Chematic 9301-D. Safety Data Sheet according to Regulation (EC) No. 453/2010 Date of issue: 11/05/2015 Revision date: : Version:

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1 Chematic 9301-D Date of issue: 11/05/2015 Revision date: : Version: SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form : Mixture Product name : Chematic 9301-D Product code : Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Industrial/Professional use spec Use of the substance/mixture : Industrial For professional use only : Acidic Concentrated Detergent Uses advised against 1.3. Details of the supplier of the safety data sheet Supplier Dober Chemical Corp Katherine's Crossing Woodridge, IL - US T F regulatory@dobergroup.com - Only Representative Doronwell Limited SN7 8WL Oxfordshire - United Kingdom T 44 (0) Emergency telephone number Emergency number : / ChemTel SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP] Acute Tox. 4 (Oral) H302 Acute Tox. 3 (Dermal) H311 Skin Irrit. 2 Eye Irrit. 2 H315 H319 Full text of H-phrases: see section 16 Adverse physicochemical, human health and environmental effects 2.2. Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP] Hazard pictograms (CLP) : Signal word (CLP) Hazardous ingredients Hazard statements (CLP) Precautionary statements (CLP) : Danger GHS06 : Ethylene glycol monobutyl ether : H302 - Harmful if swallowed H311 - Toxic in contact with skin H315 - Causes skin irritation H319 - Causes serious eye irritation : P264 - Wash hands, forearms and face thoroughly after handling P270 - Do not eat, drink or smoke when using this product P280 - Wear protective gloves/protective clothing/eye protection/face protection P301+P312 - IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell P302+P352 - IF ON SKIN: Wash with plenty of soap and water P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P312 - Call a POISON CENTER/doctor if you feel unwell P321 - Specific treatment (see First aid measures on this label) 11/05/2015 EN (English) 1/9

2 P330 - Rinse mouth P332+P313 - If skin irritation occurs: Get medical advice/attention P337+P313 - If eye irritation persists: Get medical advice/attention P361+P364 - Take off immediately all contaminated clothing and wash it before reuse P362+P364 - Take off contaminated clothing and wash it before reuse P405 - Store locked up P501 - Dispose in a safe manner in accordance with local/national regulations 2.3. Other hazards SECTION 3: Composition/information on ingredients 3.1. Substance Not applicable 3.2. Mixture Name Product identifier % Classification according to Directive 67/548/EEC Ethylene glycol monobutyl ether (CAS No) (EC no) (EC index no) Citric Acid (CAS No) (EC no) Undecan-1-ol, ethoxylated (CAS No) (EC no) Xn; R20/21/22 Xi; R36/ Not classified 1-5 Not classified Name Product identifier % Classification according to Regulation (EC) No. 1272/2008 [CLP] Ethylene glycol monobutyl ether (CAS No) (EC no) (EC index no) Citric Acid (CAS No) (EC no) Undecan-1-ol, ethoxylated (CAS No) (EC no) Full text of R- and H-phrases: see section Acute Tox. 4 (Oral), H302 Acute Tox. 3 (Dermal), H311 Acute Tox. 3 (Inhalation:vapour), H331 Skin Irrit. 2, H315 Eye Irrit. 2, H Eye Irrit. 2, H Acute Tox. 4 (Oral), H302 Eye Irrit. 2, H319 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). : Assure fresh air breathing. Allow the victim to rest. : Immediately call a POISON CENTER or doctor/physician. Remove/Take off immediately all contaminated clothing. Wash with plenty of soap and water. Specific measures (see First aid measures on this label). Wash contaminated clothing before reuse. If skin irritation occurs: Get medical advice/attention. Specific treatment (see First aid measures on this label). : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention. Call a POISON CENTER/doctor/physician if you feel unwell Most important symptoms and effects, both acute and delayed Symptoms/injuries after skin contact Symptoms/injuries after eye contact Symptoms/injuries after ingestion : Repeated exposure to this material can result in absorption through skin causing significant health hazard. Toxic in contact with skin. Causes skin irritation. : Causes serious eye irritation. : Swallowing a small quantity of this material will result in serious health hazard Indication of any immediate medical attention and special treatment needed SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media Unsuitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand. : Do not use a heavy water stream. 11/05/2015 EN (English) 2/9

