Silver Brazing Alloys. SECTION 1: Chemical product and company identification

Transcription

1 Silver Brazing Alloy ELECTRONIC COMPONENTS AND PACKAGING According to Regulation (EC) No.1907/2006 (REACH), Regulation (EC) No.453/2010 and Regulation (EC)No1272/2008-CLP SECTION 1: Chemical product and company identification n 1.1 Product Identifier Product form Product Name : Article : Silver Brazing alloy, Brazing alloy 1.2. Relevant identified ue of the ubtance or mixture and ue advied againt Relevant identified ue Indutrial/Profeional ue pec. : Indutrial For profeional ue only Ue of the ubtance/mixture : Brazing Function or ue category : Brazing agent Ue advied againt No additional information available 1.3. Detail of the upplier of the afety data heet Coining, Inc. 15 Mercede Drive Montvale, NJ Tel: +1(201) martin.oud@ametek.com 1.4. Emergency Telephone Number Emergency Number SECTION 2: Hazard identification : CHEMTREC: for US/ outide US For Chemical Emergency, Spill, Leak, Fire, Expoure, or Accident, call CHEMTREC-Day of Night Claification of the Subtance or Mixture Claification according to Directive 67/548/EEC, Regulation (EC)No1272/2008-CLP : Skin en. (cat 1) Carcinogenicity (cat 2) Specific Target Organ Toxicity-Repeated expoure (cat 1) Advere phyicochemical, human health and environmental effect No additional information available Label Element Labeling according to Directive 67/548/EEC, Regulation (EC)No1272/2008-CLP Hazard Pictogram GHS n Signal Word: Danger Hazard Statement H317 May caue allergic kin reaction

2 H351 H372 Supect of cauing cancer Caue damage to organ through prolonged or repeated expoure Precautionary Statement P261 Avoid breathing dut/fume/ga/mit/vapor/pray P270 Do not eat, drink or moke when uing thi product P273 Avoid releae to the environment P280 Wear protective glove/protective clothing/eye protection/face protection P362 Take off contaminated clothing and wah before reue. P501 Dipoe of content/container in accordance with local, regional, national and international regulation Other hazard No additional information available SECTION 3: Compoition/information on ingredient n 3.1. Subtance Not applicable 3.2. Mixture Name Product Identifier % Claification according to Regulation (EC) No. 1272/2008 [CLP] Gold (CAS No) (EC no) ; Copper (CAS No) (EC no) ; Tin (CAS No) (EC no) Silver (CAS No) (EC no) Indium (CAS No) (EC no) Nickel (CAS No) (EC no) (EC index no) Zinc (CAS No) (EC no) Palladium (CAS No) (EC no) Phophorou elemental (CAS No) (EC no) Solid Not Claified Solid Not Claified Solid Not Claified Solid Not Claified Solid Not Claified Skin Sen. 1, H317 Carc. 2, H351 STOT RE 1, H Eye Irrit. 2, H319 Aquatic Acute 1, H400 Aquatic Chronic 1, H Solid Not Claified In olid alloy_ Aquatic Chronic 3, H412 2 / 14

