BUFFALO. Reg. No.: L 6869 Act /Wet No. 36 of/van 1947

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1 Reg. No.: L 6869 Act /Wet No. 36 of/van 1947 An emulsifiable concentrate herbicide with added safener for the pre-emergence control of annual grasses and certain broadleaf weeds in maize, sugarcane and groundnuts. 'n Emulgeerbare konsentraat onkruiddoder plus beveiliger vir die vooropkomsbeheer van eenjarige grasse en sekere breëblaar- onkruide in mielies, suikerriet en grondbone. HRAC HERBICIDE GROUP CODE: K3 HRAC ONKRUIDDODERGROEP KODE: ACTIVE INGREDIENT/AKTIEWE BESTANDDEEL: Acetochlor (chloroacetanilide) / Asetochloor (chloorasetanilied) g/l Dichlormid (antidote) / Dichlormied (beveiliger). 111 g/l Registration holder / Registrasiehouer: Volcano Agroscience (Pty) Ltd trading as ARYSTA LifeScience South Africa (Pty) Ltd Co. Reg. No./Mpy. Reg. Nr.: 2009/019713/07 7 Sunbury Office Park, Off Douglas Saunders Drive, La Lucia Ridge, South Africa, 4019 Tel: Contents/Inhoud (l) Batch No. / Lot Nr.: Date of manufacture: / Datum van vervaardiging: U.N. No READ THE LABEL IN DETAIL BEFORE OPENING THE CONTAINER. / LEES DIE ETIKET VOLLEDIG VOORDAT DIE HOUER OOPGEMAAK WORD. For full particulars, see enclosed leaflet. / Vir volledige besonderhede, sien ingeslote pamflet. /25/05/

2 Reg. No.: L 6869 Act/Wet No. 36 of/van 1947 An emulsifiable concentrate herbicide with added safener for the pre-emergence control of annual grasses and certain broadleaf weeds in maize, sugarcane and groundnuts. 'n Emulgeerbare konsentraat onkruiddoder plus beveiliger vir die vooropkomsbeheer van eenjarige grasse en sekere breëblaaronkruide in mielies, suikerriet en grondbone. HRAC HERBICIDE GROUP CODE / HRAC ONKRUIDDODERGROEP KODE: K3 ACTIVE INGREDIENT / AKTIEWE BESTANDDEEL: Acetochlor (chloroacetanilide) / Asetochloor (chloorasetanilied) g/l Dichlormid (antidote) / Dichlormied (beveiliger). 111 g/l Registration holder / Registrasiehouer: Volcano Agroscience (Pty) Ltd trading as ARYSTA LifeScience South Africa (Pty) Ltd Co. Reg. No./Mpy. Reg. Nr.: 2009/019713/07 Units 54/55, 61 Marshall Drive, Mount Edgecombe, 4300 Tel: CAUTION / VERSIGTIG WARNINGS: Poisonous when swallowed. Irritating to eyes and skin. Very toxic to fish. Store in a cool place. Flammable - keep away from open flame Keep unused in this container tightly closed, locked up out of reach of children, uninformed persons, animals and away from food and feeds. Re-entry: Do not enter treated field until spray deposit has dried unless wearing protective clothing. Although this remedy has been extensively tested under a large variety of conditions, the registration holder does not warrant that it will be efficacious under all conditions because the action and effect thereof may be affected by factors such as abnormal soil, climatic and storage conditions; quality of dilution water, compatibility with other substances not indicated on the label and the occurrence of resistance of the weed against the remedy concerned, as well as by the method, time and accuracy of application. The registration holder furthermore does not accept responsibility for damage to crops, vegetation, the environment, or harm to man or animal or for lack of performance of the remedy concerned due to failure of the user to follow the label instructions or to the occurrence of conditions which could not have been foreseen in terms of the registration. Consult the supplier in the event of any uncertainty. PRECAUTIONS: - Do not eat, drink or smoke while handling this product. - Avoid contamination of food, feeds, drinking water and eating utensils For safety when mixing: - Wear eye protection (face shield). If you get in your eyes, flush it out at once. - Wear rubber gloves. - If you get it on your skin, wash it off at once. - If you spill it on your clothes, change and wash them. - Invert the empty container over the spray or mixing tank and allow to drain for at least 30 seconds after the flow has slowed down to a drip. Thereafter rinse the container three times with a volume of water equal to a minimum of 10 % of that of the container. Add the rinsings to the contents of the spray tank before destroying the container. For safety when spraying: - Avoid contact with the spray as much as you can. - Avoid spray drift onto other crops, grazing, rivers, dams and areas not under treatment. /25/05/

