Ag-Cu Brazing Alloys. SECTION 1: Chemical product and company identification

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1 Ag-Cu Brazig Alloy ELECTRONIC COMPONENTS AND PACKAGING SECTION 1: Chemical product ad compay idetificatio 1.1 Product Idetifier Product form Product Name : Article : Silver Brazig alloy, Silver Copper Brazig alloy 1.2. Relevat idetified ue of the ubtace or mixture ad ue advied agait Relevat idetified ue Idutrial/Profeioal ue pec. : Idutrial For profeioal ue oly Ue of the ubtace/mixture : Brazig Fuctio or ue category : Brazig aget Ue advied agait No additioal iformatio available 1.3. Detail of the upplier of the afety data heet Coiig, Ic. 15 Mercede Drive Motvale, NJ Tel: +1(201) Emergecy Telephoe Number Emergecy Number SECTION 2: Hazard idetificatio : CHEMTREC: for US/ outide US For Chemical Emergecy, Spill, Leak, Fire, Expoure, or Accidet, call CHEMTREC-Day of Night Claificatio of the Subtace or Mixture Claificatio accordig to Directive 67/548/EEC, Regulatio (EC)No1272/2008-CLP Not claified Advere phyicochemical, huma health ad evirometal effect No additioal iformatio available Label Elemet Labelig accordig to Directive 67/548/EEC, Regulatio (EC)No1272/2008-CLP No labelig applicable No igal word applicable 2.3. Other hazard Precautioary Statemet P261 Avoid breathig dut/fume/ga/mit/vapor/pray P270 Do ot eat, drik or moke whe uig thi product P273 Avoid releae to the eviromet P280 Wear protective glove/protective clothig/eye protectio/face protectio P362 Take off cotamiated clothig ad wah before reue. P501 Dipoe of cotet/cotaier i accordace with local, regioal, atioal ad iteratioal regulatio.

2 SECTION 3: Compoitio/iformatio o igrediet 3.1. Subtace Not applicable 3.2. Mixture Name Product Idetifier % Claificatio accordig to Regulatio (EC) No. 1272/2008 [CLP] Copper (CAS No) (EC o) ; Silver (CAS No) (EC o) Full text of H- ad EUH-phrae: ee ectio Solid, ot claified 1-99 Solid, ot claified SECTION 4: Firt aid meaure 4.1. Decriptio of firt aid meaure Firt-aid meaure geeral Firt-aid meaure after ihalatio Firt-aid meaure after ki cotact Firt-aid meaure after eye cotact Firt-aid meaure after igetio : Never give aythig by mouth to a ucociou pero. If you feel uwell, eek medical advice (how there label where poible). : Whe ymptom occur; go ito ope air ad vetilate upected area. : Removal of olidified molte material from ki require medical aitace. Cool ki rapidly with cold water after cotact with molte product : Rie cautiouly with water for everal miute. Remove cotact lee, if preet ad eay to do. Cotiue riig. : Rie mouth. Do NOT iduce vomitig Mot importat ymptom ad effect, both acute ad delayed Symptom/ijurie Symptom/ijurie after ihalatio Symptom/ijurie after ki cotact : Uder ormal coditio of ue ot expected to preet a igificat hazard. Uder millig, or phyical alteratio metal dut may be produced that caue irritatio of the repiratory tract, ki, ad may be harmful. Molte material may releae toxic ad irritatig fume. : Not expected to be a primary route of expoure. The primary acute health hazard aociated with thi product would be the potetial for expoure to fume durig metal proceig operatio. Ihalatio of dut ad fume ca caue metal fume fever. Symptom ca iclude a metallic or weet tate i the mouth, weatig, hiverig, headache, throat irritatio, fever, chill, thirtie, mucle ache, auea, vomitig, weake, fatigue, ad horte of breath. : Ski cotact i ot coidered a potetial route of expoure. The primary acute health hazard aociated with thi product would be the potetial for expoure 2 / 10

