CERTIFICATE. EN tested QAL 1 certified TUV approved Annual inspection. The certificate is valid until: 28 July 2016

Transcription

1 I Umwelt Bundes For our Environment A TÜVRheinland Precisely Right. CERTIFICATE on Product Conformity {QAL 1) Number of Certificate: _ Certified AMS: : Gasmet CEMS for CO, NO, N0, N0, S0, HCI, HF, NH3, C0, H0 and Helsinki Pulttitie BA 1 Finland ~~~ Test Institute: Energie und Umwelt GmbH This is to certify that the AMS has been tested and found to comply with: EN :009, EN 1567-:009, EN : 007 and EN 14181: 004 Certification is awarded in respect of the conditions stated in this certificate ( see also the following pages ). The present certificate replaces Certificate No of 19 August 011 EN tested QAL 1 certified TUV approved Annual inspection Publication in the German Federal Gazette (BAnz.) of 0 July 01 Umweltbundesamt Dessau, 0 August 01 The certificate is valid until: 8 July 016 Energie und Umwelt GmbH Köln, 17 August 01 ;1'~~ ~;~~;~~~ I teu@umwelt-tuv.de Tel ppa. Dr. Peter Wilbring TUV Rheinland Energie und Umwelt GmbH Am Grauen Stein Köln Accreditation according to EN ISO/IEC 1705 and certified according to ISO 9001:008. ~-=-=-=-=~--q~a~l1~.d~e--~=====================--i~nf~o~@~q~al~1 -~de~~==================~~pa~g~e_1_o_f _16 ~,

2 : 936/118384/A of 16 March 01 First certification: 9 July 011 Validity ends: 8 July 016 Publication: BAnz AT 0 July 01 B11, chapter 1, No. 3.1 Approved application The tested AMS is suitable for the use at combustion plants according to EC directive EC, at waste incinerations plants according to EC directive EC and other plants requiring official permission. The tested ranges have been chosen with respect to the wide application range of the AMS. The suitability of the AMS for this application was assessed on the basis of a laboratory test and a three months field test at a municipal waste incinerator. The AMS is authorised for the ambient temperature range from +5 C to +40 C. Any potential user should ensure, in consultation with the manufacturer, that this AMS is suitable for the installation at which it will be installed. Basis of the certification This certification is based on: test report 936/11069/A of 30 March 011 of Energie und Umwelt GmbH and test report 936/118384/A of 16 March 01 of Energie und Umwelt GmbH suitability announced by the German Environmental Agency (UBA) as the relevant body the ongoing surveillance of the product and the manufacturing process publication in the German Federal Gazette: BAnz AT 0 July 01 B11, chapter 1, No. 3.1 qal1.de info@qal1.de page of 16

3 AMS name: Gasmet CEMS for CO, NO, NO, N O, SO, HCl, HF, NH 3, CO, H O and O :, Helsinki, Finland Approval: For measurements at plants requiring official approval (i. e. plants in EC, waste incineration directive and EC large combustion plants directive) Measuring ranges during the suitability test: Component Certification range supplementary measurement ranges Unit CO mg/m³ NO mg/m³ NO mg/m³ N O mg/m³ SO mg/m³ HCl mg/m³ HF mg/m³ NH mg/m³ CO Vol.-% H O Vol.-% O Vol.-% Software versions: Calcmet: with analysing unit 4.4., OXITEC Ver np Restrictions: None Remarks: 1. Wet test gases shall be used for testing HF, HCl and NH 3.. The maintenance interval is four weeks. 3. After disruptions of plant operation, the sampling probe needs to be cleaned. 4. For O measurements, the OXITEC 500E SME 5 analyser manufactured by ENOTEC GmbH, Marienheide, Germany is integrated. 5. Complementary testing (conversion to DIN EN 1567) to Federal Environmental Agency notice of 15 July 011 (Federal Journal (BAnz.) p. 75, Chapter I, No. 4.1 and Chapter III, 10 th notification). : Energie und Umwelt GmbH, Köln Report No.: 936/118384/A of 16 March 01 qal1.de info@qal1.de page 3 of 16

