OSA H. advanced styrene acrylic dispersion. for hydroisolation products

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1 OSA H advanced styrene acrylic dispersion for hydroisolation products

SYNTHOS, the current name of the company (introduced in 2007), derives from a fusion of two words of Greek origin,

The name replicates the Company s mission which is to manufacture and supply its clients with chemical products

The name also reflects the nature of the Company s operations in chemical synthesis. SYNTHOS S.A.

Republic Wola Krzysztoporska The activity of SYNTHOS S.A.

and vinyl dispersion, and latex and dispersion adhesives), plant protection products and liposomes. SYNTHOS S.A.

makes sure that buyers are satisfied with the scope of raw materials, semi-finished products and chemical products.

character of products, attractive prices, ecological safety of their technologies and products, and on

This effort has been backed up by the implementation of a certified Integrated Quality, Environment and Work

In 2011, the company launched production of neodymium-catalyzed butadiene rubber (NdBR) in the production plant in

High quality neodymiumcatalyzed butadiene rubber is used for mixture for production of advanced car and truck

Dispersion and Adhesive manufacturing unit was added to Synthos S.A. In August 2015, Synthos S.A. completed the construction of a modern SSBR rubber production plant.

Both groups include acrylic and styrene-acrylic products as well as acrylic monomer copolymers with other monomers

2 Synexil Osakryl Synthos S.A. grew out of the companies Firma Chemiczna Dwory S.A. and Kaucuk a.s. SYNTHOS, the current name of the company (introduced in 2007), derives from a fusion of two words of Greek origin, synthesis (join) and orthos (proper, right). The name replicates the Company s mission which is to manufacture and supply its clients with chemical products for further processing, contributing to the development of each client s business. The name also reflects the nature of the Company s operations in chemical synthesis. SYNTHOS S.A. after acquisition of the INEOS Styrenics in August 2016, manages production plants in, Czech Republic, the Netherlands, and France. Oświęcim Sochaczew HEADQUARTER Breda Netherlands Wingles France Nowa Sarzyna Ribécourt France Kralupy Czech Republic Wola Krzysztoporska The activity of SYNTHOS S.A. concentrates on five main groups of products: synthetic rubbers, styrene plastics, specialist products (acrylic and vinyl dispersion, and latex and dispersion adhesives), plant protection products and liposomes. SYNTHOS S.A. is the largest European producer of synthetic rubbers and expandable polystyrenes (EPS). SYNTHOS S.A. makes sure that buyers are satisfied with the scope of raw materials, semi-finished products and chemical products. The company focuses its activities on quality and efficient customer service, as well as on the innovative character of products, attractive prices, ecological safety of their technologies and products, and on occupational safety. This effort has been backed up by the implementation of a certified Integrated Quality, Environment and Work Safety Management System. In 2011, the company launched production of neodymium-catalyzed butadiene rubber (NdBR) in the production plant in Czech Republic (Karlupy). High quality neodymiumcatalyzed butadiene rubber is used for mixture for production of advanced car and truck tires and various rubber technical products. In 2014 the Boryszew ERG S.A. Dispersion and Adhesive manufacturing unit was added to Synthos S.A. In August 2015, Synthos S.A. completed the construction of a modern SSBR rubber production plant. Synexil, Osakryl are market brands of water dispersions produced by Synthos S.A. Both groups include acrylic and styrene-acrylic products as well as acrylic monomer copolymers with other monomers and dispersions based on vinyl acetate. Synthos aqueous dispersions portfolio satisfies the needs of coatings and building and construction industry for such applications as paints, plasters, primers, putties including decorative (stuccos), varnishes and coatings for wood, adhesives for various applications such as: for wood, paper& packaging and many others. Synthos pays special attention to the ecological aspect of these products. None of dispersions contain APEO emulsifiers (alkylphenol ethoxylates), solvents, hazardous plasticizers or other substances harmful to human health or the environment included in the REACH Candidate List of Substances of Very High Concern (SVHC). All our products undergo rigorous internal quality control based on an integrated ISO system into which additional parameters, important from our business partners point of view, can be included on the client s request. MAIN AREAS OF ACTI VITY Household chemistry Adhesives 6% 2% Glass fibres and textiles 2% Paints and coatings 34% Building & construction chemistry 56% SYNTHOS DISPERSIONS DISPERSIONS SALES MARKETS

OSA H Flexible styrene acrylic dispersion Starting formulation Dry component Starting point formulation for the 2K waterproofing compound with cement Mixing in weight proportion

Excellent technical performance: very good adhesion Cement 32,5 35 Tylose MO 60016P4 Shinetsu 0,10 Carolith VA 0,2 0,5 mm Omya 64,90 excellent flexibility Wet component perfect

mm to measure flexibility of hydrophobical products no coalescing agents required Workability is defined as the time from mixing the wet and dry components, for which the compound

After ageing for 28 days from application, the slabs are wound on metal rollers with diameters: 30 mm, 25 mm, 20 mm, 15 mm, 10 mm and 5 mm respectively.