3 Symptom/ijurie after eye cotact Symptom/ijurie after igetio Chroic ymptom to fume durig metal proceig operatio. Where poible allow molte material to olidify aturally. Removal of olidified molte material from ki require medical aitace. : Not expected to be a primary route of expoure. Dut geerated from material cuttig may caue a light irritatio. Sliver may be geerated, which could caue mechaical irritatio or ijure the eye. : Igetio i ot coidered a potetial route of expoure. Silver: Chroic ki cotact or igetio of ilver dut, alt or fume ca reult i a coditio kow a Argyria, a coditio with bluih pigmetatio of the ki ad eye. Copper: Overexpoure to fume may caue metal fume fever (chill, mucle ache, auea, fever, dry throat, cough, weake, laitude); metallic or weet tate; dicoloratio of ki ad hair. Tiue damage of mucou membrae may follow chroic dut expoure Idicatio of ay immediate medical attetio ad pecial treatmet eeded If medical advice i eeded, have product cotaier or label at had. SECTION 5: Fire fightig meaure 5.1. Extiguihig media Suitable extiguihig media Uuitable extiguihig media : Doe ot bur. Ue extiguihig media appropriate for urroudig fire : Noe kow Special hazard ariig from the ubtace or mixture Fire hazard : Dut, chip, or ribbo ca be igited more eaily, by a igitio ource, by improper machiig, or by potaeou combutio if fiely divided ad damp 5.3. Advice for firefighter Firefightig itructio Protectio durig firefightig : Exercie cautio whe fightig ay chemical fire. : Do ot eter fire area without proper protective equipmet, icludig repiratory protectio. SECTION 6: Accidetal releae meaure 6.1. Peroal precautio, protective equipmet ad emergecy procedure Geeral meaure : Hadle i accordace with good idutrial hygiee ad afety practice For o-emergecy peroel Protective equipmet : Ue appropriate peroal protectio equipmet (PPE) Emergecy procedure : Evacuate ueceary peroel For emergecy repoder Protective equipmet : Equip cleaup crew with proper protectio. Emergecy procedure : Vetilate area 3 / 10

4 6.2. Evirometal precautio Avoid releae to the eviromet 6.3. Method ad material for cotaimet ad clea up For cotaimet Method for cleaig up 6.4 Referece to other ectio See headig 8, expoure cotrol ad peroal protectio. SECTION 7: Hadlig ad torage 7.1. Precautio for afe hadlig Hygiee meaure 7.2. Coditio for afe torage, icludig ay icompatibilitie Storage coditio Icompatible product 7.3. Specific ed ue() : If metal i i molte form, allow coolig ad collectig a a olid. If the metal i i olid form collect for remeltig purpoe. : Clear up pill. Immediately ad dipoe of wate afely. : Hadle i accordace with good idutrial hygiee ad afety procedure. Wah had ad other expoed area with mild oap ad water before eatig, drikig, or mokig ad agai whe leavig work. : Store i a dry, cool ad well-vetilated place. : Strog acid. Strog bae. Strog oxidizer. Brazig. SECTION 8: Expoure cotrol/peroal protectio 8.1 Cotrol parameter Copper ( ) Autria MAK (mg/m³) 0.4 mg/m³ Belgium Limit value (mg/m³) 1 mg/m³ Bulgaria OEL TWA (mg/m³) 0.1 mg/m³ Frace VLE (mg/m³) 2 mg/m³ Frace VME (mg/m³) 1 mg/m³ Italy Portugal USA ACGHI ACGIH TWA (mg/m³) 0.2 mg/m³ Latvia OEL TWA (mg/m³) 0.5 mg/m³ Spai VLA-ED (mg/m³) 1 mg/m³ The Netherlad MAC TGG 8H (mg/m³) 0.1 mg/m³ Uited Kigdom WEL TWA (mg/m³) 1 mg/m³ Uited Kigdom WEL STEL (mg/m³) 2 mg/m³ Czech Republic Expozičí limity (PEL) (mg/m3) 0.1 mg/m³ Demark Græeværdie (lagvarig) (mg/m3) 0.1 mg/m³ Filad HTP-arvo (8h) (mg/m3) 0.1 mg/m³ Hugary AK-érték 0.1 mg/m³ Hugary CK-érték 0.4 mg/m³ Irelad OEL (8 hour ref) (mg/m3) 1 mg/m³ Irelad OEL (15 mi ref) (mg/m3 2 mg/m³ Lithuaia IPRV (mg/m3) 0.2 mg/m³ 4 / 10

