SAFETY DATA SHEET. : PSX 60 Part A

Transcription

1 Page : 1 / 16 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form Trade name/designation : Mixture : 1.2. Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Main use category Use of the substance/mixture Uses advised against No data available : Industrial uses,professional uses : Adhesives, sealants 1.3. Details of the supplier of the safety data sheet NOV Fiber Glass Systems Pan Oven 20, 4191MZ Geldermalsen The Netherlands T evert.riswick@nov.com Emergency telephone number Emergency number : This telephone number is available 24 hours per day, 7 days per week. Country Official advisory body Address Emergency number IRELAND (REPUBLIC OF) UNITED KINGDOM SECTION 2: Hazards identification National Poisons Information Centre Beaumont Hospital National Poisons Information Service (Newcastle Centre) Regional Drugs and Therapeutics Centre, Wolfson Unit 2.1. Classification of the substance or mixture Beaumont Hospital Beaumont Road 9 Dublin Claremont Place Newcastle-upon-Tyne NE1 4LP Newcastle / (UK only, Monday to Friday, to hours, healthcare professionals only) Classification according to Regulation (EC) No. 1272/2008 [CLP]Mixture/Substance: SDS EU 2015: According to Regulation (EU) 2015/830 (REACH Annex II) Skin Irrit. 2 Eye Irrit. 2 Skin Sens. 1 Repr. 1A STOT RE 1 H315 H319 H317 H360FD H372 Aquatic Chronic 2 H411 Full text of H-statements: see section Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP] Extra labelling to displayextra classification(s) to display Hazard pictograms : GHS07 GHS08 GHS09

2 Page : 2 / 16 Signal word Hazardous ingredients Hazard statements Precautionary statements : Danger : dibutyltin di(acetate), Quartz, Phenol, polymer with formaldehyde, glycidyl ether : H315 - Causes skin irritation. H317 - May cause an allergic skin reaction. H319 - Causes serious eye irritation. H360FD - May damage fertility. May damage the unborn child. H372 - Causes damage to organs through prolonged or repeated exposure. H411 - Toxic to aquatic life with long lasting effects. : P201 - Obtain special instructions before use. P280 - Wear protective gloves/protective clothing/eye protection/face protection. P281 - Use personal protective equipment as required. P260 - Do not breathe dust/fume/gas/mist/vapours/spray. P337+P313 - If eye irritation persists: Get medical advice/attention. P308+P313 - IF exposed or concerned: Get medical advice/attention. P273 - Avoid release to the environment Other hazards Adverse physicochemical, human health and environmental effects Other hazards : Mechanical cutting, grinding, drilling or sanding. : Risk of dust explosion. : Results of PBT and vpvb assessment : Not applicable. SECTION 3: Composition/information on ingredients 3.1. Substance Not applicable 3.2. Mixture Substance name Product identifier % Classification according to Regulation (EC) No. 1272/2008 [CLP] Phenol, polymer with formaldehyde, glycidyl ether (CAS No.) (EC No) (EC Index) - Quartz (CAS No.) (EC No) Siloxane, dimethyl, methoxyphenyl with phenyl silsesquioxane methoxy-terminated dibutyltin di(acetate) (CAS No.) (EC No) Methanol substance with a Community workplace exposure limit substance with national workplace exposure limit(s) (AT, BE, BG, CY, CZ, DE, DK, ES, FI, FR, GB, GI, GR, HU, IE, IT, LT, LU, LV, MT, NL, PL, PT, RO, SE, SK) Skin Irrit. 2, H315 Eye Irrit. 2, H319 Skin Sens. 1, H317 Aquatic Chronic 2, H STOT RE 1, H372 (CAS No.) < 2 Acute Tox. 4 (Oral), H302 (CAS No.) (EC No) (EC Index) X < 1 Skin Corr. 1B, H314 Skin Sens. 1, H317 Muta. 2, H341 Repr. 1A, H360FD STOT SE 1, H370 STOT RE 1, H372 Aquatic Chronic 1, H410 < 0,05 Flam. Liq. 2, H225 Acute Tox. 3 (Oral), H301 Acute Tox. 3 (Dermal), H311 Acute Tox. 3 (Inhalation:vapour), H331 STOT SE 1, H370 Specific concentration limits: Substance name Product identifier Specific concentration limits Methanol (CAS No.) (EC No) (EC Index) X Full text of H-statements: see section 16 (3 =< C < 10) STOT SE 2, H371 (C >= 10) STOT SE 1, H370

