: Pb-Free Soldering Alloys

Transcription

1 Pb-Free Solderig Alloy Ti, Silver, Idium, Bimuth, Atimoy, Copper, Germaium SECTION 1: Chemical product ad compay idetificatio 1.1 Product Idetifier Product form : Article Product Name : Pb-Free Solderig Alloy Ti, Silver, Idium, Bimuth, Atimoy, Copper, Germaium - Solderig Alloy, SAC-alloy 1.2. Relevat idetified ue of the ubtace or mixture ad ue advied agait Relevat idetified ue Idutrial/Profeioal ue pec. : Idutrial For profeioal ue oly Ue of the ubtace/mixture : Solderig Fuctio or ue category : Solderig aget Ue advied agait No additioal iformatio available 1.3. Detail of the upplier of the afety data heet Coiig, Ic. 15 Mercede Drive Motvale, NJ Tel: +1(201) marti.oud@ametek.com 1.4. Emergecy Telephoe Number Emergecy Number SECTION 2: Hazard idetificatio 2.1. Claificatio of the Subtace or Mixture Claificatio GHS-US: Not claified Advere phyicochemical, huma health ad evirometal effect: No additioal iformatio available. ELECTRONIC COMPONENTS AND PACKAGING : CHEMTREC: for US/ outide US For Chemical Emergecy, Spill, Leak, Fire, Expoure, or Accidet, call CHEMTREC-Day of Night Label Elemet I Accordace with 29CFR (f)(4): Not regulated for labelig. Sigal Word: Not applicable Precautioary Statemet P261 Avoid breathig dut/fume/ga/mit/vapor/pray P270 Do ot eat, drik or moke whe uig thi product P273 Avoid releae to the eviromet P280 Wear protective glove/protective clothig/eye protectio/face protectio P501 Dipoe of cotet/cotaier i accordace with local, regioal, atioal ad iteratioal regulatio Other hazard: Thi product i preet i a maive form a a alloy. It doe ot preet the ame hazard whe the idividual compoet are i their powdered form.

2 SECTION 3: Compoitio/iformatio o igrediet 3.1. Subtace Not applicable 3.2. Mixture Name Product Idetifier % Claificatio accordig to Regulatio GHS-US Ti (CAS No) Solid Not Claified Silver (CAS No) Solid Not Claified Idium (CAS No) Solid Not Claified Bimuth (CAS No) Solid Not Claified Copper (CAS No) Solid Not Claified Atimoy (CAS No) Solid Not Claified Germaium (CAS No) Solid Not Claified Full text of H- ad P-phrae: ee ectio 16 SECTION 4: Firt aid meaure 4.1. Decriptio of firt aid meaure Firt-aid meaure geeral Firt-aid meaure after ihalatio Firt-aid meaure after ki cotact Firt-aid meaure after eye cotact Firt-aid meaure after igetio : Never give aythig by mouth to a ucociou pero. If you feel uwell, eek medical advice (how there label where poible). : Whe ymptom occur; go ito ope air ad vetilate upected area. : Removal of olidified molte material from ki require medical aitace. Cool ki rapidly with cold water after cotact with molte product : Rie cautiouly with water for everal miute. Remove cotact lee, if preet ad eay to do. Cotiue riig. : Rie mouth. Do NOT iduce vomitig Mot importat ymptom ad effect, both acute ad delayed Symptom/ijurie Symptom/ijurie after ihalatio Symptom/ijurie after ki cotact : Uder ormal coditio of ue ot expected to preet a igificat hazard. Uder millig, or phyical alteratio metal dut may be produced that caue irritatio of the repiratory tract, ki, ad may be harmful. Molte material may releae toxic ad irritatig fume. : Not expected to be a primary route of expoure. The primary acute health hazard aociated with thi product would be the potetial for expoure to fume durig metal proceig operatio. Ihalatio of dut ad fume ca caue metal fume fever. Symptom ca iclude a metallic or weet tate i the mouth, weatig, hiverig, headache, throat irritatio, fever, chill, thirtie, mucle ache, auea, vomitig, weake, fatigue, ad horte of breath. : Ski cotact i ot coidered a potetial route of expoure. The primary acute health hazard aociated with thi product would be the potetial for expoure to fume durig metal proceig operatio. Where poible allow molte 2 / 11