4 Certified product This certificate applies to automated measurement systems confirming to the following description: The measuring equipment Gasmet CEMS consist of the following parts: 1) Sampling system Sampling probe: Heated line: Pump: ) Analysers 1: HF: O : SP000H of the company of M & C, 1 m length, to 180 C heated, with PFTE filter element: µm 180 C with 4 mm teflon tube, 5 m length, (standard 5 to 30 m) heated to 180 C, with teflon membrane Gasmet CX-4000, cell temperature: 180 C, cell with optical path length: 5 m Gasmet CX-4001 for HF, cell temperature: 180 C, optical path length: 10 m ZrO test cell OXITEC 500E SME 5 in the 19''-box to the company ENOTEC with the software OXITEC Ver. 1,50 np TOC: Total-C measuring equipment Thermo-FID of the company M&A The measuring gas is pressed continuously through the three analysers in parallel (1, HF and O -measurement) by the sample pump. The amount of the gas is controlled. The injector pump of the TOC system takes a partial gas stream upstream the pump unit. 3) Computer PC standard with at least 51 MB RAM, serial interfaces, analogue input card for O and TOCanalyser, network access and Windows XP. For the evaluation of the spectrums of the analyser the spectrums are transferred via a RS3- interface into the computer and processed there. In this computer also the interface cards for the Analogous and Digital in- and output are integrated. The computer takes over also the control of sampling and the gas flows of the analysers. 4) Software The evaluation-software Calcmet is based on Windows for the Gasmet CEMS. 5) Measuring cabinet with Air-conditioning on approx. 30 C, Sampling pump, Control units, Analysers and Computer General notes This certificate is based upon the equipment tested. The manufacturer is responsible for ensuring that on-going production complies with the requirements of the EN The manufacturer is required to maintain an approved quality management system controlling the manufacture of the certified product. Both the product and the quality management systems shall be subject to regular surveillance. If a product of the current production does not conform to the certified product, Energie und Umwelt GmbH must be notified at the address given on page 1. A certification mark with an ID-Number that is specific to the certified product is presented on page 1 of this certificate. This can be applied to the product or used in publicity material for the certified product. This document as well as the certification mark remains property of Energie und Umwelt GmbH. With revocation of the publication the certificate looses its validity. After the expiration of the validity of the certificate and on requests of the Energie und Umwelt GmbH this document shall be returned and the certificate mark must not be employed anymore. The relevant version of this certificate and the validity is also accessible on the internet Address: qal1.de. qal1.de info@qal1.de page 4 of 16

5 Certification of Gasmet CEMS for CO, NO, NO, N O, SO, HCl, HF, NH 3, CO, H O and O is based on the documents listed below and the regular, continuous monitoring of the Quality Management System of the manufacturer: Initial test Baseline report 936/100448/A dated 07 July 006 TÜV Immissionsschutz und Energiesysteme GmbH, Cologne Publication: Federal Gazette (BAnz.) of 14 October 006, No. 194, p Notification of the Federal Environmental Agency of 1 September 006 Supplementary test report (Additional component: O ) 936/10340/B dated 03 September 007 TÜV Immissionsschutz und Energiesysteme GmbH, Cologne Publication: Federal Gazette (BAnz.) of 07 March 008, No. 38, p. 901 Notification of the Federal Environmental Agency of 14 February 008 Notifications Publication: Federal Gazette (BAnz.) 0 April 007, No. 75, p. 4139ff Notification of the Federal Environmental Agency of 1 April 007 (enclosure variants) Publication: Federal Gazette (BAnz.) 9 July 011, No. 133, p Notification of the Federal Environmental Agency of 15 July 011 (changes in software version) Initial certification according to EN 1567 Certificate No : 19 August 011 Validity of the certificate: 8 July 016 : 936/11069/A of 30 March 011 Energie und Umwelt GmbH, Köln Publication: BAnz. 9 July 011, No. 113, p. 75, chapter I, No. 4.1 Announcement by UBA from 15 July 011 Supplementary testing according to EN 1567 Certificate No _01: 0 August 01 Validity of the certificate: 8 July 016 : 936/118384/A of 16 March 01 Energie und Umwelt GmbH, Köln Publication: BAnz AT 0 July 01 B11, chapter 1, No. 3.1 Announcement by UBA from 06 July 01 qal1.de info@qal1.de page 5 of 16