5 Romaia OEL TWA (mg/m3) 0.50mg/m³ Romaia OEL STEL (mg/m3) 1.50 mg/m³ Slovakia NPHV (priemerá) (mg/m3) 0.1 mg/m³ Slovakia NPHV (Hraičá) (mg/m3) 0.2 mg/m³ Swede ivågrävärde (NVG) (mg/m3) 0.2 mg/m³ Portugal OEL TWA (mg/m3) 1mg/m³ Silver ( ) Autria MAK (mg/m³) 0.1 mg/m³ Belgium Limit value (mg/m³) 0.1 mg/m³ Bulgaria OEL TWA (mg/m³) 0.1 mg/m³ Cypru OEL TWA (mg/m³) 0.1 mg/m³ Frace VME (mg/m³) 0.1 mg/m³ (idicative limit) Germay TRGS 900 Occupatioal expoure 0.1 mg/m³ limit value (mg/m³) Italy Portugal USA ACGHI ACGIH TWA (mg/m³) 0.1 mg/m³ Italy OEL TWA (mg/m³) 0.1 mg/m³ Latvia OEL TWA (mg/m³) 0.5 mg/m³ Spai VLA-ED (mg/m³) 0.1 mg/m³ The Netherlad MAC TGG 8H (mg/m³) 0.1 mg/m³ Uited Kigdom WEL TWA (mg/m³) 0.1 mg/m³ Uited Kigdom WEL STEL (mg/m³) 0.3 mg/m³ (calculated) Czech Republic Expozičí limity (PEL) (mg/m3) 0.1 mg/m³ Demark Græeværdie (lagvarig) (mg/m3) 0.01 mg/m³ Filad HTP-arvo (8h) (mg/m3) 0.1 mg/m³ Hugary AK-érték 0.1 mg/m³ Hugary CK-érték 0.4 mg/m³ Irelad OEL (8 hour ref) (mg/m3) 0.1 mg/m³ Lithuaia IPRV (mg/m3) 0.1 mg/m³ Polad NDS (mg/m3) 0.05 mg/m³ Romaia OEL TWA (mg/m3) 0.1 mg/m³ Slovakia NPHV (priemerá) (mg/m3) 0.1 mg/m³ Swede ivågrävärde (NVG) (mg/m3) 0.1 mg/m³ Portugal OEL TWA (mg/m3) 0.1mg/m³ 8.2. Expoure cotrol Appropriate egieerig cotrol Peroal protective equipmet : : Eure adequate vetilatio, epecially i cofied area. : Protective goggle. Iulated glove 5 / 10

6 Had protectio : If material i hot, wear thermally reitat protective glove. Eye protectio : Durig metal proceig, chemical goggle or afety glae. Repiratory protectio : Durig metal proceig, wear approved mak. Other iformatio : Whe uig, do ot eat, drik or moke. SECTION 9: Phyical ad chemical propertie 9.1. Iformatio o bai phyical ad chemical propertie Phyical tate : Solid Appearace : Preform, quare, rig, dic, wire Color : Metallic, ilvery or coppery Odor : Odorle Odor threhold : Not applicable ph : Neutral Relative evaporatio rate (butylacetate=1) : Not applicable Meltig poit Freezig poit Boilig poit Flah poit Self igitio temperature Decompoitio temperature Flammability (olid, ga) Vapor preure Relative vapor preure at 20 C Relative deity Solubility : Ioluble Log Pow Log Kow Vicoity, kiematic Vicoity, dyamic Exploive propertie Oxidizig propertie Exploive limit 9.2 Other iformatio: No other iformatio available. 6 / 10

7 SECTION 10: Stability ad reactivity 10.1 Reactivity : Hazardou reactio will ot occur uder ormal coditio Chemical tability : Stable uder ormal coditio. Dut, chip or ribbo ca be igited more eaily, by a igitio ource, by improper machiig, or by potaeou combutio if fiely divided ad damp Poibility of hazardou reactio : Hazardou polymerizatio will ot occur Coditio to avoid : High humidity, extremely high temperature Icompatible material : Strog acid. Strog bae. Strog oxidizer Hazardou decompoitio product : Metal oxide. SECTION 11: Toxicological iformatio 11.1 Iformatio o toxicological effect Acute toxicity : Not claified Silver ( ) LD50 oral rat >2000 mg/kg Irritatio Corroivity Seitizatio Repeated doe toxicity Carciogeicity Mutageicity Toxicity for reproductio : Not claified : Not claified : Not claified : Not claified : Not claified : Not claified : Not claified SECTION 12: Ecological iformatio 12.1 Toxicity Copper ( ) LC50 fihe 1 EC50 Daphia 1 EC50 other aquatic orgaim 1 LC50 fih 2 EC50 other aquatic orgaim ( )mg/l (Expoure time: 96 h-specie: Pimephale promela) 0.03mg/l (Expoure time: 48h-Specie: Daphia maga [Static]) ( )mg/l (Expoure time:72 h-specie: Peudokircheriella ubcapitate [Static]) 0.3mg/l (Expoure time: 96h pecie: Pimephale promela [Static]) 0.031( ) mg/l (Expoure time: 96 h - Specie: Peudokircheriella ubcapitate [Static]) Silver ( ) LC50 fihe ( )mg/l (Expoure time: 96 h-specie: Pimephale 7 / 10

