SAFETY DATA SHEET. : PSX Part B Hardener

Transcription

1 Page : 1 / 21 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form Trade name/designation : Mixture : 1.2. Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Main use category Use of the substance/mixture Uses advised against No data available : Industrial use,professional uses : Hardener (Crosslinker) (adhesives) 1.3. Details of the supplier of the safety data sheet NOV Fiber Glass Systems Pan Oven 20, 4191MZ Geldermalsen The Netherlands T evert.riswick@nov.com Emergency telephone number Emergency number : This telephone number is available 24 hours per day, 7 days per week. Country Official advisory body Address Emergency number IRELAND (REPUBLIC OF) UNITED KINGDOM SECTION 2: Hazards identification National Poisons Information Centre Beaumont Hospital National Poisons Information Service (Newcastle Centre) Regional Drugs and Therapeutics Centre, Wolfson Unit 2.1. Classification of the substance or mixture Beaumont Hospital Beaumont Road 9 Dublin Claremont Place Newcastle-upon-Tyne NE1 4LP Newcastle / (UK only, Monday to Friday, to hours, healthcare professionals only) Classification according to Regulation (EC) No. 1272/2008 [CLP]Mixture/Substance: SDS EU 2015: According to Regulation (EU) 2015/830 (REACH Annex II) Acute Tox. 4 (Oral) H302 Skin Corr. 1B Skin Sens. 1 Aquatic Acute 1 Aquatic Chronic 1 H314 H317 H400 H410 Full text of H-statements: see section Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP] Extra labelling to displayextra classification(s) to display Hazard pictograms : GHS05 GHS07 GHS09

2 Page : 2 / 21 Signal word : Danger Hazardous ingredients : N-(2-aminoethyl)-N'-[3-(trimethoxysilyl)propyl]ethylenediamine, Methanol, 2,4,6- tris(dimethylaminomethyl)phenol, m-phenylenebis(methylamine), 2,2'- iminodiethylamine, diethylenetriamine Hazard statements Precautionary statements : H302 - Harmful if swallowed. H314 - Causes severe skin burns and eye damage. H317 - May cause an allergic skin reaction. H410 - Very toxic to aquatic life with long lasting effects. : P280 - Wear protective gloves/protective clothing/eye protection/face protection. P301+P330+P331 - IF SWALLOWED: rinse mouth. Do NOT induce vomiting. P303+P361+P353 - IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 - Immediately call a POISON CENTER/doctor/. P273 - Avoid release to the environment Other hazards Other hazards : Results of PBT and vpvb assessment : Not applicable. SECTION 3: Composition/information on ingredients 3.1. Substance Not applicable 3.2. Mixture Substance name Product identifier % Classification according to Regulation (EC) No. 1272/2008 [CLP] Formaldehyde, oligomeric reaction products with phenol and m-phenylenebis(methylamine) (CAS No.) (EC No) m-phenylenebis(methylamine) (CAS No.) (EC No) N-(2-aminoethyl)-N'-[3-(trimethoxysilyl)propyl]ethylenediamine (CAS No.) (EC No) ,4,6-tris(dimethylaminomethyl)phenol (CAS No.) (EC No) (EC Index) ethylbenzene substance with a Community workplace exposure limit substance with national workplace exposure limit(s) (AT, BE, BG, CY, CZ, DE, DK, ES, FI, FR, GB, GI, GR, HU, IE, IT, LT, LU, LV, MT, NL, PL, PT, RO, SE, SK) (CAS No.) (EC No) (EC Index) ,2'-iminodiethylamine, diethylenetriamine (CAS No.) (EC No) (EC Index) X Methanol (CAS No.) (EC No) (EC Index) X Aquatic Acute 1, H400 Aquatic Chronic 1, H Acute Tox. 4 (Oral), H302 Acute Tox. 4 (Inhalation:vapour), H332 Skin Corr. 1B, H314 Skin Sens. 1, H317 Aquatic Chronic 3, H Eye Dam. 1, H318 Skin Sens. 1, H317 Aquatic Chronic 2, H Acute Tox. 4 (Oral), H302 Eye Irrit. 2, H319 Skin Irrit. 2, H315 < 0,5 Flam. Liq. 2, H225 Acute Tox. 4 (Inhalation), H332 STOT RE 2, H373 Asp. Tox. 1, H304 Aquatic Chronic 3, H412 < 0,3 Acute Tox. 4 (Oral), H302 Acute Tox. 4 (Dermal), H312 Acute Tox. 2 (Inhalation), H330 Skin Corr. 1B, H314 Skin Sens. 1, H317 STOT SE 3, H335 < 0,2 Flam. Liq. 2, H225 Acute Tox. 3 (Oral), H301 Acute Tox. 3 (Dermal), H311 Acute Tox. 3 (Inhalation:vapour), H331 STOT SE 1, H370

3 Page : 3 / 21 Specific concentration limits: Substance name Product identifier Specific concentration limits Methanol (CAS No.) (EC No) (EC Index) X Full text of H-statements: see section 16 SECTION 4: First aid measures 4.1. Description of first aid measures Additional advice Inhalation Skin contact Eye contact In case of ingestion 4.2. Most important symptoms and effects, both acute and delayed Inhalation Skin contact Eye contact Ingestion (3 =< C < 10) STOT SE 2, H371 (C >= 10) STOT SE 1, H370 : First aider: Pay attention to self-protection!. Concerning personal protective equipment to use, see section 8. Never give anything by mouth to an unconscious person or a person with cramps. When in doubt or if symptoms are observed, get medical advice. Show this safety data sheet to the doctor in attendance. Treat symptomatically. : Remove person to fresh air and keep comfortable for breathing. If breathing is irregular or stopped, administer artificial respiration. Get immediate medical advice/attention. : Take off immediately all contaminated clothing. After contact with skin, wash immediately with plenty of water. Get immediate medical advice/attention. Doctor: administration of corticoid spray. : Rinse immediately carefully and thoroughly with eye-bath or water. Remove contact lenses, if present and easy to do. Continue rinsing. Get immediate medical advice/attention. : Get immediate medical advice/attention. Do not induce vomiting without medical advice. If swallowed, rinse mouth with water (only if the person is conscious). Vomiting: prevent asphyxia/aspiration pneumonia. : The following symptoms may occur: Irritation. sore throat. : Causes severe burns. May cause an allergic skin reaction. : Causes serious eye damage. : Causes severe burns. Harmful if swallowed Indication of any immediate medical attention and special treatment needed No data available SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media Unsuitable extinguishing media : Alcohol resistant foam. Dry extinguishing powder. Carbon dioxide. Dry sand. limestone powder. : Strong water jet Special hazards arising from the substance or mixture Specific hazards Hazardous decomposition products in case of fire 5.3. Advice for firefighters Firefighting instructions : Non flammable. Heating causes rise in pressure with risk of bursting. By-products from reaction with water may be toxic. Do not allow to enter into surface water or drains. : Carbon oxides (CO, CO2). Nitrogen oxides. Ammonia. : Special protective equipment for firefighters. In case of fire: Wear self-contained breathing apparatus. Use water spray jet to protect personnel and to cool endangered containers. Do not allow run-off from fire-fighting to enter drains or water courses. Dispose of waste in accordance with environmental legislation. Evacuate personnel to a safe area.