3 Symptom/ijurie after eye cotact Symptom/ijurie after igetio Chroic ymptom material to olidify aturally. Removal of olidified molte material from ki require medical aitace. : Not expected to be a primary route of expoure. Dut geerated from material cuttig may caue a light irritatio. Sliver may be geerated, which could caue mechaical irritatio or ijure the eye. : Igetio i ot coidered a potetial route of expoure. : Ti: Ha bee how to icreae icidece of arcoma i aimal tet. Chroic expoure to ti dut ad fume may reult i "taoi", a mild form of peumocoioi. Silver: Chroic ki cotact or igetio of ilver dut, alt or fume ca reult i a coditio kow a Argyria, a coditio with bluih pigmetatio of the ki ad eye. Atimoy: Expoure to dut ad fume may reult i irritatio eye, ki, oe, throat, mouth; cough; dizzie; faitig; dypea (breathig difficulty); auea, vomitig, diarrhea, tomach cramp; iomia; aorexia; uable to mell properly. Copper: Overexpoure to fume may caue metal fume fever (chill, mucle ache, auea, fever, dry throat, cough, weake, ad laitude); metallic or weet tate; dicoloratio of ki ad hair. Tiue damage of mucou membrae may follow chroic dut expoure Idicatio of ay immediate medical attetio ad pecial treatmet eeded If medical advice i eeded, have product cotaier or label at had. SECTION 5: Fire fightig meaure 5.1. Extiguihig media Suitable extiguihig media Uuitable extiguihig media : Doe ot bur. Ue extiguihig media appropriate for urroudig fire : Noe kow Special hazard ariig from the ubtace or mixture Fire hazard 5.3. Advice for firefighter Firefightig itructio Protectio durig firefightig : Dut, chip, or ribbo ca be igited more eaily, by a igitio ource, by improper machiig, or by potaeou combutio if fiely divided ad damp : Exercie cautio whe fightig ay chemical fire. : Do ot eter fire area without proper protective equipmet, icludig repiratory protectio. SECTION 6: Accidetal releae meaure 6.1. Peroal precautio, protective equipmet ad emergecy procedure Geeral meaure :Hadle i accordace with good idutrial hygiee ad afety practice For o-emergecy peroel Protective equipmet : Ue appropriate peroal protectio equipmet (PPE) Emergecy procedure : Evacuate ueceary peroel For emergecy repoder Protective equipmet : Equip cleaup crew with proper protectio. 3 / 11