* Typical tile adhesive C2 class available in the market was used for tests.. BASIC PARAMETERS ph 7,0-7,8 Solids content, % 55 ± 1 Brookfield viscosity, mpa.

-40 Mean particle size, nm 180-210 Parameter Requirements Value Method Workability 170 ± 20 min 175 own method Flexibility 20 mm 15 PN-76/C-81528 met.

14891:2009 Adhesion after exposure to calcium water 0,5 N/mm 2 0,76* PN-EN 14891:2009 Adhesion after exposure to chlorine water 0,5 N/mm 2 0,60* PN-EN 1489 1:2009 Adhesion after

0,92 PN-EN 14891:2012 Crack bridging ability at low temperature (-5C) 0,75 mm 0,92 PN-EN 14891:2012 Crack bridging ability at very low temperature (-20C) 0,75 mm 0,89 PN-EN

3 OSA H Flexible styrene acrylic dispersion Starting formulation Dry component Starting point formulation for the 2K waterproofing compound with cement Mixing in weight proportion 3:1 OSAKRYL OSA H is recommended for all hydroisolation products such as one component bitumen or dispersion and two component cement based. Excellent technical performance: very good adhesion Cement 32,5 35 Tylose MO 60016P4 Shinetsu 0,10 Carolith VA 0,2 0,5 mm Omya 64,90 excellent flexibility Wet component perfect hydrophobicity very good compatibility with cements very good compatibility with bitumen emulsions Osakryl OSA H Synthos 100 Specifications Roller set of diameters: 2,5,10,15,20 mm to measure flexibility of hydrophobical products no coalescing agents required Workability is defined as the time from mixing the wet and dry components, for which the compound is flowing and can be applied freely. Flexibility rectangular slabs formed of the compound, with dimensions 50 x 100 mm thickness 5 mm, are used for testing. After ageing for 28 days from application, the slabs are wound on metal rollers with diameters: 30 mm, 25 mm, 20 mm, 15 mm, 10 mm and 5 mm respectively. The result is the roller diameter at which the waterproofing compound does not crack. Water resistance - acc. PN-EN 14891: no water penetration visible in the photo. * Typical tile adhesive C2 class available in the market was used for tests.. BASIC PARAMETERS ph 7,0-7,8 Solids content, % 55 ± 1 Brookfield viscosity, mpa.s (4/20) MFFT, C < 0 Tg, C ca. -40 Mean particle size, nm Parameter Requirements Value Method Workability 170 ± 20 min 175 own method Flexibility 20 mm 15 PN-76/C met. A Water absorption Hydrostatic scale method < 2,0% 1,00 own method Initial adhesion 0,5 N/mm 2 0,82* PN-EN 14891:2009 Adhesion after exposure to water 0,5 N/mm 2 0,82* PN-EN 14891:2009 Adhesion after exposure to calcium water 0,5 N/mm 2 0,76* PN-EN 14891:2009 Adhesion after exposure to chlorine water 0,5 N/mm 2 0,60* PN-EN :2009 Adhesion after thermal ageing 0,5 N/mm 2 0,65* PN-EN 14891:2009 Adhesion after freezing / thawing cycles 0,5 N/mm 2 0,64* PN-EN 14891:2009 Crack bridging ability at normal conditions 0,75 mm 0,92 PN-EN 14891:2012 Crack bridging ability at low temperature (-5C) 0,75 mm 0,92 PN-EN 14891:2012 Crack bridging ability at very low temperature (-20C) 0,75 mm 0,89 PN-EN 14891:2012 Mean particle size, nm Crack bridging ability at very low temperature (-20C) 0,75 mm 0,89 PN-EN 14891:2012 Crack bridging ability at low temperature (-5C) 0,75 mm 0,92 PN-EN 14891:2012 Tg, C ca. -40 Crack bridging ability at normal conditions 0,75 mm 0,92 PN-EN 14891:2012 MFFT, C < 0 Adhesion after freezing / thawing cycles 0,5 N/mm 2 0,64* PN-EN 14891:2009 Adhesion after thermal ageing 0,5 N/mm 2 0,65* PN-EN 14891:2009 Brookfield viscosity, mpa.s (4/20)

suitability for a specific purpose. Users are advised to make their own tests to determine the safety and suitability of each such material or combination of materials for their own purpose.

