: 3-(1,3-DIMETHYLBUTYLIDENE)AMINOPROPYLTRIETHOXYSILANE, tech-95

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1 SID (1,3-DIMETHYLBUTYLIDENE)AMINOPROPYLTRIETHOXYSILANE, 3-(1,3- DIMETHYLBUTYLIDENE)AMINOPROPYLTRIETHOXYSILANE, tech- 95 SID Date of issue: 27/04/2015 Revision date: 25/09/2015 Version: 1.1 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form Physical state Substance name Product code Formula Synonyms Chemical family : Substance : Liquid : 3-(1,3-DIMETHYLBUTYLIDENE)AMINOPROPYLTRIETHOXYSILANE, : SID : C15H33NO3Si : 3-(TRIETHOXYSILYL)-N-(1,3-DIMETHYLBUTYLIDENE)PROPYLAMINE : ORGANOSILANE 1.2. Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Use of the substance/mixture Uses advised against 1.3. Details of the supplier of the safety data sheet : Chemical intermediate GELEST, INC. 11 East Steel Road Morrisville, PA USA T F (M-F): 8:00 AM - 5:30 PM EST info@gelest.com - GELEST INC. Fritz-Klatte-Strasse Frankfurt Germany T +49 (0) F +49 (0) (M-F): 8:00 AM - 4:00 PM info@gelestde.com Emergency telephone number Emergency number SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP] Skin corrosion/irritation, Category 2 H315 Serious eye damage/eye irritation, Category H319 2 Specific target organ toxicity Single H335 exposure, Category 3, Respiratory tract irritation Full text of H statements : see section 16 : CHEMTREC: (USA); (International) Adverse physicochemical, human health and environmental effects 2.2. Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP] Hazard pictograms (CLP) : GHS07 Print date: 04/09/2018 EN (English) SDS ID: SID /10

2 Signal word (CLP) Hazard statements (CLP) Precautionary statements (CLP) : Warning : H315 - Causes skin irritation. H319 - Causes serious eye irritation. H335 - May cause respiratory irritation. : P280 - Wear protective gloves/protective clothing/eye protection/face protection. P261 - Avoid breathing vapours. P264 - Wash hands thoroughly after handling. P302+P352 - IF ON SKIN: Wash with plenty of water. P304+P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing. P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing Other hazards SECTION 3: Composition/information on ingredients 3.1. Substances Substance type : Multi-constituent Name : 3-(1,3-DIMETHYLBUTYLIDENE)AMINOPROPYLTRIETHOXYSILANE, CAS-No. : Name Product identifier % Classification according to Regulation (EC) No. 1272/2008 [CLP] 3-(1,3-Dimethylbutylidene)aminopropyltriethoxysilane (CAS-No.) Skin Irrit. 2, H315 Eye Irrit. 2, H319 STOT SE 3, H335 3-(1,3-Dimethylbutylidene)aminopropyltriethoxysilane, oligomeric hydrolysate 4-Methyl-2-pentanone (CAS-No.) (EC-No.) (EC Index-No.) (CAS-No.) Skin Irrit. 2, H315 Eye Irrit. 2, H319 STOT SE 3, H Flam. Liq. 2, H225 Acute Tox. 4 (Inhalation), H332 Eye Irrit. 2, H319 STOT SE 3, H335 Full text of H-statements: see section Mixtures Not applicable SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : Remove contaminated clothing and shoes. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). If possible show this sheet; if not available show packaging or label. : Remove person to fresh air and keep comfortable for breathing. If you feel unwell, seek medical advice. : Wash with plenty of water/. Get medical advice/attention. : Immediately flush eyes thoroughly with water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical advice/attention. : Never give anything by mouth to an unconscious person. Get medical advice/attention Most important symptoms and effects, both acute and delayed Symptoms/effects : Suspected of causing cancer. Symptoms/effects after inhalation : May cause respiratory irritation. Symptoms/effects after skin contact : Causes skin irritation. Symptoms/effects after eye contact : Causes serious eye irritation. Symptoms/effects after ingestion : May be harmful if swallowed Indication of any immediate medical attention and special treatment needed SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Water spray. Foam. Carbon dioxide. Dry chemical. Print date: 04/09/2018 EN (English) SDS ID: SID /10