4 Emergecy procedure 6.2. Evirometal precautio Avoid releae to the eviromet : Vetilate area 6.3. Method ad material for cotaimet ad clea up For cotaimet Method for cleaig up 6.4 Referece to other ectio See headig 8, expoure cotrol ad peroal protectio. SECTION 7: Hadlig ad torage 7.1. Precautio for afe hadlig Hygiee meaure 7.2. Coditio for afe torage, icludig ay icompatibilitie Storage coditio Icompatible product 7.3. Specific ed ue() : If metal i i molte form, allow coolig ad collectig a a olid. If the metal i i olid form collect for remeltig purpoe. : Clear up pill. Immediately ad dipoe of wate afely. : Hadle i accordace with good idutrial hygiee ad afety procedure. Wah had ad other expoed area with mild oap ad water before eatig, drikig, or mokig ad agai whe leavig work. : Store i a dry, cool ad well-vetilated place. : Strog acid. Strog bae. Strog oxidizer. Solderig. SECTION 8: Expoure cotrol/peroal protectio 8.1 Cotrol parameter Ti ( ) Mexico OEL TWA (mg/m³) 2 mg/m³ Mexico OEL STEL (mg/m³) 4 mg/m³ USA ACGHI ACGIH TWA (mg/m³) 2 mg/m³ USA NIOSH NIOSH REL (TWA) (mg/m³) 2 mg/m³ USA IDLH US IDLH (mg/m3) 100 mg/m³ Alberta OEL TWA (mg/m³) 2 mg/m³ Britih Columbia OEL TWA (mg/m³) 2 mg/m³ Maitoba OEL TWA (mg/m³) 2 mg/m³ New Bruwick OEL TWA (mg/m³) 2 mg/m³ Newfoudlad & Labrador OEL TWA (mg/m³) 2 mg/m³ Nova Scotia OEL TWA (mg/m³) 2 mg/m³ Otario OEL TWA (mg/m³) 2 mg/m³ Price Edward Ilad OEL TWA (mg/m³) 2 mg/m³ Québec VEMP (mg/m³) 2 mg/m³ Sakatchewa OEL STEL (mg/m³) 4 mg/m³ Sakatchewa OEL TWA (mg/m³) 2 mg/m³ Silver ( ) Mexico OEL TWA (mg/m³) 0.1 mg/m³ 4 / 11

5 USA ACGHI ACGIH TWA (mg/m³) 0.1 mg/m³ USA OSHA OSHA PEL (TWA) (mg/m³) 0.01 mg/m³ Caada TLV- TWA (mg/m³) 0.1 mg/m³ Caada TLV-STEL (mg/m³) 0.3 mg/m³ Idium ( ) Mexico PEL (mg/m³) 0.1 mg/m³ Mexico TLV-STEL (mg/m³) 0.3 mg/m³ USA ACGHI TLV- TWA (mg/m³) 0.1 mg/m³ USA OSHA OSHA PEL (mg/m³) 0.1 mg/m³ Caada TLV- TWA (mg/m³) 0.1 mg/m³ Caada TLV-STEL (mg/m³) 0.3 mg/m³ Bimuth ( ) Mexico PEL/TLV-STEL (mg/m³) Not etablihed USA PEL/TLV-STEL (mg/m³) Not etablihed Caada PEL/TLV-STEL (mg/m³) Not etablihed Atimoy ( ) Mexico PEL (mg/m³) Not etablihed Mexico TLV-TWA (mg/m³) 0.5 mg/m³ Mexico TLV-STEL (mg/m³) Not etablihed USA ACGHI ACGHI- TWA (mg/m³) 0.05mg/m³ USA PEL (mg/m³) 0.5 mg/m³ USA TLV- TWA(mg/m³) 0.5 mg/m³ Caada TLV- TWA (mg/m³) 0.5 mg/m³ Caada TLV-STEL (mg/m³) 1.5 mg/m³ Mexico OEL TWA (mg/m³) 0.2 mg/m³(fume), 1 mg/m³(dut ad mit) Mexico OEL STEL (mg/m³) 2 mg/m³(fume), 2 mg/m³(dut ad mit) USA ACGHI ACGIH TWA (mg/m³) 0.2 mg/m³ USA OSHA OSHA PEL (TWA) (mg/m³) 0.1 mg/m³(fume), 1 mg/m³(dut ad mit) USA NIOSH NIOSH REL (TWA) (mg/m³) 0.1 mg/m³(fume), 1 mg/m³(dut ad mit) USA IDLH US IDLH (mg/m3) 100 mg/m³ (dut, fume ad mit) Alberta OEL TWA (mg/m³) 0.2 mg/m³ Britih Columbia OEL TWA (mg/m³) 1 mg/m³ Maitoba OEL TWA (mg/m³) 0.2 mg/m³ New Bruwick OEL TWA (mg/m³) 0.2 mg/m³ Newfoudlad & Labrador OEL TWA (mg/m³) 0.2 mg/m³ Nova Scotia OEL TWA (mg/m³) 0.2 mg/m³ Otario OEL TWA (mg/m³) 0.2 mg/m³ Price Edward Ilad OEL TWA (mg/m³) 0.2 mg/m³ Québec VEMP (mg/m³) 0.2 mg/m³ 5 / 11

