE OIL CF 40 Persistence and degradability Mineral oil Biodegradation Bioaccumulative potential MONO ENGINE OIL CF 40 Bioaccumulative potential Not established. 31 % 28 Days OECD TG 301 B Not established Mobility in soil Results of PBT and vpvb assessment Other adverse effects Additional information : Avoid release to the environment SECTION 13: Disposal considerations Waste treatment methods Waste disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Ecology - waste materials : Avoid release to the environment. SECTION 14: Transport information In accordance with ADR / RID / IMDG / IATA / ADN UN number Not regulated for transport UN proper shipping name Proper Shipping Name (ADR) Proper Shipping Name (IMDG) Proper Shipping Name (IATA) Proper Shipping Name (ADN) Proper Shipping Name (RID) Transport hazard class(es) ADR Transport hazard class(es) (ADR) IMDG Transport hazard class(es) (IMDG) IATA Transport hazard class(es) (IATA) ADN Transport hazard class(es) (ADN) RID Transport hazard class(es) (RID) Packing group Packing group (ADR) EN (English) 6/8

7 Packing group (IMDG) Packing group (IATA) Packing group (ADN) Packing group (RID) Environmental hazards Dangerous for the environment Marine pollutant Other information : No : No : No supplementary information available Special precautions for user - Overland transport - Transport by sea - Air transport - Inland waterway transport - Rail transport Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture EU-Regulations Contains no REACH substances with Annex XVII restrictions Contains no substance on the REACH candidate list Contains no REACH Annex XIV substances National regulations Germany VwVwS Annex reference 12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV Netherlands Ministry's list of carcinogens Ministry's list of mutagens NON-exhaustive list of reproductive toxins - Breastfeeding NON-exhaustive list of reproductive toxins - Fertility NON-exhaustive list of reproductive toxins - Evolution Denmark Classification remarks : Water hazard class (WGK) 3, severe hazard to waters (Classification according to VwVwS, Annex 4) : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance) : Emergency management guidelines for the storage of flammable liquids must be followed Chemical safety assessment No chemical safety assessment has been carried out SECTION 16: Other information EN (English) 7/8

8 Data sources Other information : REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006. : None. Full text of R-, H- and EUH-statements: Asp. Tox. 1 Aspiration hazard, Category 1 H304 May be fatal if swallowed and enters airways SDS EU (REACH Annex II) DISCLAIMER OF LIABILITY The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness EN (English) 8/8