: N,N'-BIS[3-(TRIETHOXYSILYL)PROPYL]UREA, 60% in ethanol

Transcription

1 SIB N,N'-BIS[3-(TRIETHOXYSILYL)PROPYL]UREA, 60% in ethanol N,N'-BIS[3-(TRIETHOXYSILYL)PROPYL]UREA, 60% in ethanol SIB Date of issue: 09/03/2016 Version: 1.0 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form : Mixture Physical state : Liquid Product name : N,N'-BIS[3-(TRIETHOXYSILYL)PROPYL]UREA, 60% in ethanol Product code : SIB Formula : C19H44N2O7Si2i Synonyms : UREA, N,N'-BIS[3-(TRIETHOXYSILYL)PROPYL]- Chemical family : ORGANOETHOXYSILANE 1.2. Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Use of the substance/mixture : Chemical intermediate For research use only Uses advised against 1.3. Details of the supplier of the safety data sheet GELEST, INC. 11 East Steel Road Morrisville, PA USA T F (M-F): 8:00 AM - 5:30 PM EST info@gelest.com - GELEST INC. Stroofstrasse 27 Geb Frankfurt am Main Germany T +49-(0) F +49-(0) (M-F): 8:00 AM - 5:30 PM info@gelestde.com Emergency telephone number Emergency number : CHEMTREC: (USA); (International) SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP] Flam. Liq. 2 H225 Skin Irrit. 2 H315 Eye Irrit. 2 H319 Full text of hazard classes and H-statements : see section Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP] Hazard pictograms (CLP) : Signal word (CLP) Hazard statements (CLP) Precautionary statements (CLP) : Danger GHS02 GHS07 : H225 - Highly flammable liquid and vapour H315 - Causes skin irritation H319 - Causes serious eye irritation : P280 - Wear protective gloves/protective clothing/eye protection/face protection P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No 09/03/2016 EN (English) SDS ID: SIB /9

2 smoking P240 - Ground/bond container and receiving equipment P264 - Wash hands thoroughly after handling P303+P361+P353 - IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing 2.3. Other hazards Other hazards not contributing to the classification : Overexposure to ethanol by skin absorption, inhalation or ingestion may have a narcotic effect (headache, nausea, drowsiness). Ethanol is metabolized to acetaldehyde and acetic acid which in large quantities result in metabolic acidosis, CNS depression and death due to respiratory arrest. This product contains ethanol which is classified as a carcinogen by IARC in alcoholic beverages. SECTION 3: Composition/information on ingredients 3.1. Substance Not applicable 3.2. Mixture Name Product identifier % Classification according to Regulation (EC) No. 1272/2008 [CLP] N,N'-Bis[3-(triethoxysilyl)propyl]urea (CAS No) > 60 Skin Irrit. 2, H315 Eye Irrit. 2, H319 STOT SE 3, H335 Ethanol (CAS No) (EC no) (EC index no) Full text of H-statements: see section 16 < 40 Flam. Liq. 2, H225 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : Remove contaminated clothing and shoes. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). If possible show this sheet; if not available show packaging or label. : Remove victim to fresh air and keep at rest in a position comfortable for breathing. Get medical advice/attention if you feel unwell. : Wash with plenty of soap and water. Get medical advice/attention. : Immediately flush eyes thoroughly with water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical advice/attention. : Never give anything by mouth to an unconscious person. Immediately call a POISON CENTER or doctor/physician Most important symptoms and effects, both acute and delayed Symptoms/injuries after inhalation Symptoms/injuries after skin contact Symptoms/injuries after eye contact Symptoms/injuries after ingestion : May cause respiratory irritation. Overexposure may cause: Cough. Headache. Nausea. : Causes skin irritation. : Causes serious eye irritation. : May be harmful if swallowed Indication of any immediate medical attention and special treatment needed SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media Unsuitable extinguishing media : Water spray. Foam. Carbon dioxide. Dry chemical. : Do not use straight streams Special hazards arising from the substance or mixture Fire hazard Explosion hazard : Highly flammable liquid and vapour. Irritating fumes and organic acid vapors may develop when material is exposed to elevated temperatures or open flame. : May form flammable/explosive vapour-air mixture Advice for firefighters Firefighting instructions : Exercise caution when fighting any chemical fire. Use water spray to cool exposed surfaces. 09/03/2016 EN (English) SDS ID: SIB /9