3 For safety after spraying: - Clean applicator thoroughly after use and dispose of wash water where it will not contaminate crops, grazing, rivers or dams. - Destroy empty container and do not use for any other purpose. - Change and wash your work clothes. - Wash yourself. USE RESTRICTIONS: 1. Do not use on inbred parent lines of maize hybrids or experimental or newly released cultivars without first consulting with your chemical supplier or with the seed company concerned. 2. Do not use on poorly drained soils or soils with a compaction layer as under these conditions waterlogging can occur and the herbicide may cause crop injury. 3. When tank mixing other herbicides with the restrictions and warnings on the labels of the herbicides concerned, must be adhered to. 4. Do not apply to sandy soils which are susceptible to wind erosion. 5. Flood irrigation can reduce weed control performance. 6. Crop restrictions : Maize and ERUPT should be applied as a split application only and are restricted to areas other than the lower potential soils of the Northwest Province, North and Western Free State. DIRECTIONS FOR USE: Use only as indicated. COMPATIBILITY: No known cases of incompatibility with other agricultural chemicals have yet been reported. If tank mixes are however desired, first mix small quantities of the chemical separately in water - then add these together whilst stirring and check for any signs of incompatibility e.g. flocculation, etc., before making mixtures in spray tank. is compatible with Ametryn 500 SC, Diuron 800 SC, Cheetah 600 SC, Alachlor 384 EC, Eland, Rhino, Erupt and EPTC 720. MIXING INSTRUCTIONS: Half fill the spray tank with clean water then add the required amount of and stir thoroughly. When using tank mixes, mix the required volume of chemicals to be tank mixed with a little water separately before adding each one individually to the spray tank. Then fill the spray tank to the correct volume with water. Do not mix the products as concentrates. Ensure thorough agitation before and during spraying. APPLICATION: - BUFFULO can be applied by means of a tractor drawn boom sprayer or equivalent equipment fitted with a choice and arrangement of fan-type spray nozzles ensuring even distribution and good recovery of spray mixture onto the soil. Apply in at least 200 water / ha. - must ideally be applied immediately following planting but not later than 5 days after planting. - Continual rain or sprinkler irrigation of at least 15 mm is needed after application to leach the chemical into the soil where weed seeds germinate. If however rainfall does not occur in time and weeds begin to emerge and develop, a shallow cultivation must be carried out to destroy these weeds and to mix the herbicide with the upper mm of soil. - To ensure good weed control the seedbed must be fine, firm and free of any existing weed growth or excessive crop residues prior to application. /25/05/

4 APPLICATION RATES: A. Maize single application Table 1: For control of annual grasses and certain broadleaf weeds. % CLAY /ha REMARKS NOTE: (Maize) 1,0 1,3 1,3 1,65 1,65 1,8 2,0 Apply pre-emergence within 3 days after planting of maize. Use the lower dosage rate if a short period of weed control is required between application and a cultivation and / or a follow-up application. The higher rates must be used in cases of high grass pressure and / or for the suppression of yellow nutsedge. Low temperatures and / or heavy prolonged rains soon after planting may cause herbicide damage to the crop such as reduced germination, stunting, etc. These symptoms can be aggravated when seed is planted too deep. Seed smaller than 4 flat has a higher risk for damage. Table 2: The control of annual grasses and certain broadleaf weeds and the variable yellow nutsedge (Cyperus esculentus) control. Apply as a pre-emergence tank mix with ERUPT within 3 days after planting. % CLAY /ha ERUPT /ha 0,4-0,8 0,6-1,0 0,8-1,1 0,75-1,2 3,2 3,7 4,6 5,7 The higher rate should be used for heavy Digitaria sanguinalis (Crab-fingergrass) control. Table 3: The control of annual grasses and improved broadleaf weeds control. can be tank mixed with either Rhino, ERUPT, Atrazine SC or Cheetah 600 SC and applied post plant, pre-emergence of crop and weeds. % CLAY + Rhino /ha OR + ERUPT /ha > 41 0,4 0,6 0,6 0,6 0,8 0,8 1,0 1,0 1,4 2,75 5,0 0,8 0,8 0,8 0,8 0,8 5,0 6,25 7,5 /25/05/