3 Page : 3 / 16 SECTION 4: First aid measures 4.1. Description of first aid measures Additional advice Inhalation Skin contact Eye contact In case of ingestion : Never give anything by mouth to an unconscious person or a person with cramps. IF exposed or concerned: Get medical advice/attention. : Allow breathing of fresh air. Allow the victim to rest Most important symptoms and effects, both acute and delayed Symptoms/injuries Inhalation Skin contact Eye contact Ingestion : Wash with plenty of soap and water. Wash contaminated clothing before reuse. If skin irritation occurs: Get medical advice/attention. : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention. : May damage fertility. May damage the unborn child. Causes damage to organs through prolonged or repeated exposure. : May cause irritation or asthma-like symptoms. : Causes skin irritation. May cause an allergic skin reaction. : Causes serious eye irritation. : May cause gastrointestinal irritation, nausea, vomiting and diarrhoea Indication of any immediate medical attention and special treatment needed No data available SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media Unsuitable extinguishing media : Water spray. Alcohol resistant foam. Dry extinguishing powder. Carbon dioxide. : Strong water jet Special hazards arising from the substance or mixture Specific hazards Explosion hazard Hazardous decomposition products in case of fire 5.3. Advice for firefighters Firefighting instructions Protection during firefighting SECTION 6: Accidental release measures : Non flammable. Heating causes rise in pressure with risk of bursting. : Mechanical cutting, grinding, drilling or sanding. : Risk of dust explosion. : Aldehydes. Carbon oxides (CO, CO2). Phenol. : Special protective equipment for firefighters. In case of fire: Wear self-contained breathing apparatus. Use water spray jet to protect personnel and to cool endangered containers. Do not allow run-off from fire-fighting to enter drains or water courses. Dispose of waste in accordance with environmental legislation. Evacuate personnel to a safe area. Use water spray or fog for cooling exposed containers. : Do not enter fire area without proper protective equipment, including respiratory protection Personal precautions, protective equipment and emergency procedures For non-emergency personnel Protective equipment For non-emergency personnel Measures in case of dust release : Use personal protective equipment as required. Concerning personal protective equipment to use, see section 8. : Evacuate personnel to a safe area. Stay upwind/keep distance from source. Provide adequate ventilation. Do not breathe dust. Avoid contact with skin, eyes and clothing. Avoid generation of dust. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Ensure equipment is adequately grounded. Use explosion-proof machinery, apparatus, ventilation facilities, tools etc. : Exclude sources of ignition and ventilate the area. Do not breathe dust.

4 Page : 4 / For emergency responders Protective equipment : Equip cleanup crew with proper protection. For further information refer to section 8: "Exposure controls/personal protection" Environmental precautions Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters. Avoid release to the environment Methods and material for containment and cleaning up For containment Methods for cleaning up 6.4. Reference to other sections : Stop leak if safe to do so. See Heading 8. Concerning disposal elimination after cleaning, see section 13. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling Hygiene measures 7.2. Conditions for safe storage, including any incompatibilities Technical measures Storage conditions Storage temperature : < 38 C Heat and ignition sources Packaging materials 7.3. Specific end use(s) No data available. : Take up mechanically, placing in appropriate containers for disposal. Dispose of waste product or used containers according to local regulations. Avoid generation of dust. Knock down dust with water spray jet. Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials. Use non-sparking tools. : Provide adequate ventilation. Use personal protective equipment as required. Concerning personal protective equipment to use, see section 8. Do not breathe dust. Avoid contact with skin, eyes and clothing. Take any precaution to avoid mixing with incompatible materials. See also section 10. Ensure proper process control to avoid excess waste discharge (temperature, concentration, ph, time). Do not allow contact with soil, surface or ground water. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Avoid generation of dust. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Ensure equipment is adequately grounded. Use explosion-proof machinery, apparatus, ventilation facilities, tools etc. Use only nonsparking tools. Keep good industrial hygiene. : Wash hands before breaks and immediately after using the product. When using do not eat, drink or smoke. Keep away from food, drink and animal feedingstuffs. Keep work clothes separately. Take off contaminated clothing. Wash contaminated clothing before reuse. Contaminated work clothing should not be allowed out of the workplace. : Keep in a dry, cool and well-ventilated place. Do not store near or with any of the incompatible materials listed in section 10. : Keep only in the original container in a cool, well ventilated place away from : Keep container closed when not in use. : Keep away from open flames, hot surfaces and sources of ignition. Keep out of direct sunlight. : Keep/Store only in original container. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Quartz ( ) Austria MAK (mg/m³) 0,15 mg/m³ (yearly average, valid till 12/31/2013-alveolar dust, respirable fraction) Belgium Limit value (mg/m³) 0,1 mg/m³ (alveolar dust) Bulgaria OEL TWA (mg/m³) 0,07 mg/m³ (respirable fraction)