3 Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection. Avoid all eye and skin contact and do not breathe vapour and mist. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures General measures : Eliminate every possible source of ignition. Use special care to avoid static electric charges For non-emergency personnel Protective equipment : Wear protective equipment as described in Section 8. Emergency procedures : Evacuate unnecessary personnel For emergency responders Protective equipment : Do not attempt to take action without suitable protective equipment. Equip cleanup crew with proper protection. For further information refer to section 8: "Exposure controls/personal protection" Environmental precautions Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters. Avoid release to the environment Methods and material for containment and cleaning up For containment Methods for cleaning up 6.4. Reference to other sections See Heading 8. Exposure controls and personal protection. : Contain any spills with dikes or absorbents to prevent migration and entry into sewers or streams. : Clean up any spills as soon as possible, using an absorbent material to collect it. Sweep or shovel spills into appropriate container for disposal. Use only non-sparking tools. SECTION 7: Handling and storage 7.1. Precautions for safe handling Additional hazards when processed Precautions for safe handling Hygiene measures : Handle empty containers with care because residual vapours are flammable. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. : Avoid all eye and skin contact and do not breathe vapour and mist. Ground/bond container and receiving equipment. Take precautionary measures against static discharge. Use only outdoors or in a well-ventilated area. Use only non-sparking tools. : Wash contaminated clothing before reuse. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work Conditions for safe storage, including any incompatibilities Technical measures Storage conditions Incompatible materials Storage area 7.3. Specific end use(s) SECTION 8: Exposure controls/personal protection 8.1. Control parameters : Proper grounding procedures to avoid static electricity should be followed. Use explosion-proof ventilating equipment. : Keep container tightly closed. Keep in a cool place. Store locked up. : Acids. alcohols. Oxidizing agent. Peroxides. : Store in a well-ventilated place. Store away from heat. Austria MAK (mg/m³) 1900 mg/m³ Austria MAK (ppm) 1000 ppm Austria MAK Short time value (mg/m³) 3800 mg/m³ Austria MAK Short time value (ppm) 2000 ppm Belgium Limit value (mg/m³) 1907 mg/m³ Belgium Limit value (ppm) 1000 ppm Bulgaria OEL TWA (mg/m³) 1000 mg/m³ France VLE (mg/m³) 9500 mg/m³ France VLE (ppm) 5000 ppm France VME (mg/m³) 1900 mg/m³ France VME (ppm) 1000 ppm Germany TRGS 900 Occupational exposure limit value (mg/m³) 960 mg/m³ (The risk of damage to the embryo or fetus can be excluded when AGW and BGW values are observed) 09/03/2016 EN (English) SDS ID: SIB /9