4 Page : 4 / 21 SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures For non-emergency personnel Protective equipment For non-emergency personnel Measures in case of dust release For emergency responders For emergency responders 6.2. Environmental precautions : Use personal protective equipment as required. Concerning personal protective equipment to use, see section 8. : Evacuate personnel to a safe area. Stay upwind/keep distance from source. Provide adequate ventilation. Do not breathe vapour/aerosol. Avoid contact with skin, eyes and clothing. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Ensure equipment is adequately grounded. Use explosion-proof machinery, apparatus, ventilation facilities, tools etc. : Exclude sources of ignition and ventilate the area. Do not breathe dust. : Ensure procedures and training for emergency decontamination and disposal are in place. Concerning personal protective equipment to use, see section 8. Do not allow to enter into ground-water, surface water or drains. If the product contaminates rivers and lakes or drains inform respective authorities Methods and material for containment and cleaning up For containment Methods for cleaning up 6.4. Reference to other sections : Stop leak if safe to do so. : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Take up mechanically, placing in appropriate containers for disposal. Use non-sparking tools. Collect spillage. Store away from other materials. Dispose of waste product or used containers according to local regulations. Concerning personal protective equipment to use, see section 8. Disposal: see section 13. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling Hygiene measures 7.2. Conditions for safe storage, including any incompatibilities Technical measures Packaging materials 7.3. Specific end use(s) No data available. : Provide adequate ventilation. Use personal protective equipment as required. Concerning personal protective equipment to use, see section 8. Do not breathe vapour/aerosol. Avoid contact with skin, eyes and clothing. Take any precaution to avoid mixing with incompatible materials. See also section 10. Ensure proper process control to avoid excess waste discharge (temperature, concentration, ph, time). Do not allow contact with soil, surface or ground water. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Use only non-sparking tools. : Wash hands before breaks and immediately after using the product. When using do not eat, drink or smoke. Keep away from food, drink and animal feedingstuffs. Keep work clothes separately. Take off contaminated clothing. Wash contaminated clothing before reuse. Contaminated work clothing should not be allowed out of the workplace. : Keep in a dry, cool and well-ventilated place. Do not store near or with any of the incompatible materials listed in section 10. Bund storage facilities to prevent soil and water pollution in the event of spillage. : Keep/Store only in original container. SECTION 8: Exposure controls/personal protection 8.1. Control parameters

5 Page : 5 / 21 Methanol ( ) EU IOELV TWA (mg/m³) 260 mg/m³ EU IOELV TWA (ppm) 200 ppm Austria MAK (mg/m³) 260 mg/m³ Austria MAK (ppm) 200 ppm Austria MAK Short time value (mg/m³) 1040 mg/m³ Austria MAK Short time value (ppm) 800 ppm Belgium Limit value (mg/m³) 266 mg/m³ Belgium Limit value (ppm) 200 ppm Belgium Short time value (mg/m³) 333 mg/m³ Belgium Short time value (ppm) 250 ppm Bulgaria OEL TWA (mg/m³) 260,0 mg/m³ Bulgaria OEL TWA (ppm) 200 ppm Croatia GVI (granična vrijednost izloženosti) (mg/m³) 260 mg/m³ Croatia GVI (granična vrijednost izloženosti) (ppm) 200 ppm Cyprus OEL TWA (mg/m³) 260 mg/m³ Cyprus OEL TWA (ppm) 200 ppm Czech Republic Expoziční limity (PEL) (mg/m³) 250 mg/m³ Denmark Grænseværdie (langvarig) (mg/m³) 260 mg/m³ Denmark Grænseværdie (langvarig) (ppm) 200 ppm Estonia OEL TWA (mg/m³) 260 mg/m³ Estonia OEL TWA (ppm) 200 ppm Estonia OEL STEL (mg/m³) 350 mg/m³ Estonia OEL STEL (ppm) 250 ppm Finland HTP-arvo (8h) (mg/m³) 270 mg/m³ Finland HTP-arvo (8h) (ppm) 200 ppm Finland HTP-arvo (15 min) 330 mg/m³ Finland HTP-arvo (15 min) (ppm) 250 ppm France VME (mg/m³) 260 mg/m³ (restrictive limit) France VME (ppm) 200 ppm (restrictive limit) France VLE (mg/m³) 1300 mg/m³ France VLE (ppm) 1000 ppm Germany Germany TRGS 900 Occupational exposure limit value (mg/m³) TRGS 900 Occupational exposure limit value (ppm) 270 mg/m³ (The risk of damage to the embryo or fetus can be excluded when AGW and BGW values are observed) 200 ppm (The risk of damage to the embryo or fetus can be excluded when AGW and BGW values are observed) Germany TRGS 903 (BGW) 30 mg/l (Medium: urine - Time: end of shift - Parameter: Methanol) 30 mg/l (Medium: urine - Time: end of several shifts - Parameter: Methanol (for long-term exposures) Gibraltar OEL TWA (mg/m³) 260 mg/m³ Gibraltar OEL TWA (ppm) 200 ppm Greece OEL TWA (mg/m³) 260 mg/m³ Greece OEL TWA (ppm) 200 ppm Greece OEL STEL (mg/m³) 325 mg/m³ Greece OEL STEL (ppm) 250 ppm