3 5.2. Special hazards arising from the substance or mixture Fire hazard : Not flammable Advice for firefighters Firefighting instructions Protection during firefighting : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire-fighting water from entering environment. : Do not enter fire area without proper protective equipment, including respiratory protection. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures For non-emergency personnel Emergency procedures For emergency responders Protective equipment Emergency procedures : Evacuate unnecessary personnel. : Equip cleanup crew with proper protection. : Ventilate area Environmental precautions Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters Methods and material for containment and cleaning up Methods for cleaning up 6.4. Reference to other sections See Heading 8. Exposure controls and personal protection. : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling Hygiene measures : Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapour. No smoking. : Do not eat, drink or smoke when using this product. Wash hands, forearms and face thoroughly after handling Conditions for safe storage, including any incompatibilities Technical measures Storage conditions Incompatible products Incompatible materials 7.3. Specific end use(s) : Comply with applicable regulations. : Keep container closed when not in use. Keep only in the original container in a cool, wellventilated place. : Strong bases. Strong acids. SECTION 8: Exposure controls/personal protection 8.1. Control parameters : Sources of ignition. Direct sunlight. EU IOELV TWA (mg/m³) 98 mg/m³ EU IOELV TWA (ppm) 20 ppm EU IOELV STEL (mg/m³) 246 mg/m³ EU IOELV STEL (ppm) 50 ppm Austria MAK (mg/m³) 98 mg/m³ Austria MAK (ppm) 20 ppm Austria MAK Short time value (mg/m³) 200 mg/m³ Austria MAK Short time value (ppm) 40 ppm Belgium Limit value (mg/m³) 98 mg/m³ Belgium Limit value (ppm) 20 ppm Belgium Short time value (mg/m³) 246 mg/m³ Belgium Short time value (ppm) 50 ppm Bulgaria OEL TWA (mg/m³) 20 mg/m³ Bulgaria OEL TWA (ppm) 98 ppm Bulgaria OEL STEL (mg/m³) 246 mg/m³ Bulgaria OEL STEL (ppm) 50 ppm Croatia GVI (granična vrijednost izloženosti) (mg/m³) 98 mg/m³ 11/05/2015 EN (English) 3/9