6 Sakatchewa OEL STEL (mg/m³) 0.6 mg/m³ Sakatchewa OEL TWA (mg/m³) 0.2 mg/m³ Yuko OEL Stel (mg/m³) 0.2 mg/m³ Yuko OEL TWA (mg/m³) 0.2 mg/m³ Germaium ( ) Mexico PEL/TLV-STEL (mg/m³) Not etablihed USA PEL/TLV-STEL (mg/m³) Not etablihed Caada PEL/TLV-STEL (mg/m³) Not etablihed 8.2. Expoure cotrol Appropriate egieerig cotrol Peroal protective equipmet : : Eure adequate vetilatio, epecially i cofied area. : Protective goggle. Iulated glove Had protectio : If material i hot, wear thermally reitat protective glove. Eye protectio : Durig metal proceig, chemical goggle or afety glae. Repiratory protectio : Durig metal proceig, wear approved mak. Other iformatio : Whe uig, do ot eat, drik or moke. SECTION 9: Phyical ad chemical propertie 9.1. Iformatio o bai phyical ad chemical propertie Phyical tate : Solid Appearace : Preform, quare, rig, dic Color : Metallic Odor : Odorle Odor threhold : Not applicable ph : Neutral Relative evaporatio rate (butylacetate=1) : Not applicable Meltig poit Freezig poit Boilig poit Flah poit Self igitio temperature Decompoitio temperature Flammability (olid, ga) Vapor preure 6 / 11

7 Relative vapor preure at 20 C Relative deity Solubility Log Pow Log Kow Vicoity, kiematic Vicoity, dyamic Exploive propertie Oxidizig propertie Exploive limit : Ioluble 9.2 Other iformatio No other iformatio available SECTION 10: Stability ad reactivity 10.1 Reactivity Hazardou reactio will ot occur uder ormal coditio Chemical tability Stable uder ormal coditio. Dut, chip or ribbo ca be igited more eaily, by a igitio ource, by improper machiig, or by potaeou combutio if fiely divided ad damp Poibility of hazardou reactio Hazardou polymerizatio will ot occur Coditio to avoid Direct ulight. Extremely high or low temperature Icompatible material Strog acid. Strog bae. Strog oxidizer Hazardou decompoitio product Metal oxide. SECTION 11: Toxicological iformatio 11.1 Iformatio o toxicological effect Acute toxicity Silver ( ) LD50 oral rat : Not claified >2000 mg/kg Atimoy ( ) LD50 oral rat 100 mg/kg Irritatio Corroivity : Not claified : Not claified 7 / 11

8 Seitizatio Repeated doe toxicity Carciogeicity Mutageicity Toxicity for reproductio : Not claified : Not claified : Not claified : Not claified : Not claified SECTION 12: Ecological iformatio 12.1 Toxicity LC50 fihe 1 EC50 Daphia 1 EC50 other aquatic orgaim 1 LC50 fih 2 EC50 other aquatic orgaim ( )mg/l (Expoure time: 96 h-specie: Pimephale promela) 0.03mg/l (Expoure time: 48h-Specie: Daphia maga [Static]) ( )mg/l (Expoure time:72 h-specie: Peudokircheriella ubcapitate [Static]) 0.3mg/l (Expoure time: 96h pecie: Pimephale promela [Static]) 0.031( ) mg/l (Expoure time: 96 h - Specie: Peudokircheriella ubcapitate [Static]) Silver ( ) LC50 fihe 1 EC50 Daphia 1 LC50 fih Peritece ad degradability Solderig Alloy Peritece ad degradability ( )mg/l (Expoure time: 96 h-specie: Pimephale promela [Static]) mg/l (Expoure time: 48h-Specie: Daphia maga [Static]) mg/l (Expoure time: 96h pecie: Ocorhychu myki [flowthrough]) Not etablihed Peritece ad degradability Not readily biodegradable Bioaccumulative potetial Solderig Alloy Bioaccumulative potetial Not etablihed 12.4 Mobility i oil No additioal iformatio available Reult of PBT ad vpvb aemet No additioal iformatio available Other advere effect 8 / 11