4 Germany TRGS 900 Occupational exposure limit value (ppm) 500 ppm (The risk of damage to the embryo or fetus can be excluded when AGW and BGW values are observed) Greece OEL TWA (mg/m³) 1900 mg/m³ Greece OEL TWA (ppm) 1000 ppm Italy - Portugal - USA ACGIH ACGIH STEL (ppm) 1000 ppm Latvia OEL TWA (mg/m³) 1000 mg/m³ USA IDLH US IDLH (ppm) 3300 ppm (10% LEL) USA NIOSH NIOSH REL (TWA) (mg/m³) 1900 mg/m³ USA NIOSH NIOSH REL (TWA) (ppm) 1000 ppm USA OSHA OSHA PEL (TWA) (mg/m³) 1900 mg/m³ USA OSHA OSHA PEL (TWA) (ppm) 1000 ppm Spain VLA-EC (mg/m³) 1910 mg/m³ Spain VLA-EC (ppm) 1000 ppm Switzerland VLE (mg/m³) 1920 mg/m³ Switzerland VLE (ppm) 1000 ppm Switzerland VME (mg/m³) 960 mg/m³ Switzerland VME (ppm) 500 ppm Netherlands Grenswaarde TGG 8H (mg/m³) 260 mg/m³ Netherlands Grenswaarde TGG 15MIN (mg/m³) 1900 mg/m³ United Kingdom WEL TWA (mg/m³) 1920 mg/m³ United Kingdom WEL TWA (ppm) 1000 ppm United Kingdom WEL STEL (mg/m³) 5760 mg/m³ (calculated) United Kingdom WEL STEL (ppm) 3000 ppm (calculated) Czech Republic Expoziční limity (PEL) (mg/m³) 1000 mg/m³ Denmark Grænseværdie (langvarig) (mg/m³) 1900 mg/m³ Denmark Grænseværdie (langvarig) (ppm) 1000 ppm Finland HTP-arvo (8h) (mg/m³) 1900 mg/m³ Finland HTP-arvo (8h) (ppm) 1000 ppm Finland HTP-arvo (15 min) 2500 mg/m³ Finland HTP-arvo (15 min) (ppm) 1300 ppm Hungary AK-érték 1900 mg/m³ Hungary CK-érték 7600 mg/m³ Ireland OEL (15 min ref) (ppm) 1000 ppm Lithuania IPRV (mg/m³) 1000 mg/m³ Lithuania IPRV (ppm) 500 ppm Lithuania TPRV (mg/m³) 1900 mg/m³ Lithuania TPRV (ppm) 1000 ppm Norway Grenseverdier (AN) (mg/m³) 950 mg/m³ Norway Grenseverdier (AN) (ppm) 500 ppm Norway Grenseverdier (Korttidsverdi) (mg/m3) 950 mg/m³ Norway Grenseverdier (Korttidsverdi) (ppm) 500 ppm Poland NDS (mg/m³) 1900 mg/m³ Romania OEL TWA (mg/m³) 1900 mg/m³ Romania OEL TWA (ppm) 1000 ppm Romania OEL STEL (mg/m³) 9500 mg/m³ Romania OEL STEL (ppm) 5000 ppm Slovakia NPHV (priemerná) (mg/m³) 960 mg/m³ Slovakia NPHV (priemerná) (ppm) 500 ppm Slovakia NPHV (Hraničná) (mg/m³) 1920 mg/m³ Sweden nivågränsvärde (NVG) (mg/m³) 1000 mg/m³ Sweden nivågränsvärde (NVG) (ppm) 500 ppm 09/03/2016 EN (English) SDS ID: SIB /9

5 Sweden kortidsvärde (KTV) (mg/m³) 1900 mg/m³ Sweden kortidsvärde (KTV) (ppm) 1000 ppm Canada (Quebec) VEMP (mg/m³) 1880 mg/m³ Canada (Quebec) VEMP (ppm) 1000 ppm Australia TWA (mg/m³) 1880 mg/m³ Australia TWA (ppm) 1000 ppm Portugal OEL TWA (ppm) 1000 ppm Portugal OEL chemical category (PT) A4 - Not Classifiable as a Human Carcinogen 8.2. Exposure controls Appropriate engineering controls Personal protective equipment : Provide local exhaust or general room ventilation. : Avoid all unnecessary exposure. Emergency eye wash fountains and safety showers should be available in the immediate vicinity of any potential exposure. Hand protection Eye protection Skin and body protection Respiratory protection : Neoprene or nitrile rubber gloves. : Chemical goggles. Contact lenses should not be worn. : Wear suitable protective clothing. : Where exposure through inhalation may occur from use, respiratory protection equipment is recommended. NIOSH-certified combination organic vapor - amine gas (brown cartridge) respirator. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Appearance : Clear liquid. Molecular mass : g/mol Colour : Straw. Odour : Mild. Ethanol. Odour threshold Refractive index ph Relative evaporation rate (butylacetate=1) Melting point Freezing point : < 0 C Boiling point : 76 C (initial, ethanol) Flash point : 17 C Auto-ignition temperature Decomposition temperature Flammability (solid, gas) : Highly flammable liquid and vapour Vapour pressure : 42 mm 20 C (ethanol) Relative vapour density at 20 C Relative density : VOC content : < 40 % Solubility : Reacts with water. Log Pow Log Kow Viscosity, kinematic Viscosity, dynamic Explosive properties Oxidising properties Explosive limits : vol % (lower; upper: ethanol) 9.2. Other information SECTION 10: Stability and reactivity Reactivity 09/03/2016 EN (English) SDS ID: SIB /9

