1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION 2. COMPOSITION/INFORMATION ON INGREDIENTS

Transcription

1 Material Safety Data Sheet Revision Date: 06/07/2006 Issue date: 06/07/2006 Version: CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Region: Europe Company Name & Address Henkel Loctite Adhesives Ltd. Multicore Solders Technologies House, Wood Lane End Hemel Hempstead, Herts HP2 4RQ, UK Tel: +44 (0) Fax: +44 (0) Emergency Tel: +44 (0) Product type: Liquid flux 2. COMPOSITION/INFORMATION ON INGREDIENTS Distillates (petroleum), hydrotreated light EINECS-No. % Classification F;R11 R67 Xi;R Xi;R Xi;R Xn;R65 R66 Additional Information: For the explanation of the listed risk phrases refer to Section HAZARDS IDENTIFICATION Highly flammable. Irritating to eyes. May cause sensitization by skin contact. Vapours may cause drowsiness and dizziness. 4. FIRST AID MEASURES Inhalation: Eye contact: Move to fresh air. If symptoms persist, seek medical advice. Flush eyes immediately with plenty of water for at least 15 minutes. Seek medical attention immediately. 1 of 6

2 Ingestion: Skin contact: Do not induce vomiting. Rinse mouth with water then give plenty of water to drink. Consult a physician. Rinse off with plenty of water. If irritation persists, seek medical advice. 5. FIRE-FIGHTING MEASURES Extinguishing media: Special fire fighting procedures: Unusual fire or explosion hazards: Hazardous combustion products: Water spray (fog), foam, dry chemical or carbon dioxide. Fire fighters should wear positive pressure breathing apparatus. Vapours may form explosive mixtures with air. Thermal decomposition can lead to release of irritating gases and vapours. 6. ACCIDENTAL RELEASE MEASURES Environmental precautions: Clean-up methods: Prevent product from entering drains or open waters. Remove all sources of ignition. Ensure adequate ventilation. Wear suitable protective clothing, gloves and eye/face protection. Soak up with inert absorbent. Store in a closed container until ready for disposal. 7. HANDLING AND STORAGE Handling: Storage: Incompatible products: Keep away from sources of ignition - No smoking. Use only in well-ventilated areas. Avoid contact with skin and eyes. Use of safety glasses and gloves is advisable. Store in original containers. Keep away from heat and sources of ignition. Take measures to prevent the build up of electrostatic charge. Keep away from oxidising agents. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION ACGIH TLV Austria Belgium Czech 200 ppm TWA 400 ppm STEL 200 ppm MAK 2000 mg/m³ STEL 500 mg/m³ MAK 800 ppm STEL 100 mg/m³ MAK 15 ppm MAK 1248 mg/m³ VLE 400 ppm VLE 500 ppm VLE 997 mg/m³ VLE 500 mg/m 3 TWA 100 mg/m 3 TWA Estonia Greece Finland France Hungary 600 mg/m 3 STEL 250 ppm STEL 350 mg/m 3 TWA 150 ppm TWA 500 ppm STEL 1225 mg/m 3 STEL 980 mg/m 3 TWA 200 ppm TWA 250 ppm STEL 500 mg/m³ TWA 620 mg/m³ STEL 400 ppm VLE 980 mg/m³ VLE 0.1 mg/m³ VME 2000 mg/m 3 STEL 500 mg/m 3 TWA 2 of 6

3 Germany Ireland Netherlands Norway Portugal 1000 mg/m³ Peak 200 ppm MAK 400 ppm Peak 500 mg/m³ MAK 100 mg/m³ MAK 100 mg/m³ Peak 1225 mg/m³ STEL 500 ppm STEL 980 mg/m³ TWA 250 ppm MAC 650 mg/m³ MAC 50 mg/m³ MAC 9 ppm MAC Skin absorber 100 ppm TWA 245 mg/m³ TWA Poland Spain Sweden UK EH mg/m 3 NDSCh 900 mg/m 3 NDS 1250 mg/m³ VLA-EC 400 ppm VLA-ED 500 ppm VLA-EC 998 mg/m³ VLA-ED 150 ppm LLV 250 ppm STV 350 mg/m³ LLV 600 mg/m³ STV 100 mg/m³ VLA-ED 100 mg/m³ LLV 15 ppm LLV 200 mg/m³ STV 30 ppm STV 999 mg/m 3 TWA 500 ppm STEL 1250 mg/m 3 STEL flux fume: 0.05 mg/m³ TWA (As total resin acids) 0.15 mg/m³ STEL (As total resin acids) Engineering controls: Respiratory protection: Skin protection: Eye/face protection: Ensure adequate ventilation, especially in confined areas. Where reasonably practicable this should be achieved by the use of local exhaust ventilation and good general extraction. In case of insufficient ventilation, wear suitable respiratory equipment. For hand protection, use rubber or plastic gloves. Eye protection should be used where there is any risk of splashing. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical state: Colour: Odour: ph: Vapour pressure: Boiling point/range: Melting point/range: liquid brown alcoholic not determined 6.6 kpa at 25ºC (77ºF) 82 C (178 F) not determined Specific gravity: Vapour density: Flash point: Autoignition temperature: heavier than air 14 C (57 F) 398 C (750 F) Flammable limits in air - lower %: 2.0 Flammable limits in air - upper %: 12.0 Solubility in water: partly miscible VOC content: 60-70% 3 of 6