5 Page : 5 / 16 Quartz ( ) Croatia GVI (granična vrijednost izloženosti) (mg/m³) 0,1 mg/m³ 0,1 mg/m³ (regulated under Quartz sandrespirable dust) Czech Republic Expoziční limity (PEL) (mg/m³) 0,1 mg/m³ (dust) Denmark Grænseværdie (langvarig) (mg/m³) 0,3 mg/m³ (total) 0,1 mg/m³ (respirable) Estonia OEL TWA (mg/m³) 0,1 mg/m³ (respirable dust) Finland HTP-arvo (8h) (mg/m³) 0,05 mg/m³ (respirable) France VME (mg/m³) 0,1 mg/m³ (restrictive limit-alveolar fraction) Hungary AK-érték 0,15 mg/m³ (respirable) Ireland OEL (8 hours ref) (mg/m³) 0,1 mg/m³ (respirable dust) Ireland OEL (15 min ref) (mg/m3) 0,3 mg/m³ (calculated-respirable dust) Lithuania IPRV (mg/m³) 0,1 mg/m³ (Silicon dioxide variation-respirable fraction) Netherlands Grenswaarde TGG 8H (mg/m³) 0,075 mg/m³ (respirable dust) Poland NDS (mg/m³) 2 mg/m³ (>50% free crystalline silica-inhalable fraction) 0,3 mg/m³ (>50% free crystalline silicarespirable fraction) 4,0 mg/m³ (2% to 50% free crystalline silicainhalable fraction) 1,0 mg/m³ (2% to 50% free crystalline silicarespirable fraction) Portugal OEL TWA (mg/m³) 0,025 mg/m³ (respirable fraction) Romania OEL TWA (mg/m³) 0,1 mg/m³ (respirable fraction, dust) Slovakia NPHV (priemerná) (mg/m³) 0,1 mg/m³ (in Cristobalite or Tridymite-total aerosol) Slovenia OEL TWA (mg/m³) 0,15 mg/m³ (respirable fraction) Spain VLA-ED (mg/m³) 0,05 mg/m³ (reclassified IARC group 2A to group 1-respirable fraction) Sweden nivågränsvärde (NVG) (mg/m³) 0,1 mg/m³ (respirable dust) United Kingdom WEL TWA (mg/m³) 0,1 mg/m³ (respirable) United Kingdom WEL STEL (mg/m³) 0,3 mg/m³ (calculated-respirable) Norway Grenseverdier (AN) (mg/m³) 0,3 mg/m³ (Dust containing.alpha.-quartz, Cristobalite and/or Tridymite is evaluated by summation formula-total dust) 0,1 mg/m³ (Dust containing.alpha.-quartz, Cristobalite and/or Tridymite is evaluated by summation formula-respirable dust) Norway Grenseverdier (Korttidsverdi) (mg/m3) 0,3 mg/m³ (Dust containing.alpha.-quartz, Cristobalite and/or Tridymite is evaluated by summation formula-total dust) 0,1 mg/m³ (Dust containing.alpha.-quartz, Cristobalite and/or Tridymite is evaluated by summation formula-respirable dust) Switzerland VME (mg/m³) 0,15 mg/m³ (respirable dust) Australia TWA (mg/m³) 0,1 mg/m³ (respirable dust) Canada (Quebec) VEMP (mg/m³) 0,1 mg/m³ (respirable dust) USA - ACGIH ACGIH TWA (mg/m³) 0,025 mg/m³ (respirable fraction) USA - IDLH US IDLH (mg/m³) 50 mg/m³ (respirable dust)