6 Page : 6 / 21 Methanol ( ) Hungary AK-érték 260 mg/m³ Ireland OEL (8 hours ref) (mg/m³) 260 mg/m³ Ireland OEL (8 hours ref) (ppm) 200 ppm Ireland OEL (15 min ref) (mg/m3) 780 mg/m³ (calculated) Ireland OEL (15 min ref) (ppm) 600 ppm (calculated) Italy OEL TWA (mg/m³) 260 mg/m³ Italy OEL TWA (ppm) 200 ppm Latvia OEL TWA (mg/m³) 260 mg/m³ Latvia OEL TWA (ppm) 200 ppm Lithuania IPRV (mg/m³) 260 mg/m³ Lithuania IPRV (ppm) 200 ppm Luxembourg OEL TWA (mg/m³) 260 mg/m³ Luxembourg OEL TWA (ppm) 200 ppm Malta OEL TWA (mg/m³) 260 mg/m³ Malta OEL TWA (ppm) 200 ppm Netherlands Grenswaarde TGG 8H (mg/m³) 133 mg/m³ Netherlands Grenswaarde TGG 8H (ppm) 100 ppm Poland NDS (mg/m³) 100 mg/m³ Poland NDSCh (mg/m³) 300 mg/m³ Portugal OEL TWA (mg/m³) 260 mg/m³ (indicative limit value) Portugal OEL TWA (ppm) 200 ppm (indicative limit value) Portugal OEL STEL (ppm) 250 ppm Romania OEL TWA (mg/m³) 260 mg/m³ Romania OEL TWA (ppm) 200 ppm Romania OEL STEL (ppm) 5 ppm Slovakia NPHV (priemerná) (mg/m³) 260 mg/m³ Slovakia NPHV (priemerná) (ppm) 200 ppm Slovenia OEL TWA (mg/m³) 260 mg/m³ Slovenia OEL TWA (ppm) 200 ppm Spain VLA-ED (mg/m³) 266 mg/m³ (indicative limit value) Spain VLA-ED (ppm) 200 ppm (indicative limit value) Sweden nivågränsvärde (NVG) (mg/m³) 250 mg/m³ Sweden nivågränsvärde (NVG) (ppm) 200 ppm Sweden kortidsvärde (KTV) (mg/m³) 350 mg/m³ Sweden kortidsvärde (KTV) (ppm) 250 ppm United Kingdom WEL TWA (mg/m³) 266 mg/m³ United Kingdom WEL TWA (ppm) 200 ppm United Kingdom WEL STEL (mg/m³) 333 mg/m³ United Kingdom WEL STEL (ppm) 250 ppm Norway Grenseverdier (AN) (mg/m³) 130 mg/m³ Norway Grenseverdier (AN) (ppm) 100 ppm Norway Grenseverdier (Korttidsverdi) (mg/m3) 130 mg/m³ Norway Grenseverdier (Korttidsverdi) (ppm) 100 ppm

7 Page : 7 / 21 Methanol ( ) Switzerland VME (mg/m³) 260 mg/m³ Switzerland VME (ppm) 200 ppm Switzerland VLE (mg/m³) 1040 mg/m³ Switzerland VLE (ppm) 800 ppm Australia TWA (mg/m³) 262 mg/m³ Australia TWA (ppm) 200 ppm Australia STEL (mg/m³) 328 mg/m³ Australia STEL (ppm) 250 ppm Canada (Quebec) VECD (mg/m³) 328 mg/m³ Canada (Quebec) VECD (ppm) 250 ppm Canada (Quebec) VEMP (mg/m³) 262 mg/m³ Canada (Quebec) VEMP (ppm) 200 ppm USA - ACGIH ACGIH TWA (ppm) 200 ppm USA - ACGIH ACGIH STEL (ppm) 250 ppm USA - IDLH US IDLH (ppm) 6000 ppm USA - NIOSH NIOSH REL (TWA) (mg/m³) 260 mg/m³ USA - NIOSH NIOSH REL (TWA) (ppm) 200 ppm USA - NIOSH NIOSH REL (STEL) (mg/m³) 325 mg/m³ USA - NIOSH NIOSH REL (STEL) (ppm) 250 ppm USA - OSHA OSHA PEL (TWA) (mg/m³) 260 mg/m³ USA - OSHA OSHA PEL (TWA) (ppm) 200 ppm ethylbenzene ( ) EU IOELV TWA (mg/m³) 442 mg/m³ EU IOELV TWA (ppm) 100 ppm EU IOELV STEL (mg/m³) 884 mg/m³ EU IOELV STEL (ppm) 200 ppm Austria MAK (mg/m³) 440 mg/m³ Austria MAK (ppm) 100 ppm Austria MAK Short time value (mg/m³) 880 mg/m³ Austria MAK Short time value (ppm) 200 ppm Belgium Limit value (mg/m³) 442 mg/m³ Belgium Limit value (ppm) 100 ppm Belgium Short time value (mg/m³) 551 mg/m³ Belgium Short time value (ppm) 125 ppm Bulgaria OEL TWA (mg/m³) 435 mg/m³ Bulgaria OEL STEL (mg/m³) 545 mg/m³ Croatia GVI (granična vrijednost izloženosti) (mg/m³) 442 mg/m³ Croatia GVI (granična vrijednost izloženosti) (ppm) 100 ppm Croatia KGVI (kratkotrajna granična vrijednost 884 mg/m³ izloženosti) (mg/m³) Croatia KGVI (kratkotrajna granična vrijednost 200 ppm izloženosti) (ppm) Cyprus OEL TWA (mg/m³) 442 mg/m³ Cyprus OEL TWA (ppm) 100 ppm Cyprus OEL STEL (mg/m³) 884 mg/m³ Cyprus OEL STEL (ppm) 200 ppm Czech Republic Expoziční limity (PEL) (mg/m³) 200 mg/m³