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7 936/118384/A Measured component CO Certification range 0-5 Vol.-% Sum of positive CS at zero point 0.00 Vol.-% Sum of negative CS at zero point 0.00 Vol.-% Sum of postive CS at reference point 0.10 Vol.-% Sum of negative CS at reference point Vol.-% Maximum sum of cross sensitivities Vol.-% Uncertainty of cross sensitivity Vol.-% Standard deviation from paired measurements under field conditions * u D Vol.-% (Vol.-%)² Lack of fit u lof Vol.-% (Vol.-%)² Zero drift from field test u d,z Vol.-% (Vol.-%)² Span drift from field test u d,s Vol.-% (Vol.-%)² Influence of ambient temperature at span u t 0.31 Vol.-% (Vol.-%)² Influence of supply voltage u v Vol.-% (Vol.-%)² Cross sensitivity (interference) u i Vol.-% 0.70 (Vol.-%)² Influence of sample gas flow u p Vol.-% (Vol.-%)² Uncertainty of reference material at 70% of certification range u rm 0.0 Vol.-% (Vol.-%)² 0.64 Vol.-% Total expanded uncertainty U = u c * k = u c * Vol.-% Relative total expanded uncertainty U in % of the range 5 Vol.-% 5.0 Requirement of 000/76/EC and 001/80/EC U in % of the range 5 Vol.-% 10.0 Requirement of EN U in % of the range 5 Vol.-% 7.5 ** For this component no requirements in the EC-directives 001/80/EG und 000/76/EG are given. The chosen value is recommended by the certification body. qal1.de info@qal1.de page 7 of 16

8 936/118384/A Measured component CO Certification range 0-75 mg/m³ Sum of positive CS at zero point 0.3 mg/m³ Sum of negative CS at zero point 0.00 mg/m³ Sum of postive CS at reference point 1.90 mg/m³ Sum of negative CS at reference point mg/m³ Maximum sum of cross sensitivities 1.90 mg/m³ Uncertainty of cross sensitivity mg/m³ Standard deviation from paired measurements under field conditions * u D mg/m³ 0.8 (mg/m³)² Lack of fit u lof mg/m³ (mg/m³)² Zero drift from field test u d,z mg/m³ (mg/m³)² Span drift from field test u d,s 0.89 mg/m³ (mg/m³)² Influence of ambient temperature at span u t 0.08 mg/m³ (mg/m³)² Influence of supply voltage u v 0.98 mg/m³ (mg/m³)² Cross sensitivity (interference) u i mg/m³ 1.00 (mg/m³)² Influence of sample gas flow u p mg/m³ (mg/m³)² Uncertainty of reference material at 70% of certification range u rm mg/m³ (mg/m³)² 1.54 mg/m³ Total expanded uncertainty U = u c * k = u c * mg/m³ Relative total expanded uncertainty U in % of the ELV 50 mg/m³ 6.0 Requirement of 000/76/EC and 001/80/EC U in % of the ELV 50 mg/m³ 10.0 Requirement of EN U in % of the ELV 50 mg/m³ 7.5 qal1.de info@qal1.de page 8 of 16