6 Page : 6 / 16 Quartz ( ) USA - NIOSH NIOSH REL (TWA) (mg/m³) 0,05 mg/m³ (respirable dust) Methanol ( ) EU IOELV TWA (mg/m³) 260 mg/m³ EU IOELV TWA (ppm) 200 ppm Austria MAK (mg/m³) 260 mg/m³ Austria MAK (ppm) 200 ppm Austria MAK Short time value (mg/m³) 1040 mg/m³ Austria MAK Short time value (ppm) 800 ppm Belgium Limit value (mg/m³) 266 mg/m³ Belgium Limit value (ppm) 200 ppm Belgium Short time value (mg/m³) 333 mg/m³ Belgium Short time value (ppm) 250 ppm Bulgaria OEL TWA (mg/m³) 260,0 mg/m³ Bulgaria OEL TWA (ppm) 200 ppm Croatia GVI (granična vrijednost izloženosti) (mg/m³) 260 mg/m³ Croatia GVI (granična vrijednost izloženosti) (ppm) 200 ppm Cyprus OEL TWA (mg/m³) 260 mg/m³ Cyprus OEL TWA (ppm) 200 ppm Czech Republic Expoziční limity (PEL) (mg/m³) 250 mg/m³ Denmark Grænseværdie (langvarig) (mg/m³) 260 mg/m³ Denmark Grænseværdie (langvarig) (ppm) 200 ppm Estonia OEL TWA (mg/m³) 260 mg/m³ Estonia OEL TWA (ppm) 200 ppm Estonia OEL STEL (mg/m³) 350 mg/m³ Estonia OEL STEL (ppm) 250 ppm Finland HTP-arvo (8h) (mg/m³) 270 mg/m³ Finland HTP-arvo (8h) (ppm) 200 ppm Finland HTP-arvo (15 min) 330 mg/m³ Finland HTP-arvo (15 min) (ppm) 250 ppm France VME (mg/m³) 260 mg/m³ (restrictive limit) France VME (ppm) 200 ppm (restrictive limit) France VLE (mg/m³) 1300 mg/m³ France VLE (ppm) 1000 ppm Germany Germany TRGS 900 Occupational exposure limit value (mg/m³) TRGS 900 Occupational exposure limit value (ppm) 270 mg/m³ (The risk of damage to the embryo or fetus can be excluded when AGW and BGW values are observed) 200 ppm (The risk of damage to the embryo or fetus can be excluded when AGW and BGW values are observed) Germany TRGS 903 (BGW) 30 mg/l (Medium: urine - Time: end of shift - Parameter: Methanol) 30 mg/l (Medium: urine - Time: end of several shifts - Parameter: Methanol (for long-term exposures) Gibraltar OEL TWA (mg/m³) 260 mg/m³ Gibraltar OEL TWA (ppm) 200 ppm Greece OEL TWA (mg/m³) 260 mg/m³ Greece OEL TWA (ppm) 200 ppm

7 Page : 7 / 16 Methanol ( ) Greece OEL STEL (mg/m³) 325 mg/m³ Greece OEL STEL (ppm) 250 ppm Hungary AK-érték 260 mg/m³ Ireland OEL (8 hours ref) (mg/m³) 260 mg/m³ Ireland OEL (8 hours ref) (ppm) 200 ppm Ireland OEL (15 min ref) (mg/m3) 780 mg/m³ (calculated) Ireland OEL (15 min ref) (ppm) 600 ppm (calculated) Italy OEL TWA (mg/m³) 260 mg/m³ Italy OEL TWA (ppm) 200 ppm Latvia OEL TWA (mg/m³) 260 mg/m³ Latvia OEL TWA (ppm) 200 ppm Lithuania IPRV (mg/m³) 260 mg/m³ Lithuania IPRV (ppm) 200 ppm Luxembourg OEL TWA (mg/m³) 260 mg/m³ Luxembourg OEL TWA (ppm) 200 ppm Malta OEL TWA (mg/m³) 260 mg/m³ Malta OEL TWA (ppm) 200 ppm Netherlands Grenswaarde TGG 8H (mg/m³) 133 mg/m³ Netherlands Grenswaarde TGG 8H (ppm) 100 ppm Poland NDS (mg/m³) 100 mg/m³ Poland NDSCh (mg/m³) 300 mg/m³ Portugal OEL TWA (mg/m³) 260 mg/m³ (indicative limit value) Portugal OEL TWA (ppm) 200 ppm (indicative limit value) Portugal OEL STEL (ppm) 250 ppm Romania OEL TWA (mg/m³) 260 mg/m³ Romania OEL TWA (ppm) 200 ppm Romania OEL STEL (ppm) 5 ppm Slovakia NPHV (priemerná) (mg/m³) 260 mg/m³ Slovakia NPHV (priemerná) (ppm) 200 ppm Slovenia OEL TWA (mg/m³) 260 mg/m³ Slovenia OEL TWA (ppm) 200 ppm Spain VLA-ED (mg/m³) 266 mg/m³ (indicative limit value) Spain VLA-ED (ppm) 200 ppm (indicative limit value) Sweden nivågränsvärde (NVG) (mg/m³) 250 mg/m³ Sweden nivågränsvärde (NVG) (ppm) 200 ppm Sweden kortidsvärde (KTV) (mg/m³) 350 mg/m³ Sweden kortidsvärde (KTV) (ppm) 250 ppm United Kingdom WEL TWA (mg/m³) 266 mg/m³ United Kingdom WEL TWA (ppm) 200 ppm United Kingdom WEL STEL (mg/m³) 333 mg/m³ United Kingdom WEL STEL (ppm) 250 ppm Norway Grenseverdier (AN) (mg/m³) 130 mg/m³ Norway Grenseverdier (AN) (ppm) 100 ppm