8 Page : 8 / 21 ethylbenzene ( ) Denmark Grænseværdie (langvarig) (mg/m³) 217 mg/m³ Denmark Grænseværdie (langvarig) (ppm) 50 ppm Estonia OEL TWA (mg/m³) 442 mg/m³ Estonia OEL TWA (ppm) 100 ppm Estonia OEL STEL (mg/m³) 884 mg/m³ Estonia OEL STEL (ppm) 200 ppm Finland HTP-arvo (8h) (mg/m³) 220 mg/m³ Finland HTP-arvo (8h) (ppm) 50 ppm Finland HTP-arvo (15 min) 880 mg/m³ Finland HTP-arvo (15 min) (ppm) 200 ppm France VME (mg/m³) 88,4 mg/m³ (restrictive limit) France VME (ppm) 20 ppm (restrictive limit) France VLE (mg/m³) 442 mg/m³ (restrictive limit) France VLE (ppm) 100 ppm (restrictive limit) Germany Germany TRGS 900 Occupational exposure limit value (mg/m³) TRGS 900 Occupational exposure limit value (ppm) 88 mg/m³ (The risk of damage to the embryo or fetus can be excluded when AGW and BGW values are observed) 20 ppm (The risk of damage to the embryo or fetus can be excluded when AGW and BGW values are observed) Germany TRGS 903 (BGW) 300 mg/g (Medium: urine - Time: end of shift - Parameter: Mandelic acid plus Phenylglyoxylic acid) Gibraltar OEL TWA (mg/m³) 442 mg/m³ Gibraltar OEL TWA (ppm) 100 ppm Gibraltar OEL STEL (mg/m³) 884 mg/m³ Gibraltar OEL STEL (ppm) 200 ppm Greece OEL TWA (mg/m³) 435 mg/m³ Greece OEL TWA (ppm) 100 ppm Greece OEL STEL (mg/m³) 545 mg/m³ Greece OEL STEL (ppm) 125 ppm Hungary AK-érték 442 mg/m³ Hungary CK-érték 884 mg/m³ Ireland OEL (8 hours ref) (mg/m³) 442 mg/m³ Ireland OEL (8 hours ref) (ppm) 100 ppm Ireland OEL (15 min ref) (mg/m3) 884 mg/m³ Ireland OEL (15 min ref) (ppm) 200 ppm Italy OEL TWA (mg/m³) 442 mg/m³ Italy OEL TWA (ppm) 100 ppm Italy OEL STEL (mg/m³) 884 mg/m³ Italy OEL STEL (ppm) 200 ppm Latvia OEL TWA (mg/m³) 442 mg/m³ Latvia OEL TWA (ppm) 100 ppm Lithuania IPRV (mg/m³) 442 mg/m³ Lithuania IPRV (ppm) 100 ppm

9 Page : 9 / 21 ethylbenzene ( ) Lithuania TPRV (mg/m³) 884 mg/m³ Lithuania TPRV (ppm) 200 ppm Luxembourg OEL TWA (mg/m³) 442 mg/m³ Luxembourg OEL TWA (ppm) 100 ppm Luxembourg OEL STEL (mg/m³) 884 mg/m³ Luxembourg OEL STEL (ppm) 200 ppm Malta OEL TWA (mg/m³) 442 mg/m³ Malta OEL TWA (ppm) 100 ppm Malta OEL STEL (mg/m³) 884 mg/m³ Malta OEL STEL (ppm) 200 ppm Netherlands Grenswaarde TGG 8H (mg/m³) 215 mg/m³ Netherlands Grenswaarde TGG 15MIN (mg/m³) 430 mg/m³ Poland NDS (mg/m³) 200 mg/m³ Poland NDSCh (mg/m³) 400 mg/m³ Portugal OEL TWA (mg/m³) 442 mg/m³ (indicative limit value) Portugal OEL TWA (ppm) 100 ppm (indicative limit value) Portugal OEL STEL (mg/m³) 884 mg/m³ (indicative limit value) Portugal OEL STEL (ppm) 200 ppm (indicative limit value) Romania OEL TWA (mg/m³) 442 mg/m³ Romania OEL TWA (ppm) 100 ppm Romania OEL STEL (mg/m³) 884 mg/m³ Romania OEL STEL (ppm) 200 ppm Slovakia NPHV (priemerná) (mg/m³) 442 mg/m³ Slovakia NPHV (priemerná) (ppm) 100 ppm Slovakia NPHV (Hraničná) (mg/m³) 884 mg/m³ Slovenia OEL TWA (mg/m³) 442 mg/m³ Slovenia OEL TWA (ppm) 100 ppm Slovenia OEL STEL (mg/m³) 884 mg/m³ Slovenia OEL STEL (ppm) 200 ppm Spain VLA-ED (mg/m³) 441 mg/m³ (indicative limit value) Spain VLA-ED (ppm) 100 ppm (indicative limit value) Spain VLA-EC (mg/m³) 884 mg/m³ Spain VLA-EC (ppm) 200 ppm Sweden nivågränsvärde (NVG) (mg/m³) 200 mg/m³ Sweden nivågränsvärde (NVG) (ppm) 50 ppm Sweden kortidsvärde (KTV) (mg/m³) 450 mg/m³ Sweden kortidsvärde (KTV) (ppm) 100 ppm United Kingdom WEL TWA (mg/m³) 441 mg/m³ United Kingdom WEL TWA (ppm) 100 ppm United Kingdom WEL STEL (mg/m³) 552 mg/m³ United Kingdom WEL STEL (ppm) 125 ppm Norway Grenseverdier (AN) (mg/m³) 20 mg/m³ Norway Grenseverdier (AN) (ppm) 5 ppm Norway Grenseverdier (Korttidsverdi) (mg/m3) 20 mg/m³