They do not guarantee certain properties of the products nor their Starting formulation Starting point formulation for dispersion liquid membrane Research & Development Laboratory Water 26,08 Calgon

022 Byk Chemie 0,20 Tytanpol R-001 ZCh. Police 2,00 Dolomit P 60 ZSM Piotrowice 25,15 Mica SG Quarzwerke 3,00 Necires EPX-L Neville 2,00 Osakryl OSA H Synthos S.A. 38,0 Water resistance acc.

The dispersion is ideal for all waterproofing products which is confirmed by the above test results.

Water absorption of all products is tested with a hydrostatic scale for 24 hours.

Parameter Requirements Value Method Water absorption Hydrostatic scale method < 2,0% 1,55 own method Initial adhesion 0,5 N/mm 2 1,52* PN-EN 14891:2009 Adhesion after exposure to water 0,5 N/mm 2

4 suitability for a specific purpose. Users are advised to make their own tests to determine the safety and suitability of each such material or combination of materials for their own purpose. The information given herein is based on trials carried out by SYNTHOS S.A. according to current standards and the present state of our knowledge. They do not guarantee certain properties of the products nor their Starting formulation Starting point formulation for dispersion liquid membrane Research & Development Laboratory Water 26,08 Calgon TK BK Giulini 0,10 Bermocoll EBS 481 FQ AKZO NOBEL 0,40 Alpamine N41 Arkema 0,12 Metolat 514 Münzing 0,30 Glikol propylenowy POCH 1,00 Mirecide M/90 Lamirsa 0,20 Mirecide TF/458 ECO Lamirsa 0,30 Byk 022 Byk Chemie 0,20 Tytanpol R-001 ZCh. Police 2,00 Dolomit P 60 ZSM Piotrowice 25,15 Mica SG Quarzwerke 3,00 Necires EPX-L Neville 2,00 Osakryl OSA H Synthos S.A. 38,0 Water resistance acc. PN-EN 14891: no water penetration visible in the photo. Osakryl OSA H has been developed by the Research and Development Laboratory of Synthos S.A. to meet growing demands of the construction chemical producers. The dispersion is ideal for all waterproofing products which is confirmed by the above test results. With high flexibility and hydrophobicity the product may also be an innovative solution for acrylic sealants, flexible and waterproofing paint. Water absorption of all products is tested with a hydrostatic scale for 24 hours. Hisol D 180 Nae Woi 0,80 Byk 022 Byk Chemie 0,35 Specifications * Typical tile adhesive C2 class available in the market was used for tests. Parameter Requirements Value Method Water absorption Hydrostatic scale method < 2,0% 1,55 own method Initial adhesion 0,5 N/mm 2 1,52* PN-EN 14891:2009 Adhesion after exposure to water 0,5 N/mm 2 1,22* PN-EN 14891:2009 Elongation at break > 100 % 391 PN-EN 527-3:1998 Crack bridging ability at normal conditions 0,75 mm 0,91 PN-EN 14891:2012 Crack bridging ability at low temperature (-5C) 0,75 mm 0,90 PN-EN 14891:2012 Crack bridging ability at very low temperature (-20C) 0,75 mm 0,87 PN-EN 14891:2012 Contact and information SALES DEPARTMENT Tel.: , , ds@synthosgroup.com TECHNICAL SERVICE Tel.: , , ds-ts@synthosgroup.com The information given herein is based on trials carried out by SYNTHOS S.A. according to current standards and the present state of our knowledge. They do not guarantee certain properties of the products nor their suitability for a specific purpose. Users are advised to make their own tests to determine the safety and suitability of each such material or combination of materials for their own purpose. Crack bridging ability at very low temperature (-20C) 0,75 mm 0,87 PN-EN 14891:2012 Crack bridging ability at low temperature (-5C) 0,75 mm 0,90 PN-EN 14891:2012 Crack bridging ability at normal conditions 0,75 mm 0,91 PN-EN 14891:2012 Relative elongation of coats > 100 % 391 PN-EN 527-3:1998 Adhesion after exposure to water 0,5 N/mm 2 1,22* PN-EN 14891:2009

5 SYNTHOS S.A. ul. Chemików Oświęcim, POLAND tel fax VAT EU PL

EUROPEAN COATINGS SHOW 2011: WACKER Presents Novel Polymer Dispersions and Alpha-Silanes for Ecologically Sound Adhesives and Sealants

Wacker Chemie AG Hanns-Seidel-Platz 4 81737 München, Germany www.wacker.com PRESS RELEASE Number 17 EUROPEAN COATINGS SHOW 2011: WACKER Presents Novel Polymer Dispersions and Alpha-Silanes for Ecologically