8 Page : 8 / 16 Methanol ( ) Norway Grenseverdier (Korttidsverdi) (mg/m3) 130 mg/m³ Norway Grenseverdier (Korttidsverdi) (ppm) 100 ppm Switzerland VME (mg/m³) 260 mg/m³ Switzerland VME (ppm) 200 ppm Switzerland VLE (mg/m³) 1040 mg/m³ Switzerland VLE (ppm) 800 ppm Australia TWA (mg/m³) 262 mg/m³ Australia TWA (ppm) 200 ppm Australia STEL (mg/m³) 328 mg/m³ Australia STEL (ppm) 250 ppm Canada (Quebec) VECD (mg/m³) 328 mg/m³ Canada (Quebec) VECD (ppm) 250 ppm Canada (Quebec) VEMP (mg/m³) 262 mg/m³ Canada (Quebec) VEMP (ppm) 200 ppm USA - ACGIH ACGIH TWA (ppm) 200 ppm USA - ACGIH ACGIH STEL (ppm) 250 ppm USA - IDLH US IDLH (ppm) 6000 ppm USA - NIOSH NIOSH REL (TWA) (mg/m³) 260 mg/m³ USA - NIOSH NIOSH REL (TWA) (ppm) 200 ppm USA - NIOSH NIOSH REL (STEL) (mg/m³) 325 mg/m³ USA - NIOSH NIOSH REL (STEL) (ppm) 250 ppm USA - OSHA OSHA PEL (TWA) (mg/m³) 260 mg/m³ USA - OSHA OSHA PEL (TWA) (ppm) 200 ppm Additional information 8.2. Exposure controls Engineering control measures Hand protection Eye protection Body protection Respiratory protection : Atmospheric monitoring at regular intervals. Personal monitoring : Local exhaust and general ventilation must be adequate to meet exposure standards. Organisational measures to prevent /limit releases, dispersion and exposure. Mechanical cutting, grinding, drilling or sanding. : Potential dust explosion hazard. Explosion-proof apparatus have to be used. Ensure equipment is adequately grounded. : Wear suitable gloves resistant to chemical penetration. Butyl rubber. Nitrile rubber. Neoprene. The quality of the protective gloves resistant to chemicals must be chosen as a function of the specific working place concentration and quantity of hazardous substances. : Safety glasses with side shields (EN166) : Wear suitable protective clothing : In case of insufficient ventilation, wear suitable respiratory equipment. Effective dust mask (EN 149). Half-face mask (EN 140). Full face mask (EN 136). Filter type: ABEK + P (EN 143). The filter class must be suitable for the maximum contaminant concentration (gas/vapour/aerosol/particulates) that may arise when handling the product. If the concentration is exceeded, self-contained breathing apparatus must be used. (EN 137). Wear appropriate mask SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : liquid Appearance : Paste.