10 Page : 10 / 21 ethylbenzene ( ) Norway Grenseverdier (Korttidsverdi) (ppm) 5 ppm Switzerland VME (mg/m³) 220 mg/m³ Switzerland VME (ppm) 50 ppm Switzerland VLE (mg/m³) 220 mg/m³ Switzerland VLE (ppm) 50 ppm Australia TWA (mg/m³) 434 mg/m³ Australia TWA (ppm) 100 ppm Australia STEL (mg/m³) 543 mg/m³ Australia STEL (ppm) 125 ppm Canada (Quebec) VECD (mg/m³) 543 mg/m³ Canada (Quebec) VECD (ppm) 125 ppm Canada (Quebec) VEMP (mg/m³) 434 mg/m³ Canada (Quebec) VEMP (ppm) 100 ppm USA - ACGIH ACGIH TWA (ppm) 20 ppm USA - IDLH US IDLH (ppm) 800 ppm (10% LEL) USA - NIOSH NIOSH REL (TWA) (mg/m³) 435 mg/m³ USA - NIOSH NIOSH REL (TWA) (ppm) 100 ppm USA - NIOSH NIOSH REL (STEL) (mg/m³) 545 mg/m³ USA - NIOSH NIOSH REL (STEL) (ppm) 125 ppm USA - OSHA OSHA PEL (TWA) (mg/m³) 435 mg/m³ USA - OSHA OSHA PEL (TWA) (ppm) 100 ppm m-phenylenebis(methylamine) ( ) Austria MAK (mg/m³) 0,1 mg/m³ Austria MAK Short time value (mg/m³) 0,1 mg/m³ Austria OEL - Ceilings (mg/m³) 0,1 mg/m³ Denmark Grænseværdie (ceiling) (ppm) 0,02 ppm Denmark Grænseværdie (ceiling) (mg/m³) 0,1 mg/m³ Finland HTP-arvo (15 min) 0,1 mg/m³ Finland OEL Ceiling (mg/m³) 0,1 mg/m³ France VLE (mg/m³) 0,1 mg/m³ Portugal OEL - Ceilings (mg/m³) 0,1 mg/m³ Slovenia OEL TWA (mg/m³) 0,1 mg/m³ Norway Grenseverdier (Takverdi) (mg/m³) 0,1 mg/m³ Switzerland VME (mg/m³) 0,1 mg/m³ Canada (Quebec) PLAFOND (mg/m³) 0,1 mg/m³ USA - ACGIH ACGIH Ceiling (mg/m³) 0,1 mg/m³ USA - NIOSH NIOSH REL (ceiling) (mg/m³) 0,1 mg/m³ 2,2'-iminodiethylamine, diethylenetriamine ( ) Austria MAK (mg/m³) 4 mg/m³ Austria MAK (ppm) 1 ppm Belgium Limit value (mg/m³) 4,3 mg/m³ Belgium Limit value (ppm) 1 ppm Bulgaria OEL TWA (mg/m³) 4,0 mg/m³ Croatia GVI (granična vrijednost izloženosti) (mg/m³) 4,3 mg/m³ Croatia GVI (granična vrijednost izloženosti) (ppm) 1 ppm

11 Page : 11 / 21 2,2'-iminodiethylamine, diethylenetriamine ( ) Czech Republic Expoziční limity (PEL) (mg/m³) 4 mg/m³ Denmark Grænseværdie (langvarig) (mg/m³) 4 mg/m³ Denmark Grænseværdie (langvarig) (ppm) 1 ppm Estonia OEL TWA (mg/m³) 4,5 mg/m³ Estonia OEL TWA (ppm) 1 ppm Estonia OEL STEL (mg/m³) 10 mg/m³ Estonia OEL STEL (ppm) 2 ppm Finland HTP-arvo (8h) (mg/m³) 4,3 mg/m³ Finland HTP-arvo (8h) (ppm) 1 ppm Finland HTP-arvo (15 min) 13 mg/m³ Finland HTP-arvo (15 min) (ppm) 3 ppm France VME (mg/m³) 4 mg/m³ France VME (ppm) 1 ppm Greece OEL TWA (mg/m³) 4 mg/m³ Greece OEL TWA (ppm) 1 ppm Hungary AK-érték 4 mg/m³ Hungary CK-érték 4 mg/m³ Ireland OEL (8 hours ref) (mg/m³) 4 mg/m³ Ireland OEL (8 hours ref) (ppm) 1 ppm Ireland OEL (15 min ref) (mg/m3) 12 mg/m³ (calculated) Ireland OEL (15 min ref) (ppm) 3 ppm (calculated) Lithuania IPRV (mg/m³) 4,5 mg/m³ Lithuania IPRV (ppm) 1 ppm Lithuania TPRV (mg/m³) 10 mg/m³ Lithuania TPRV (ppm) 2 ppm Poland NDS (mg/m³) 4 mg/m³ Poland NDSCh (mg/m³) 12 mg/m³ Portugal OEL TWA (ppm) 1 ppm Romania OEL TWA (mg/m³) 2 mg/m³ Romania OEL TWA (ppm) 0,5 ppm Romania OEL STEL (mg/m³) 4 mg/m³ Romania OEL STEL (ppm) 1 ppm Spain VLA-ED (mg/m³) 4,3 mg/m³ Spain VLA-ED (ppm) 1 ppm Sweden nivågränsvärde (NVG) (mg/m³) 4,5 mg/m³ Sweden nivågränsvärde (NVG) (ppm) 1 ppm Sweden kortidsvärde (KTV) (mg/m³) 10 mg/m³ Sweden kortidsvärde (KTV) (ppm) 2 ppm United Kingdom WEL TWA (mg/m³) 4,3 mg/m³ United Kingdom WEL TWA (ppm) 1 ppm United Kingdom WEL STEL (mg/m³) 12,9 mg/m³ (calculated) United Kingdom WEL STEL (ppm) 3 ppm (calculated) Norway Grenseverdier (AN) (mg/m³) 4 mg/m³

12 Page : 12 / 21 2,2'-iminodiethylamine, diethylenetriamine ( ) Norway Grenseverdier (AN) (ppm) 1 ppm Norway Grenseverdier (Korttidsverdi) (mg/m3) 4 mg/m³ Norway Grenseverdier (Korttidsverdi) (ppm) 1 ppm Switzerland VME (mg/m³) 4 mg/m³ Switzerland VME (ppm) 1 ppm Australia TWA (mg/m³) 4,2 mg/m³ Australia TWA (ppm) 1 ppm Canada (Quebec) VEMP (mg/m³) 4,2 mg/m³ Canada (Quebec) VEMP (ppm) 1 ppm USA - ACGIH ACGIH TWA (ppm) 1 ppm USA - NIOSH NIOSH REL (TWA) (mg/m³) 4 mg/m³ USA - NIOSH NIOSH REL (TWA) (ppm) 1 ppm 8.2. Exposure controls Engineering control measures Personal protection equipment Hand protection Eye protection Body protection Respiratory protection Thermal hazard protection : Local exhaust and general ventilation must be adequate to meet exposure standards. Organisational measures to prevent /limit releases, dispersion and exposure. Safe handling: see section 7. Use only at a place, which is equipped with a safety shower. Provide eye shower and label its location conspicuously. : The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. : Wear chemically resistant gloves (tested to EN374). Suitable material: NBR (Nitrile rubber), Neoprene. The quality of the protective gloves resistant to chemicals must be chosen as a function of the specific working place concentration and quantity of hazardous substances. : Use suitable eye protection. (EN166): Goggles. Face protection shield : Wear suitable protective clothing. Wear suitable coveralls to prevent exposure to the skin. Chemical protection clothing. Chemical resistant safety shoes : In case of insufficient ventilation, wear suitable respiratory equipment. Effective dust mask (EN 149). Half-face mask (EN 140). Full face mask (EN 136). Filter type: ABEK + P (EN 143). The filter class must be suitable for the maximum contaminant concentration (gas/vapour/aerosol/particulates) that may arise when handling the product. If the concentration is exceeded, self-contained breathing apparatus must be used. (EN 137) : Not required under normal use. Use dedicated equipment. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : liquid Appearance : Paste. Colour : white. Yellow. Odour : Amines. Odour threshold ph Relative evaporation rate (butylacetate=1) Melting point/freezing point Freezing point Initial boiling point and boiling range Flash point

