ENGINE OIL SHPD 10W-30

Transcription

1 Date of issue: Revision date: supersedes: Version: 2.1 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form : Mixture Product name : ENGINE OIL SHPD 10W-30 Product code : Type of product : Lubricant Product group : Engine oil (lubricant) 1.2. Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Main use category Industrial/Professional use spec Use of the substance/mixture Function or use category : Professional use,industrial use : For professional use only : This oil should not be used for any other purpose than the intended use without expert advice. : Lubricants and additives Uses advised against 1.3. Details of the supplier of the safety data sheet Transnational Blenders B.V. (under license of 77 Lubricants) Wieldrechtseweg BG Dordrecht - Netherlands T +31 (0) info@tnb.nl Emergency telephone number Emergency number : +31 (0) Monday to Friday: 09:00-16:00 (CET) SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP]Mixture/Substance: SDS EU 2015: According to Regulation (EU) 2015/830 (REACH Annex II) Not classified 2.2. Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP] Extra labelling to displayextra classification(s) to display EUH-statements Child-resistant fastening Tactile warning : EUH210 - Safety data sheet available on request EUH208 - Contains Calcium long chain alkaryl sulphonate( ). May produce an allergic reaction : No : No 2.3. Other hazards Adverse physicochemical, human health and environmental effects Other hazards not contributing to the classification : To our knowledge, this product does not present any particular risk, provided it is handled in accordance with good occupational hygiene and safety practice. : Flammable liquids. Prolonged or repeated skin contact with the material will remove natural oils which leads to a dermatitis. Spills of this product present a serious slipping hazard. SECTION 3: Composition/information on ingredients 3.1. Substance Not applicable 3.2. Mixture Comments : Mixture of mineral base oils (PCA-content < 3 % - IP 346) and additives. This product is not considered to be hazardous Note L : The classification as a carcinogen need not apply if it can be shown that the substance contains less than 3 % DMSO extract as measured by IP 346 Determination of polycyclic EN (English) 1/8

2 aromatics in unused lubricating base oils and asphaltene free petroleum fractions Dimethyl sulphoxide extraction refractive index method, Institute of Petroleum, London. This note applies only to certain complex oil-derived substances in Part 3. Name Product identifier % Classification according to Regulation (EC) No. 1272/2008 [CLP] Distillates (petroleum), hydrotreated heavy paraffinic (CAS No) (EC no) (EC index no) >= 75 Asp. Tox. 1, H Asp. Tox. 1, H304 Polyolefine polyamine succinimide, Polyol 1-5 Aquatic Chronic 4, H413 SN 500 substance with a Community workplace exposure limit (CAS No) (EC no) (EC index no) Not classified Polyolefine polyamine succinimide (EC no) POLYMER 1-5 Aquatic Chronic 4, H413 Calcium long chain alkaryl sulphonate (CAS No) ,1-0,5 Skin Sens. 1, H317 Aquatic Chronic 4, H413 Full text of H-statements: see section 16 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : Remove person to fresh air and keep comfortable for breathing. : Wash skin with plenty of water. : Rinse eyes with water as a precaution. : Call a poison center or a doctor if you feel unwell Most important symptoms and effects, both acute and delayed Symptoms/injuries Symptoms/injuries after inhalation Symptoms/injuries after skin contact Symptoms/injuries after eye contact Symptoms/injuries after ingestion 4.3. Indication of any immediate medical attention and special treatment needed Treat symptomatically. SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Water spray. Dry powder. Foam. Carbon dioxide Special hazards arising from the substance or mixture Hazardous decomposition products in case of fire : Toxic fumes may be released Advice for firefighters Protection during firefighting : Do not attempt to take action without suitable protective equipment. Self-contained breathing apparatus. Complete protective clothing. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures For non-emergency personnel Protective equipment Emergency procedures For emergency responders Protective equipment : Eliminate all ignition sources if safe to do so. : Ventilate spillage area. : Do not attempt to take action without suitable protective equipment. Wear suitable protective clothing, gloves and eye/face protection. For further information refer to section 8: "Exposure controls/personal protection" Environmental precautions Avoid release to the environment Methods and material for containment and cleaning up For containment : Contain any spills with dikes or absorbents to prevent migration and entry into sewers or streams EN (English) 2/8