9 Page : 9 / 16 Colour Odour Odour threshold ph Relative evaporation rate (butylacetate=1) Melting point/freezing point Freezing point Initial boiling point and boiling range : Black. : slight. epoxy-like. Flash point : > 200 C Auto-ignition temperature Decomposition temperature Flammability (solid, gas) Vapour pressure : Non flammable : < 1 mmhg (20 C) Vapour density : 1 (Air = 1.0) Relative density Solubility Partition coefficient n-octanol/water Kinematic viscosity Dynamic viscosity Explosive properties Oxidising properties Explosive limits 9.2. Other information No data available SECTION 10: Stability and reactivity Reactivity Non flammable. Danger of polymerisation Chemical stability. Water: Negligible : cp (@25 C) : Not applicable. : Not applicable. The product is stable under storage at normal ambient temperatures Possibility of hazardous reactions Exothermic reaction with: Amines, alcohols, Strong acids and strong bases, Strong oxidizing agents, Heat. Risk of dust explosion Conditions to avoid Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Direct sunlight. Extremely high or low temperatures Incompatible materials Strong acids and strong bases. alcohols. Strong oxidizing agents. Amines. Catalyst Hazardous decomposition products fume. Carbon monoxide. Carbon dioxide. Phenols. Aldehydes. SECTION 11: Toxicological information Information on toxicological effects Acute toxicity Phenol, polymer with formaldehyde, glycidyl ether ( ) LD50/oral/rat : Not classified (Based on available data, the classification criteria are not met.) > 2000 mg/kg

10 Page : 10 / 16 Phenol, polymer with formaldehyde, glycidyl ether ( ) LD50/dermal/rat > 2000 mg/kg dibutyltin di(acetate) ( ) LD50/oral/rat 32 mg/kg Methanol ( ) LD50/oral/rat 6200 mg/kg LC50/inhalation/4h/rat (ppm) ppm (Exposure time: 8 h) Skin corrosion/irritation Serious eye damage/eye irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity Reproductive toxicity STOT-single exposure STOT-repeated exposure Aspiration hazard : Causes skin irritation. ph : Causes serious eye irritation. ph : May cause an allergic skin reaction. : Not classified Based on available data, the classification criteria are not met. : Not classified Based on available data, the classification criteria are not met. : May damage fertility. May damage the unborn child. : Not classified Based on available data, the classification criteria are not met. : Causes damage to organs through prolonged or repeated exposure. : Not classified Based on available data, the classification criteria are not met. Other adverse effects Other information : Based on available data, the classification criteria are not met. : Symptoms related to the physical, chemical and toxicological characteristics. For further information see section 4. SECTION 12: Ecological information Toxicity Environmental properties Ecology - water : Toxic to aquatic life with long lasting effects. : Toxic to aquatic life with long lasting effects. Phenol, polymer with formaldehyde, glycidyl ether ( ) LC50 fish 1 > 1-10 Methanol ( ) LC50 fish mg/l (Exposure time: 96 h - Species: Pimephales promelas [flow-through]) EC50 Daphnia 1 > mg/l LC50 fish 2 > 100 mg/l (Exposure time: 96 h - Species: Pimephales promelas [static]) Persistence and degradability Persistence and degradability Bioaccumulative potential Partition coefficient n-octanol/water Bioaccumulative potential Methanol ( ) BCF fish 1 < 10 Partition coefficient n-octanol/water -0,77 No data available. No data available Not established.

11 Page : 11 / Mobility in soil Ecology - soil Results of PBT and vpvb assessment No data available No data available Other adverse effects Additional information : Avoid release to the environment SECTION 13: Disposal considerations Waste treatment methods Waste disposal recommendations Additional information Further ecological information Codes of waste (2001/573/EC, 75/442/EEC, 91/689/EEC) SECTION 14: Transport information In accordance with ADR / RID / IMDG / IATA / ADN UN number UN number : 3082 UN-No : 3082 UN-No : 3082 UN-No. (ADN) : 3082 UN-No. (RID) : UN proper shipping name Proper Shipping Name Proper Shipping Name (IMDG) Proper Shipping Name (IATA) Proper Shipping Name (ADN) Proper Shipping Name (RID) Transport document description (ADR) Transport document description (IMDG) Transport hazard class(es) ADR Transport hazard class(es) (ADR) : 9 Danger labels (ADR) : 9 : Do not allow contact with soil, surface or ground water. Dispose of empty containers and wastes safely. Safe handling: see section 7. Refer to manufacturer/supplier for information on recovery/recycling. Recycling is preferred to disposal or incineration. If recycling is not possible, eliminate in accordance with local valid waste disposal regulations. : Handle contaminated packages in the same way as the substance itself. Dispose of contaminated materials in accordance with current regulations. : Avoid release to the environment. : This material and its container must be disposed of as hazardous waste Waste codes should be assigned by the user based on the application for which the product was used. : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. : Environmentally hazardous substance, liquid, n.o.s. : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. : UN 3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Phenol, polymer with formaldehyde, glycidyl ether), 9, III, (E) : UN 3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S., 9, III, MARINE POLLUTANT/ENVIRONMENTALLY HAZARDOUS :