3 Unsuitable extinguishing media : Do not use straight streams Special hazards arising from the substance or mixture Fire hazard : Irritating fumes and organic acid vapors may develop when material is exposed to elevated temperatures or open flame Advice for firefighters Firefighting instructions Protection during firefighting : Use water spray to cool exposed surfaces. Exercise caution when fighting any chemical fire. : Do not enter fire area without proper protective equipment, including respiratory protection. Avoid all eye and skin contact and do not breathe vapour and mist. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures For non-emergency personnel Protective equipment : Wear protective equipment as described in Section 8. Emergency procedures : Evacuate unnecessary personnel For emergency responders Protective equipment : Do not attempt to take action without suitable protective equipment. Equip cleanup crew with proper protection. For further information refer to section 8: "Exposure controls/personal protection" Environmental precautions Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters Methods and material for containment and cleaning up For containment Methods for cleaning up 6.4. Reference to other sections See Heading 8. Exposure controls and personal protection. : Contain any spills with dikes or absorbents to prevent migration and entry into sewers or streams. : Clean up any spills as soon as possible, using an absorbent material to collect it. Sweep or shovel spills into appropriate container for disposal. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling Hygiene measures : Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Avoid all eye and skin contact and do not breathe vapour and mist. Use only outdoors or in a well-ventilated area. : Wash contaminated clothing before reuse. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work Conditions for safe storage, including any incompatibilities Storage conditions : Keep container tightly closed. Store locked up. Incompatible materials : Acids. alcohols. Oxidizing agent. Peroxides. Moisture. Water : Storage area 7.3. Specific end use(s) SECTION 8: Exposure controls/personal protection 8.1. Control parameters : Store in a well-ventilated place. Store away from heat. EU IOELV TWA (mg/m³) 83 mg/m³ EU IOELV TWA (ppm) 20 ppm EU IOELV STEL (mg/m³) 208 mg/m³ EU IOELV STEL (ppm) 50 ppm Austria MAK (mg/m³) 83 mg/m³ Austria MAK (ppm) 20 ppm Austria MAK Short time value (mg/m³) 208 mg/m³ Austria MAK Short time value (ppm) 50 ppm Belgium Limit value (mg/m³) 83 mg/m³ Belgium Limit value (ppm) 20 ppm Belgium Short time value (mg/m³) 208 mg/m³ Belgium Short time value (ppm) 50 ppm Print date: 04/09/2018 EN (English) SDS ID: SID /10

4 Bulgaria OEL TWA (mg/m³) 50 mg/m³ Bulgaria OEL STEL (mg/m³) 200 mg/m³ Cyprus OEL TWA (mg/m³) 83 mg/m³ Cyprus OEL TWA (ppm) 20 ppm Cyprus OEL STEL (mg/m³) 208 mg/m³ Cyprus OEL STEL (ppm) 50 ppm France VLE (mg/m³) 208 mg/m³ (restrictive limit) France VLE (ppm) 50 ppm (restrictive limit) France VME (mg/m³) 83 mg/m³ (restrictive limit) France VME (ppm) 20 ppm (restrictive limit) Germany TRGS 900 Occupational exposure limit value (mg/m³) 83 mg/m³ Germany TRGS 900 Occupational exposure limit value (ppm) 20 ppm Germany TRGS 903 Biological limit value 3.5 mg/l (Medium: urine - Time: end of shift - Parameter: 4-Methylpentan-2-one) Gibraltar Eight hours mg/m3 83 mg/m³ Gibraltar Eight hours ppm 20 ppm Gibraltar Short-term mg/m3 208 mg/m³ Gibraltar Short-term ppm 50 ppm Greece OEL TWA (mg/m³) 410 mg/m³ Greece OEL TWA (ppm) 100 ppm Greece OEL STEL (mg/m³) 410 mg/m³ Greece OEL STEL (ppm) 100 ppm Italy - Portugal - USA ACGIH ACGIH TWA (ppm) 20 ppm Italy - Portugal - USA ACGIH ACGIH STEL (ppm) 75 ppm Italy OEL TWA (mg/m³) 83 mg/m³ Italy OEL TWA (ppm) 20 ppm Italy OEL STEL (mg/m³) 208 mg/m³ Italy OEL STEL (ppm) 50 ppm Latvia OEL TWA (mg/m³) 83 mg/m³ Latvia OEL TWA (ppm) 20 ppm USA IDLH US IDLH (ppm) 500 ppm USA NIOSH NIOSH REL (TWA) (mg/m³) 205 mg/m³ USA NIOSH NIOSH REL (TWA) (ppm) 50 ppm USA NIOSH NIOSH REL (STEL) (mg/m³) 300 mg/m³ USA NIOSH NIOSH REL (STEL) (ppm) 75 ppm USA OSHA OSHA PEL (TWA) (mg/m³) 410 mg/m³ USA OSHA OSHA PEL (TWA) (ppm) 100 ppm Spain VLA-ED (mg/m³) 83 mg/m³ (indicative limit value) Spain VLA-ED (ppm) 20 ppm (indicative limit value) Spain VLA-EC (mg/m³) 208 mg/m³ Spain VLA-EC (ppm) 50 ppm Switzerland KZGW (mg/m³) 164 mg/m³ Switzerland KZGW (ppm) 40 ppm Switzerland MAK (mg/m³) 82 mg/m³ Switzerland MAK (ppm) 20 ppm Netherlands Grenswaarde TGG 8H (mg/m³) 104 mg/m³ Netherlands Grenswaarde TGG 15MIN (mg/m³) 208 mg/m³ United Kingdom WEL TWA (mg/m³) 208 mg/m³ United Kingdom WEL TWA (ppm) 50 ppm United Kingdom WEL STEL (mg/m³) 416 mg/m³ United Kingdom WEL STEL (ppm) 100 ppm Czech Republic Expoziční limity (PEL) (mg/m³) 80 mg/m³ Denmark Grænseværdie (langvarig) (mg/m³) 83 mg/m³ Denmark Grænseværdie (langvarig) (ppm) 20 ppm Print date: 04/09/2018 EN (English) SDS ID: SID /10