3 (EC index no) Full text of H- and EUH-phrae: ee ection 16 SECTION 4: Firt aid meaure n 4.1. Decription of firt aid meaure Firt-aid meaure general Firt-aid meaure after inhalation Firt-aid meaure after kin contact Firt-aid meaure after eye contact Firt-aid meaure after ingetion : Never give anything by mouth to an unconciou peron. If you feel unwell, eek medical advice (how there label where poible). : When ymptom occur; go into open air and ventilate upected area. : Removal of olidified molten material from kin require medical aitance. Cool kin rapidly with cold water after contact with molten product : Rine cautiouly with water for everal minute. Remove contact lene, if preent and eay to do. Continue rining. : Rine mouth. Do NOT induce vomiting Mot important ymptom and effect, both acute and delayed Symptom/injurie Symptom/injurie after inhalation Symptom/injurie after kin contact Symptom/injurie after eye contact Symptom/injurie after ingetion Chronic ymptom : Under normal condition of ue not expected to preent a ignificant hazard. Under milling, or phyical alteration metal dut may be produced that caue irritation of the repiratory tract, kin, and may be harmful. Molten material may releae toxic and irritating fume. : Not expected to be a primary route of expoure. The primary acute health hazard aociated with thi product would be the potential for expoure to fume during metal proceing operation. Inhalation of dut and fume can caue metal fume fever. Symptom can include a metallic or weet tate in the mouth, weating, hivering, headache, throat irritation, fever, chill, thirtine, mucle ache, nauea, vomiting, weakne, fatigue, and hortne of breath. : Skin contact i not conidered a potential route of expoure. The primary acute health hazard aociated with thi product would be the potential for expoure to fume during metal proceing operation. Where poible allow molten material to olidify naturally. Removal of olidified molten material from kin require medical aitance. : Not expected to be a primary route of expoure. Dut generated from material cutting may caue a light irritation. Sliver may be generated, which could caue mechanical irritation or injure the eye. : Ingetion i not conidered a potential route of expoure. : Tin: Ha been hown to increae incidence of arcoma in animal tet. Chronic expoure to tin dut and fume may reult in "tannoi", a mild form of pneumoconioi. Silver: Chronic kin contact or ingetion of ilver dut, alt or fume can reult in a condition known a Argyria, a condition with bluih pigmentation of the kin and eye. Indium: May caue damage to repiratory ytem. Copper: Overexpoure to fume may caue metal fume fever (chill, mucle ache, nauea, fever, dry throat, cough, weakne, laitude); metallic or weet 3 / 14

4 tate; dicoloration of kin and hair. Tiue damage of mucou membrane may follow chronic dut expoure. Nickel: May caue a form of dermatiti known a nickel itch. Intetinal irritation, which may caue diorder, convulion and aphyxia. Zinc: Prolonged expoure to high concentration of zinc fume may caue "zinc hake", an involuntary twitching of the mucle. Otherwie, zinc i non-toxic Indication of any immediate medical attention and pecial treatment needed If medical advice i needed, have product container or label at hand. SECTION 5: Fire fighting meaure 5.1. Extinguihing media Suitable extinguihing media Unuitable extinguihing media : Doe not burn. Ue extinguihing media appropriate for urrounding fire : None known Special hazard ariing from the ubtance or mixture Fire hazard : Dut, chip, or ribbon can be ignited more eaily, by an ignition ource, by improper machining, or by pontaneou combution if finely divided and damp 5.3. Advice for firefighter Firefighting intruction Protection during firefighting : Exercie caution when fighting any chemical fire. : Do not enter fire area without proper protective equipment, including repiratory protection. SECTION 6: Accidental releae meaure 6.1. Peronal precaution, protective equipment and emergency procedure General meaure For non-emergency peronnel Protective equipment Emergency procedure For emergency reponder Protective equipment Emergency procedure 6.2. Environmental precaution Avoid releae to the environment : Handle in accordance with good indutrial hygiene and afety practice. : Ue appropriate peronal protection equipment (PPE) : Evacuate unneceary peronnel. : Equip cleanup crew with proper protection. : Ventilate area 6.3. Method and material for containment and clean up For containment : If metal i in molten form, allow cooling and collecting a a olid. If the metal i in olid form collect for remelting purpoe. 4 / 14

5 Method for cleaning up 6.4 Reference to other ection See heading 8, expoure control and peronal protection. SECTION 7: Handling and torage 7.1. Precaution for afe handling Hygiene meaure 7.2. Condition for afe torage, including any incompatibilitie Storage condition Incompatible product 7.3. Specific end ue() : Clear up pill. Immediately and dipoe of wate afely. : Handle in accordance with good indutrial hygiene and afety procedure. Wah hand and other expoed area with mild oap and water before eating, drinking, or moking and again when leaving work. : Store in a dry, cool and well-ventilated place. : Strong acid. Strong bae. Strong oxidizer. Brazing. SECTION 8: Expoure control/peronal protection 8.1 Control parameter Copper ( ) Autria MAK (mg/m³) 0.4 mg/m³ Belgium Limit value (mg/m³) 1 mg/m³ Bulgaria OEL TWA (mg/m³) 0.1 mg/m³ France VLE (mg/m³) 2 mg/m³ France VME (mg/m³) 1 mg/m³ Italy Portugal USA ACGHI ACGIH TWA (mg/m³) 0.2 mg/m³ Latvia OEL TWA (mg/m³) 0.5 mg/m³ Spain VLA-ED (mg/m³) 1 mg/m³ The Netherland MAC TGG 8H (mg/m³) 0.1 mg/m³ United Kingdom WEL TWA (mg/m³) 1 mg/m³ United Kingdom WEL STEL (mg/m³) 2 mg/m³ Czech Republic Expoziční limity (PEL) (mg/m3) 0.1 mg/m³ Denmark Græneværdie (langvarig) (mg/m3) 0.1 mg/m³ Finland HTP-arvo (8h) (mg/m3) 0.1 mg/m³ Hungary AK-érték 0.1 mg/m³ Hungary CK-érték 0.4 mg/m³ Ireland OEL (8 hour ref) (mg/m3) 1 mg/m³ Ireland OEL (15 min ref) (mg/m3 2 mg/m³ Lithuania IPRV (mg/m3) 0.2 mg/m³ Romania OEL TWA (mg/m3) 0.50mg/m³ Romania OEL STEL (mg/m3) 1.50 mg/m³ Slovakia NPHV (priemerná) (mg/m3) 0.1 mg/m³ 5 / 14