4 Croatia GVI (granična vrijednost izloženosti) (ppm) 20 ppm Croatia KGVI (kratkotrajna granična vrijednost izloženosti) (mg/m³) 246 mg/m³ Croatia KGVI (kratkotrajna granična vrijednost izloženosti) 50 ppm (ppm) Cyprus OEL TWA (mg/m³) 98 mg/m³ Cyprus OEL TWA (ppm) 20 ppm Cyprus OEL STEL (mg/m³) 246 mg/m³ Cyprus OEL STEL (ppm) 50 ppm Czech Republic Expoziční limity (PEL) (mg/m³) 100 mg/m³ Denmark Grænseværdie (langvarig) (mg/m³) 98 mg/m³ Denmark Grænseværdie (langvarig) (ppm) 20 ppm Estonia OEL TWA (mg/m³) 98 mg/m³ Estonia OEL TWA (ppm) 20 ppm Estonia OEL STEL (mg/m³) 246 mg/m³ Estonia OEL STEL (ppm) 50 ppm Finland HTP-arvo (8h) (mg/m³) 98 mg/m³ Finland HTP-arvo (8h) (ppm) 20 ppm Finland HTP-arvo (15 min) 250 mg/m³ Finland HTP-arvo (15 min) (ppm) 50 ppm France VME (mg/m³) 49 mg/m³ (indicative limit) France VME (ppm) 10 ppm (indicative limit) France VLE (mg/m³) 246 mg/m³ (indicative limit) France VLE (ppm) 50 ppm (indicative limit) Germany TRGS 900 Occupational exposure limit value (mg/m³) 49 mg/m³ (The risk of damage to the embryo or fetus can be excluded when AGW and BGW values are observed) Germany TRGS 900 Occupational exposure limit value (ppm) 10 ppm (The risk of damage to the embryo or fetus can be excluded when AGW and BGW values are observed) Germany TRGS 903 (BGW) 100 mg/l (Medium: urine - Time: end of several shifts - Parameter: Butoxyacetic acid (for long-term exposures) 200 mg/l (Medium: urine - Time: end of several shifts - Parameter: Butoxyacetic acid (after hydrolysis; for long-term exposures) Gibraltar OEL TWA (mg/m³) 98 mg/m³ Gibraltar OEL TWA (ppm) 20 ppm Gibraltar OEL STEL (mg/m³) 246 mg/m³ Gibraltar OEL STEL (ppm) 50 ppm Greece OEL TWA (mg/m³) 120 mg/m³ Greece OEL TWA (ppm) 25 ppm Hungary AK-érték 98 mg/m³ Hungary CK-érték 246 mg/m³ Ireland OEL (8 hours ref) (mg/m³) 98 mg/m³ Ireland OEL (8 hours ref) (ppm) 20 ppm Ireland OEL (15 min ref) (mg/m3) 246 mg/m³ Ireland OEL (15 min ref) (ppm) 50 ppm Italy OEL TWA (mg/m³) 98 mg/m³ Italy OEL TWA (ppm) 20 ppm Italy OEL STEL (mg/m³) 246 mg/m³ Italy OEL STEL (ppm) 50 ppm Latvia OEL TWA (mg/m³) 98 mg/m³ Latvia OEL TWA (ppm) 20 ppm Lithuania IPRV (mg/m³) 50 mg/m³ 11/05/2015 EN (English) 4/9

5 Lithuania IPRV (ppm) 10 ppm Lithuania TPRV (mg/m³) 100 mg/m³ Lithuania TPRV (ppm) 20 ppm Luxembourg OEL TWA (mg/m³) 98 mg/m³ Luxembourg OEL TWA (ppm) 20 ppm Luxembourg OEL STEL (mg/m³) 246 mg/m³ Luxembourg OEL STEL (ppm) 50 ppm Malta OEL TWA (mg/m³) 98 mg/m³ Malta OEL TWA (ppm) 20 ppm Malta OEL STEL (mg/m³) 246 mg/m³ Malta OEL STEL (ppm) 50 ppm Netherlands Grenswaarde TGG 8H (mg/m³) 100 mg/m³ Netherlands Grenswaarde TGG 15MIN (mg/m³) 246 mg/m³ Poland NDS (mg/m³) 98 mg/m³ Poland NDSCh (mg/m³) 200 mg/m³ Portugal OEL TWA (mg/m³) 98 mg/m³ (indicative limit value) Portugal OEL TWA (ppm) 20 ppm (indicative limit value) Portugal OEL STEL (mg/m³) 246 mg/m³ (indicative limit value) Portugal OEL STEL (ppm) 50 ppm (indicative limit value) Romania OEL TWA (mg/m³) 150 mg/m³ Romania OEL TWA (ppm) 30 ppm Romania OEL STEL (mg/m³) 250 mg/m³ Romania OEL STEL (ppm) 50 ppm Slovakia NPHV (priemerná) (mg/m³) 98 mg/m³ Slovakia NPHV (priemerná) (ppm) 20 ppm Slovakia NPHV (Hraničná) (mg/m³) 246 mg/m³ Slovenia OEL TWA (mg/m³) 98 mg/m³ Slovenia OEL TWA (ppm) 20 ppm Slovenia OEL STEL (mg/m³) 245 mg/m³ Slovenia OEL STEL (ppm) 50 ppm Spain VLA-ED (mg/m³) 98 mg/m³ (indicative limit value) Spain VLA-ED (ppm) 20 ppm (indicative limit value) Spain VLA-EC (mg/m³) 245 mg/m³ Spain VLA-EC (ppm) 50 ppm Sweden nivågränsvärde (NVG) (mg/m³) 50 mg/m³ Sweden nivågränsvärde (NVG) (ppm) 10 ppm Sweden kortidsvärde (KTV) (mg/m³) 100 mg/m³ Sweden kortidsvärde (KTV) (ppm) 20 ppm United Kingdom WEL TWA (mg/m³) 123 mg/m³ United Kingdom WEL TWA (ppm) 25 ppm United Kingdom WEL STEL (mg/m³) 246 mg/m³ United Kingdom WEL STEL (ppm) 50 ppm Norway Gjennomsnittsverdier (AN) (mg/m³) 50 mg/m³ Norway Gjennomsnittsverdier (AN) (ppm) 10 ppm Norway Gjennomsnittsverdier (Korttidsverdi) (mg/m3) 75 mg/m³ Norway Gjennomsnittsverdier (Korttidsverdi) (ppm) 20 ppm Switzerland VME (mg/m³) 49 mg/m³ Switzerland VME (ppm) 10 ppm Switzerland VLE (mg/m³) 98 mg/m³ Switzerland VLE (ppm) 20 ppm Australia TWA (mg/m³) 96.9 mg/m³ Australia TWA (ppm) 20 ppm Australia STEL (mg/m³) 242 mg/m³ 11/05/2015 EN (English) 5/9