9 Other iformatio SECTION 13: Dipoal iformatio 13.1 Wate treatmet method Wate dipoal recommedatio SECTION 14: Traport iformatio : Avoid releae to the eviromet I Accordace with DOT : Not regulated for traport I Accordace with IMDG : Not regulated for traport I Accordace with IATA : Not regulated for traport I Accordace with TDG : Not regulated for traport. SECTION 15: Regulatory iformatio : Scrap metal alloy uually ha value. Cotact commercial reclaimer for recyclig. Otherwie, dipoe of wate material i accordace with all local, regioal, atioal ad iteratioal regulatio Safety, health ad evirometal regulatio/legilatio pecific for the ubtace or mixture US Federal Regulatio All igrediet are lited o the EPA TSCA Ivetory. Copper/Copper Alloy SARA Sectio 311/312 Hazard Clae Delayed (chroic) health hazard Lited o the Uited State TSCA (Toxic Subtace Cotrol Act) Ivetory Lited o Uited State SARA Sectio 313 SARA Sectio 313 Emiio Reportig 1% Silver ( ) Lited o the Uited State TSCA (Toxic Subtace Cotrol Act) Ivetory Lited o Uited State SARA Sectio 313 SARA Sectio 313 Emiio Reportig 1% Atimoy ( ) Lited o the Uited State TSCA (Toxic Subtace Cotrol Act) Ivetory Lited o Uited State CERCLA 500 lb fial RQ (o reportig of releae of thi hazardou ubtace i required if the diameter of the piece of the olid metal releaed i >100 μm ); 2270 kg fial RQ (o reportig of releae of thi hazardou ubtace i required if the diameter of the piece of the olid metal releaed i >100 μm ) US State Regulatio: 9 / 11

10 1 U.S. - Maachuett Right To Kow Lit U.S. New Jerey Right to Kow Hazardou Subtace Lit U.S. Peylvaia RTK (Right to Kow) Lit- Evirometal Hazard Lit U.S. Peylvaia RTK (Right to Kow) Lit Caadia Regulatio All igrediet are lited o the Caadia Dometic Subtace Lit Copper/Copper Alloy WHMIS Claificatio Ucotrolled product accordig to WHMIS claificatio criteria Lited o the Caadia DSL (Dometic Subtace Lit) Lited o the Caadia IDL (Igrediet Dicloure Lit) IDL Cocetratio 1% WHMIS Claificatio Ucotrolled product accordig to WHMIS claificatio criteria 15.2 Chemical afety aemet No chemical afety aemet ha bee carried out. SECTION 16: Other iformatio Other iformatio GHS Full Text Phrae: Thi Safety Data Sheet ha bee etablihed i accordace with the SDS requiremet of the OSHA Regulatio 29 CFR Acute Tox.1 (Ihalatio: dut, mit) Acute toxicity (ihalatio: dut, mit) Category 1 Acute Tox.2 (Dermal) Acute toxicity (dermal) Category 2 Acute Tox.3 (Oral) Acute toxicity (oral) Category 2 Aquatic Acute 1 Hazardou to the aquatic eviromet-acute Hazard Category 1 Aquatic Chroic 1 Hazardou to the aquatic eviromet-chroic Hazard Category 1 Aquatic Chroic 3 Hazardou to the aquatic eviromet-chroic Hazard Category 3 Carc.2 Carciogeicity Category 2 Eye Irrit. 2 Seriou eye damage/eye irritatio Category 2 Flam. Sol. 1 Flammable olid Category 1 Pyr. Sol. 1 Pyrophoric olid Category 1 Ski Corr. 1A Ski corroio/irritatio Category 1A Ski Se. 1 Ski eitizatio Category 1 STOT RE 1 Specific target orga toxicity (repeated expoure) Category 1 STOT Se 3 Specific target orga toxicity (igle expoure) Category 3 H228 H250 Flammable olid Catche fire potaeouly if expoed to air 10 / 11