3 Methods for cleaning up Other information : Take up liquid spill into absorbent material. : Dispose of materials or solid residues at an authorized site Reference to other sections For further information refer to section 13. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling Hygiene measures : Ensure good ventilation of the work station. Wear personal protective equipment. : Do not eat, drink or smoke when using this product. Always wash hands after handling the product Conditions for safe storage, including any incompatibilities Storage conditions Storage temperature : 45 C Storage area Special rules on packaging 7.3. Specific end use(s) SECTION 8: Exposure controls/personal protection 8.1. Control parameters : Store in a well-ventilated place. Keep cool. : Store away from heat. Store in a well-ventilated place. : Keep only in original container. Store in a closed container. Distillates (petroleum), hydrotreated heavy paraffinic ( ) EU IOELV TWA (mg/m³) 5 mg/m³ Belgium Limit value (mg/m³) 5 mg/m³ USA - ACGIH ACGIH TWA (mg/m³) 5 mg/m³ USA - ACGIH ACGIH STEL (mg/m³) 10 mg/m³ USA - NIOSH NIOSH REL (TWA) (mg/m³) 5 mg/m³ USA - NIOSH NIOSH REL (STEL) (mg/m³) 10 mg/m³ EU IOELV TWA (mg/m³) 5 mg/m³ EU IOELV STEL (mg/m³) 10 mg/m³ Belgium Limit value (mg/m³) 5 mg/m³ 8 Hrs Belgium Short time value (mg/m³) 10 mg/m³ 15 Min Bulgaria OEL TWA (mg/m³) 5 mg/m³ 8 Hrs Czech Republic Expoziční limity (PEL) (mg/m³) 10 mg/m³ Czech Republic Expoziční limity (NPK-P) (mg/m³) 5 mg/m³ 8 Hrs Denmark Grænseværdie (kortvarig) (mg/m³) 1 mg/m³ Finland HTP-arvo (15 min) 5 mg/m³ 8 Hrs Greece OEL TWA (mg/m³) 5 mg/m³ 8 Hrs Hungary CK-érték 5 mg/m³ Ireland OEL (8 hours ref) (mg/m³) 5 mg/m³ 8 Hrs Latvia OEL TWA (mg/m³) 5 mg/m³ 8 Hrs Lithuania IPRV (mg/m³) 1 mg/m³ 8 Hrs Lithuania TPRV (mg/m³) 3 mg/m³ 15 Min Netherlands Grenswaarde TGG 8H (mg/m³) 5 mg/m³ 8 Hrs Portugal OEL TWA (mg/m³) 5 mg/m³ 8 Hrs Portugal OEL STEL (mg/m³) 10 mg/m³ Romania OEL TWA (mg/m³) 5 mg/m³ 8 Hrs Romania OEL STEL (mg/m³) 10 mg/m³ 15 Min Slovakia NPHV (priemerná) (mg/m³) 5 mg/m³ 8 Hrs Spain VLA-ED (mg/m³) 5 mg/m³ 8 Hrs Spain VLA-EC (mg/m³) 10 mg/m³ 15 Min Sweden nivågränsvärde (NVG) (mg/m³) 1 mg/m³ Sweden kortidsvärde (KTV) (mg/m³) 3 mg/m³ United Kingdom WEL TWA (mg/m³) 500 mg/m³ Norway Grenseverdier (AN) (mg/m³) 1 mg/m³ EN (English) 3/8