12 Page : 12 / 16 IMDG Transport hazard class(es) (IMDG) : 9 Danger labels (IMDG) : 9 : IATA Transport hazard class(es) (IATA) : 9 Hazard labels (IATA) : 9 : ADN Transport hazard class(es) (ADN) : 9 Danger labels (ADN) : 9 : RID Transport hazard class(es) (RID) : 9 Danger labels (RID) : 9 : Packing group Packing group (ADR) Packing group (IMDG) Packing group (IATA) Packing group (ADN) Packing group (RID) Environmental hazards Dangerous for the environment Marine pollutant Other information : III : III : III : III : III : Yes : Yes : No supplementary information available

13 Page : 13 / Special precautions for user Special precautions for user - Overland transport Classification code (ADR) : M6 Special Provisions : 274, 335, 601 Limited quantities (ADR) Excepted quantities (ADR) Packing instructions (ADR) Special packing provisions (ADR) Mixed packing provisions (ADR) Portable tank and bulk container instructions (ADR) Portable tank and bulk container special provisions (ADR) Tank code (ADR) Vehicle for tank carriage : 5l : E1 : P001, IBC03, LP01, R001 : PP1 : MP19 : T4 : TP1, TP29 : LGBV : AT Transport category (ADR) : 3 Special provisions for carriage - Packages (ADR) Special provisions for carriage - Loading, unloading and handling (ADR) : V12 : CV13 Hazard identification number (Kemler No.) : 90 Orange plates : tunnel restriction code EAC code : E : 3Z - Transport by sea Special provisions (IMDG) : 274, 335 Limited quantities (IMDG) Excepted quantities (IMDG) Packing instructions (IMDG) Special packing provisions (IMDG) IBC packing instructions (IMDG) Tank instructions (IMDG) Tank special provisions (IMDG) EmS-No. (Fire) EmS-No. (Spillage) Stowage category (IMDG) - Air transport PCA Excepted quantities (IATA) PCA Limited quantities (IATA) PCA limited quantity max net quantity (IATA) : 5 L : E1 : P001, LP01 : PP1 : IBC03 : T4 : TP2, TP29 : F-A : S-F : A : E1 : Y964 : 30kgG PCA packing instructions (IATA) : 964 PCA max net quantity (IATA) : 450L CAO packing instructions (IATA) : 964

14 Page : 14 / 16 CAO max net quantity (IATA) Special provisions (IATA) ERG code (IATA) : 450L : A97, A158, A197 : 9L - Inland waterway transport Classification code (ADN) : M6 Special provisions (ADN) : 274, 335, 61 Limited quantities (ADN) Excepted quantities (ADN) Carriage permitted (ADN) Equipment required (ADN) : 5 L : E1 : T : PP Number of blue cones/lights (ADN) : 0 Carriage prohibited (ADN) Not subject to ADN - Rail transport Classification code (RID) : No : No : M6 Special provisions (RID) : 274, 335, 601 Limited quantities (RID) Excepted quantities (RID) Packing instructions (RID) Special packing provisions (RID) Mixed packing provisions (RID) Portable tank and bulk container instructions (RID) Portable tank and bulk container special provisions (RID) Tank codes for RID tanks (RID) : 5L : E1 : P001, IBC03, LP01, R001 : PP1 : MP19 : T4 Transport category (RID) : 3 Special provisions for carriage Packages (RID) Special provisions for carriage - Loading, unloading and handling (RID) Colis express (express parcels) (RID) : TP1, TP29 : LGBV : W12 : CW13, CW31 : CE8 Hazard identification number (RID) : 90 Carriage prohibited (RID) : No Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Code: IBC SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture EU-Regulations The following restrictions are applicable according to Annex XVII of the REACH Regulation (EC) No 1907/2006: 3. Liquid substances or mixtures which are regarded as dangerous in accordance with Directive 1999/45/EC or are fulfilling the criteria for any of the following hazard classes or categories set out in Annex I to Regulation (EC) No 1272/ a. Substances or mixtures fulfilling the criteria for any of the following hazard classes or categories set out in Annex I to Regulation (EC) No 1272/2008: Hazard classes 2.1 to 2.4, 2.6 and 2.7, 2.8 types A and B, 2.9, 2.10, 2.12, 2.13 categories 1 and 2, 2.14 categories 1 and 2, 2.15 types A to F Phenol, polymer with formaldehyde, glycidyl ether - Methanol Methanol