5 Finland HTP-arvo (8h) (mg/m³) 80 mg/m³ Finland HTP-arvo (8h) (ppm) 20 ppm Finland HTP-arvo (15 min) 210 mg/m³ Finland HTP-arvo (15 min) (ppm) 50 ppm Hungary AK-érték 83 mg/m³ Hungary CK-érték 208 mg/m³ Ireland OEL (8 hours ref) (mg/m³) 83 mg/m³ Ireland OEL (8 hours ref) (ppm) 20 ppm Ireland OEL (15 min ref) (mg/m3) 208 mg/m³ Ireland OEL (15 min ref) (ppm) 50 ppm Lithuania IPRV (mg/m³) 83 mg/m³ Lithuania IPRV (ppm) 20 ppm Lithuania TPRV (mg/m³) 208 mg/m³ Lithuania TPRV (ppm) 50 ppm Malta OEL TWA (mg/m³) 83 mg/m³ Malta OEL TWA (ppm) 20 ppm Malta OEL STEL (mg/m³) 208 mg/m³ Malta OEL STEL (ppm) 50 ppm Norway Grenseverdier (AN) (mg/m³) 83 mg/m³ Norway Grenseverdier (AN) (ppm) 20 ppm Norway Grenseverdier (Korttidsverdi) (mg/m3) 83 mg/m³ Norway Grenseverdier (Korttidsverdi) (ppm) 20 ppm Poland NDS (mg/m³) 83 mg/m³ Poland NDSCh (mg/m³) 200 mg/m³ Romania OEL TWA (mg/m³) 200 mg/m³ 83 mg/m³ (regulated under 4-Methylpentan-2-one) Romania OEL TWA (ppm) 47 ppm 20 ppm (regulated under 4-Methylpentan-2-one) Romania OEL STEL (mg/m³) 300 mg/m³ 208 mg/m³ (regulated under 4-Methylpentan-2-one) Romania OEL STEL (ppm) 71 ppm 50 ppm (regulated under 4-Methylpentan-2-one) Slovakia NPHV (priemerná) (mg/m³) 83 mg/m³ Slovakia NPHV (priemerná) (ppm) 20 ppm Slovakia NPHV (Hraničná) (mg/m³) 166 mg/m³ Sweden nivågränsvärde (NVG) (mg/m³) 100 mg/m³ Sweden nivågränsvärde (NVG) (ppm) 25 ppm Sweden kortidsvärde (KTV) (mg/m³) 200 mg/m³ Sweden kortidsvärde (KTV) (ppm) 50 ppm Canada (Quebec) VECD (mg/m³) 307 mg/m³ Canada (Quebec) VECD (ppm) 75 ppm Canada (Quebec) VEMP (mg/m³) 205 mg/m³ Canada (Quebec) VEMP (ppm) 50 ppm Australia TWA (mg/m³) 205 mg/m³ Australia TWA (ppm) 50 ppm Australia STEL (mg/m³) 307 mg/m³ Australia STEL (ppm) 75 ppm Portugal OEL TWA (mg/m³) 83 mg/m³ (indicative limit value) Portugal OEL TWA (ppm) 20 ppm (indicative limit value) Portugal OEL STEL (mg/m³) 208 mg/m³ (indicative limit value) Portugal OEL STEL (ppm) 50 ppm (indicative limit value) Print date: 04/09/2018 EN (English) SDS ID: SID /10