4 USA - OSHA OSHA PEL (TWA) (mg/m³) 5 mg/m³ SN 500 ( ) EU IOELV TWA (mg/m³) 5 mg/m³ 8 HRS EU IOELV STEL (mg/m³) 10 mg/m³ 15 min Austria MAK (mg/m³) 5 mg/m³ Belgium Limit value (mg/m³) 5 mg/m³ 8 HRS Belgium Short time value (mg/m³) 10 mg/m³ 15 MIN Bulgaria OEL TWA (mg/m³) 5 mg/m³ 8 HRS Czech Republic Expoziční limity (PEL) (mg/m³) 10 mg/m³ Czech Republic Expoziční limity (NPK-P) (mg/m³) 5 mg/m³ 8 HRS Denmark Grænseværdie (langvarig) (mg/m³) 1 Denmark Grænseværdie (kortvarig) (mg/m³) 2 mg/m³ Finland HTP-arvo (8h) (mg/m³) 5 mg/m³ 8 Hrs Greece OEL TWA (mg/m³) 5 mg/m³ 8 hrs Hungary AK-érték < 5 mg/m³ Hungary CK-érték 0 mg/m³ Ireland OEL (8 hours ref) (mg/m³) 5 mg/m³ 8 Hrs Italy OEL STEL (mg/m³) 10 mg/m³ Latvia OEL TWA (mg/m³) 5 mg/m³ 8 Hrs Lithuania IPRV (mg/m³) 3 mg/m³ 15 min Lithuania TPRV (mg/m³) 1 mg/m³ 8 Hrs Netherlands Grenswaarde TGG 8H (mg/m³) 5 mg/m³ 8 Hrs Poland NDS (mg/m³) 5 mg/m³ 8 hrs Poland NDSP (mg/m³) 10 mg/m³ 15 minutes Portugal OEL TWA (mg/m³) 5 mg/m³ 8 Hrs Portugal OEL STEL (mg/m³) 10 mg/m³ Romania OEL TWA (mg/m³) 5 mg/m³ 8 Hrs Romania OEL STEL (mg/m³) 10 mg/m³ 15 min Slovakia NPHV (priemerná) (mg/m³) 5 mg/m³ 8 hrs Spain VLA-ED (mg/m³) 5 mg/m³ 8 Hrs Spain VLA-EC (mg/m³) 10 mg/m³ 15 min Sweden nivågränsvärde (NVG) (mg/m³) 1 mg/m³ Sweden kortidsvärde (KTV) (mg/m³) 3 mg/m³ United Kingdom WEL TWA (mg/m³) 5 mg/m³ 8 Hrs Norway Grenseverdier (AN) (mg/m³) 1 mg/m³ Australia TWA (mg/m³) 5 mg/m³ 8 Hrs Canada (Quebec) VECD (mg/m³) 10 mg/m³ Canada (Quebec) VEMP (mg/m³) 5 mg/m³ USA - ACGIH ACGIH TWA (mg/m³) >= mg/m³ USA - OSHA OSHA PEL (TWA) (mg/m³) 5 mg/m³ 8.2. Exposure controls Appropriate engineering controls Personal protective equipment : Ensure good ventilation of the work station. : Gloves. Safety glasses. Protective clothing EN (English) 4/8

5 Hand protection Eye protection Skin and body protection Respiratory protection : Protective gloves : Safety glasses : Wear suitable protective clothing : In case of insufficient ventilation, wear suitable respiratory equipment Environmental exposure controls : Avoid release to the environment. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Appearance : Characteristics. Colour Odour : Characteristics. Odour threshold ph Relative evaporation rate (butylacetate=1) Melting point Freezing point : -36 C Boiling point Flash point : > 215 C Auto-ignition temperature Decomposition temperature Flammability (solid, gas) Vapour pressure Relative vapour density at 20 C Relative density Density : 872,7 C Solubility : Insoluble in water. Log Pow Viscosity, kinematic : 78 C Viscosity, dynamic Explosive properties Oxidising properties Explosive limits 9.2. Other information Other properties : See Product Data Sheet for detailed information. SECTION 10: Stability and reactivity Reactivity The product is non-reactive under normal conditions of use, storage and transport Chemical stability Stable under normal conditions Possibility of hazardous reactions No dangerous reactions known under normal conditions of use Conditions to avoid None under recommended storage and handling conditions (see section 7) Incompatible materials Hazardous decomposition products Under normal conditions of storage and use, hazardous decomposition products should not be produced EN (English) 5/8