6 Australia STEL (ppm) 50 ppm Canada (Quebec) VEMP (mg/m³) 97 mg/m³ Canada (Quebec) VEMP (ppm) 20 ppm Japan Exposure limits (ACGIH) TWA 20 ppm,stel - USA - ACGIH ACGIH TWA (ppm) 20 ppm USA - IDLH US IDLH (ppm) 700 ppm USA - NIOSH NIOSH REL (TWA) (mg/m³) 24 mg/m³ USA - NIOSH NIOSH REL (TWA) (ppm) 5 ppm USA - OSHA OSHA PEL (TWA) (mg/m³) 240 mg/m³ USA - OSHA OSHA PEL (TWA) (ppm) 50 ppm 8.2. Exposure controls Personal protective equipment Hand protection Eye protection Skin and body protection Respiratory protection Other information : Avoid all unnecessary exposure. : Wear protective gloves/protective clothing/eye protection/face protection protective gloves : Chemical goggles or safety glasses : Wear suitable protective clothing : Use a properly fitted, particulate filter respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator : Do not eat, drink or smoke during use. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Appearance : Liquid. Colour : amber. Odour : mild. Odour threshold ph : 2.5 Relative evaporation rate (butylacetate=1) Melting point Freezing point : Not available Boiling point Flash point : Not available Auto-ignition temperature Decomposition temperature Flammability (solid, gas) : Non flammable Vapour pressure : Not available Relative vapour density at 20 C : 1 Relative density : 1.09 Density : 1.09 g/ml Solubility : Water: Not available Log Pow Viscosity, kinematic Viscosity, dynamic : Not available Explosive properties Oxidising properties Explosive limits 9.2. Other information VOC content : 0 % 11/05/2015 EN (English) 6/9