9 936/118384/A Measured component H O Certification range 0-30 Vol.-% Sum of positive CS at zero point 0.00 Vol.-% Sum of negative CS at zero point 0.00 Vol.-% Sum of postive CS at reference point 1.10 Vol.-% Sum of negative CS at reference point Vol.-% Maximum sum of cross sensitivities 1.10 Vol.-% Uncertainty of cross sensitivity 0.63 Vol.-% Standard deviation from paired measurements under field conditions * u D 0.9 Vol.-% (Vol.-%)² Lack of fit u lof 0.30 Vol.-% (Vol.-%)² Zero drift from field test u d,z Vol.-% (Vol.-%)² Span drift from field test u d,s Vol.-% (Vol.-%)² Influence of ambient temperature at span u t 0.31 Vol.-% (Vol.-%)² Influence of supply voltage u v 0.6 Vol.-% (Vol.-%)² Cross sensitivity (interference) u i 0.63 Vol.-% (Vol.-%)² Influence of sample gas flow u p 0.11 Vol.-% (Vol.-%)² Uncertainty of reference material at 70% of certification range u rm 0.4 Vol.-% (Vol.-%)² 0.95 Vol.-% Total expanded uncertainty U = u c * k = u c * Vol.-% Relative total expanded uncertainty U in % of the range 30 Vol.-% 6. Requirement of 000/76/EC and 001/80/EC U in % of the range 30 Vol.-% 10.0 Requirement of EN U in % of the range 30 Vol.-% 7.5 ** For this component no requirements in the EC-directives 001/80/EG und 000/76/EG are given. The chosen value is recommended by the certification body. qal1.de info@qal1.de page 9 of 16

10 936/118384/A Measured component HCL Certification range 0-15 mg/m³ Sum of positive CS at zero point 0.00 mg/m³ Sum of negative CS at zero point mg/m³ Sum of postive CS at reference point 0.60 mg/m³ Sum of negative CS at reference point mg/m³ Maximum sum of cross sensitivities 0.60 mg/m³ Uncertainty of cross sensitivity mg/m³ Standard deviation from paired measurements under field conditions * u D 0.09 mg/m³ (mg/m³)² Lack of fit u lof mg/m³ (mg/m³)² Zero drift from field test u d,z mg/m³ (mg/m³)² Span drift from field test u d,s mg/m³ (mg/m³)² Influence of ambient temperature at span u t 0.65 mg/m³ (mg/m³)² Influence of supply voltage u v mg/m³ (mg/m³)² Cross sensitivity (interference) u i mg/m³ 0.10 (mg/m³)² Influence of sample gas flow u p mg/m³ 0.00 (mg/m³)² Uncertainty of reference material at 70% of certification range u rm 0.11 mg/m³ (mg/m³)² 0.61 mg/m³ Total expanded uncertainty U = u c * k = u c * mg/m³ Relative total expanded uncertainty U in % of the ELV 10 mg/m³ 1.0 Requirement of 000/76/EC and 001/80/EC U in % of the ELV 10 mg/m³ 40.0 Requirement of EN U in % of the ELV 10 mg/m³ 30.0 qal1.de info@qal1.de page 10 of 16

11 96/118384/A Measured component N O Certification range mg/m³ Sum of positive CS at zero point 0.00 mg/m³ Sum of negative CS at zero point 0.00 mg/m³ Sum of postive CS at reference point 3.0 mg/m³ Sum of negative CS at reference point mg/m³ Maximum sum of cross sensitivities 3.0 mg/m³ Uncertainty of cross sensitivity mg/m³ Standard deviation from paired measurements under field conditions * u D mg/m³ (mg/m³)² Lack of fit u lof mg/m³ (mg/m³)² Zero drift from field test u d,z mg/m³ (mg/m³)² Span drift from field test u d,s mg/m³ (mg/m³)² Influence of ambient temperature at span u t 0.5 mg/m³ (mg/m³)² Influence of supply voltage u v mg/m³ (mg/m³)² Cross sensitivity (interference) u i mg/m³ (mg/m³)² Influence of sample gas flow u p mg/m³ (mg/m³)² Uncertainty of reference material at 70% of certification range u rm mg/m³ (mg/m³)².4 mg/m³ Total expanded uncertainty U = u c * k = u c * mg/m³ Relative total expanded uncertainty U in % of the range 100 mg/m³ 4.4 Requirement of 000/76/EC and 001/80/EC U in % of the range 100 mg/m³ 0.0 Requirement of EN U in % of the range 100 mg/m³ 15.0 ** For this component no requirements in the EC-directives 001/80/EG und 000/76/EG are given. The chosen value is recommended by the certification body. qal1.de info@qal1.de page 11 of 16