15 Page : 15 / 16 3.b. Substances or mixtures fulfilling the criteria for any of the following hazard classes or categories set out in Annex I to Regulation (EC) No 1272/2008: Hazard classes 3.1 to 3.6, 3.7 adverse effects on sexual function and fertility or on development, 3.8 effects other than narcotic effects, 3.9 and c. Substances or mixtures fulfilling the criteria for any of the following hazard classes or categories set out in Annex I to Regulation (EC) No 1272/2008: Hazard class Substances classified as flammable gases category 1 or 2, flammable liquids categories 1, 2 or 3, flammable solids category 1 or 2, substances and mixtures which, in contact with water, emit flammable gases, category 1, 2 or 3, pyrophoric liquids category 1 or pyrophoric solids category 1, regardless of whether they appear in Part 3 of Annex VI to Regulation (EC) No 1272/2008 or not. Contains no substance on the REACH candidate list Contains no REACH Annex XIV substances - Phenol, polymer with formaldehyde, glycidyl ether - Quartz - dibutyltin di(acetate) - Siloxane, dimethyl, methoxyphenyl with phenyl silsesquioxane methoxy-terminated - Methanol - Phenol, polymer with formaldehyde, glycidyl ether - dibutyltin di(acetate) Methanol National regulations Germany VwVwS Annex reference 12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV : Water hazard class (WGK) 3, severe hazard to waters (Classification according to VwVwS, Annex 4) : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance) Netherlands SZW-lijst van kankerverwekkende stoffen SZW-lijst van mutagene stoffen NIET-limitatieve lijst van voor de voortplanting giftige stoffen Borstvoeding NIET-limitatieve lijst van voor de voortplanting giftige stoffen Vruchtbaarheid NIET-limitatieve lijst van voor de voortplanting giftige stoffen Ontwikkeling Denmark Classification remarks Recommendations Danish Regulation : Quartz is listed : None of the components are listed : None of the components are listed : None of the components are listed : Methanol is listed : Emergency management guidelines for the storage of flammable liquids must be followed : Young people below the age of 18 years are not allowed to use the product Pregnant/breastfeeding women working with the product must not be in direct contact with the product Chemical safety assessment Chemical safety assessments for substances in this mixture were not carried out. SECTION 16: Other information Sources of key data used to compile the datasheet Other information : REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006. : None.

16 Page : 16 / 16 Full text of H- and EUH-statements: Acute Tox. 3 (Dermal) Acute toxicity (dermal), Category 3 Acute Tox. 3 (Inhalation:vapour) Acute toxicity (inhal.), Category 3 Acute Tox. 3 (Oral) Acute toxicity Category 3 Acute Tox. 4 (Oral) Acute toxicity Category 4 Aquatic Chronic 1 Hazardous to the aquatic environment - chronic hazard category 1 Aquatic Chronic 2 Hazardous to the aquatic environment - chronic hazard category 2 Eye Irrit. 2 Serious eye damage/eye irritation Category 2 Flam. Liq. 2 Flammable liquids, Category 2 Muta. 2 Germ cell mutagenicity, hazard categories 2 Repr. 1A Skin Corr. 1B Reproductive toxicity, Category 1A Skin corrosion/irritation, Category 1B Skin Irrit. 2 Skin corrosion/irritation, Category 2 Skin Sens. 1 Skin sensitisation, hazard category 1 STOT RE 1 Specific target organ toxicity Repeated exposure, Category 1 STOT SE 1 Specific target organ toxicity single exposure, Category 1 H225 H301 H302 H311 H314 H315 H317 H319 H331 H341 H360FD H370 H372 H410 H411 Highly flammable liquid and vapour. Toxic if swallowed. Harmful if swallowed. Toxic in contact with skin. Causes severe skin burns and eye damage. Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation. Toxic if inhaled. Suspected of causing genetic defects. May damage fertility. May damage the unborn child. Causes damage to organs. Causes damage to organs through prolonged or repeated exposure. Very toxic to aquatic life with long lasting effects. Toxic to aquatic life with long lasting effects. The contents and format of this SDS are in accordance with EEC Commission Directive 1999/45/EC, 67/548/EC, 1272/2008/EC and EEC Commission Regulation 1907/2006/EC (REACH) Annex II. DISCLAIMER OF LIABILITY The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This SDS was prepared and is to be used only for this product. If the product is used as a component in another product, this SDS information may not be applicable.