6 Slovakia NPHV (Hraničná) (mg/m3) 0.2 mg/m³ Sweden nivågränvärde (NVG) (mg/m3) 0.2 mg/m³ Portugal OEL TWA (mg/m3) 1mg/m³ Tin ( ) Autria MAK (mg/m³) 4 mg/m³ Belgium Limit value (mg/m³) 2 mg/m³ Cypru OEL TWA (mg/m³) 2 mg/m³ Italy Portugal USA ACGHI ACGIH TWA (mg/m³) 2 mg/m³ Spain VLA-ED (mg/m³) 2 mg/m³ Finland HTP-arvo (8h) (mg/m3) 2 mg/m³ Ireland OEL (8 hour ref) (mg/m3) 2 mg/m³ Malta OEL TWA (mg/m³) 2 mg/m³ Poland NDS (mg/m³) 2 mg/m³ Portugal OEL TWA (mg/m³) 2 mg/m³ Silver ( ) Autria MAK (mg/m³) 0.1 mg/m³ Belgium Limit value (mg/m³) 0.1 mg/m³ Bulgaria OEL TWA (mg/m³) 0.1 mg/m³ Cypru OEL TWA (mg/m³) 0.1 mg/m³ France VME (mg/m³) 0.1 mg/m³ (indicative limit) Germany TRGS 900 Occupational expoure 0.1 mg/m³ limit value (mg/m³) Italy Portugal USA ACGHI ACGIH TWA (mg/m³) 0.1 mg/m³ Italy OEL TWA (mg/m³) 0.1 mg/m³ Latvia OEL TWA (mg/m³) 0.5 mg/m³ Spain VLA-ED (mg/m³) 0.1 mg/m³ The Netherland MAC TGG 8H (mg/m³) 0.1 mg/m³ United Kingdom WEL TWA (mg/m³) 0.1 mg/m³ United Kingdom WEL STEL (mg/m³) 0.3 mg/m³ (calculated) Czech Republic Expoziční limity (PEL) (mg/m3) 0.1 mg/m³ Denmark Græneværdie (langvarig) (mg/m3) 0.01 mg/m³ Finland HTP-arvo (8h) (mg/m3) 0.1 mg/m³ Hungary AK-érték 0.1 mg/m³ Hungary CK-érték 0.4 mg/m³ Ireland OEL (8 hour ref) (mg/m3) 0.1 mg/m³ Lithuania IPRV (mg/m3) 0.1 mg/m³ Poland NDS (mg/m3) 0.05 mg/m³ Romania OEL TWA (mg/m3) 0.1 mg/m³ Slovakia NPHV (priemerná) (mg/m3) 0.1 mg/m³ Sweden nivågränvärde (NVG) (mg/m3) 0.1 mg/m³ 6 / 14