5 Plus % Clay Atrazine SC Cheetah 600 SC ,0 1,3 1,3 1,65 1,65 1,8 2,0 1,75 2,5 2,0 2,5 4,75 3,5 5,0 2,1 2,7 3,3 - When a short soil persistence is required in view of follow-up crops use only 1,5 Atrazine SC / ha on soils up to 35% clay and 2,0 l Atrazine SC / ha on soils over 35% clay. - Adhere to the use restrictions as indicated on the labels of the products containing triazine for follow-up crops. - Not recommended where marked with a. - + ERUPT should be applied as a split application only, and are restricted to areas other than the lower potential soils of the NorthWest Province and North and Western Free State. - Use the lower rates on lighter soils and lower weed population pressure. Table 4 : The control of annual grasses and broadleaf weeds in North West Province, North and Western Free State. and Atrazine SC tank mix can be applied post plant within 3 days of planting. Use the lower dosage on lighter soils where a dosage range is indicated. % Clay + Atrazine SC / h a 0, 5 1,0 2,0 2,5 2,25 2,75 2,25 3,0 Table 5: Extended control of Sweet Buffalo grass (Panicum schinzii) and Herringbone grass (Urochloa panicoides) in NorthWest Province, North and Western Free State. and Rhino can be applied in a tank mix post plant within 3 days of planting. % Clay + Rhino ,2 0,2 0,3 not recommended 2,75 not recommended /25/05/

6 B: MAIZE FOLLOW-UP APPLICATION TABLE 6: The control of annual grasses and extended broadleaf weed control. can be applied to the soil surface within 3 days of planting. Follow up with Atrazine SC or Cheetah 600 SC, before emergence of weeds after a cultivation, or early post-emergence as a tank mix of Atrazine SC plus 2,4-D amine before broadleaf weeds are at the 5 leaf stage. Crab-fingergrass (Digitaria sanguinalis) must be treated before the 3-leaf stage. Cheetah 600 SC should be applied before broadleaf weeds are at the 2 to 3-leaf stage and before grasses have emerged. % Clay Post plant Preemergence Follow up application Buffalo /ha Pre-emergence of weeds Plus Atrazine SC /ha Early Post emergence of weeds Cheetah /ha 600 SC 1,0 1,3 1,3 1,65 1,65 1,8 2,5 4,75 2,1 2,7 3,3 Atrazine SC 2,0 + 0,75 of 2,4D-Amine (480 g/ ) >40 2,0 5,0 Table 7: Extended control of annual grasses and broadleaf weeds. Apply as an overall or band treatment post plant within 3 days after planting followed by an early post emergence treatment of Rhino according to label recommendation to give extended grass and broadleaf weed control. Dosage rates should be adjusted accordingly for band treatment. The lower rates of should be used on lighter soils. % Clay Post plant pre-emergence Follow up application. Early post emergence Rhino ,5 0,75 0,75 1,0 1,3 1,0 1,5 3,0 3,5 3,5 6,0 /25/05/