6 SECTION 11: Toxicological information Information on toxicological effects Acute toxicity Distillates (petroleum), hydrotreated heavy paraffinic ( ) LD50 oral (rat) > 5000 mg/kg LD50 dermal (rabbit) > 2000 mg/kg LD50 oral (rat) LD50 dermal (rabbit) LC50 inhalation (rat) (Vapours - mg/l/4h) SN 500 ( ) LD50 oral (rat) Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity Reproductive toxicity Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Aspiration hazard ENGINE OIL SHPD 10W-30 Viscosity, kinematic > 5000 mg/kg > 5000 mg/kg > 5000 mg/l/4h 5000 mg/kg 78 C SECTION 12: Ecological information Toxicity Ecology - general : The product is not considered harmful to aquatic organisms or to cause long-term adverse effects in the environment. Distillates (petroleum), hydrotreated heavy paraffinic ( ) EC50 Daphnia mg/l LC50 fish 1 LC50 other aquatic organisms 1 SN 500 ( ) LC50 fish 1 16 mg/l 0,1 mg/l 16 mg/l 96 Hrs Persistence and degradability Biodegradation Bioaccumulative potential 31 % 28 Days OECD TG 301 B Distillates (petroleum), hydrotreated heavy paraffinic ( ) Log Kow > Mobility in soil Results of PBT and vpvb assessment Other adverse effects SECTION 13: Disposal considerations Waste treatment methods Waste treatment methods : Dispose of contents/container in accordance with licensed collector s sorting instructions EN (English) 6/8

7 SECTION 14: Transport information In accordance with ADR / RID / IMDG / IATA / ADN UN number Not regulated for transport UN proper shipping name Proper Shipping Name (ADR) Proper Shipping Name (IMDG) Proper Shipping Name (IATA) Proper Shipping Name (ADN) Proper Shipping Name (RID) Transport hazard class(es) ADR Transport hazard class(es) (ADR) IMDG Transport hazard class(es) (IMDG) IATA Transport hazard class(es) (IATA) ADN Transport hazard class(es) (ADN) RID Transport hazard class(es) (RID) Packing group Packing group (ADR) Packing group (IMDG) Packing group (IATA) Packing group (ADN) Packing group (RID) Environmental hazards Dangerous for the environment Marine pollutant Other information : No : No : No supplementary information available Special precautions for user - Overland transport - Transport by sea - Air transport - Inland waterway transport - Rail transport Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture EU-Regulations EN (English) 7/8

8 Contains no REACH substances with Annex XVII restrictions Contains no substance on the REACH candidate list Contains no REACH Annex XIV substances National regulations Germany VwVwS Annex reference 12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV Netherlands Ministry's list of carcinogens Ministry's list of mutagens NON-exhaustive list of reproductive toxins - Breastfeeding NON-exhaustive list of reproductive toxins - Fertility NON-exhaustive list of reproductive toxins - Evolution Denmark Classification remarks : Water hazard class (WGK) 3, severe hazard to waters (Classification according to VwVwS, Annex 4) : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance) : Distillates (petroleum), hydrotreated heavy paraffinic is listed : Distillates (petroleum), hydrotreated heavy paraffinic is listed : None of the components are listed : None of the components are listed : None of the components are listed : Emergency management guidelines for the storage of flammable liquids must be followed Chemical safety assessment No chemical safety assessment has been carried out SECTION 16: Other information Full text of H- and EUH-statements: Aquatic Chronic 4 Hazardous to the aquatic environment Chronic Hazard, Category 4 Asp. Tox. 1 Aspiration hazard, Category 1 Skin Sens. 1 Sensitisation Skin, Category 1 H304 May be fatal if swallowed and enters airways H317 May cause an allergic skin reaction H413 May cause long lasting harmful effects to aquatic life EUH208 Contains. May produce an allergic reaction EUH210 Safety data sheet available on request SDS EU (REACH Annex II) DISCLAIMER OF LIABILITY The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness EN (English) 8/8