13 Page : 13 / 21 Auto-ignition temperature Decomposition temperature Flammability (solid, gas) Vapour pressure Vapour density : Not applicable,liquid Relative density : 1,2-1,25 Solubility Partition coefficient n-octanol/water Kinematic viscosity Dynamic viscosity Explosive properties Oxidising properties Explosive limits 9.2. Other information No data available SECTION 10: Stability and reactivity Reactivity. Water : Not applicable. : Not applicable. Non flammable. Exothermic reaction with: Epoxy resin, Peroxides. Reference to other sections: 10.4 & Chemical stability The product is stable under storage at normal ambient temperatures Possibility of hazardous reactions Exothermic reaction with: Epoxy resin. Danger of explosion on contact with : Peroxides Conditions to avoid Safe handling: see section Incompatible materials Sodium hypochlorite. Acids. Oxidising substances. Peroxides. Safe handling: see section Hazardous decomposition products Reference to other sections: 5.2. Carbon oxides (CO, CO2). Nitrogen oxides. ammonia. SECTION 11: Toxicological information Information on toxicological effects Acute toxicity ATE CLP (oral) : Oral: Harmful if swallowed. 1550, mg/kg bodyweight Methanol ( ) LD50/oral/rat 6200 mg/kg LC50/inhalation/4h/rat (ppm) ppm (Exposure time: 8 h) 2,4,6-tris(dimethylaminomethyl)phenol ( ) LD50/oral/rat 1200 mg/kg LD50/dermal/rat 1280 mg/kg ethylbenzene ( ) LD50/oral/rat LD50/dermal/rabbit LC50/inhalation/4h/rat 3500 mg/kg mg/kg 17,2 mg/l/4h

14 Page : 14 / 21 m-phenylenebis(methylamine) ( ) LD50/oral/rat 660 mg/kg LD50/dermal/rabbit 2 g/kg LC50/inhalation/4h/rat (ppm) 700 ppm/1h 2,2'-iminodiethylamine, diethylenetriamine ( ) LD50/oral/rat 1080 mg/kg LD50/dermal/rabbit 672 mg/kg LC50/inhalation/4h/rat 70 mg/l/4h Skin corrosion/irritation Serious eye damage/eye irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity Reproductive toxicity STOT-single exposure STOT-repeated exposure Aspiration hazard : Causes severe skin burns and eye damage. ph : Causes severe skin burns and eye damage. ph : May cause an allergic skin reaction. : Not classified (Based on available data, the classification criteria are not met.) : Not classified (Based on available data, the classification criteria are not met.) : Not classified (Based on available data, the classification criteria are not met.) : Not classified (Based on available data, the classification criteria are not met.) : Not classified (Based on available data, the classification criteria are not met.) : Not classified (Based on available data, the classification criteria are not met.) Other information : Symptoms related to the physical, chemical and toxicological characteristics. For further information see section 4. SECTION 12: Ecological information Toxicity Environmental properties : Very toxic to aquatic life with long lasting effects. Methanol ( ) LC50 fish mg/l (Exposure time: 96 h - Species: Pimephales promelas [flow-through]) EC50 Daphnia 1 > mg/l LC50 fish 2 > 100 mg/l (Exposure time: 96 h - Species: Pimephales promelas [static]) ethylbenzene ( ) LC50 fish 1 11,0-18,0 mg/l (Exposure time: 96 h - Species: Oncorhynchus mykiss [static]) EC50 Daphnia 1 1,8-2,4 mg/l (Exposure time: 48 h - Species: Daphnia magna) LC50 fish 2 4,2 mg/l (Exposure time: 96 h - Species: Oncorhynchus mykiss [semi-static]) 2,2'-iminodiethylamine, diethylenetriamine ( ) LC50 fish mg/l (Exposure time: 96 h - Species: Poecilia reticulata [static]) EC50 Daphnia 1 16 mg/l (Exposure time: 48 h - Species: Daphnia magna) LC50 fish mg/l (Exposure time: 96 h - Species: Poecilia reticulata [semi-static]) Persistence and degradability Persistence and degradability Bioaccumulative potential Partition coefficient n-octanol/water Methanol ( ) BCF fish 1 < 10 Partition coefficient n-octanol/water -0,77 Not readily biodegradable (according to OECD criteria). No data available

15 Page : 15 / 21 ethylbenzene ( ) BCF fish 1 15 Partition coefficient n-octanol/water 3,118 2,2'-iminodiethylamine, diethylenetriamine ( ) BCF fish 1 0,3-1,7 Partition coefficient n-octanol/water -1, Mobility in soil Ecology - soil Results of PBT and vpvb assessment No data available No data available Other adverse effects Additional information SECTION 13: Disposal considerations Waste treatment methods Waste treatment methods Waste disposal recommendations Additional information Codes of waste (2001/573/EC, 75/442/EEC, 91/689/EEC) SECTION 14: Transport information In accordance with ADR / RID / IMDG / IATA / ADN UN number UN number : 2735 UN-No : 2735 UN-No : 2735 UN-No. (ADN) : 2735 UN-No. (RID) : UN proper shipping name Proper Shipping Name Proper Shipping Name (IMDG) Proper Shipping Name (IATA) Proper Shipping Name (ADN) Proper Shipping Name (RID) Transport document description (ADR) Transport document description (IMDG) Transport hazard class(es) ADR Transport hazard class(es) (ADR) : 8 : Dispose of contents/container in accordance with licensed collector s sorting instructions. : Do not allow contact with soil, surface or ground water. Dispose of empty containers and wastes safely. Safe handling: see section 7. Refer to manufacturer/supplier for information on recovery/recycling. : Handle contaminated packages in the same way as the substance itself. Dispose of contaminated materials in accordance with current regulations. : This material and its container must be disposed of as hazardous waste Waste codes should be assigned by the user based on the application for which the product was used. : AMINES, LIQUID, CORROSIVE, N.O.S. : AMINES, LIQUID, CORROSIVE, N.O.S. : Amines, liquid, corrosive, n.o.s. : AMINES, LIQUID, CORROSIVE, N.O.S. : AMINES, LIQUID, CORROSIVE, N.O.S. : UN 2735 AMINES, LIQUID, CORROSIVE, N.O.S. (m-phenylenebis(methylamine)), 8, II, (E), ENVIRONMENTALLY HAZARDOUS : UN 2735 AMINES, LIQUID, CORROSIVE, N.O.S., 8, II, MARINE POLLUTANT/ENVIRONMENTALLY HAZARDOUS