7 Portugal OEL TWA (mg/m3) 0.1mg/m³ Indium ( ) Autria MAK (mg/m³) 0.2 mg/m³ Belgium Limit value (mg/m³) 0.1 mg/m³ Italy Portugal USA ACGHI ACGIH TWA (mg/m³) 0.1 mg/m³ Spain VLA-ED (mg/m³) 0.1 mg/m³ United Kingdom WEL TWA (mg/m³) 0.1 mg/m³ United Kingdom WEL STEL (mg/m³) 0.3 mg/m³ Denmark Græneværdie (langvarig) (mg/m3) 0.1 mg/m³ Finland HTP-arvo (8h) (mg/m3) 0.1 mg/m³ Ireland OEL (8 hour ref) (mg/m3) 0.1 mg/m³ Ireland OEL (15 min ref) (mg/m3 0.3 mg/m³ Lithuania IPRV (mg/m3) 0.1 mg/m³ Sweden nivågränvärde (NVG) (mg/m3) 0.1 mg/m³ Portugal OEL TWA (mg/m3) 0.1 mg/m³ Nickel ( ) Belgium Limit value (mg/m³) 1 mg/m³ Bulgaria OEL TWA (mg/m³) 0.05 mg/m³ France VME (mg/m³) 1 mg/m³ (metal grating) Italy Portugal USA ACGHI ACGIH TWA (mg/m³) 1.5 mg/m³ Latvia OEL TWA (mg/m³) 0.05 mg/m³ Spain VLA-ED (mg/m³) 1 mg/m³(manufacturing, commercialization, and ue ue retriction under REACH) United Kingdom WEL TWA (mg/m³) 0.5 mg/m³ United Kingdom WEL STEL (mg/m³) 1.5 mg/m³ (calculated) Czech Republic Expoziční limity (PEL) (mg/m3) 0.5 mg/m³ Denmark Græneværdie (langvarig) (mg/m3) 0.05 mg/m³ Finland HTP-arvo (8h) (mg/m3) 1 mg/m³ Hungary AK-érték 0.1 mg/m³ Hungary CK-érték 0.1 mg/m³ Ireland OEL (8 hour ref) (mg/m3) 4 mg/m³ Lithuania IPRV (mg/m3) 0.5 mg/m³ Poland NDS (mg/m3) 0.25 mg/m³ Romania OEL TWA (mg/m3) 0.10mg/m³ Romania OEL STEL (mg/m3) 0.50 mg/m³ Sweden nivågränvärde (NVG) (mg/m3) 0.5 mg/m³ Portugal OEL TWA (mg/m3) 1.5 mg/m³ Portugal OEL chemical category (PT) A5 Not Supected a a Human Carcinogen 7 / 14

8 Palladium ( ) Finland HTP-arvo (8h) (mg/m3) 0.5 mg/m³ Phophorou elemental ( ) Autria MAK (mg/m³) 0.2 mg/m³ Germany TRGS 900 Occupational expoure limit value (mg/m³) 0.01 mg/m³ (The rik of damage to the embryo or fetu can be excluded when AGW and BGW value are oberved) Latvia OEL TWA (mg/m³) 0.03 mg/m³ United Kingdom WEL TWA (mg/m³) 0.1 mg/m³ Czech Republic Expoziční limity (PEL) (mg/m3 0.1 mg/m³ Hungary AK-érték 0.1 mg/m³ Hungary CK-érték 0.1 mg/m³ Slovakia NPHV (priemerná) (mg/m3) 0.05 mg/m³ Slovakia NPHV (Hraničná) (mg/m3) 0.1 mg/m³ (Yellow, white) 8.2. Expoure control Appropriate engineering control Peronal protective equipment : : Enure adequate ventilation, epecially in confined area. : Protective goggle. Inulated glove Hand protection : If material i hot, wear thermally reitant protective glove. Eye protection : During metal proceing, chemical goggle or afety glae. Repiratory protection : During metal proceing, wear approved mak. Other information : When uing, do not eat, drink or moke. SECTION 9: Phyical and chemical propertie 9.1. Information on bai phyical and chemical propertie Phyical tate : Solid Appearance : Preform, quare, ring, dic, wire Color : Metallic, ilvery or coppery Odor : Odorle Odor threhold : Not applicable ph : Neutral 8 / 14