6 10.2. Chemical stability Stable when stored in sealed containers Possibility of hazardous reactions Conditions to avoid Heat. Sparks. Open flame Incompatible materials Acids. alcohols. Oxidizing agent. Peroxides Hazardous decomposition products Organic acid vapors. SECTION 11: Toxicological information Information on toxicological effects Acute toxicity LD50 oral rat LC50 inhalation rat (mg/l) ATE CLP (oral) ATE CLP (vapours) ATE CLP (dust,mist) Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity IARC group Reproductive toxicity Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Aspiration hazard Symptoms/injuries after inhalation Symptoms/injuries after skin contact Symptoms/injuries after eye contact Symptoms/injuries after ingestion Reason for classification SECTION 12: Ecological information Toxicity Ecology - general LC50 fish 1 EC50 Daphnia 1 LC50 fish 2 EC50 Daphnia mg/kg mg/l/4h mg/kg bodyweight mg/l/4h mg/l/4h : Causes skin irritation. : Causes serious eye irritation. 1 - Carcinogenic to humans : May cause respiratory irritation. Overexposure may cause: Cough. Headache. Nausea. : Causes skin irritation. : Causes serious eye irritation. : May be harmful if swallowed. : Expert judgment : Toxic to aquatic life ml/l (Exposure time: 96 h - Species: Oncorhynchus mykiss [static]) mg/l (Exposure time: 48 h - Species: Daphnia magna) > 100 mg/l (Exposure time: 96 h - Species: Pimephales promelas [static]) 2 mg/l (Exposure time: 48 h - Species: Daphnia magna [Static]) Persistence and degradability Bioaccumulative potential Log Pow Mobility in soil 09/03/2016 EN (English) SDS ID: SIB /9

7 12.5. Results of PBT and vpvb assessment Other adverse effects SECTION 13: Disposal considerations Waste treatment methods Sewage disposal recommendations Waste disposal recommendations Additional information Ecology - waste materials SECTION 14: Transport information UN number UN-No. (ADR) : 1993 UN-No. (IATA) : 1993 UN-No. (IMDG) : UN proper shipping name Proper Shipping Name (ADR) Proper Shipping Name (IATA) Proper Shipping Name (IMDG) : Do not dispose of waste into sewer. : Dispose in a safe manner in accordance with local/national regulations. Dispose of contents/container to licensed waste disposal facility. : Handle empty containers with care because residual vapours are flammable. : Avoid release to the environment. : FLAMMABLE LIQUID, N.O.S. : Flammable liquid, n.o.s. : FLAMMABLE LIQUID, N.O.S. Transport document description (ADR) : UN 1993 FLAMMABLE LIQUID, N.O.S. (N,N'-BIS[3-(TRIETHOXYSILYL)PROPYL]UREA, 60% in ethanol), 3, II, (D/E) Transport hazard class(es) Class (ADR) : 3 Class (IATA) : 3 Class (IMDG) : 3 Danger labels (ADR) : 3 Hazard labels (IATA) : 3 Danger labels (IMDG) : Packing group Packing group (ADR) : II Packing group (IATA) : II Packing group (IMDG) : II Environmental hazards Other information : No supplementary information available Special precautions for user Overland transport Hazard identification number (Kemler No.) : 33 Classification code (ADR) : F1 09/03/2016 EN (English) SDS ID: SIB /9