7 Table 8: Extended control of annual grasses and broadleaf weeds under dry conditions and the suppression of yellow nutsedge (Cyperus esculentus). Apply as a pre plant, shallow incorporated treatment followed by an early post plant, pre- or post emerge treatment of Rhino or Atrazine SC or Cheetah 600 SC or a post emerge treatment of Atrazine SC plus 2,4D- amine tankmix. Incorporation of should be in a fine, even seedbed free of clods and trash, using a tine implement set as 5 10 cm to give an effective incorporation depth of 2,5 5 cm. Tines should be set to give an even incorporation with a rolling basket, drag harrow or spring loaded fine tooth harrow in tandem. The incorporation of is not recommended on soils of % clay nor those over 35% clay. Pre-plant Post plant follow up application incorporated % clay Pre-emergence or Early post emergence Atrazine SC Early post emergence Rhino SC /ha Cheetah 600 SC ,5 2,0 2,5 4,75 3,5 2,7 3,3 Atrazine SC 2,0 + 0,75 of 2,4 D Amine (480 g / ) Not Recommended C: Maize split application Table 9: Extended control of annual grasses and broadleaf weeds. Apply as a post plant pre-emergence treatment within 3 days of planting followed by an early post emergence treatment of: - tank mixed with either Atrazine SC alone or with Atrazine SC plus Cheetah 600 SC. % Clay Post plant Pre-emergence Early post emergence lt per ha l per ha l per ha Plus l per ha 0,75 0,75 2,0 Atrazine SC or with 2,1 Cheetah 600 SC 1,0 3,0 Atrazine SC or 2,0 Atrazine SC plus 2,7 Cheetah 600 SC 1,3 1,0 3,0 3,5 Atrazine SC or 2,0 Atrazine SC plus 3,3 Cheetah 600 SC ,65 1,0 3,0 5,0 Atrazine SC or 2,0 Atrazine SC plus Cheetah 600 SC /25/05/

8 Early post emergence treatments must be applied before the 5-leaf stage of broadleaf weeds and before tillering of annual grasses. Crab-fingergrass (Digitaria Sanguinalis) must be treated before the 3 leaf stage. D: MAIZE FOLLOW UP APPLICATION AFTER EPTAM SUPER TREATMENT For extended weed control in EPTC Plus or Eptam Super treated maize, apply within 3 weeks after planting alone (see maize single application Table 1) or in a tank mix with either Rhino or ERUPT or Atrazine SC or Cheetah 600 SC within 3 weeks after planting (see maize single application in tables 2 5). Before applying, all existing weeds should be destroyed by a shallow cultivation. Where the crop has emerged, all applications should be directed inter row and not over the crop row. E: MAIZE CONSERVATION TILLAGE Apply a tank mix of Duiker/SHAIK-DOWN 180 and prior to or within 1 day after planting the crop (see maize single application Table 1). This treatment is directed at destroying existing young weeds and having pre-emerged herbicidal action. In the event of a total weed cover at application time, little to no pre-emergence activity of could be expected. It is recommended in such situations that should be applied as a tankmixture ( see tables 2 5 ). The planting process may result in weed emergence on or near the row and use should be made of a later post emergence treatment. The above tank mix can be mixed with Atrazine SC (see maize single application in tables 2 5) but it is essential to establish herbicide compatibility before large scale application. (The quality of the water used for dilution most often determines the compatibility). Do not spray this mix if there are signs of flocculation or setting out in the spray tank. If compatibility problems do occur, spray the Atrazine SC separately. F: SUGAR CANE PRE-EMERGE APPLICATION can be used in combination with other herbicides for pre- and post emergence weed control in plant ratoon sugarcane. TABLE 10: Annual grasses, broadleaf weed and yellow nutsedge (cyperus esculentus) control. / ha + / ha 2,0 3,0 Ametryn 500 SC 2,0 3,0 Diuron SC 3,0 The higher dosage rates should be used on heavier soils (30% + clay) and also where a longer residual action is required and/or for improved control of Cyperus esculentus (yellow nutsedge). The lower dosage rates should be used on lighter soils. /25/05/

9 G: SUGAR CANE POST EMERGENCE APPLICATION TABLE 11: Annual grasses, broadleaf weed and Cyperus esculentus (yellow nutsedge) control. Remark 1. May only be applied up to and including the 2 3 leaf stage of the cane. 2. Controls Cyperus esculentus (Yellow nutsedge). 1. May only be applied up to and including the 2 3 leaf stage of the cane. 2. Controls Cyperus esculentus (Yellow nutsedge). 1. After the 5-leaf stage of the cane, the treatment should be directed between the rows. Application 2,0 3,0 + Ametryn 500 SC 3,0 5,0 + Paraquat 1,5 2,0 3,0 + Diuron 2,5 3,0 + Paraquat 1,5 2,0 3,0 + Ametryn 500 SC 6,0 + Non-ionic surfactant 0,2 % of spray volume (i.e. Volcano 90) The higher dosage rates should be used on heavier soils. The above post-emergence treatments should be made before tillering of annual grasses. will not cause foliar injury to sugarcane. However, certain herbicides in the above tank mix combinations may cause injury. Consult the relevant labels regarding use restrictions prior to use. H: GROUNDNUTS Table 12: The control of annual grasses and certain broadleaf weeds. % clay 40 1,0 1,3 1,3 1,65 1,65 1,8 2,0 /25/05/