4 10. STABILITY AND REACTIVITY Hazardous decomposition products: Incompatability: Conditions to avoid: Thermal decomposition can lead to release of irritating gases and vapours. Incompatible with oxidising agents. Dissolves aluminium and zinc slowly with formation of hydrogen. Keep away from open flames, hot surfaces and sources of ignition. 11. TOXICOLOGICAL INFORMATION Inhalation: Skin: Eyes: Ingestion: Inhalation of vapours in high concentration may cause irritation of respiratory system. Symptoms of overexposure may be headache, dizziness, tiredness, nausea and vomiting. Fumes evolved at soldering temperatures will irritate the nose, throat and lungs. Prolonged or repeated exposure to flux fumes may result in sensitisation in sensitive workers. May cause sensitization by skin contact. Prolonged skin contact may cause skin irritation and/or dermatitis. Contact with eyes will cause irritation. May cause irritation to the digestive tract. Ingestion of large quantities may cause liver or kidney damage. 12. ECOLOGICAL INFORMATION Mobility: Bioaccumulation: Ecotoxicity: Persistence and degradability: No data available. No data available. No data is available on the product itself. Isopropyl alcohol: LC50/96h/Fathead minnows = 1000 mg/l EC50/24h/Daphnia = 9714 mg/l No data available. WGK Water Classification (VwVwS): Class DISPOSAL CONSIDERATIONS Product Disposal methods: European Waste Catalogue: Dispose of this material and its container as a hazardous or special waste. Incineration under controlled conditions is recommended other solvents and solvent mixtures. Packaging Disposal Methods: Empty containers should be transported/delivered using a registered waste carrier to local recyclers for disposal Do not incinerate closed containers. 14. TRANSPORT INFORMATION ICAO/IATA (Air): Identification number: UN1219 Proper shipping name: Isopropanol solution Hazard class or division: 3 Packing group: II IMO/IMDG (Sea) Identification number: UN1219 Item No. : MB of 6

5 Proper shipping name: Isopropanol solution Hazard class or division: 3 Packing group: II EmS: F-E, S-D Marine pollutant: Not applicable ADR/RID (Road/Rail) UN Number UN1219 Proper shipping name: Isopropanol solution Hazard class or division 3 Packing group II 15. REGULATORY INFORMATION Contains: Indication of danger: Xi - Irritant. F - Highly flammable. Risk Phrases: R11 - Highly flammable. R36 - Irritating to eyes. R43 - May cause sensitization by skin contact. R67 - Vapours may cause drowsiness and dizziness. Safety Phrases: Additional Labelling: UK National regulations: S16 - Keep away from sources of ignition - No smoking. S24 - Avoid contact with skin. S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S37 - Wear suitable gloves. S51 - Use only in well ventilated areas. When heated fumes may cause sensitisation by inhalation. The Health & Safety at Work etc. Act The Control of Substances Hazardous to Health Regulations 2002 L5: General Approved Code of Practice to the COSHH Regulations HS(G)97: A Step by Step Guide to the COSHH Regulations HS(G)193: COSHH essentials: Easy steps to control chemicals (G)51: The Storage of Highly Flammable Liquids in Containers(G)140: The Safe Use and Handling of Highly Flammable Liquids: The Spraying of Highly Flammable Liquids IND (G)248L: Solder fume and you(g)249l: Controlling health risks from rosin (colophony) based solder fluxes 16. OTHER INFORMATION Supercedes Sheet Dated: 23/01/2006 Prepared by: Barry Chase Senior Specialist Product Safety & Regulatory Affairs - Europe MSDS data Revised: 24/04/2006 The information in this safety data sheet was obtained from reputable sources and to the best of our knowledge is accurate and current at the mentioned date. Neither Loctite nor its subsidiary companies accept any liability arising out of the use of the information provided here or the use, application or processing of the product(s) described herein. Attention of users is drawn to the possible hazards from improper use of the product(s). This safety data sheet was prepared in accordance with Commission Directive 2004/73/EC adapting to technical progress for the 29th time Council Directive 67/548/EEC, and Commission Directive 1999/45/EC. 5 of 6

6 Explanation of Section 2 R - Phrases R11 - Highly flammable. R36 - Irritating to eyes. R43 - May cause sensitization by skin contact. R65 - Harmful: may cause lung damage if swallowed. R67 - Vapours may cause drowsiness and dizziness. 6 of 6