8 Orange plates : Special provisions (ADR) : 274, 601, 640C Transport category (ADR) : 2 Tunnel restriction code (ADR) : D/E Limited quantities (ADR) : 1l Excepted quantities (ADR) : E2 EAC code : 3YE Transport by sea Special provisions (IMDG) : 274 Limited quantities (IMDG) : 1 L Excepted quantities (IMDG) : E2 Packing instructions (IMDG) : P001 IBC packing instructions (IMDG) : IBC02 Tank instructions (IMDG) : T7 Tank special provisions (IMDG) : TP1, TP8, TP28 EmS-No. (Fire) : F-E EmS-No. (Spillage) : S-E Stowage category (IMDG) : B Air transport CAO packing instructions (IATA) : 364 CAO max net quantity (IATA) : 60L PCA packing instructions (IATA) : 353 PCA Limited quantities (IATA) : Y341 PCA limited quantity max net quantity (IATA) : 1L PCA max net quantity (IATA) : 5L PCA Excepted quantities (IATA) : E2 Special provisions (IATA) : A3 ERG code (IATA) : 3H Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture EU-Regulations Contains no REACH substances with Annex XVII restrictions Contains no substance on the REACH candidate list Contains no REACH Annex XIV substances National regulations Water hazard class (WGK) : 3 - severe hazard to waters N,N'-BIS[3-(TRIETHOXYSILYL)PROPYL]UREA, 60% in ethanol TSCA Exemption/Exclusion CAUTION: This material is supplied for research and development purposes subject to the R&D exemption under TSCA, 40 CFR , and must meet the requirements of the exemption, including supervision by a "technically qualified individual" as defined by 40 CFR 720.3(ee). The use of this material for "commercial purposes" as defined by 40 CFR 720.3(r) is not permitted in the United States N,N'-Bis[3-(triethoxysilyl)propyl]urea ( ) Not listed on the United States TSCA (Toxic Substances Control Act) inventory 09/03/2016 EN (English) SDS ID: SIB /9

9 Listed on IARC (International Agency for Research on Cancer) Listed on the AICS (Australian Inventory of Chemical Substances) Listed on the Canadian DSL (Domestic Substances List) Listed on IECSC (Inventory of Existing Chemical Substances Produced or Imported in China) Listed on the EEC inventory EINECS (European Inventory of Existing Commercial Chemical Substances) Listed on the Japanese ENCS (Existing & New Chemical Substances) inventory Listed on the Korean ECL (Existing Chemicals List) Listed on NZIoC (New Zealand Inventory of Chemicals) Listed on PICCS (Philippines Inventory of Chemicals and Chemical Substances) Listed on the United States TSCA (Toxic Substances Control Act) inventory Listed on the Canadian IDL (Ingredient Disclosure List) Listed on INSQ (Mexican national Inventory of Chemical Substances) Listed on Turkish inventory of chemical Chemical safety assessment SECTION 16: Other information Abbreviations and acronyms : Abbreviations: ND: Not Determined, No Data; NA: Not Applicable; LD: Lethal Dose; LC: Lethal Concentration; ATE: Acute Toxicity Estimates; H: hour; : C unless otherwise stated; mm: millimeters Hg, torr; PEL: permissible exposure level; TWA: time weighted average; TLV: threshold limit value; TG: Test Guideline; NIOSH: National Institute for Occupational Safety and Health; IARC: International Agency for Research on Cancer; NTP: National Toxicology Program; HMIS: Hazardous Material Information System; CAS No.: Chemcial Abstract Service Registration Number; EC No.: European Commission Registration Number; EC Index No.: European Commission Index Number; OECD: The Organisation for Economic Co-operation and Development. Full text of H- and EUH-statements: Eye Irrit. 2 Serious eye damage/eye irritation, Category 2 Flam. Liq. 2 Flammable liquids, Category 2 Skin Irrit. 2 Skin corrosion/irritation, Category 2 STOT SE 3 Specific target organ toxicity Single exposure, Category 3, Respiratory tract irritation H225 H315 H319 H335 Highly flammable liquid and vapour Causes skin irritation Causes serious eye irritation May cause respiratory irritation Prepared by safety and environmental affairs. SDS EU (REACH Annex II) - Custom according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830 The information contained in this document has been gathered from reference materials and/or Gelest, Inc. test data and is to the best knowledge and belief of Gelest, Inc. accurate and reliable. Such information is offered solely for your consideration, investigation and verification. It is not suggested or guaranteed that the hazard precautions or procedures described are the only ones which exist. Gelest, Inc. makes no warranties, express or implied, with respect to the use of such information and assumes no responsibility therefore. Information on this safety data sheet is not intended to constitute a basis for product specifications Gelest Inc. Morrisville, PA /03/2016 EN (English) SDS ID: SIB /9