11 H300 H310 H314 H317 H319 H330 H335 H351 H372 H400 H410 H412 P261 P270 P273 P280 P501 Fatal if wallowed Fatal i cotact with ki Caue evere ki bur ad eye damage May caue a allergic ki reactio Caue eriou eye irritatio Fatal if ihaled May caue repiratory irritatio Supected of cauig cacer Caue damage to orga through prologed or repeated expoure Very toxic to aquatic life Very toxic to aquatic life with log latig effect Harmful to aquatic life with log latig effect Avoid breathig dut/fume/ga/mit/vapor/pray Do ot eat, drik or moke whe uig thi product Avoid releae to the eviromet Wear protective glove/protective clothig/eye protectio/face protectio Dipoe of cotet/cotaier i accordace with local, regioal, atioal ad iteratioal regulatio. Key/Leged ACGIH = America Coferece of Govermetal Idutrial Hygieit; ADG = Autralia Code for the traport of Dagerou Good by Road ad Rail; ADR/RID = Europea Agreemet of Dagerou by Road/Rail; AS = Stadard Autralia; DFG = Deutche Forchuggemeichaft; DOT= Departmet of Traportatio; DSL = Dometic Subtace Lit; EEC = Europea Ecoomic Commuity; EINECS = Europea Ivetory of Exitig Commercial Chemical Subtace; ELINCS = Europea Lit of Notified Chemical Subtace; EU = Europea Uio; HMIS = Hazardou Material Idetificatio Sytem; IARC = Iteratioal Agecy for Reearch o Cacer; IATA = Iteratioal Air Traport Aociatio; IDLH= Immediately Dagerou to Life or Health; IMO = Iteratioal Maritime Orgaizatio; MAK = Maximum Cocetratio Value i the Workplace; NDSL = No-Dometic Subtace Lit; NFPA = Natioal Fire Protectio Aociatio; NIOSH = Natioal Ititute for Occupatioal Safety & Health ; NTP = Natioal Toxicology Program; OSHA=Occupatioal Safety ad Health Admiitratio; PEL= Permiible Expoure Limit; REL= Recommeded Expoure Limit; STEL = Short-term Expoure Limit; TDG = Traportatio of Dagerou Good; TLV = Threhold Limit Value; TSCA = Toxic Subtace Cotrol Act; TWA Time weighted Average. Thi iformatio i baed o our curret kowledge ad i iteded to decribe the product for the purpoe of health, afety ad evirometal requiremet oly. It hould ot therefore be cotrued a guarateeig ay pecific property of the product. STATEMENT OF LIABILITY-DISCLAIMER To the bet of the COINING, INC kowledge, the iformatio ad recommedatio cotaied i thi publicatio are reliable ad accurate a of the date prepared. However, accuracy, uitability, or completee are ot guarateed, ad o warraty, guaratee, or repreetatio, expreed or implied, i made by COINING, INC. a to the abolute correcte or ufficiecy of ay repreetatio cotaied i thi ad other publicatio; COINING, INC. aume o repoibility i coectio therewith; or ca it be aumed that all acceptable afety meaure are cotaied i thi ad other publicatio, or that other or additioal meaure may ot be required uder particular or exceptioal coditio or circumtace. Data may be chaged from time to time. 11 / 11