6 8.2. Exposure controls Appropriate engineering controls: Provide local exhaust or general room ventilation. Personal protective equipment: Avoid all unnecessary exposure. Emergency eye wash fountains and safety showers should be available in the immediate vicinity of any potential exposure. Hand protection: Neoprene or nitrile rubber gloves Eye protection: Chemical goggles. Contact lenses should not be worn Skin and body protection: Wear suitable protective clothing Respiratory protection: Where exposure through inhalation may occur from use, respiratory protection equipment is recommended. NIOSH-certified combination organic vapor - amine gas (brown cartridge) respirator. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state Appearance Molecular mass Colour Odour Odour threshold : Liquid : Liquid. : g/mol Refractive index : ph Relative evaporation rate (butylacetate=1) : < 1 Melting point : Straw. Amber. Freezing point : < 0 C Boiling point Flash point : 131 C Auto-ignition temperature Decomposition temperature Flammability (solid, gas) : Mild. Amine. Ammonia-like. : mm Hg Vapour pressure : < 1 mm 25 C Relative vapour density at 20 C : > 1 Relative density : 0.93 % Volatiles : < 40 % Solubility Log Pow Log Kow Viscosity, kinematic Viscosity, dynamic Explosive properties Oxidising properties Explosive limits 9.2. Other information SECTION 10: Stability and reactivity Reactivity : Reacts with water. Print date: 04/09/2018 EN (English) SDS ID: SID /10

7 10.2. Chemical stability Stable when stored in sealed containers Possibility of hazardous reactions Reacts with water and moisture in air, liberating ethanol Conditions to avoid Heat. Open flame. Sparks Incompatible materials Acids. alcohols. Oxidizing agent. Peroxides. Moisture. Water : Hazardous decomposition products Organic amine vapors. SECTION 11: Toxicological information Information on toxicological effects Acute toxicity LD50 oral rat LD50 dermal rabbit LC50 inhalation rat (mg/l) Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity IARC group National Toxicology Program (NTP) Status Reproductive toxicity STOT-single exposure STOT-repeated exposure Aspiration hazard Symptoms/effects after inhalation Symptoms/effects after skin contact Symptoms/effects after eye contact Symptoms/effects after ingestion Reason for classification SECTION 12: Ecological information Toxicity Acute aquatic toxicity Chronic aquatic toxicity LC50 fish 1 EC50 Daphnia mg/kg 3000 mg/kg mg/l/4h : Causes skin irritation. : Causes serious eye irritation. 2B - Possibly carcinogenic to humans 1 - Evidence of Carcinogenicity : May cause respiratory irritation. : May cause respiratory irritation. : Causes skin irritation. : Causes serious eye irritation. : May be harmful if swallowed. : Expert judgment mg/l (Exposure time: 96 h - Species: Pimephales promelas [flow-through]) 170 mg/l (Exposure time: 48 h - Species: Daphnia magna) Persistence and degradability Bioaccumulative potential Log Pow Mobility in soil Results of PBT and vpvb assessment Print date: 04/09/2018 EN (English) SDS ID: SID /10