7 SECTION 10: Stability and reactivity Reactivity Chemical stability Stable under normal conditions Possibility of hazardous reactions Conditions to avoid Direct sunlight. Extremely high or low temperatures Incompatible materials Strong acids. Strong bases Hazardous decomposition products Fume. Carbon monoxide. Carbon dioxide. SECTION 11: Toxicological information Information on toxicological effects Acute toxicity : Oral: Harmful if swallowed. Dermal: Toxic in contact with skin. ATE CLP (oral) ATE CLP (dermal) LD50 oral rat LD50 oral LD50 dermal rabbit LD50 dermal LC50 inhalation rat (ppm) LC50 inhalation rat (Vapours - mg/l/4h) Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity Reproductive toxicity Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Aspiration hazard Potential adverse human health effects and symptoms mg/kg bodyweight mg/kg bodyweight 470 mg/kg 470 mg/kg 220 mg/kg 220 mg/kg 450 ppm/4h 2.2 mg/l/4h : Causes skin irritation. Causes skin irritation ph: 2.5 : Causes serious eye irritation. ph: 2.5 : Based on available data, the classification criteria are not met. Harmful if swallowed. Toxic in contact with skin. SECTION 12: Ecological information Toxicity LC50 fishes 1 EC50 Daphnia 1 LC50 fish 2 Citric Acid ( ) LC50 fishes mg/l (Exposure time: 96 h - Species: Lepomis macrochirus [static]) > 1000 mg/l (Exposure time: 48 h - Species: Daphnia magna) 2950 mg/l (Exposure time: 96 h - Species: Lepomis macrochirus) 1516 mg/l (Exposure time: 96 h - Species: Lepomis macrochirus [static]) Persistence and degradability Chematic 9301-D Persistence and degradability 11/05/2015 EN (English) 7/9

8 Undecan-1-ol, ethoxylated ( ) Persistence and degradability Bioaccumulative potential Chematic 9301-D Bioaccumulative potential Log Pow Citric Acid ( ) Log Pow Undecan-1-ol, ethoxylated ( ) Bioaccumulative potential 0.81 (at 25 C) (at 20 C) Mobility in soil Results of PBT and vpvb assessment Other adverse effects Additional information : Avoid release to the environment SECTION 13: Disposal considerations Waste treatment methods Waste disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Ecology - waste materials : Hazardous waste due to toxicity. Avoid release to the environment. SECTION 14: Transport information In accordance with ADR / RID / IMDG / IATA / ADN UN number UN-No. (ADR) UN-No. (IMDG) UN-No.(IATA) UN-No.(ADN) UN-No. (RID) UN proper shipping name Proper Shipping Name (ADR) Proper Shipping Name (IMDG) Proper Shipping Name (IATA) Proper Shipping Name (ADN) Proper Shipping Name (RID) Transport hazard class(es) ADR Transport hazard class(es) (ADR) IMDG Transport hazard class(es) (IMDG) IATA Transport hazard class(es) (IATA) ADN Transport hazard class(es) (ADN) RID Transport hazard class(es) (RID) 11/05/2015 EN (English) 8/9

9 14.4. Packing group Packing group (ADR) Packing group (IMDG) Packing group (IATA) Packing group (ADN) Packing group (RID) Environmental hazards Dangerous for the environment Marine pollutant Other information : No : No : No supplementary information available SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture EU-Regulations Contains no substances with Annex XVII restrictions Chematic 9301-D is not on the REACH Candidate List Contains no REACH candidate substance Contains no REACH Annex XIV substances. VOC content : 0 % National regulations Germany Water hazard class (WGK) : 3 - strongly hazardous to water Chemical safety assessment No chemical safety assessment has been carried out SECTION 16: Other information Other information : None. Full text of R-, H- and EUH-phrases: Acute Tox. 3 (Dermal) Acute toxicity (dermal), Category 3 Acute Tox. 3 (Inhalation:vapour) Acute toxicity (inhalation:vapour) Category 3 Acute Tox. 4 (Oral) Acute toxicity (oral), Category 4 Eye Irrit. 2 Serious eye damage/eye irritation, Category 2 Skin Irrit. 2 Skin corrosion/irritation, Category 2 H302 Harmful if swallowed H311 H315 H319 H331 Toxic in contact with skin Causes skin irritation Causes serious eye irritation Toxic if inhaled R20/21/22 Harmful by inhalation, in contact with skin and if swallowed R36/38 Irritating to eyes and skin Xi Xn Irritant Harmful Dober SDS EU To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. 11/05/2015 EN (English) 9/9