8 EC50 Daphia 1 LC50 fih 2 promela [Static]) mg/l (Expoure time: 48h-Specie: Daphia maga [Static]) mg/l (Expoure time: 96h pecie: Ocorhychu myki [flowthrough]) 12.2 Peritece ad degradability Solderig ad Brazig Alloy Peritece ad degradability Not etablihed Copper ( ) Peritece ad degradability Not readily biodegradable Bioaccumulative potetial Brazig Alloy Bioaccumulative potetial Not etablihed 12.4 Mobility i oil No additioal iformatio available Reult of PBT ad vpvb aemet No additioal iformatio available Other advere effect Other iformatio : Avoid releae to the eviromet. SECTION 13: Dipoal iformatio 13.1 Wate treatmet method Wate dipoal recommedatio : Dipoe of wate material i accordace with all local, regioal, atioal ad iteratioal regulatio. SECTION 14: Traport iformatio UN umber : Not regulated for traport UN proper hippig ame : Not applicable Traport hazard cla(e) : Not applicable Packig group : Not applicable Evirometal hazard Other iformatio : No upplemetary iformatio available Special precautio for uer : Not applicable Overlad traport : Not regulated for traport Air traport : Not regulated for traport Traport i bulk accordig to Aex II of MARPOL 73/78 ad the IBC Code 8 / 10

9 SECTION 15: Regulatory iformatio Safety, health ad evirometal regulatio/legilatio pecific for the ubtace or mixture EU-Regulatio Authorizatio ad/or retrictio o ue (Aex XVII): Cotai o REACH cadidate ubtace Natioal regulatio No additioal iformatio available Chemical afety aemet No chemical afety aemet ha bee carried out. SECTION 16: Other iformatio Other iformatio Full text of H- ad EUH-phrae: : Thi ha bee etablihed i accordace with the applicable Europea Uio legilatio. Claificatio i accordace with calculatio method of regulatio (EC)1272/2008 CLP/EC 1999/45 DPD. Acute Tox.1 (Ihalatio: dut, mit) Acute toxicity (ihalatio: dut, mit) Category 1 Acute Tox.2 (Dermal) Acute toxicity (dermal) Category 2 Acute Tox.3 (Oral) Acute toxicity (oral) Category 2 Aquatic Acute 1 Hazardou to the aquatic eviromet-acute Hazard Category 1 Aquatic Chroic 1 Hazardou to the aquatic eviromet-chroic Hazard Category 1 Aquatic Chroic 3 Hazardou to the aquatic eviromet-chroic Hazard Category 3 Carc.2 Carciogeicity Category 2 Eye Irrit. 2 Seriou eye damage/eye irritatio Category 2 Flam. Sol. 1 Flammable olid Category 1 Pyr. Sol. 1 Pyrophoric olid Category 1 Ski Corr. 1A Ski corroio/irritatio Category 1A Ski Se. 1 Ski eitizatio Category 1 STOT RE 1 Specific target orga toxicity (repeated expoure) Category 1 STOT Se 3 Specific target orga toxicity (igle expoure) Category 3 H228 H250 H300 H310 H314 H317 H319 H330 Flammable olid Catche fire potaeouly if expoed to air Fatal if wallowed Fatal i cotact with ki Caue evere ki bur ad eye damage May caue a allergic ki reactio Caue eriou eye irritatio Fatal if ihaled 9 / 10

10 H335 H351 H372 H400 H410 H412 May caue repiratory irritatio Supected of cauig cacer Caue damage to orga through prologed or repeated expoure Very toxic to aquatic life Very toxic to aquatic life with log latig effect Harmful to aquatic life with log latig effect SDS EU (REACH ANNEX II) Thi iformatio i baed o our curret kowledge ad i iteded to decribe the product for the purpoe of health, afety ad evirometal requiremet oly. It hould ot therefore be cotrued a guarateeig ay pecific property of the product. STATEMENT OF LIABILITY-DISCLAIMER To the bet of the COINING, INC kowledge, the iformatio ad recommedatio cotaied i thi publicatio are reliable ad accurate a of the date prepared. However, accuracy, uitability, or completee are ot guarateed, ad o warraty, guaratee, or repreetatio, expreed or implied, i made by COINING, INC. a to the abolute correcte or ufficiecy of ay repreetatio cotaied i thi ad other publicatio; COINING, INC. aume o repoibility i coectio therewith; or ca it be aumed that all acceptable afety meaure are cotaied i thi ad other publicatio, or that other or additioal meaure may ot be required uder particular or exceptioal coditio or circumtace. Data may be chaged from time to time. 10 / 10