8 12.6. Other adverse effects Other adverse effects : This substance may be hazardous to the environment. SECTION 13: Disposal considerations Waste treatment methods Sewage disposal recommendations Product/Packaging disposal recommendations Ecology - waste materials SECTION 14: Transport information UN number In accordance with ADR / RID / IMDG / IATA / ADN : Do not dispose of waste into sewer. : May be incinerated. Dispose in a safe manner in accordance with local/national regulations. Dispose of contents/container to licensed waste disposal facility. : Avoid release to the environment UN number UN-No. (ADR) UN-No. (IMDG) UN-No. (IATA) UN-No. (ADN) UN-No. (RID) UN proper shipping name Proper Shipping Name (ADR) Proper Shipping Name (IMDG) Proper Shipping Name (IATA) Proper Shipping Name (ADN) Proper Shipping Name (RID) Transport hazard class(es) ADR Transport hazard class(es) (ADR) IMDG Transport hazard class(es) (IMDG) IATA Transport hazard class(es) (IATA) ADN Transport hazard class(es) (ADN) RID Transport hazard class(es) (RID) Packing group Packing group (ADR) Packing group (IMDG) Packing group (IATA) Packing group (ADN) Packing group (RID) Environmental hazards Dangerous for the environment Marine pollutant Other information : No : No : No supplementary information available Special precautions for user - Overland transport No data available Print date: 04/09/2018 EN (English) SDS ID: SID /10

9 - Transport by sea No data available - Air transport No data available - Inland waterway transport No data available - Rail transport No data available Transport in bulk according to Annex II of Marpol and the IBC Code Not applicable SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture EU-Regulations No REACH Annex XVII restrictions 3-(1,3-DIMETHYLBUTYLIDENE)AMINOPROPYLTRIETHOXYSILANE, is not on the REACH Candidate List 3-(1,3-DIMETHYLBUTYLIDENE)AMINOPROPYLTRIETHOXYSILANE, is not on the REACH Annex XIV List % Volatiles : < 40 % National regulations Germany 12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV Netherlands SZW-lijst van kankerverwekkende stoffen SZW-lijst van mutagene stoffen NIET-limitatieve lijst van voor de voortplanting giftige stoffen Borstvoeding NIET-limitatieve lijst van voor de voortplanting giftige stoffen Vruchtbaarheid NIET-limitatieve lijst van voor de voortplanting giftige stoffen Ontwikkeling Denmark Danish National Regulations : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance) : The substance is not listed : The substance is not listed : The substance is not listed : The substance is not listed : The substance is not listed : Young people below the age of 18 years are not allowed to use the product Chemical safety assessment SECTION 16: Other information Abbreviations and acronyms: Abbreviations: ND: Not Determined, No Data; NA: Not Applicable; LD: Lethal Dose; LC: Lethal Concentration; ATE: Acute Toxicity Estimates; H: hour; : C unless otherwise stated; mm: millimeters Hg, torr; PEL: permissible exposure level; TWA: time weighted average; TLV: threshold limit value; TG: Test Guideline; NIOSH: National Institute for Occupational Safety and Health; IARC: International Agency for Research on Cancer; NTP: National Toxicology Program; HMIS: Hazardous Material Information System; CAS No.: Chemcial Abstract Service Registration Number; EC No.: European Commission Registration Number; EC Index No.: European Commission Index Number; OECD: The Organisation for Economic Co-operation and Development; GHS: The Globally Harmonized System of Classification and Labelling; APF: Assigned Protection Factor Other information : Prepared by safety and environmental affairs. Full text of H- and EUH-statements: Acute Tox. 4 (Inhalation) Acute toxicity (inhal.), Category 4 Eye Irrit. 2 Serious eye damage/eye irritation, Category 2 Flam. Liq. 2 Flammable liquids, Category 2 Skin Irrit. 2 Skin corrosion/irritation, Category 2 Print date: 04/09/2018 EN (English) SDS ID: SID /10

10 STOT SE 3 H225 H315 H319 H332 H335 Specific target organ toxicity Single exposure, Category 3, Respiratory tract irritation Highly flammable liquid and vapour. Causes skin irritation. Causes serious eye irritation. Harmful if inhaled. May cause respiratory irritation. SDS EU (REACH Annex II) - Custom The information contained in this document has been gathered from reference materials and/or Gelest, Inc. test data and is to the best knowledge and belief of Gelest, Inc. accurate and reliable. Such information is offered solely for your consideration, investigation and verification. It is not suggested or guaranteed that the hazard precautions or procedures described are the only ones which exist. Gelest, Inc. makes no warranties, express or implied, with respect to the use of such information and assumes no responsibility therefore. Information on this safety data sheet is not intended to constitute a basis for product specifications Gelest Inc. Morrisville, PA Print date: 04/09/2018 EN (English) SDS ID: SID /10