16 Page : 16 / 21 Danger labels (ADR) : 8 : IMDG Transport hazard class(es) (IMDG) : 8 Danger labels (IMDG) : 8 : IATA Transport hazard class(es) (IATA) : 8 Hazard labels (IATA) : 8 : ADN Transport hazard class(es) (ADN) : 8 Danger labels (ADN) : 8 : RID Transport hazard class(es) (RID) : 8 Danger labels (RID) : 8 : Packing group Packing group (ADR) Packing group (IMDG) Packing group (IATA) Packing group (ADN) Packing group (RID) : II : II : II : II : II

17 Page : 17 / Environmental hazards Dangerous for the environment Marine pollutant Other information : Yes : Yes : No supplementary information available Special precautions for user Special precautions for user - Overland transport Classification code (ADR) : C7 Special Provisions : 274 Limited quantities (ADR) Excepted quantities (ADR) Packing instructions (ADR) Mixed packing provisions (ADR) Portable tank and bulk container instructions (ADR) Portable tank and bulk container special provisions (ADR) Tank code (ADR) Vehicle for tank carriage : 1l : E2 : P001, IBC02 : MP15 : T11 : TP1, TP27 : L4BN : AT Transport category (ADR) : 2 Hazard identification number (Kemler No.) : 80 Orange plates : tunnel restriction code EAC code APP code : E : 2X : B - Transport by sea Special provisions (IMDG) : 274 Limited quantities (IMDG) Excepted quantities (IMDG) Packing instructions (IMDG) IBC packing instructions (IMDG) Tank instructions (IMDG) Tank special provisions (IMDG) EmS-No. (Fire) EmS-No. (Spillage) Stowage category (IMDG) Stowage and segregation (IMDG) Properties and observations (IMDG) : 1 L : E2 : P001 : IBC02 : T11 : TP1, TP27 : F-A : S-B : A : 'Separated from' acids. : Colourless to yellowish liquids or solutions with a pungent odour. Miscible with or soluble in water. When involved in a fire, evolve toxic gases. Corrosive to most metals, especially to copper and its alloys. Reacts violently with acids. Cause burns to skin, eyes and mucous membranes. - Air transport PCA Excepted quantities (IATA) PCA Limited quantities (IATA) : E2 : Y840

18 Page : 18 / 21 PCA limited quantity max net quantity (IATA) : 0.5L PCA packing instructions (IATA) : 851 PCA max net quantity (IATA) : 1L CAO packing instructions (IATA) : 855 CAO max net quantity (IATA) Special provisions (IATA) ERG code (IATA) - Inland waterway transport Classification code (ADN) : 30L : A3 : 8L : C7 Special provisions (ADN) : 274 Limited quantities (ADN) Excepted quantities (ADN) Carriage permitted (ADN) Equipment required (ADN) : 1 L : E2 : T Number of blue cones/lights (ADN) : 0 Carriage prohibited (ADN) Not subject to ADN - Rail transport Classification code (RID) : PP, EP : No : No : C7 Special provisions (RID) : 274 Limited quantities (RID) Excepted quantities (RID) Packing instructions (RID) Mixed packing provisions (RID) Portable tank and bulk container instructions (RID) Portable tank and bulk container special provisions (RID) Tank codes for RID tanks (RID) : 1L : E2 : P001, IBC02 : MP15 : T11 Transport category (RID) : 2 Colis express (express parcels) (RID) : TP1, TP27 : L4BN : CE6 Hazard identification number (RID) : 80 Carriage prohibited (RID) : No Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Code: IBC SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture EU-Regulations The following restrictions are applicable according to Annex XVII of the REACH Regulation (EC) No 1907/2006: 3. Liquid substances or mixtures which are regarded as dangerous in accordance with Directive 1999/45/EC or are fulfilling the criteria for any of the following hazard classes or categories set out in Annex I to Regulation (EC) No 1272/2008 Formaldehyde, oligomeric reaction products with phenol and m-phenylenebis(methylamine) - N- (2-aminoethyl)-N'-[3- (trimethoxysilyl)propyl]ethylenediamine - Methanol - 2,4,6- tris(dimethylaminomethyl)phenol - ethylbenzene - 2,2'-iminodiethylamine, diethylenetriamine