12 936/118384/A Measured component NH 3 Certification range 0-15 mg/m³ Sum of positive CS at zero point 0.06 mg/m³ Sum of negative CS at zero point 0.00 mg/m³ Sum of postive CS at reference point 0.30 mg/m³ Sum of negative CS at reference point mg/m³ Maximum sum of cross sensitivities mg/m³ Uncertainty of cross sensitivity mg/m³ Standard deviation from paired measurements under field conditions * u D mg/m³ (mg/m³)² Lack of fit u lof mg/m³ (mg/m³)² Zero drift from field test u d,z mg/m³ (mg/m³)² Span drift from field test u d,s 0.31 mg/m³ (mg/m³)² Influence of ambient temperature at span u t mg/m³ (mg/m³)² Influence of supply voltage u v mg/m³ (mg/m³)² Cross sensitivity (interference) u i mg/m³ 0.10 (mg/m³)² Influence of sample gas flow u p mg/m³ (mg/m³)² Uncertainty of reference material at 70% of certification range u rm 0.11 mg/m³ (mg/m³)² 0.49 mg/m³ Total expanded uncertainty U = u c * k = u c * mg/m³ Relative total expanded uncertainty U in % of the ELV 10 mg/m³ 9.6 Requirement of 000/76/EC and 001/80/EC U in % of the ELV 10 mg/m³ 40.0 Requirement of EN U in % of the ELV 10 mg/m³ 30.0 ** For this component no requirements in the EC-directives 001/80/EG und 000/76/EG are given. The chosen value is recommended by the certification body. qal1.de info@qal1.de page 1 of 16

13 936/118384/A Measured component NO Certification range 0-00 mg/m³ Sum of positive CS at zero point 1.66 mg/m³ Sum of negative CS at zero point 0.00 mg/m³ Sum of postive CS at reference point 7.90 mg/m³ Sum of negative CS at reference point mg/m³ Maximum sum of cross sensitivities 7.90 mg/m³ Uncertainty of cross sensitivity mg/m³ Standard deviation from paired measurements under field conditions * u D 1.00 mg/m³ (mg/m³)² Lack of fit u lof mg/m³ 0.70 (mg/m³)² Zero drift from field test u d,z mg/m³ (mg/m³)² Span drift from field test u d,s.887 mg/m³ (mg/m³)² Influence of ambient temperature at span u t 0.59 mg/m³ 0.80 (mg/m³)² Influence of supply voltage u v mg/m³ 0.36 (mg/m³)² Cross sensitivity (interference) u i mg/m³ (mg/m³)² Influence of sample gas flow u p mg/m³ (mg/m³)² Uncertainty of reference material at 70% of certification range u rm mg/m³.613 (mg/m³)² 5.86 mg/m³ Total expanded uncertainty U = u c * k = u c * mg/m³ Relative total expanded uncertainty U in % of the ELV 00 mg/m³ 5.7 Requirement of 000/76/EC and 001/80/EC U in % of the ELV 00 mg/m³ 0.0 Requirement of EN U in % of the ELV 00 mg/m³ 15.0 qal1.de info@qal1.de page 13 of 16