9 Relative evaporation rate (butylacetate=1) Melting point Freezing point Boiling point Flah point Self ignition temperature Decompoition temperature Flammability (olid, ga) Vapor preure Relative vapor preure at 20 C Relative denity Solubility Log Pow Log Kow Vicoity, kinematic Vicoity, dynamic Exploive propertie Oxidizing propertie Exploive limit : Not applicable : Inoluble 9.2 Other information: No other information available. SECTION 10: Stability and reactivity 10.1 Reactivity : Hazardou reaction will not occur under normal condition Chemical tability : Stable under normal condition. Dut, chip or ribbon can be ignited more eaily, by an ignition ource, by improper machining, or by pontaneou combution if finely divided and damp Poibility of hazardou reaction : Hazardou polymerization will not occur Condition to avoid : Direct unlight. Extremely high or low temperature Incompatible material : Strong acid. Strong bae. Strong oxidizer Hazardou decompoition product : Metal oxide. SECTION 11: Toxicological information 11.1 Information on toxicological effect Acute toxicity : Not claified Silver ( ) LD50 oral rat >2000 mg/kg 9 / 14

10 Phophorou elemental ( ) LD50 oral rat Ld50 dermal rat 3.03 mg/kg 100 mg/kg LC50 inhalation rat (mg/l) 4.3 mg/l (expoure time: 1h) Nickel ( ) LD50 oral rat Irritation Corroivity Senitization Repeated doe toxicity Carcinogenicity Mutagenicity Toxicity for reproduction >9000 mg/kg : Not claified : Not claified : Not claified : Not claified : Not claified : Not claified : Not claified SECTION 12: Ecological information 12.1 Toxicity Copper ( ) LC50 fihe 1 EC50 Daphnia 1 EC50 other aquatic organim 1 LC50 fih 2 EC50 other aquatic organim ( )mg/l (Expoure time: 96 h-specie: Pimephale promela) 0.03mg/l (Expoure time: 48h-Specie: Daphnia magna [Static]) ( )mg/l (Expoure time:72 h-specie: Peudokirchneriella ubcapitate [Static]) 0.3mg/l (Expoure time: 96h pecie: Pimephale promela [Static]) 0.031( ) mg/l (Expoure time: 96 h - Specie: Peudokirchneriella ubcapitate [Static]) Silver ( ) LC50 fihe 1 EC50 Daphnia 1 LC50 fih ( )mg/l (Expoure time: 96 h-specie: Pimephale promela [Static]) mg/l (Expoure time: 48h-Specie: Daphnia magna [Static]) mg/l (Expoure time: 96h pecie: Oncorhynchu myki [flowthrough]) Zinc ( ) LC50 fihe 1 EC50 Daphnia mg/l (Expoure time: 96 h-specie: Pimephale promela [flowthrough]) mg/l (Expoure time: 48h-Specie: Daphnia magna [Static]) 10 / 14

11 EC50 other aquatic organim 1 LC50 fih 2 EC50 other aquatic organim mg/l (Expoure time:96 h-specie: Peudokirchneriella ubcapitate [Static]) mg/l (Expoure time: 96h pecie: Pimephale promela [emitatic]) mg/l (Expoure time: 72 h - Specie: Peudokirchneriella ubcapitate [Static]) Phophorou elemental ( ) LC50 fihe 1 EC50 Daphnia 1 LC50 fih 2 EC50 other aquatic organim mg/l (Expoure time: 96 h-specie: Lepomi macrochiru [flow-through]) 0.03mg/l (Expoure time: 48h-Specie: Daphnia magna [Static]) mg/l (Expoure time: 96 h-specie: Lepomi macrochiru [Static]) ) mg/l (Expoure time: 48 h - Specie: Daphnia magna [Static]) Nickel ( ) LC50 fihe 1 EC50 Daphnia 1 EC50 other aquatic organim 1 LC50 fih 2 EC50 Dahnia 2 EC50 other aquatic organim mg/l (Expoure time: 96 h-specie: Brachydanio rerio]) 100 mg/l (Expoure time: 48h-Specie: Daphnia magna) 0.18 mg/l (Expoure time:72 h-specie: Peudokirchneriella ubcapitate) 1.3mg/l (Expoure time: 96h Specie: Cyprinu carpio [emi-tatic]) 1 mg/l (Expoure time: 48h-Specie: Daphnia magna [Static]) ( mg/l (Expoure time: 96 h - Specie: Peudokirchneriella ubcapitate [Static]) 12.2 Peritence and degradability Soldering and Brazing Alloy Peritence and degradability Not etablihed Copper ( ) Peritence and degradability Not readily biodegradable Bioaccumulative potential Brazing Alloy Bioaccumulative potential Not etablihed 12.4 Mobility in oil No additional information available Reult of PBT and vpvb aement No additional information available Other advere effect 11 / 14