19 Page : 19 / 21 3.a. Substances or mixtures fulfilling the criteria for any of the following hazard classes or categories set out in Annex I to Regulation (EC) No 1272/2008: Hazard classes 2.1 to 2.4, 2.6 and 2.7, 2.8 types A and B, 2.9, 2.10, 2.12, 2.13 categories 1 and 2, 2.14 categories 1 and 2, 2.15 types A to F 3.b. Substances or mixtures fulfilling the criteria for any of the following hazard classes or categories set out in Annex I to Regulation (EC) No 1272/2008: Hazard classes 3.1 to 3.6, 3.7 adverse effects on sexual function and fertility or on development, 3.8 effects other than narcotic effects, 3.9 and c. Substances or mixtures fulfilling the criteria for any of the following hazard classes or categories set out in Annex I to Regulation (EC) No 1272/2008: Hazard class Substances classified as flammable gases category 1 or 2, flammable liquids categories 1, 2 or 3, flammable solids category 1 or 2, substances and mixtures which, in contact with water, emit flammable gases, category 1, 2 or 3, pyrophoric liquids category 1 or pyrophoric solids category 1, regardless of whether they appear in Part 3 of Annex VI to Regulation (EC) No 1272/2008 or not. Contains no substance on the REACH candidate list Contains no REACH Annex XIV substances Methanol - ethylbenzene - N-(2-aminoethyl)-N'-[3- (trimethoxysilyl)propyl]ethylenediamine - Methanol - 2,4,6- tris(dimethylaminomethyl)phenol - ethylbenzene - m-phenylenebis(methylamine) - 2,2'- iminodiethylamine, diethylenetriamine - Formaldehyde, oligomeric reaction products with phenol and m- phenylenebis(methylamine) - N-(2-aminoethyl)- N'-[3-(trimethoxysilyl)propyl]ethylenediamine - ethylbenzene - m-phenylenebis(methylamine) Methanol - ethylbenzene National regulations Germany VwVwS Annex reference 12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV : Water hazard class (WGK) 3, severe hazard to waters (Classification according to VwVwS, Annex 4) : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance) Netherlands SZW-lijst van kankerverwekkende stoffen SZW-lijst van mutagene stoffen NIET-limitatieve lijst van voor de voortplanting giftige stoffen Borstvoeding NIET-limitatieve lijst van voor de voortplanting giftige stoffen Vruchtbaarheid NIET-limitatieve lijst van voor de voortplanting giftige stoffen Ontwikkeling Denmark Classification remarks Recommendations Danish Regulation : None of the components are listed : None of the components are listed : None of the components are listed : None of the components are listed : Methanol is listed : Emergency management guidelines for the storage of flammable liquids must be followed : Young people below the age of 18 years are not allowed to use the product Pregnant/breastfeeding women working with the product must not be in direct contact with the product Chemical safety assessment Chemical safety assessments for substances in this mixture were not carried out. SECTION 16: Other information

20 Page : 20 / 21 Abbreviations and acronyms: ABM = Algemene beoordelingsmethodiek ADN = Accord Européen relatif au Transport International des Marchandises Dangereuses par voie de Navigation du Rhin ADR = Accord européen relatif au transport international des marchandises Dangereuses par Route CLP = Classification, Labelling and Packaging Regulation according to 1272/2008/EC IATA = International Air Transport Association IMDG = International Maritime Dangerous Goods Code LEL = Lower Explosive Limit/Lower Explosion Limit UEL = Upper Explosion Limit/Upper Explosive Limit REACH = Registration, Evaluation, Authorisation and Restriction of Chemicals BTT = Breakthrough time (maximum wearing time) DMEL = Derived Minimal Effect level DNEL = Derived No Effect Level EC50 = Median Effective Concentration EL50 = Median effective level ErC50 = EC50 in terms of reduction of growth rate ErL50 = EL50 in terms of reduction of growth rate EWC = European waste catalogue LC50 = Median lethal concentration LD50 = Median lethal dose LL50 = Median lethal level NA = Not applicable NOEC = No observed effect concentration NOEL: no-observed-effect level NOELR = No observed effect loading rate NOAEC = No observed adverse effect concentration NOAEL = No observed adverse effect level N.O.S. = Not Otherwise Specified OEL = Occupational Exposure Limits - Short Term Exposure Limits (STELs) PNEC = Predicted No Effect Concentration Quantitative structure-acivity relationship (QSAR) STOT = Specific Target Organ Toxicity TWA = time weighted average VOC = Volatile organic compounds WGK = Wassergefährdungsklasse (Water Hazard Class under German Federal Water Management Act) Full text of H- and EUH-statements: Acute Tox. 2 (Inhalation) Acute toxicity (inhal.), Category 2 Acute Tox. 3 (Dermal) Acute toxicity (dermal), Category 3 Acute Tox. 3 (Inhalation:vapour) Acute toxicity (inhal.), Category 3 Acute Tox. 3 (Oral) Acute toxicity Category 3 Acute Tox. 4 (Dermal) Acute toxicity (dermal), Category 4 Acute Tox. 4 (Inhalation) Acute toxicity (inhal.), Category 4 Acute Tox. 4 (Inhalation:vapour) Acute toxicity (inhal.), Category 4 Acute Tox. 4 (Oral) Acute toxicity Category 4 Aquatic Acute 1 Hazardous to the aquatic environment - Aquatic Acute 1 Aquatic Chronic 1 Hazardous to the aquatic environment - chronic hazard category 1 Aquatic Chronic 2 Hazardous to the aquatic environment - chronic hazard category 2

21 Page : 21 / 21 Aquatic Chronic 3 Hazardous to the aquatic environment - chronic hazard category 3 Asp. Tox. 1 Aspiration hazard, Category 1 Eye Dam. 1 Serious eye damage/eye irritation Category 1 Eye Irrit. 2 Serious eye damage/eye irritation Category 2 Flam. Liq. 2 Flammable liquids, Category 2 Skin Corr. 1B Skin corrosion/irritation, Category 1B Skin Irrit. 2 Skin corrosion/irritation, Category 2 Skin Sens. 1 Skin sensitisation, hazard category 1 STOT RE 2 Specific target organ toxicity Repeated exposure, Category 2 STOT SE 1 Specific target organ toxicity single exposure, Category 1 STOT SE 3 H225 H301 H302 H304 H311 H312 H314 H315 H317 H318 H319 H330 H331 H332 H335 H370 H373 H400 H410 H411 H412 Specific target organ toxicity Single exposure, Category 3, Respiratory tract irritation Highly flammable liquid and vapour. Toxic if swallowed. Harmful if swallowed. May be fatal if swallowed and enters airways. Toxic in contact with skin. Harmful in contact with skin. Causes severe skin burns and eye damage. Causes skin irritation. May cause an allergic skin reaction. Causes serious eye damage. Causes serious eye irritation. Fatal if inhaled. Toxic if inhaled. Harmful if inhaled. May cause respiratory irritation. Causes damage to organs. May cause damage to organs through prolonged or repeated exposure. Very toxic to aquatic life. Very toxic to aquatic life with long lasting effects. Toxic to aquatic life with long lasting effects. Harmful to aquatic life with long lasting effects. The contents and format of this SDS are in accordance with EEC Commission Directive 1999/45/EC, 67/548/EC, 1272/2008/EC and EEC Commission Regulation 1907/2006/EC (REACH) Annex II. DISCLAIMER OF LIABILITY The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This SDS was prepared and is to be used only for this product. If the product is used as a component in another product, this SDS information may not be applicable.