10 WEED CONTROL: Refer to list of weeds controlled below. The control of yellow nut-sedge as well as some broadleaf weeds may be variable depending on favorable conditions. Refer to list of variable weed control for specific information. To increase the spectrum of broadleaf weeds controlled, it is recommended that either tank mixes or follow up application of standard registered broadleaf herbicides are used in combination with, in accordance with the manufacturer's label recommendations. Such applications must be made according to label recommendations of the products as recommended by manufacturer. LIST OF WEEDS CONTROLLED BY : Annual grasses: Brachiaria eruciformis sweet signal grass Chloris virgata feathertop Chloris Digitaria sanguinalis crab-fingergrass Eleusine indica goose grass Panicum maximum common buffalo grass Panicum schinzii sweet buffalo grass Setaria pallide-fusca Garden bristle grass Urochloa panicoides herringbone grass Annual broadleaf weeds: Amaranthus deflexus Amaranthus hybridus Amaranthus spinosus Chenopodium album Chenopodium carinatum Commelina benghalensis Datura spp Hibiscus trionum Physalis angulata Portulaca oleracea Schkuhria pinnata Tagetes minuta perennial pigweed Common pigweed thorny pigweed white goosefoot green goosefoot Benghal wandering Jew thorn apple (early germinating only) bladder weed wild gooseberry purslane Dwarf marigold khaki weed Since controls annual grasses, other annual grasses that are not listed may be controlled to a greater or lesser degree. The registration holder does not accept any liability in respect of the control of unlisted weeds. CONTROL OF THE FOLLOWING WEEDS IS VARIABLE: Cyperus esculentus yellow nutsedge Where the control of Cyperus esculentus is dependent on the following: Where a dosage choice is given, the higher rate should be used. Planting must be preceded by a deep ploughing. must be applied immediately after planting or within 2 days. ± 12mm rain/irrigation must fall within 7 10 days of spraying. NOTE: Cyperus esculentus control may only be achieved under the following conditions: Planting into a fine and firm seedbed must be directly preceded by a deep mouldboard ploughing. Spraying must take place within 2 days after planting and sufficient continual soaking rain (at least 15 mm on light soils and 25 mm on heavy soils) has to occur before the yellow nutsedge plants start to germinate and develop. /25/05/

11 WEEDS CONTROLLED BY AND DIFFERENT TANK MIXTURES AT THE HIGHER APPLICATION RATE. BROADLEAF WEEDS Acanthospermum australe Acanthospermum glabratum Acanthospermum hispidum Amaranthus hybridus Amaranthus spinosus Amaranthus thunbergii Bidens bipinnata Bidens pilosa Chenopodium album Chenopodium carinatum Cleome monophylla Cleome rubella Commelina benghalensis Cosmos bipinnatus Crotolaria sphaerocarpa Datura ferox Datura stramonium Galinsoga parviflora Gisekia pharnaceoides Hibiscus trionum Hibiscus cannabinus Nicandra physaloides Physalis angulata Portulaca oleracea Richardia brasiliensis Schkuhria pinnata Tagetes minuta Vigna vexillata eight-seeded prostrate starbur five-seeded prostrate starbur upright starbur Common pigweed thorny pigweed red pigweed spanish black jack blackjack White goosefoot green goosefoot spindlepod pretty lady Bengal wandering Jew cosmos Mealie Crotalaria Large thorn apple (early germination only) Thorn apple (early germination only) gallant soldier gisekia Bladder weed Kenaf apple-of-peru Wild gooseberry Purslane Tropical Richardia Dwarf marigold Khakiweed (early germination only) Wild-cowpea Weeds marked with will be controlled by a tank mixed of with the lower rate of Atrazine SC as indicated above. Drought or water logging may result in reduced weed control. /25/05/

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