14 936/118384/A Measured component NO Certification range 0-00 mg/m³ Sum of positive CS at zero point 1.14 mg/m³ Sum of negative CS at zero point 0.00 mg/m³ Sum of postive CS at reference point.40 mg/m³ Sum of negative CS at reference point mg/m³ Maximum sum of cross sensitivities mg/m³ Uncertainty of cross sensitivity mg/m³ Repeatability standard deviation at set point * u r mg/m³ (mg/m³)² Lack of fit u lof mg/m³ (mg/m³)² Zero drift from field test u d,z mg/m³ 1.03 (mg/m³)² Span drift from field test u d,s mg/m³ (mg/m³)² Influence of ambient temperature at span u t mg/m³ (mg/m³)² Influence of supply voltage u v 0.90 mg/m³ (mg/m³)² Cross sensitivity (interference) u i mg/m³ (mg/m³)² Influence of sample gas flow u p mg/m³ (mg/m³)² Uncertainty of reference material at 70% of certification range u rm mg/m³.613 (mg/m³)² 4.36 mg/m³ Total expanded uncertainty U = u c * k = u c * mg/m³ Relative total expanded uncertainty U in % of the ELV 131 mg/m³ 6.5 Requirement of 000/76/EC and 001/80/EC U in % of the ELV 131 mg/m³ 0.0 Requirement of EN U in % of the ELV 131 mg/m³ 15.0 qal1.de info@qal1.de page 14 of 16

15 Zirconia 936/118384/A Measured component O Certification range 0-5 Vol.-% Sum of positive CS at zero point 0.00 Vol.-% Sum of negative CS at zero point 0.00 Vol.-% Sum of postive CS at reference point 0.00 Vol.-% Sum of negative CS at reference point 0.00 Vol.-% Maximum sum of cross sensitivities 0.00 Vol.-% Uncertainty of cross sensitivity Vol.-% Standard deviation from paired measurements under field conditions * u D Vol.-% 0.00 (Vol.-%)² Lack of fit u lof Vol.-% (Vol.-%)² Zero drift from field test u d,z 0.09 Vol.-% (Vol.-%)² Span drift from field test u d,s Vol.-% (Vol.-%)² Influence of ambient temperature at span u t Vol.-% 0.07 (Vol.-%)² Influence of supply voltage u v Vol.-% (Vol.-%)² Cross sensitivity (interference) u i Vol.-% (Vol.-%)² Influence of sample gas flow u p Vol.-% (Vol.-%)² Uncertainty of reference material at 70% of certification range u rm 0.0 Vol.-% (Vol.-%)² 0.30 Vol.-% Total expanded uncertainty U = u c * k = u c * Vol.-% Relative total expanded uncertainty U in % of the range 5 Vol.-%.3 Requirement of 000/76/EC and 001/80/EC U in % of the range 5 Vol.-% 10.0 Requirement of EN U in % of the range 5 Vol.-% 7.5 ** For this component no requirements in the EC-directives 001/80/EG und 000/76/EG are given. The chosen value is recommended by the certification body. qal1.de info@qal1.de page 15 of 16

16 936/118384/A Measured component SO Certification range 0-75 mg/m³ Sum of positive CS at zero point 0.4 mg/m³ Sum of negative CS at zero point 0.00 mg/m³ Sum of postive CS at reference point.30 mg/m³ Sum of negative CS at reference point -.90 mg/m³ Maximum sum of cross sensitivities -.90 mg/m³ Uncertainty of cross sensitivity mg/m³ Repeatability standard deviation at set point * u r mg/m³ 0.17 (mg/m³)² Lack of fit u lof mg/m³ (mg/m³)² Zero drift from field test u d,z mg/m³ 0.10 (mg/m³)² Span drift from field test u d,s mg/m³ (mg/m³)² Influence of ambient temperature at span u t mg/m³ (mg/m³)² Influence of supply voltage u v mg/m³ (mg/m³)² Cross sensitivity (interference) u i mg/m³.808 (mg/m³)² Influence of sample gas flow u p 0.6 mg/m³ (mg/m³)² Uncertainty of reference material at 70% of certification range u rm mg/m³ (mg/m³)².40 mg/m³ Total expanded uncertainty U = u c * k = u c * mg/m³ Relative total expanded uncertainty U in % of the ELV 50 mg/m³ 9.4 Requirement of 000/76/EC and 001/80/EC U in % of the ELV 50 mg/m³ 0.0 Requirement of EN U in % of the ELV 50 mg/m³ 15.0 qal1.de info@qal1.de page 16 of 16