12 Other information : Avoid releae to the environment. SECTION 13: Dipoal information 13.1 Wate treatment method Wate dipoal recommendation : Dipoe of wate material in accordance with all local, regional, national and international regulation. SECTION 14: Tranport information UN number : Not regulated for tranport UN proper hipping name : Not applicable Tranport hazard cla(e) : Not applicable Packing group : Not applicable Environmental hazard Other information : No upplementary information available Special precaution for uer : Not applicable Overland tranport : Not regulated for tranport Air tranport : Not regulated for tranport Tranport in bulk according to Annex II of MARPOL 73/78 and the IBC Code SECTION 15: Regulatory information Safety, health and environmental regulation/legilation pecific for the ubtance or mixture EU-Regulation Authorization and/or retriction on ue (Annex XVII): 27. Nickel Nickel 40. Subtance claified a flammable gae category 1 or 2, flammable liquid categorie 1, 2 or 3, flammable olid category 1 or 2 ubtance and mixture which, in contact with water, emit flammable gae, category 1,2 or 3, pyrophoric liquid category 1 or pyrophoric olid category 1, regardle of whether they appear in Part 3 of Annex VI to Regulation (EC) No 1272/2008 or not. Contain no REACH candidate ubtance. Phophoru elemental n National regulation No additional information available Chemical afety aement No chemical afety aement ha been carried out. 12 / 14

13 SECTION 16: Other information n Other information Full text of R-, H- and EUH-phrae: : Thi Safety Data Sheet ha been etablihed in accordance with the applicable European Union legilation. Claification in accordance with calculation method of regulation (EC)1272/2008 CLP/EC 1999/45 DPD. Acute Tox.1 (Inhalation: dut, mit) Acute toxicity (inhalation: dut, mit) Category 1 Acute Tox.2 (Dermal) Acute toxicity (dermal) Category 2 Acute Tox.3 (Oral) Acute toxicity (oral) Category 2 Aquatic Acute 1 Hazardou to the aquatic environment-acute Hazard Category 1 Aquatic Chronic 1 Hazardou to the aquatic environment-chronic Hazard Category 1 Aquatic Chronic 3 Hazardou to the aquatic environment-chronic Hazard Category 3 Carc.2 Carcinogenicity Category 2 Eye Irrit. 2 Seriou eye damage/eye irritation Category 2 Flam. Sol. 1 Flammable olid Category 1 Pyr. Sol. 1 Pyrophoric olid Category 1 Skin Corr. 1A Skin corroion/irritation Category 1A Skin Sen. 1 Skin enitization Category 1 STOT RE 1 Specific target organ toxicity (repeated expoure) Category 1 STOT Se 3 Specific target organ toxicity (ingle expoure) Category 3 H228 H250 H300 H310 H314 H317 H319 H330 H335 H351 H372 H400 H410 H412 Flammable olid Catche fire pontaneouly if expoed to air Fatal if wallowed Fatal in contact with kin Caue evere kin burn and eye damage May caue an allergic kin reaction Caue eriou eye irritation Fatal if inhaled May caue repiratory irritation Supected of cauing cancer Caue damage to organ through prolonged or repeated expoure Very toxic to aquatic life Very toxic to aquatic life with long lating effect Harmful to aquatic life with long lating effect SDS EU (REACH ANNEX II) Thi information i baed on our current knowledge and i intended to decribe the product for the purpoe of health, afety and environmental requirement only. It hould not therefore be contrued a guaranteeing any pecific property of the product. 13 / 14

14 STATEMENT OF LIABILITY-DISCLAIMER To the bet of the COINING, INC knowledge, the information and recommendation contained in thi publication are reliable and accurate a of the date prepared. However, accuracy, uitability, or completene are not guaranteed, and no warranty, guarantee, or repreentation, expreed or implied, i made by COINING, INC. a to the abolute correctne or ufficiency of any repreentation contained in thi and other publication; COINING, INC. aume no reponibility in connection therewith; nor can it be aumed that all acceptable afety meaure are contained in thi and other publication, or that other or additional meaure may not be required under particular or exceptional condition or circumtance. Data may be changed from time to time. 14 / 14